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Basic description of pneumatic fracturing and atomized injections, and chemical formation services

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  1. 1. Practical Solutions For Complex Problems Presented to
  2. 2. ARS TECHNOLOGIES FAMILY OF COMPANIES Practical Solutions For Complex Problems Proven Experience Better Amendment Delivery Safe, Knowledgeable & Convenient Chemical Services
  3. 3. PRESENTER Robert Kelley, Ph.D. Vice President of Technology Development ARS Technologies, Inc 732-253-8131 bk@arstechnologies.com
  4. 4. PROVEN EXPERIENCE
  5. 5. PROVEN EXPERIENCE Technologies Developed by Prestigious University Research Program 10 Ph.D.s 5 US Patents
  6. 6. PROVEN EXPERIENCE Technologies Developed by Prestigious University Research Program 10 Ph.D.s 5 US Patents Certified by USEPA Site Program
  7. 7. PROVEN EXPERIENCE Technologies Developed by Prestigious University Research Program 10 Ph.D.s 5 US Patents Certified by USEPA Site Program 300 + Sites
  8. 8. PROVEN EXPERIENCE Technologies Developed by Prestigious University Research Program 10 Ph.D.s 5 US Patents Certified by USEPA Site Program 300 + Sites 19 Years Commercial Experience
  9. 9. Safety Record Full-Time Health and Safety Officer “Stop-Job” Policy Empowers Any Worker to Stop Operation on SIte If They Believe the Site Unsafe Zero Loss Time Cases Zero Property Loss Claims
  10. 10. NATIONWIDE PRESENCE New Berkeley Chicago Brunswick Wilmington Atlanta Houston Orlando
  11. 11. SERVICES
  12. 12. SERVICES
  13. 13. OUR TECHNOLOGIES Pneumatic Fracturing Gas is injected into the subsurface at pressures exceeding the natural in-situ pressures and at flow rates that exceed nature permeability
  14. 14. OUR TECHNOLOGIES Pneumatic Fracturing Gas is injected into the subsurface at pressures exceeding the natural in-situ pressures and at flow rates that exceed nature permeability
  15. 15. OUR TECHNOLOGIES Pneumatic Fracturing Soil Vapor Gas is injected into the Extraction subsurface at pressures exceeding the natural in-situ pressures and at Pump and Treat flow rates that exceed nature permeability Air Sparging
  16. 16. OUR TECHNOLOGIES Pneumatic Fracturing Soil Vapor Gas is injected into the Extraction subsurface at pressures exceeding the natural in-situ pressures and at Pump and Treat flow rates that exceed nature permeability Air Sparging Atomized Liquid Injection Atomized Liquid injection is a very Injections effective method for injecting liquids/ slurries/powder uniformly within all types of geology
  17. 17. OUR TECHNOLOGIES Pneumatic Fracturing Soil Vapor Gas is injected into the Extraction subsurface at pressures exceeding the natural in-situ pressures and at Pump and Treat flow rates that exceed nature permeability Air Sparging Atomized Liquid Injection Atomized Liquid Ferox™ZVI injection is a very Injections effective method for injecting liquids/ slurries/powder Chemox uniformly within all types of geology Bioaugmentation
  18. 18. COMPLEX GEOLOGY PRESENTS MAJOR CHALLENGES Fractured Rock Fine Sands Heterogeneous Clay
  19. 19. FRACTURING TECHNOLOGY Permeability Enhancement
  20. 20. FRACTURING TECHNOLOGY Permeability Enhancement
  21. 21. GAS FRACTURING CHARACTERIZED
  22. 22. GAS FRACTURING CHARACTERIZED Relatively Low Pressure, High Volume Process
  23. 23. GAS FRACTURING CHARACTERIZED Relatively Low Pressure, High Volume Process 15 second Injection Per interval
