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Interview   Project
Hydrocarbon gases         Non-Hydrocarbon gases

      Methane C1              Hydrogen sulfide H2S

       Ethane C2               Water vapor H2O(V)

      Propane C3               Carbon dioxide CO2

      Butane C4                   Nitrogen N2

      Pentane C5                  Mercury Hg
     Hexane+ C6+



What is the meaning of + ?
Hydrocarbon gases              Non-hydrocarbon gases

Methane C1        77-99 %    Hydrogen sulfide H2S    0-4 PPM
 Ethane C2       0.05-20 %   Carbon dioxide CO2     0.1-3.44 %
Propane C3        0.01-5 %       Nitrogen N2        0.11-.83 %
 Butane C4        0-1.74 %   Water vapor H2O(V)
Pentane C5        0-0.24 %
Hexane+ C6+       0-0.08 %
Composition   Reservoir
Hydrocarbon gases                      Non-hydrocarbon gases

     Lean                   Rich        Sour     Sweet     Wet          Dry
   Ethane C2
                         Ethane C2      H2S       H2S     H2O(V)       H2O(V)
  Propane C3
                                        CO2       CO2
   Butane C4             Propane C3
  Pentane C5
 Hexane+ C6+             Butane C4

                         Pentane C5

                        Hexane+ C6+

Note: The C1 is the main component in
both
Natural gas reservoir   Oil and associated gas reservoir
TCF: Trillion Cubic feet
Domestic 2% CNG 1%
        Petrochemical 12%


                                              Electricity 56 %
Industry 29 %
UP-Stream          Down-Stream




                Gas treatment       Consumers


   Gas
Production                           Factory
Reason                       Process                 Contaminant

                                Gas production from wells
                                                                     Oil

 Acid                                                             Condensate
 gas
              H2o       Acid         Liquids removal
                                                                  Free Water

                                                                     H2S
         Corrosion             Acid gas removal (Sweeting)
                                                                     CO2


H.C.+ H2O          Hydrate     Water removal (Dehydration)         H2O(V)
  (Physical combination)


                                      Compression           ?
        Pipe blockage


                                      National Grid
National Grid
                       Field Treatment                            Consumers
                     Up- Stream Process                    Down- Stream Process
       Well
                                                       C1
                                                      C2
                                                      C3
                                                      C4
                                                      C5+
                                         NGL

                                               Sales gas     National Grid
                Field Treatment      Factory                              Consumers


Rich Gas Well
LNG      C1
                                              C2
                      Sales gas
                                    Factory

                                  National Grid
                Field Treatment                    Consumers

Lean Gas Well
Products

 NGL


                           $
           National Grid

Rich gas
Gas Processing   Gas Distribution      Gas Transmission



  Factories                   National Grid
El-Salam El-Tarek El-Obayid El-Qasr


            WDGC
   Western Desert Gas Complex

             Sales Gas                National Grid

            C2/C3 (gas)                  Sidpec

             C3 (Liq.)                 Naftomar

            LPG (Liq.)                 Petro Gas

            Cond. (Liq.)                Ameryia
                                        crude oil
Bed 2       Bed 3 Abu-sanan




Ameryia LPG Recovery Plant

         Sales Gas             National Grid


     C2/C3 (gas)                  WDGC


         LPG (Liq.)             Petro Gas

     Cond. (Liq.)                Ameryia
                                 crude oil
Components
             Co2   H2S   N2   C1   C2     C3   IC4   NC4   IC5   Nc5   C6   C7+

Acid gas
LNG
LPG
Commercial
propane
Condensate
NGL
LNG           Export




                    Lean gas
                                                         Domestic
             Gas treatment                 Sales gas      Industry
                                                       CNG stations
                    Rich gas


   Gas
Production                                  C2/C3      Petrochemicals
                               NGL            C3          Export
                                         LPG(C3/C4)      Domestic
                                         Condensate     Oil refinery
                                            C5+            (API)

