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Integrity  Service  Excellence
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SOARD
Research Portfolio
AFOSR Spring Review
March 2013
James Fillerup, PE, Director
Southern Office of Aerospace
Research and Development
Air Force Office of Scientific Research
2
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SOARD - Smallest of Int’l Offices
Two Project Officers cover
a broad range of scientific disciplines
(rule of thumb: if a topic of the AFOSR BAA - check it out)
City locations of research partners
• Primary focus - Fillerup
– Space Sciences
– Material Sciences
– Structural Mech / Aerodyn
• Primary focus - Pokines
– Nanomaterials
– Bionano
– Aero morphing systems
SOARD relies on AFOSR POs expertise.
FY12: 42 projects / 33 Institutions
SOARD (2009)
Santiago, Chile
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3
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Briefing Contents
• Space Science Portfolio
– Solar, Ionosphere, Magnetosphere (Kent Miller (AFOSR), RV)
• Molecular Physics
– Isotope Decay Project (Tom Hussey, John Luginsland (AFOSR), Maj Robert Lee,
(USAFA))
• Material Science
– Ferroelectric Nanoparticles (Charles Lee (AFOSR), Dean Evans (RX))
– Extremophiles: Synthesis of Se nanoparticles (Hugh DeLong (AFOSR))
• Structural Mechanics
– Filament Wound Structures (Matt Triplett, (Army ARDEC), Dave Stargel
(AFOSR)
• Aerodynamics
– Stability of Coaxial Jets (Ivett Leyva (RQ))
4
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Space is Big in So. Am.
Astronomical Observatories - Chile
Las Campanas Observatory
(Carnegie)
Cerro Tololo Observatory
(NSF)
Gemini Observatory
(Int’l partners - twin telescope in Hawaii)
Alma Radio Observatory
(Several Int’l partners)
Chilean researchers get 10% of time - no charge
Created strong Univ. Astrophysics Departments
5
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AF interest in Space Science
• Forecasting the geospace environment of Earth, for
Space Situational Awareness
– Solar Physics
– Magnetospheric Physics
– Ionospheric and Thermospheric
Physics
• Necessary for:
– Satellite drag predictions
– Radiation belt perturbations
– Communications/navigation/surveillance
So. Am. partnerships provide access to southern hemisphere skies
6
Solar Physics Research
Leoncito Astronomical Complex – Argentina
Solar Observatory
CASLEO Observatory Complex
Solar Observatory Facility
Collaborators:
- AFOSR / RV, US
- University Mackenzie, Brazil
(Lead PI: Pierre Kaufmann)
- UNICAMP, Brazil
- USP, Brazil
- CASLEO, Argentina
Supporting agencies
- FAPESP, CNPq, Brazil
- CONICET, Argentina
- AFOSR, US
Facility owned by Brazil - Operated by CASLEO
The Search For New Approach To Detect
Solar CME Precursors At Sub-THz And
Mid-IR Frequencies
Distribution A: Approved for public release; distribution is unlimited
7
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Solar Physics
Submm-w 2 sec pulsations maximize with CME launched nearly 10 min before large flare onset!
Kaufmann et al., Solar Phys. 2012
BBSO
RHESSI
and
SST
Distribution A: Approved for public release; distribution is unlimited
Solar Circular Mm-w Polarization Patrollers
(Operations at CASLEO started November 2011)
90 GHz
16.5 cm diam
lens
45 GHz
44 cm diam
Offset
parabola
Covers the spectral frequency gab from 20 to 200 GHz
Valio et al., Solar Phys. 2013
Distribution A: Approved for public release; distribution is unlimited
Distribution A: Approved for public release; distribution is unlimited
13 March 2012 solar burst – also observed at 200 GHz, 30 THz, Hα at El Leoncito;
by AFRL RST microwaves and by SDO – currently under joint investigation
45 GHz, R and L
90GHz, R and L
R - L
In preparation, 2013
10
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Ionosphere Research with Brazil
The Problem:
Ionospheric bubbles are rarefied plasma
regions. Ionospheric irregularities
inside the bubbles have scale size
varying from cm to km.