  24. 24. GAS FRACTURING CHARACTERIZED Relatively Low Pressure, High Volume Process 15 second Injection Per interval 1 meter packer interval
  25. 25. GAS FRACTURING CHARACTERIZED Relatively Low Pressure, High Volume Process 15 second Injection Per interval 1 meter packer interval Fracture ROI 15-70 ft
  26. 26. PNEUMATIC FRACTURING
  27. 27. OTHER FRACTURING METHODS
  28. 28. OTHER FRACTURING METHODS Hydraulic Fracturing Oil Field Use As Well As Development Tool Well Drillers As Water Well Development Tool
  29. 29. OTHER FRACTURING METHODS Hydraulic Fracturing Oil Field Use As Well As Development Tool Well Drillers As Water Well Development Tool Blast Fracturing Use Of Down-hole Explosives Blast Fracturing Can Break Competent Rock
  30. 30. PNEUMATIC FRACTURE APPLICATION METHODS “How Is Fracturing Applied”
  31. 31. PNEUMATIC FRACTURE APPLICATION METHODS “How Is Fracturing Applied”
  32. 32. PNEUMATIC FRACTURE APPLICATION METHODS “How Is Fracturing Applied” Open Borehole (4in – 6in diameter)
  33. 33. PNEUMATIC FRACTURE APPLICATION METHODS “How Is Fracturing Applied” Open Borehole (4in – 6in diameter) Cased Borehole
  34. 34. PNEUMATIC FRACTURE APPLICATION METHODS “How Is Fracturing Applied” Open Borehole (4in – 6in diameter) Cased Borehole Direct-Push-Drilling Methods GeoProbe 5,6,7, Series — Shallow Depth GeoProbe 8040 — Intermediate Depth/Difficult Conditions Sonic — Deep Depth/Difficult Conditions
  35. 35. PRESSURE — TIME HISTORY CURVES Tells Us What’s Happening Below the Ground
  36. 36. PRESSURE — TIME HISTORY CURVES Tells Us What’s Happening Below the Ground 150 Pressure (psig) 100 50 0 Culver City, California 0 10 20 30 (Clay) Elapsed Time (s) Depth: 16 to 19 ft. bgs.
  37. 37. PRESSURE — TIME HISTORY CURVES Tells Us What’s Happening Below the Ground 150 Pressure (psig) 100 50 0 Culver City, California 0 10 20 30 (Clay) Elapsed Time (s) Depth: 16 to 19 ft. bgs. 20 Pressure (psig) 15 10 Auburn, Indiana 0 (sandy Silt) 0 5 10 15 Depth: 6-8 ft bgs. Elapsed Time (s)
  38. 38. HOW WE MONITOR PNEUMATIC FRACTURING
  39. 39. HOW WE MONITOR PNEUMATIC FRACTURING Down-Hole Pressure Pressure-Time History Curves
  40. 40. HOW WE MONITOR PNEUMATIC FRACTURING Down-Hole Pressure Pressure-Time History Curves Pressure Influence Pressure Gauges on Monitoring Wells
  41. 41. HOW WE MONITOR PNEUMATIC FRACTURING Down-Hole Pressure Pressure-Time History Curves Pressure Influence Pressure Gauges on Monitoring Wells Ground Surface Heave Observe Small Ground Movement
  42. 42. WHAT WE CAN EXPECT FROM PNEUMATIC FRACTURING
  43. 43. WHAT WE CAN EXPECT FROM PNEUMATIC FRACTURING Increased Radius of Influence (3-6 Times)
  44. 44. WHAT WE CAN EXPECT FROM PNEUMATIC FRACTURING Increased Radius of Influence (3-6 Times) Increased Bulk Conductivity (1-4 OM) •Reduction in Geologic Heterogeneity (less diffusion limited zones) •Uniform emplacement of Injected Substances •Increased in Mass Removal •Increased Dewaterability or airflow
  45. 45. 18
  46. 46. 19
  47. 47. ATOMIZED LIQUID INJECTION
  48. 48. ATOMIZED LIQUID INJECTION
  49. 49. ATOMIZED LIQUID INJECTION Ferox™ZVI Chemox Atomized Liquid injection is a very effective method for injecting liquids/ slurries/powder uniformly within all Bioaugmentation types of geology
  50. 50. CONFIRMATORY SOIL SAMPLING (85-88 ft. bgs. 17 ft)
  51. 51. CONFIRMATORY SOIL SAMPLING (85-88 ft. bgs. 17 ft) 150 Pressure (psig) 100 50 0 0 10 20 30 Elapsed Time (s)
  52. 52. CONFIRMATORY SOIL SAMPLING (85-88 ft. bgs. 17 ft)
  53. 53. CONFIRMATORY SOIL SAMPLING (85-88 ft. bgs. 17 ft) 150 Pressure (psig) 100 50 0 0 10 20 30 Elapsed Time (s)