    Up-Stream Process          Down-Stream Process       Products
National
Dehydration       Chilling     Grid




Storage       Fractionation
National
Dehydration      Chilling      Grid




 Storage      Fractionation
H2O




CH4
H2O



    Hydrate

T             P
Psi
Adsorption               Absorption

Molecules
                             Molecules



                              Liquid
Solid Surface
                              Solvent
Wet gas              Hot Regen gas
                       Wet Regen gas




                         Molecular sieve




                        Hot Regen gas
                        Cold Regen gas
Dry gas




          Adsorption    Heating    Cooling
PFD: Process Flow Diagram
0   4   8   12   16   20   24
National
Dehydration      Chilling      Grid




 Storage      Fractionation
Pressure reduction                    Refrigeration




Turbo-Expander       Joule-Thomson valve            Refrigerant

High P   Low P
High T   Low T                             High T                 Low T

                   High P         Low P
                   High T         Low T

                                                    Refrigerant
Pressure reduction



   Turbo-Expander                           Joule-Thomson valve


  • For Gas only                           • For Liquid and Gas
  • Produce work                           • Doesn't produce work
  • More efficient

    ΔP           ΔT                           ΔP           ΔT




             W
Expander         Compressor
Shell side Flow in


Tube side Flow out




                     Shell side Flow out

Tube side Flow in
NGL

                           Pressure
                          reduction
                         National Grid
       Field Treatment                   Consumers

                         Pipe storage
Well
Refrigeration
Compressor

                                                      Air cooler


Vapor Refrigerant


                           Process Gas               Condenser
Latent heat of
 vaporization
                     Evaporator -Chiller
Liquid Refrigerant




                                     Joule-Thomson valve
Gas Refrigerant




Hot Process Gas




Cold Process Gas   Liquid Refrigerant
Compressor

      -42 °C                                        Air cooler
       1 bar                           80 °C
                                       20 bar
  Vapor Propane


                         Process Gas               Condenser
Latent heat of
 vaporization                                                50 °C
                                                             20 bar
                   Evaporator -Chiller
  Liquid Propane

      -42 °C
       1 bar
                                   Joule-Thomson valve
120° C                     GAS - (STEAM)
100° C




                            LIQUID - (WATER)


0° C
                               SOLID - (ICE)


         335 KJ   419 KJ                   2676 KJ   D

                  1 kg water at 1 bar pressure
National
Dehydration       Chilling     Grid




 Storage      Fractionation
•Distillation :The process of separating materials by successively heating to vaporize
a portion and then cooling to liquefy a part of the vapor. Materials to be separated
must differ in boiling point and/or relative volatility.
C2/C3




NGL
National
Dehydration       Chilling     Grid




Storage       Fractionation
Evaporation                  Boiling




Ordinary evaporation is a surface            The boiling point is defined
phenomenon - some molecules have             as the temperature at which
enough kinetic energy to escape. If the      the saturated vapor pressure
container is closed, an equilibrium is       of a liquid is equal to the
reached where an equal number of             surrounding atmospheric
molecules return to the surface. The         pressure
pressure of this equilibrium is called the
saturation vapor pressure.
vapor pressure (true vapor pressure): The pressure exerted by the equilibrium
vapor of a liquid when confined in a closed tank.




                            Water boils at 100 °C

                                       Because

                 vapor pressure of water = 1 atm @ 100 °C
1 atm




Storage pressure   Vapor pressure
Storage pressure   Vapor pressure




 Propane




   LPG




Condensate
Pressurized
                  Vapor pressure of C3&C4
                    @ ambient T 1 atm
   Propane

     LPG



Non- Pressuried    Vapor pressure of C5
                   @ ambient T 1 atm
  Condensate
Pressurized              Refrigerated