The amplitude fading (scintillations) if
deep enough and long enough, can
potentially cause tracking loss.
receiver
GPS satellites
11
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LISN / NSF
Santa Maria-RS,
Porto Velho-RO
Rio Branco-AC
Parintins-AM
Tefé-AM
Boa Vista-RR
Dourados-MS
Santarém-PA
Alta Floresta-MT
Ilhéus-BA
Cuiabá-MT
São Luís
Also LISN station at Alcon, Peru
GPS scintillation stations in Brazil
Additiona Stations
(2010):
Belo Horizonte MG
Brasília
Natal RN
Pato Branco PR
Imperatriz-MA
Petrolina-PE
São José dos Campos SP
São Gabriel da Cachoeira AM
CURRENT STATIONS
TEC and scintillation stations (LISN)
Additional TEC and Scintillations stations
installed 2010
MAGNETIC
EQUATOR
Data Collection Stations - Brazil
Project: “Ionospheric Irregularities
Predictions and Plumes
Characterization for Satellite
Data Validation”
PI: Eurico de Paula, National Institution
for Space Research (INPE)
12
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São Luis Station, Brazil
Example: São Luis VHF incoherent scatter radar plumes analysis
GPS antennas at São Luis during the AFRL/INPE campaign
(installation on February 2008)
Cooperation in Atmospheric, Ionospheric and Magnetospheric Research MOU.
• MOU signed in June 2001. SAF/IA is in process of negotiating a new MOU.
13
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Magnetosphere Research
Magnetometer
Monitoring Stations
SAMBA Stations
(in Chile)
McMAC
IGPP-LANL
CARISMA
Solar wind interaction w/
magnetosphere
Objective: Study of geomagnetic phenomena
(i.e., magnetic storms) and processes that affect
particle fluxes in the radiation belts
Collaborators:
- US:, NASA, RV, Boston College
- Chile: U of Santiago, (Lead PI: Stepanova),
U of Chile, U of Concepcion
Radiation Belts
14
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USAFA
SSA Tracking Telescope in Chile
Mamalluca Observatory
Future site of USAFA tracking telescope
Proposed FTN Station and 50 cm telescope
Collaborators
• USAF Academy
• AFOSR / RV
• Universidad of La Serena
• Mamalluca Observatory
USAFA Falcon Telescope Network
(FTN) For SSA
• Space Situational Awareness (SSA) - To detect,
track, identify, image, predict future positions of
space objects
• A network of remote telescopes with one located in
Chile providing access to southern hemisphere
15
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FTN: Global Coverage
Created by C1C Lance Wilhelm and C1C Brandon Mueller
Global Coverage, (LEO, 1000 km)
Global Coverage (GEO)
• U.S
• Colorado Mesa University (Grand
Junction)
• Fort Lewis College (Durango)
• Northeastern Junior College
(Sterling)
• Otero Junior College (La Junta)
• Penn State University (State
College)
• Chile
• Universidad de La Serena (La
Serena) & Observatorio Mamalluca
(Vicuña)
• Australia
• University of Queensland (Brisbane)
• Curtin University (Perth)
• University of New South Wales &
EOS (Canberra)
• Potential: South Africa, Kauai
Community College, International Space
University
Partners
16
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Molecular Physics
Periodic Nuclear Decay Rates
The Mystery of Periodic Nuclear Decay Rates
 Familiar exponential decay law:
 Periodic Variations Reported in 25 Long-
term Nuclear Decay Experiments
• Select β & E.C. Decay Affected
• Wide variety of detectors types
• Few experiments run for many years;
independent confirmation difficult
Raises the possibility that either the detectors or
the decays in question are being affected in some
fashion by an external influence such as seasonal
variations or solar radiation.
Regardless of causality, understanding nature of
periodicities offers crucial insight into long-term
detector operations supporting scientific, national
defense, and industrial applications.
17
Distribution A: Approved for public release; distribution is unlimited
CCHEN Decay Experiment:
Present Status
Detector Network of 4 Sites
• Chilean Commission of Nuclear Energy
(CCHEN)
• USAFA
• Purdue University
• Brigham Young University
• Mimic IMS Measurements but
at Higher Data Rates & longer
Integration Times
• Variety of Detectors, Sources
– Empty Detectors as Control
– Monitor Environ. Variables
– Custom, Full Lead Shielding
• CCHEN detectors set up &
calibrated in Sept 2012
– Data looks good, but too soon to
evaluate significance
– Expect 2 yr runtime, first results in
9 months
View of Test Chambers (top), Gieger Mueller and NaI
Detectors with 54Mn, 32Si, 36Cl, 90Sr, and empty NaI detector
in separate chamber.