  54. 54. MATERIAL EMPLACEMENT THROUGH FLUIDIZATION (77-80 ft bg, 17 ft from injection pt)
  55. 55. MATERIAL EMPLACEMENT THROUGH FLUIDIZATION (77-80 ft bg, 17 ft from injection pt) 20 Pressure (psig) 15 10 0 0 5 10 15 Elapsed Time (s)
  56. 56. PRE AND POST INJECTION ATOMIZED EMPLACEMENT
  57. 57. PRE AND POST INJECTION ATOMIZED EMPLACEMENT
  58. 58. PRE AND POST INJECTION ATOMIZED EMPLACEMENT
  59. 59. ENGINEERED APPROACH Allows for Safe Injections Under Buildings/Structures
  60. 60. ENGINEERED APPROACH Allows for Safe Injections Under Buildings/Structures
  61. 61. ARS ADVANCED DRILLING SERVICE
  62. 62. ARS ADVANCED DRILLING SERVICE Geoprobe 8040 Offers Advanced Drilling Methods
  63. 63. ARS ADVANCED DRILLING SERVICE Geoprobe 8040 Offers Advanced Drilling Methods Cost-effective Alternative To Sonic Drilling
  64. 64. ARS ADVANCED DRILLING SERVICE Geoprobe 8040 Offers Advanced Drilling Methods Cost-effective Alternative To Sonic Drilling Site Investigation & Remediation
  65. 65. ARS ADVANCED DRILLING SERVICE Geoprobe 8040 Offers Advanced Drilling Methods Cost-effective Alternative To Sonic Drilling Site Investigation & Remediation Nationwide Service
  66. 66. INJECTION, SAMPLING, WELL INSTALLATION
  67. 67. INJECTION, SAMPLING, WELL INSTALLATION
  68. 68. INJECTION, SAMPLING, WELL INSTALLATION Direct Push
  69. 69. INJECTION, SAMPLING, WELL INSTALLATION Direct Push Auger
  70. 70. INJECTION, SAMPLING, WELL INSTALLATION Direct Push Auger Air Rotary
  71. 71. INJECTION, SAMPLING, WELL INSTALLATION Direct Push Auger Air Rotary Injection Pump 35 gpm 270 psi
  72. 72. INJECTION, SAMPLING, WELL INSTALLATION
  73. 73. INJECTION, SAMPLING, WELL INSTALLATION
  74. 74. INJECTION, SAMPLING, WELL INSTALLATION Turns Large Augers Up to 8.5”
  75. 75. INJECTION, SAMPLING, WELL INSTALLATION Turns Large Augers Up to 8.5” Pushes Large Size Rods Up to 4.5”
  76. 76. INJECTION, SAMPLING, WELL INSTALLATION Turns Large Augers Up to 8.5” Pushes Large Size Rods Up to 4.5” Pushes Rods Deeper Up to 200’
  77. 77. INJECTION, SAMPLING, WELL INSTALLATION
  78. 78. INJECTION, SAMPLING, WELL INSTALLATION
  79. 79. INJECTION, SAMPLING, WELL INSTALLATION Install 2” Monitoring Wells with no cuttings
  80. 80. INJECTION, SAMPLING, WELL INSTALLATION Install 2” Monitoring Wells with no cuttings Quick and Easy to Convert from DPT to Rotary
  81. 81. INJECTION, SAMPLING, WELL INSTALLATION Install 2” Monitoring Wells with no cuttings Quick and Easy to Convert from DPT to Rotary Track Mounted Access
  82. 82. INJECTION, SAMPLING, WELL INSTALLATION Install 2” Monitoring Wells with no cuttings Quick and Easy to Convert from DPT to Rotary Track Mounted Access ARS Tech’s Highly Experienced Crew Provide Safe Efficient Operations
  83. 83. ARS SERVICES
  84. 84. ARS SERVICES Pneumatic Fracturing
  85. 85. ARS SERVICES Pneumatic Fracturing Liquid Atomized Injection
  86. 86. ARS SERVICES Pneumatic Fracturing Liquid Atomized Injection Ferox (Zero Valent Iron)
  87. 87. ARS SERVICES Pneumatic Fracturing Liquid Atomized Injection Ferox (Zero Valent Iron) Chemical Oxidation
  88. 88. ARS SERVICES Pneumatic Fracturing Liquid Atomized Injection Ferox (Zero Valent Iron) Chemical Oxidation Advanced Drilling Services
  89. 89. CHEMICALS & FORMULATION SERVICES
  90. 90. HEPURE SERVICES
  91. 91. HEPURE SERVICES
  92. 92. HEPURE SERVICES  Site Ready Materials and Chemicals – ZVI powders - H-200 Plus, HC-15 – Permanganate - NaMn04 , KMnO4 – Peroxygens – Bioaugmentation & BioStimulation • EVO, Microbes