T) Ambient   T) Critical   T) Ambient     T) Critical




             96 °C                      -82 °C




         Propane                        Methane
V.P.=10 bar @ 50 °C




                         Rault law
Vapor pressure of mixture (C3/C4) = (XC3*V.P. C3) + (XC4*V.P. C4)
Exhaust                High pressure gas
                             500 °C



                                             Centrifugal
      Axial compressor           Turbine
                                             compressor
Air


                 Combustion chamber


                                           Low pressure gas
                         Fuel

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Gas Composition and Processing

  • 1.
  • 2. Interview Project
  • 3. Hydrocarbon gases Non-Hydrocarbon gases Methane C1 Hydrogen sulfide H2S Ethane C2 Water vapor H2O(V) Propane C3 Carbon dioxide CO2 Butane C4 Nitrogen N2 Pentane C5 Mercury Hg Hexane+ C6+ What is the meaning of + ?
  • 4. Hydrocarbon gases Non-hydrocarbon gases Methane C1 77-99 % Hydrogen sulfide H2S 0-4 PPM Ethane C2 0.05-20 % Carbon dioxide CO2 0.1-3.44 % Propane C3 0.01-5 % Nitrogen N2 0.11-.83 % Butane C4 0-1.74 % Water vapor H2O(V) Pentane C5 0-0.24 % Hexane+ C6+ 0-0.08 %
  • 5. Composition Reservoir
  • 6. Hydrocarbon gases Non-hydrocarbon gases Lean Rich Sour Sweet Wet Dry Ethane C2 Ethane C2 H2S H2S H2O(V) H2O(V) Propane C3 CO2 CO2 Butane C4 Propane C3 Pentane C5 Hexane+ C6+ Butane C4 Pentane C5 Hexane+ C6+ Note: The C1 is the main component in both
  • 7. Natural gas reservoir Oil and associated gas reservoir
  • 8.
  • 10. Domestic 2% CNG 1% Petrochemical 12% Electricity 56 % Industry 29 %
  • 11. UP-Stream Down-Stream Gas treatment Consumers Gas Production Factory
  • 12. Reason Process Contaminant Gas production from wells Oil Acid Condensate gas H2o Acid Liquids removal Free Water H2S Corrosion Acid gas removal (Sweeting) CO2 H.C.+ H2O Hydrate Water removal (Dehydration) H2O(V) (Physical combination) Compression ? Pipe blockage National Grid
  • 13.
  • 14. National Grid Field Treatment Consumers Up- Stream Process Down- Stream Process Well C1 C2 C3 C4 C5+ NGL Sales gas National Grid Field Treatment Factory Consumers Rich Gas Well
  • 15. LNG C1 C2 Sales gas Factory National Grid Field Treatment Consumers Lean Gas Well
  • 16. Products NGL $ National Grid Rich gas
  • 17. Gas Processing Gas Distribution Gas Transmission Factories National Grid
  • 18. El-Salam El-Tarek El-Obayid El-Qasr WDGC Western Desert Gas Complex Sales Gas National Grid C2/C3 (gas) Sidpec C3 (Liq.) Naftomar LPG (Liq.) Petro Gas Cond. (Liq.) Ameryia crude oil
  • 19. Bed 2 Bed 3 Abu-sanan Ameryia LPG Recovery Plant Sales Gas National Grid C2/C3 (gas) WDGC LPG (Liq.) Petro Gas Cond. (Liq.) Ameryia crude oil
  • 20. Components Co2 H2S N2 C1 C2 C3 IC4 NC4 IC5 Nc5 C6 C7+ Acid gas LNG LPG Commercial propane Condensate NGL
  • 21. LNG Export Lean gas Domestic Gas treatment Sales gas Industry CNG stations Rich gas Gas Production C2/C3 Petrochemicals NGL C3 Export LPG(C3/C4) Domestic Condensate Oil refinery C5+ (API) Up-Stream Process Down-Stream Process Products
  • 22. National Dehydration Chilling Grid Storage Fractionation