18
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Material Science
and the Mexican Initiative
National Labs work with universities, but, only
receive graduate students.
Major funding support by CONACYT
CONACYT Research Centers
19
Distribution A: Approved for public release; distribution is unlimited
AFOSR – CONACYT
Joint Projects
Final Program Review tentatively scheduled Aug - Sept 2013 in Mexico
20
Distribution A: Approved for public release; distribution is unlimited
Success story: Development of
Ferroelectric Nanoparticles
Critical temperatures of BaTiO3
ceramics as a function of grain size.
Barium titanate, BaTiO3, is a white
powder and transparent as larger
crystals. It is a ferroelectric ceramic
material, with a photorefractive effect
and piezoelectric properties.
• General belief by researchers -
Typical BaTiO3 loses its
ferroelectricity at sizes smaller
than 30-50 nm
• Size restrictions limited number
of potential applications
Collaborators: AFRL/RXPJ, AFOSR
CIQA, Mexico
21
Distribution A: Approved for public release; distribution is unlimited
Mechanically Induced
Surface Stress
Particle sizes limited to:
• ~1 µm with simple
solvents
• 9 nm with surfactant
zirconia ball mill
gif file from wikipedia
Bottom up – synthesizes particles from atoms and molecules
Top down –particles are reduced to nanometer size by grinding
• AFRL/RXPJ developed the world’s smallest
ferroelectric nanoparticle, as small as 9 nm.
• Surface stress believed key to this achievement
• Through collaboration with CIQA, a strain map
was made on RXPJ’s nanoparticles, proving
the hypothesis that surface stress was present.
HRTEM image Strain Map
Distribution A: Approved for public release; distribution is unlimited
Examples of Systems
with Disparate Nanoparticle Roles
• Photorefractive beam coupling: electric torque
• Liquid crystal display: DC bias
• Metatronics (Metananocircuits): current/voltage source
• Massive Dipole Field Effects
Results with 9 nm-harvested stressed
ferroelectric nanoparticles
• Photorefractive beam coupling: electric torque
• Liquid crystal display: DC bias
• Metatronics (Metananocircuits)
• Massive Dipole Field Effects
23
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Extremophile Research
• Collaborators: AFOSR & BioScience Foundation, Chile.
– Studies started with isolation of novel heat resistant micro-
organism from laboratory drying ovens: E1 and E2. (2007)
– One unexpected result: Biosynthesis of Selenium (Se)
nanoparticles by E1
E2
Se NANOPARTICLES
BIOSYNTHESIS
Identification of microorganisms
24
Distribution A: Approved for public release; distribution is unlimited
Project Accomplishment
GDH
POR
Characterization of enzymes
GDH and POR
• Isolation of novel heat resistant microorganism: E1 and E2.
• Desiccation resistance for the microorganisms
• Isolation and characterization of enzymes: GDH and PDH or POR.
• Lipids Profiles and analysis. Studies of DNA repair mechanisms.
• Contribution of the antioxidant enzymes to the resistance to extreme and
fluctuating UV radiation.
• Cloning and expression into Escherichia coli of genes
E1 Genome
analysis
Catalase
(CAT)
Superoxide
dismutase
(SOD)
Specific
Primers
design
Expression of genes
in E.coli
Extremophile - Accomplishments
Bioscience Foundation, Chile
25
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 To study the role of enzymes in the biosynthesis of Se nanoparticles.
 To study the effect of temperature, pH and salt concentrations in Se
nanoparticle size and shape.
 To demonstrate that this is an enzyme-mediated process.
