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Elimination Reactions ppt..pptx

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Elimination Reactions ppt..pptx

  1. 1. ORGANIC CHEMISTRY PREPARED BY: FARHAN AHMAD
  2. 2. What are elimination reactions? Discuss in detail.
  3. 3. Elimination reactions:  The elimination reaction is an organic reaction in which two substituents are removed from a molecule to form a new product.  This process takes place in the presence of acid, base, metal and sometimes through heating.  Through this process it is possible to synthesize unsaturated organic compounds from saturated ones.  The elimination is mechanically the reverse of the addition reaction.
  4. 4. Steps involves in elimination reactions: The elimination reaction involves three fundamental steps:  Removal of proton  Formation of C=C pi bond  Breaking of the bond to leaving group.2
  5. 5. Nomenclatures used in elimination reaction:  When a hydrogen atom is removed from the compound as a proton, the process is called deprotonation.  If a halogen is removed then it is called dehalogenation.  If both hydrogen and halogen are removed, then it is called dehydrohalogenation.  If hydrogen and oxygen are removed together, as in the case of alcohols, then it is a dehydration or β-Elimination.
  6. 6. Types of Elimination Reaction: There are two types of elimination reaction: E1 type E2 type
  7. 7. E1 Type: Two step removal mechanism process. Also known as unimolecular elimination. Formation of an intermediate. The reaction rate is proportional to the cocentration of the compound to be transformed( First order Kinetics)
  8. 8. E2 Types: One step Mechanism Also known as Bimolecular reaction Carbon leaving group and carbon hydrogen bonds break off simultaneously Stereo selective and regioselective

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