  93. 93. Cost to Time Relationship Peroxygens Expensive, But Fast Expensive and Slow COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  94. 94. Cost to Time Relationship Peroxygens Expensive, But Fast Expensive and Slow COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  95. 95. Cost to Time Relationship Peroxygens Expensive, But Fast Expensive and Slow COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  96. 96. Cost to Time Relationship Peroxygens Expensive, But Fast Expensive and Slow COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  97. 97. Cost to Time Relationship Peroxygens Expensive, But Fast Expensive and Slow COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  98. 98. Cost to Time Relationship Expensive, But Fast Expensive and Slow Permanganate Peroxygens COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  99. 99. Cost to Time Relationship Expensive, But Fast Expensive and Slow Permanganate Peroxygens COST $ Inexpensive, and Fast Inexpensive, But Slow TIME
  100. 100. Cost to Time Relationship Expensive, But Fast Expensive and Slow Permanganate Peroxygens COST $ Catalyzed Iron Ferox(tm) Inexpensive, and Fast Inexpensive, But Slow TIME
  101. 101. Cost to Time Relationship Expensive, But Fast Expensive and Slow Permanganate Peroxygens COST $ Catalyzed Iron Ferox(tm) Inexpensive, and Fast Inexpensive, But Slow TIME
  102. 102. Cost to Time Relationship Expensive, But Fast Expensive and Slow Permanganate Peroxygens COST $ Catalyzed Iron Ferox(tm) Bioremediation Inexpensive, and Fast Inexpensive, But Slow TIME
  103. 103. Cost to Time Relationship Expensive, But Fast Expensive and Slow ? nZVI ? Permanganate Peroxygens COST $ Catalyzed Iron Ferox(tm) Bioremediation Inexpensive, and Fast Inexpensive, But Slow TIME
  104. 104. ZVI IRON POWDERS
  105. 105. ZVI IRON POWDERS
  106. 106. ZVI IRON POWDERS  Micron Scale Zero Valent Iron Powder
  107. 107. ZVI IRON POWDERS  Micron Scale Zero Valent Iron Powder  Emulsified Zero Valent Iron Powder
  108. 108. ZVI IRON POWDERS  Micron Scale Zero Valent Iron Powder  Emulsified Zero Valent Iron Powder  Nanoscale Zero Valent Iron Powder
  109. 109. 38
  110. 110. Iron Quality Matters Competitor’s Product Hepure’s Product 39
  111. 111. ZVI IRON POWDERS Brand Characteristics • Pure Feedstock • Reactive Alternative to Scrap HCA Filings • 3 Grades (Course, Fine and Ultrafine) • Atomized Powder HC-15 • Catalytic Iron--Very High Reactivity • 2 Grades (Fine and Ultrafine) • Successor to Most Widely Used ZVI H200 Plus •Application Specific Blend 40
  112. 112. 41
  113. 113. “EVERYTHING BUT BOOTS ON THE GROUND”
  114. 114. “EVERYTHING BUT BOOTS ON THE GROUND”
  115. 115. “EVERYTHING BUT BOOTS ON THE GROUND”  Just In Time Tanker Delivery
  116. 116. “EVERYTHING BUT BOOTS ON THE GROUND”  Just In Time Tanker Delivery  Totes, Drums, Pails
  117. 117. “EVERYTHING BUT BOOTS ON THE GROUND”  Just In Time Tanker Delivery  Totes, Drums, Pails  Dosatrons, Flowmeters
  118. 118. “EVERYTHING BUT BOOTS ON THE GROUND”  Just In Time Tanker Delivery  Totes, Drums, Pails  Dosatrons, Flowmeters  Manifold Setups
  119. 119. “EVERYTHING BUT BOOTS ON THE GROUND”  Just In Time Tanker Delivery  Totes, Drums, Pails  Dosatrons, Flowmeters  Manifold Setups  Pumps, Hosing
  120. 120. “EVERYTHING BUT BOOTS ON THE GROUND”  Just In Time Tanker Delivery  Totes, Drums, Pails  Dosatrons, Flowmeters  Manifold Setups  Pumps, Hosing  Tankage
  121. 121. HOW ARE YOU DOING YOUR ON-SITE CHEMOX MIXING?