Research Goals to be acomplished
Nanocrystals biosynthesis
1.Local supersaturation
2.Nucleation
3.Growth
Se Nanoparticles biosynthesis
Influence of enzymes on selenium
nanoparticles synthesis
Complex phenomenon,
not well studied
Se Nanoparticles
Extremophile – Future Goals
Bioscience Foundation, Chile
26
Distribution A: Approved for public release; distribution is unlimited
Structural Mechanics
Filament Wound Structures
• Project: Damage and Progressive Failure
of Filament Wound Structures
– Collaborators, Army ARDEC, AFOSR, and
ta, Univ of Sao Paulo
• Objective: Investigate new mathematical
formulation for damage models used in
aviation filament wound structures
• High precision, low computational
cost
• Necessary for: structural integrity, health
monitoring, and service life assessment
27
Distribution A: Approved for public release; distribution is unlimited
Structural Mechanics
Filament Wound Structures
Motivation Challenges
Composites Aluminium Titatium Steel Others
Glass fiber
Aluminium Carbon sandwich composites
Carbon composite laminates
Aluminium / steel / titanium
[e.g., Boeing - 787]
Materials used by weight
Ply (orthotropic)
Structure
Matrix
Fiber
Laminate (anisotropic)
Micromechanics
Macromechanics
Structural analysis
3
21
z
yx
Intra-ply Failure
Inter-ply Failure
How to calculate stress and strain distribution
with high accuracy and low computational cost?
How to predict damage/failure modes and loads
with high precision and low computational cost?
Heterogeneity
Anisotropy
High Specific Properties
28
Distribution A: Approved for public release; distribution is unlimited
Damage Model Implementation
Filament Wound Structures
ABAQUS
and
UMAT/VUMAT
1-Constitutive Law
2-Failure Criteria
1
2
1
3
3-Degradation Law
29
Distribution A: Approved for public release; distribution is unlimited
Damage Model Validation
Filament Wound Structures
•Tensile
•Compression
•Shear
•Bending
•ModeI
•ModeII
•Mix Mode
•Hopkinson’sbar
Abaqusimplicit subroutines
for plane and curved geometry
UEL
UMAT
Abaqusexplicit subroutines for
planeand curved geometry
VUEL
VUMAT
•4 pointBending
•Indentationon
planeand curved
specimens
•Impact on plane
andcurved
specimens
Model
parameters
Model
evaluation
Experimentaltests Computationalmodel
Abaqus
30
Distribution A: Approved for public release; distribution is unlimited
Example of Validation Test Results
Filament Wound Structures
Compression Analyses
Maximum Failure Stress
~ 450 MPa
Matrix Failure
Non-linear behavior
Micro-buckling and
kinking of fibers
Local phenomena
Laminate: [15]10
Uniaxial
Compression
Tests
31
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Aerodynamics
Stability of Coaxial Free Jet Flow
Objective: Perform a
stability analysis for coaxial
jets to better understand the
natural hydrodynamic
instabilities of this canonical
geometry for liquid rocket
engines
• Baseflow will be
established
• The outer jet and the inner
jet wall thickness will be
incorporated into analysis
Benefits:
• Better understanding of
the natural instability
modes of this class of
injectors and how the
wall thickness affects the
hydrodynamics
.
.
.
.
Inner Jet
Core
Initial
Merging Zone
Outer Jet
Core
Intermediate
Merging Zone
Fully Merged
Zone
Outer mixing region
Inner mixing region
Recirculation
Zone
Uo, ρo
Ui, ρi
Recess
Lip
thickness
w
d4 d3 d2
d1
u’, p’
BASELINE WITH ACOUSTICS BASELINE WITH ACOUSTICS
Examples of coaxial base and acoustic driven flows
Collaborators: Fluminense Federal University, Brazil
AFRL/RQRE Edwards, AFOSR
32
Distribution A: Approved for public release; distribution is unlimited
Concluding Remarks
State of Latin American Research
• Latin American research is growing fast and becoming more
visible on the global scale.
– Between 2000 and 2010*
• Growth of more than 9% per year in scholarly output
• 70% increase in its share of world papers and citations
• SOARD Project Officers will continue to cover a broad range of
topics in BAA seeking the best scientists of Latin America.
– Space portfolio will remain a key area to take advantage of unique
recourses space research worldwide)
– Group formed in AFOSR to coordinate space research worldwide.