  • 23. National Dehydration Chilling Grid Storage Fractionation
  • 25. H2O Hydrate T P
  • 26. Psi
  • 27. Adsorption Absorption Molecules Molecules Liquid Solid Surface Solvent
  • 28. Wet gas Hot Regen gas Wet Regen gas Molecular sieve Hot Regen gas Cold Regen gas Dry gas Adsorption Heating Cooling
  • 29. PFD: Process Flow Diagram
  • 30. 0 4 8 12 16 20 24
  • 31.
  • 32.
  • 33. National Dehydration Chilling Grid Storage Fractionation
  • 34. Pressure reduction Refrigeration Turbo-Expander Joule-Thomson valve Refrigerant High P Low P High T Low T High T Low T High P Low P High T Low T Refrigerant
  • 35. Pressure reduction Turbo-Expander Joule-Thomson valve • For Gas only • For Liquid and Gas • Produce work • Doesn't produce work • More efficient ΔP ΔT ΔP ΔT W Expander Compressor
  • 36.
  • 37.
  • 38.
  • 39. Shell side Flow in Tube side Flow out Shell side Flow out Tube side Flow in
  • 40.
  • 41. NGL Pressure reduction National Grid Field Treatment Consumers Pipe storage Well
  • 43.
  • 44. Compressor Air cooler Vapor Refrigerant Process Gas Condenser Latent heat of vaporization Evaporator -Chiller Liquid Refrigerant Joule-Thomson valve
  • 45. Gas Refrigerant Hot Process Gas Cold Process Gas Liquid Refrigerant
  • 46.
  • 47. Compressor -42 °C Air cooler 1 bar 80 °C 20 bar Vapor Propane Process Gas Condenser Latent heat of vaporization 50 °C 20 bar Evaporator -Chiller Liquid Propane -42 °C 1 bar Joule-Thomson valve
  • 48. 120° C GAS - (STEAM) 100° C LIQUID - (WATER) 0° C SOLID - (ICE) 335 KJ 419 KJ 2676 KJ D 1 kg water at 1 bar pressure
  • 49.
  • 50. National Dehydration Chilling Grid Storage Fractionation
  • 51. •Distillation :The process of separating materials by successively heating to vaporize a portion and then cooling to liquefy a part of the vapor. Materials to be separated must differ in boiling point and/or relative volatility.
  • 52.
  • 54. National Dehydration Chilling Grid Storage Fractionation
  • 55. Evaporation Boiling Ordinary evaporation is a surface The boiling point is defined phenomenon - some molecules have as the temperature at which enough kinetic energy to escape. If the the saturated vapor pressure container is closed, an equilibrium is of a liquid is equal to the reached where an equal number of surrounding atmospheric molecules return to the surface. The pressure pressure of this equilibrium is called the saturation vapor pressure.
  • 56. vapor pressure (true vapor pressure): The pressure exerted by the equilibrium vapor of a liquid when confined in a closed tank. Water boils at 100 °C Because vapor pressure of water = 1 atm @ 100 °C
  • 57.
  • 58. 1 atm Storage pressure Vapor pressure
  • 59.
  • 60. Storage pressure Vapor pressure Propane LPG Condensate
  • 61. Pressurized Vapor pressure of C3&C4 @ ambient T 1 atm Propane LPG Non- Pressuried Vapor pressure of C5 @ ambient T 1 atm Condensate
  • 62. Pressurized Refrigerated T) Ambient T) Critical T) Ambient T) Critical 96 °C -82 °C Propane Methane
  • 63. V.P.=10 bar @ 50 °C Rault law Vapor pressure of mixture (C3/C4) = (XC3*V.P. C3) + (XC4*V.P. C4)
  • 64.
  • 65.
  • 66.
  • 67.
  • 68. Exhaust High pressure gas 500 °C Centrifugal Axial compressor Turbine compressor Air Combustion chamber Low pressure gas Fuel