  122. 122. HOW ARE YOU DOING YOUR ON-SITE CHEMOX MIXING? OR
  123. 123. HOW ARE YOU DOING YOUR ON-SITE CHEMOX MIXING? OR
  124. 124. 44
  125. 125. CUSTOM BLENDING & SITE DELIVERY
  126. 126. CUSTOM BLENDING & SITE DELIVERY
  127. 127. CUSTOM BLENDING & SITE DELIVERY  Cost-effective Nationwide Service
  128. 128. CUSTOM BLENDING & SITE DELIVERY  Cost-effective Nationwide Service  NaMnO , KMnO , Emulsified Vegetable 4 4 Oil, Sodium Lactate
  129. 129. CUSTOM BLENDING & SITE DELIVERY  Cost-effective Nationwide Service  NaMnO , KMnO , Emulsified Vegetable 4 4 Oil, Sodium Lactate  “Just In Time” Site-ready Delivery
  130. 130. CUSTOM BLENDING & SITE DELIVERY  Cost-effective Nationwide Service  NaMnO , KMnO , Emulsified Vegetable 4 4 Oil, Sodium Lactate  “Just In Time” Site-ready Delivery  Eliminates Mixing-related Health And Safety Issues
  131. 131. CUSTOM BLENDING & SITE DELIVERY  Cost-effective Nationwide Service  NaMnO , KMnO , Emulsified Vegetable 4 4 Oil, Sodium Lactate  “Just In Time” Site-ready Delivery  Eliminates Mixing-related Health And Safety Issues  Resolves QA/QC Concerns
  132. 132. SODIUM PERMANGANATE (NaMnO4)
  133. 133. SODIUM PERMANGANATE (NaMnO4)  High Purity Standard For Insitu Injection
  134. 134. SODIUM PERMANGANATE (NaMnO4)  High Purity Standard For Insitu Injection  Available In “Site Ready” 2,000 – 5,000 Gal. Bulk Tanker Trucks
  135. 135. SODIUM PERMANGANATE (NaMnO4)  High Purity Standard For Insitu Injection  Available In “Site Ready” 2,000 – 5,000 Gal. Bulk Tanker Trucks  Available In (10-40%) Concentration
  136. 136. POTASSIUM PERMANGANATE (KMnO4)
  137. 137. POTASSIUM PERMANGANATE (KMnO4)  Tech Grade Chemicals
  138. 138. POTASSIUM PERMANGANATE (KMnO4)  Tech Grade Chemicals  Available As Dry Or “Site Ready” 1,000 – 5,000 Gal. Blended Bulk Tanker Trucks
  139. 139. POTASSIUM PERMANGANATE (KMnO4)  Tech Grade Chemicals  Available As Dry Or “Site Ready” 1,000 – 5,000 Gal. Blended Bulk Tanker Trucks  Blended Available In (1-7%) Concentration
  140. 140. POTASSIUM PERMANGANATE (KMnO4)  Tech Grade Chemicals  Available As Dry Or “Site Ready” 1,000 – 5,000 Gal. Blended Bulk Tanker Trucks  Blended Available In (1-7%) Concentration  Established Product QA/QC Program
  141. 141. POTASSIUM PERMANGANATE (KMnO4)  Tech Grade Chemicals  Available As Dry Or “Site Ready” 1,000 – 5,000 Gal. Blended Bulk Tanker Trucks  Blended Available In (1-7%) Concentration  Established Product QA/QC Program  Avoid Homeland Security’s 300+ List
  142. 142. BIOREMEDIATION PRODUCTS
  143. 143. BIOREMEDIATION PRODUCTS  H60 - Emusified Vegetable Oil Substrate (SRS)
  144. 144. BIOREMEDIATION PRODUCTS  H60 - Emusified Vegetable Oil Substrate (SRS)  H45 - Emulsified Vegetable Oil Substrate (QRS)
  145. 145. BIOREMEDIATION PRODUCTS  H60 - Emusified Vegetable Oil Substrate (SRS)  H45 - Emulsified Vegetable Oil Substrate (QRS)  HSL - Sodium Lactate Substrate
  146. 146. BIOREMEDIATION PRODUCTS  H60 - Emusified Vegetable Oil Substrate (SRS)  H45 - Emulsified Vegetable Oil Substrate (QRS)  HSL - Sodium Lactate Substrate  EZVI – Emulsified Zero Valent Iron
  147. 147. BIOREMEDIATION PRODUCTS  H60 - Emusified Vegetable Oil Substrate (SRS)  H45 - Emulsified Vegetable Oil Substrate (QRS)  HSL - Sodium Lactate Substrate  EZVI – Emulsified Zero Valent Iron  Microbial Culture
  148. 148. ARS TECHNOLOGIES FAMILY OF COMPANIES Practical Solutions For Complex Problems Proven Experience Better Amendment Delivery Safe, Knowledgeable & Convenient Chemical Services
  149. 149. FOR MORE INFORMATION Websites www.arstechnologies.com www.hepure.com www.pressure_grouting.com ftp site www.onlinefilefolder.com User: arsfiles Password: arspublic

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