* Research Trends Issue 31 November 2012

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Fillerup - SOARD Research Portfolio - Spring Review 2013

  • 1. 1 Integrity  Service  Excellence Distribution A: Approved for public release; distribution is unlimited SOARD Research Portfolio AFOSR Spring Review March 2013 James Fillerup, PE, Director Southern Office of Aerospace Research and Development Air Force Office of Scientific Research
  • 2. 2 Distribution A: Approved for public release; distribution is unlimited SOARD - Smallest of Int’l Offices Two Project Officers cover a broad range of scientific disciplines (rule of thumb: if a topic of the AFOSR BAA - check it out) City locations of research partners • Primary focus - Fillerup – Space Sciences – Material Sciences – Structural Mech / Aerodyn • Primary focus - Pokines – Nanomaterials – Bionano – Aero morphing systems SOARD relies on AFOSR POs expertise. FY12: 42 projects / 33 Institutions SOARD (2009) Santiago, Chile Distribution A: Approved for public release; distribution is unlimited
  • 3. 3 Distribution A: Approved for public release; distribution is unlimited Briefing Contents • Space Science Portfolio – Solar, Ionosphere, Magnetosphere (Kent Miller (AFOSR), RV) • Molecular Physics – Isotope Decay Project (Tom Hussey, John Luginsland (AFOSR), Maj Robert Lee, (USAFA)) • Material Science – Ferroelectric Nanoparticles (Charles Lee (AFOSR), Dean Evans (RX)) – Extremophiles: Synthesis of Se nanoparticles (Hugh DeLong (AFOSR)) • Structural Mechanics – Filament Wound Structures (Matt Triplett, (Army ARDEC), Dave Stargel (AFOSR) • Aerodynamics – Stability of Coaxial Jets (Ivett Leyva (RQ))
  • 4. 4 Distribution A: Approved for public release; distribution is unlimited Space is Big in So. Am. Astronomical Observatories - Chile Las Campanas Observatory (Carnegie) Cerro Tololo Observatory (NSF) Gemini Observatory (Int’l partners - twin telescope in Hawaii) Alma Radio Observatory (Several Int’l partners) Chilean researchers get 10% of time - no charge Created strong Univ. Astrophysics Departments
  • 5. 5 Distribution A: Approved for public release; distribution is unlimited AF interest in Space Science • Forecasting the geospace environment of Earth, for Space Situational Awareness – Solar Physics – Magnetospheric Physics – Ionospheric and Thermospheric Physics • Necessary for: – Satellite drag predictions – Radiation belt perturbations – Communications/navigation/surveillance So. Am. partnerships provide access to southern hemisphere skies
  • 6. 6 Solar Physics Research Leoncito Astronomical Complex – Argentina Solar Observatory CASLEO Observatory Complex Solar Observatory Facility Collaborators: - AFOSR / RV, US - University Mackenzie, Brazil (Lead PI: Pierre Kaufmann) - UNICAMP, Brazil - USP, Brazil - CASLEO, Argentina Supporting agencies - FAPESP, CNPq, Brazil - CONICET, Argentina - AFOSR, US Facility owned by Brazil - Operated by CASLEO The Search For New Approach To Detect Solar CME Precursors At Sub-THz And Mid-IR Frequencies Distribution A: Approved for public release; distribution is unlimited
  • 7. 7 Distribution A: Approved for public release; distribution is unlimited Solar Physics Submm-w 2 sec pulsations maximize with CME launched nearly 10 min before large flare onset! Kaufmann et al., Solar Phys. 2012 BBSO RHESSI and SST
  • 8. Distribution A: Approved for public release; distribution is unlimited Solar Circular Mm-w Polarization Patrollers (Operations at CASLEO started November 2011) 90 GHz 16.5 cm diam lens 45 GHz 44 cm diam Offset parabola Covers the spectral frequency gab from 20 to 200 GHz Valio et al., Solar Phys. 2013 Distribution A: Approved for public release; distribution is unlimited
  • 9. Distribution A: Approved for public release; distribution is unlimited 13 March 2012 solar burst – also observed at 200 GHz, 30 THz, Hα at El Leoncito; by AFRL RST microwaves and by SDO – currently under joint investigation 45 GHz, R and L 90GHz, R and L R - L In preparation, 2013
