Uploaded chemistry presentation

K
EXTRACTING METAL FROM ITS
          ORES
      Chemistry Holiday Homework
CONTENTS

•   What Are Ores ?
•   Metal Ores
•   How To Extract Metals From Ores ?
•   Reduction Of Metal Ores
•   Effects On Environment
WHAT ARE ORES ?
          • An ore is any naturally-
            occurring source of a metal
            that you can economically
            extract the metal from.

          • Aluminium, for example, is the
            most common metal in the
            Earth's crust, occurring in all
            sorts of minerals.
An Ore
METAL ORES
          • Metals are usually found in ores
            containing mineral.
          • They are combined with Oxygen or
            Sulphur to form Oxides or Sulphides.
          • Sulphide Ores are converted to Oxides
            by heating them in air (called roasting)
          • Eg : Zinc Sulphide to Zinc Oxide

  Zinc                              Zinc         Sulphur
Sulphide             Oxygen
                                   Oxide         Dioxide


ZnS (s)             1 ½ O2 (g)     ZnO (s)        SO2 (g)
HOW TO EXTRACT METALS FROM
            ORES ?
• To obtain a metal , it’s ore , a reducing
  agent is used to remove the Oxygen , in a
  reduction reaction .
• Examples of some reducing agents :




                                 Made from
   An impure form of            Methane and
        carbon                    Water
REDUCTION OF METAL ORES
    • Iron , Manganese And Copper
          Carbon and Carbon monoxide
           are the reducing agents in the
           extraction of Fe , Mn & Cu
          These are cheap because coke
           can be used which is cheaply
           produced by heating coal in
           absence of air
          Extraction of Iron is done in a
           blast furnace which reaches
           temperatures of 2000K
Haematite   Fe2O3(s)




 Carbon
            3CO (g)
Monoxide




  Iron       2Fe(I)




 Carbon       3 CO2
 Dioxide
Manganese is produced by the reduction
of its Oxide with Carbon.

2MnO(s)      C(s)           2MnI(s)     CO2(g)


 Copper used to be produced this way but
 nowadays some ores are converted into
 solutions containing Cu2+ ions.
 The copper is extracted by reducing with
 scrap iron
 This is greener as no CO2 is produced
 and scra p iron is cheap and readily
 available
 Also , solution can be made from low
 grade ore so it is readily available
• Extracting O ther Metals
 Some metals can’t be extracted using carbon
  reduction such as Aluminium , Titanium , and
  Tungsten.
 Aluminium cannot be extracted because it is
  more reactive than metals.
 Titanium and Tungsten also can’t because they
  will form a metal carbide which would make the
  metal brittle.
• Extraction Of Aluminium
 Aluminium is extracted from purified
  bauxite ore (mainly Al2O3)
 Oxide is dissolved in molten cryolite
  , which forms a solution which melts at
  around 1240K (Al2O3 melts at 2435K)
 Therefore less energy is required
 Alumi nium is produced at negative
 electrode
 Oxygen is produced at positive electrode
 This gives us an equation :



 Al2O3(I)               2Al(I)       1 ½ O(g)
• Extraction Of Titanium
 As Titanium can’t be reduced by Carbon it
  is reduced by Sodium or Magnesium.
 It is an expensive process as Titanium
  Oxide is first converted to Titanium
  Chloride by reacting it with coke and
  Chlorine at 1173K
 Titanium Chloride is then reduced by
 Sodium or Magnesium int o Titanium under
 an inert argon atmosphere at 1300K
• Extraction Of Tungsten
 Tungsten is extracted from it’s Oxide ,
  WO3 by redu ction with H2 at high temp.
 However , there is some risk as H2 is a
  flammable gas , so using it as a reducing
  agent is a last resort
EFFECTS ON ENVIRONMENT
• Recycling scrap metals has many
  environmental and economic advantage.
• It reduces the amount of scrap metal in
  landfill and it has already been extracted
  from its ore so energy is not required
  again.
THANK

YOU
1 de 17

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Uploaded chemistry presentation

  • 1. EXTRACTING METAL FROM ITS ORES Chemistry Holiday Homework
  • 2. CONTENTS • What Are Ores ? • Metal Ores • How To Extract Metals From Ores ? • Reduction Of Metal Ores • Effects On Environment
  • 3. WHAT ARE ORES ? • An ore is any naturally- occurring source of a metal that you can economically extract the metal from. • Aluminium, for example, is the most common metal in the Earth's crust, occurring in all sorts of minerals. An Ore
  • 4. METAL ORES • Metals are usually found in ores containing mineral. • They are combined with Oxygen or Sulphur to form Oxides or Sulphides. • Sulphide Ores are converted to Oxides by heating them in air (called roasting) • Eg : Zinc Sulphide to Zinc Oxide Zinc Zinc Sulphur Sulphide Oxygen Oxide Dioxide ZnS (s) 1 ½ O2 (g) ZnO (s) SO2 (g)
  • 5. HOW TO EXTRACT METALS FROM ORES ? • To obtain a metal , it’s ore , a reducing agent is used to remove the Oxygen , in a reduction reaction . • Examples of some reducing agents : Made from An impure form of Methane and carbon Water
  • 6. REDUCTION OF METAL ORES • Iron , Manganese And Copper  Carbon and Carbon monoxide are the reducing agents in the extraction of Fe , Mn & Cu  These are cheap because coke can be used which is cheaply produced by heating coal in absence of air  Extraction of Iron is done in a blast furnace which reaches temperatures of 2000K
  • 7. Haematite Fe2O3(s) Carbon 3CO (g) Monoxide Iron 2Fe(I) Carbon 3 CO2 Dioxide
  • 8. Manganese is produced by the reduction of its Oxide with Carbon. 2MnO(s) C(s) 2MnI(s) CO2(g)  Copper used to be produced this way but nowadays some ores are converted into solutions containing Cu2+ ions.  The copper is extracted by reducing with scrap iron
  • 9.  This is greener as no CO2 is produced and scra p iron is cheap and readily available  Also , solution can be made from low grade ore so it is readily available
  • 10. • Extracting O ther Metals  Some metals can’t be extracted using carbon reduction such as Aluminium , Titanium , and Tungsten.  Aluminium cannot be extracted because it is more reactive than metals.  Titanium and Tungsten also can’t because they will form a metal carbide which would make the metal brittle.
  • 11. • Extraction Of Aluminium  Aluminium is extracted from purified bauxite ore (mainly Al2O3)  Oxide is dissolved in molten cryolite , which forms a solution which melts at around 1240K (Al2O3 melts at 2435K)  Therefore less energy is required
  • 12.  Alumi nium is produced at negative electrode  Oxygen is produced at positive electrode  This gives us an equation : Al2O3(I) 2Al(I) 1 ½ O(g)
  • 13. • Extraction Of Titanium  As Titanium can’t be reduced by Carbon it is reduced by Sodium or Magnesium.  It is an expensive process as Titanium Oxide is first converted to Titanium Chloride by reacting it with coke and Chlorine at 1173K
  • 14.  Titanium Chloride is then reduced by Sodium or Magnesium int o Titanium under an inert argon atmosphere at 1300K
  • 15. • Extraction Of Tungsten  Tungsten is extracted from it’s Oxide , WO3 by redu ction with H2 at high temp.  However , there is some risk as H2 is a flammable gas , so using it as a reducing agent is a last resort
  • 16. EFFECTS ON ENVIRONMENT • Recycling scrap metals has many environmental and economic advantage. • It reduces the amount of scrap metal in landfill and it has already been extracted from its ore so energy is not required again.