  • 10. 10 Distribution A: Approved for public release; distribution is unlimited Ionosphere Research with Brazil The Problem: Ionospheric bubbles are rarefied plasma regions. Ionospheric irregularities inside the bubbles have scale size varying from cm to km. The amplitude fading (scintillations) if deep enough and long enough, can potentially cause tracking loss. receiver GPS satellites
  • 11. 11 Distribution A: Approved for public release; distribution is unlimited LISN / NSF Santa Maria-RS, Porto Velho-RO Rio Branco-AC Parintins-AM Tefé-AM Boa Vista-RR Dourados-MS Santarém-PA Alta Floresta-MT Ilhéus-BA Cuiabá-MT São Luís Also LISN station at Alcon, Peru GPS scintillation stations in Brazil Additiona Stations (2010): Belo Horizonte MG Brasília Natal RN Pato Branco PR Imperatriz-MA Petrolina-PE São José dos Campos SP São Gabriel da Cachoeira AM CURRENT STATIONS TEC and scintillation stations (LISN) Additional TEC and Scintillations stations installed 2010 MAGNETIC EQUATOR Data Collection Stations - Brazil Project: “Ionospheric Irregularities Predictions and Plumes Characterization for Satellite Data Validation” PI: Eurico de Paula, National Institution for Space Research (INPE)
  • 12. 12 Distribution A: Approved for public release; distribution is unlimited São Luis Station, Brazil Example: São Luis VHF incoherent scatter radar plumes analysis GPS antennas at São Luis during the AFRL/INPE campaign (installation on February 2008) Cooperation in Atmospheric, Ionospheric and Magnetospheric Research MOU. • MOU signed in June 2001. SAF/IA is in process of negotiating a new MOU.
  • 13. 13 Distribution A: Approved for public release; distribution is unlimited Magnetosphere Research Magnetometer Monitoring Stations SAMBA Stations (in Chile) McMAC IGPP-LANL CARISMA Solar wind interaction w/ magnetosphere Objective: Study of geomagnetic phenomena (i.e., magnetic storms) and processes that affect particle fluxes in the radiation belts Collaborators: - US:, NASA, RV, Boston College - Chile: U of Santiago, (Lead PI: Stepanova), U of Chile, U of Concepcion Radiation Belts
  • 14. 14 Distribution A: Approved for public release; distribution is unlimited USAFA SSA Tracking Telescope in Chile Mamalluca Observatory Future site of USAFA tracking telescope Proposed FTN Station and 50 cm telescope Collaborators • USAF Academy • AFOSR / RV • Universidad of La Serena • Mamalluca Observatory USAFA Falcon Telescope Network (FTN) For SSA • Space Situational Awareness (SSA) - To detect, track, identify, image, predict future positions of space objects • A network of remote telescopes with one located in Chile providing access to southern hemisphere
  • 15. 15 Distribution A: Approved for public release; distribution is unlimited FTN: Global Coverage Created by C1C Lance Wilhelm and C1C Brandon Mueller Global Coverage, (LEO, 1000 km) Global Coverage (GEO) • U.S • Colorado Mesa University (Grand Junction) • Fort Lewis College (Durango) • Northeastern Junior College (Sterling) • Otero Junior College (La Junta) • Penn State University (State College) • Chile • Universidad de La Serena (La Serena) & Observatorio Mamalluca (Vicuña) • Australia • University of Queensland (Brisbane) • Curtin University (Perth) • University of New South Wales & EOS (Canberra) • Potential: South Africa, Kauai Community College, International Space University Partners
  • 16. 16 Distribution A: Approved for public release; distribution is unlimited Molecular Physics Periodic Nuclear Decay Rates The Mystery of Periodic Nuclear Decay Rates  Familiar exponential decay law:  Periodic Variations Reported in 25 Long- term Nuclear Decay Experiments • Select β & E.C. Decay Affected • Wide variety of detectors types • Few experiments run for many years; independent confirmation difficult Raises the possibility that either the detectors or the decays in question are being affected in some fashion by an external influence such as seasonal variations or solar radiation. Regardless of causality, understanding nature of periodicities offers crucial insight into long-term detector operations supporting scientific, national defense, and industrial applications.
  • 17. 17 Distribution A: Approved for public release; distribution is unlimited CCHEN Decay Experiment: Present Status Detector Network of 4 Sites • Chilean Commission of Nuclear Energy (CCHEN) • USAFA • Purdue University • Brigham Young University • Mimic IMS Measurements but at Higher Data Rates & longer Integration Times • Variety of Detectors, Sources – Empty Detectors as Control – Monitor Environ. Variables – Custom, Full Lead Shielding • CCHEN detectors set up & calibrated in Sept 2012 – Data looks good, but too soon to evaluate significance – Expect 2 yr runtime, first results in 9 months View of Test Chambers (top), Gieger Mueller and NaI Detectors with 54Mn, 32Si, 36Cl, 90Sr, and empty NaI detector in separate chamber.
  • 18. 18 Distribution A: Approved for public release; distribution is unlimited Material Science and the Mexican Initiative National Labs work with universities, but, only receive graduate students. Major funding support by CONACYT CONACYT Research Centers
  • 19. 19 Distribution A: Approved for public release; distribution is unlimited AFOSR – CONACYT Joint Projects Final Program Review tentatively scheduled Aug - Sept 2013 in Mexico
  • 20. 20 Distribution A: Approved for public release; distribution is unlimited Success story: Development of Ferroelectric Nanoparticles Critical temperatures of BaTiO3 ceramics as a function of grain size. Barium titanate, BaTiO3, is a white powder and transparent as larger crystals. It is a ferroelectric ceramic material, with a photorefractive effect and piezoelectric properties. • General belief by researchers - Typical BaTiO3 loses its ferroelectricity at sizes smaller than 30-50 nm • Size restrictions limited number of potential applications Collaborators: AFRL/RXPJ, AFOSR CIQA, Mexico
  • 21. 21 Distribution A: Approved for public release; distribution is unlimited Mechanically Induced Surface Stress Particle sizes limited to: • ~1 µm with simple solvents • 9 nm with surfactant zirconia ball mill gif file from wikipedia Bottom up – synthesizes particles from atoms and molecules Top down –particles are reduced to nanometer size by grinding • AFRL/RXPJ developed the world’s smallest ferroelectric nanoparticle, as small as 9 nm. • Surface stress believed key to this achievement • Through collaboration with CIQA, a strain map was made on RXPJ’s nanoparticles, proving the hypothesis that surface stress was present. HRTEM image Strain Map
  • 22. Distribution A: Approved for public release; distribution is unlimited Examples of Systems with Disparate Nanoparticle Roles • Photorefractive beam coupling: electric torque • Liquid crystal display: DC bias • Metatronics (Metananocircuits): current/voltage source • Massive Dipole Field Effects Results with 9 nm-harvested stressed ferroelectric nanoparticles • Photorefractive beam coupling: electric torque • Liquid crystal display: DC bias • Metatronics (Metananocircuits) • Massive Dipole Field Effects
  • 23. 23 Distribution A: Approved for public release; distribution is unlimited Extremophile Research • Collaborators: AFOSR & BioScience Foundation, Chile. – Studies started with isolation of novel heat resistant micro- organism from laboratory drying ovens: E1 and E2. (2007) – One unexpected result: Biosynthesis of Selenium (Se) nanoparticles by E1 E2 Se NANOPARTICLES BIOSYNTHESIS Identification of microorganisms
  • 24. 24 Distribution A: Approved for public release; distribution is unlimited Project Accomplishment GDH POR Characterization of enzymes GDH and POR • Isolation of novel heat resistant microorganism: E1 and E2. • Desiccation resistance for the microorganisms • Isolation and characterization of enzymes: GDH and PDH or POR. • Lipids Profiles and analysis. Studies of DNA repair mechanisms. • Contribution of the antioxidant enzymes to the resistance to extreme and fluctuating UV radiation. • Cloning and expression into Escherichia coli of genes E1 Genome analysis Catalase (CAT) Superoxide dismutase (SOD) Specific Primers design Expression of genes in E.coli Extremophile - Accomplishments Bioscience Foundation, Chile
  • 25. 25 Distribution A: Approved for public release; distribution is unlimited  To study the role of enzymes in the biosynthesis of Se nanoparticles.  To study the effect of temperature, pH and salt concentrations in Se nanoparticle size and shape.  To demonstrate that this is an enzyme-mediated process. Research Goals to be acomplished Nanocrystals biosynthesis 1.Local supersaturation 2.Nucleation 3.Growth Se Nanoparticles biosynthesis Influence of enzymes on selenium nanoparticles synthesis Complex phenomenon, not well studied Se Nanoparticles Extremophile – Future Goals Bioscience Foundation, Chile
  • 26. 26 Distribution A: Approved for public release; distribution is unlimited Structural Mechanics Filament Wound Structures • Project: Damage and Progressive Failure of Filament Wound Structures – Collaborators, Army ARDEC, AFOSR, and ta, Univ of Sao Paulo • Objective: Investigate new mathematical formulation for damage models used in aviation filament wound structures • High precision, low computational cost • Necessary for: structural integrity, health monitoring, and service life assessment
  • 27. 27 Distribution A: Approved for public release; distribution is unlimited Structural Mechanics Filament Wound Structures Motivation Challenges Composites Aluminium Titatium Steel Others Glass fiber Aluminium Carbon sandwich composites Carbon composite laminates Aluminium / steel / titanium [e.g., Boeing - 787] Materials used by weight Ply (orthotropic) Structure Matrix Fiber Laminate (anisotropic) Micromechanics Macromechanics Structural analysis 3 21 z yx Intra-ply Failure Inter-ply Failure How to calculate stress and strain distribution with high accuracy and low computational cost? How to predict damage/failure modes and loads with high precision and low computational cost? Heterogeneity Anisotropy High Specific Properties
  • 28. 28 Distribution A: Approved for public release; distribution is unlimited Damage Model Implementation Filament Wound Structures ABAQUS and UMAT/VUMAT 1-Constitutive Law 2-Failure Criteria 1 2 1 3 3-Degradation Law
  • 29. 29 Distribution A: Approved for public release; distribution is unlimited Damage Model Validation Filament Wound Structures •Tensile •Compression •Shear •Bending •ModeI •ModeII •Mix Mode •Hopkinson’sbar Abaqusimplicit subroutines for plane and curved geometry UEL UMAT Abaqusexplicit subroutines for planeand curved geometry VUEL VUMAT •4 pointBending •Indentationon planeand curved specimens •Impact on plane andcurved specimens Model parameters Model evaluation Experimentaltests Computationalmodel Abaqus
  • 30. 30 Distribution A: Approved for public release; distribution is unlimited Example of Validation Test Results Filament Wound Structures Compression Analyses Maximum Failure Stress ~ 450 MPa Matrix Failure Non-linear behavior Micro-buckling and kinking of fibers Local phenomena Laminate: [15]10 Uniaxial Compression Tests
  • 31. 31 Distribution A: Approved for public release; distribution is unlimited Aerodynamics Stability of Coaxial Free Jet Flow Objective: Perform a stability analysis for coaxial jets to better understand the natural hydrodynamic instabilities of this canonical geometry for liquid rocket engines • Baseflow will be established • The outer jet and the inner jet wall thickness will be incorporated into analysis Benefits: • Better understanding of the natural instability modes of this class of injectors and how the wall thickness affects the hydrodynamics . . . . Inner Jet Core Initial Merging Zone Outer Jet Core Intermediate Merging Zone Fully Merged Zone Outer mixing region Inner mixing region Recirculation Zone Uo, ρo Ui, ρi Recess Lip thickness w d4 d3 d2 d1 u’, p’ BASELINE WITH ACOUSTICS BASELINE WITH ACOUSTICS Examples of coaxial base and acoustic driven flows Collaborators: Fluminense Federal University, Brazil AFRL/RQRE Edwards, AFOSR
  • 32. 32 Distribution A: Approved for public release; distribution is unlimited Concluding Remarks State of Latin American Research • Latin American research is growing fast and becoming more visible on the global scale. – Between 2000 and 2010* • Growth of more than 9% per year in scholarly output • 70% increase in its share of world papers and citations • SOARD Project Officers will continue to cover a broad range of topics in BAA seeking the best scientists of Latin America. – Space portfolio will remain a key area to take advantage of unique recourses space research worldwide) – Group formed in AFOSR to coordinate space research worldwide. * Research Trends Issue 31 November 2012