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ABCP LABS
- AN OVERVIEW-

August- 2013
Laboratory - aims and activities
Technical services for impartial solution to the cement industry as well as
to the civil construction industry





Raw material, cement and based-cement product tests
Calibration services
Conformity mark
Environmental monitoring in cement plants

August 2013

2
Laboratory - Certifications
 ISO 9001 by ABS – Quality Evaluation
 Acreditation by INMETRO NBR ISO / IEC 17025
•RBC (calibration lab network)
•RBLE (test method lab network)

August 2013

3
Laboratory- Awards


Quality Award Sinaprocim /Sinprocim 2010
Vitória Prize, for physical and mechanical tests
– Prize indicated by means of an independ institute of public survey (IBOPE)

Winner team

ABCP President Renato Giusti

August 2013

4
Laboratory - Services










Technical assistance in production process
Technical assistance to the cement consumers
Development of products
Development of analytical tests
Concrete durability studies
Calibration of equipaments
Trainings
Standard reference materials

Raw materials

Cement and
SCM

Clinker

Mortars and
concrete

August 2013

5
Laboratory - Expertise

Metrology

Industrialized mortars

Cement

Chemistry
August 2013

6
Laboratory - Expertise

Mineralogy

Concrete

Environment

Soil - Cement
August 2013

7
August 2013

8
Laboratory of Mineralogy

Raw materials
 Selection and sampling
 Mineralogycal Characterization
 Dosage studies
 Burnability
 Calibration curves for XRFA
August 2013

9
Laboratory of Mineralogy
Raw material characterization techniques

XRFA

XRDA

DTA/ TG

Fused beads preparation apparatus
August 2013

10
Laboratory of Mineralogy
Burnability tests for raw meals

High temperature furnace

August 2013

11
Laboratory of Mineralogy
Cement characterization techniques

Conduction calorimetry
Cement pre hydration studies
Anomalous setting time and strength evolution
Cement – admixtures compatibility
Determination of slag and fly ash contents
Kiln system deposits
Selective solution

August 2013

12
Laboratory of Mineralogy – Optical Microscopy



SCM quality evaluation



Clinker grindability



Manucfacturing process
evaluation



Rocks and sands for
concrete aggregates

August 2013

13
Laboratory of Mineralogy – clinker microscopy

Detecting problems of
Raw meal grinding...

August 2013

14
Laboratory of Mineralogy – clinker microscopy

Reducing atmosphere inside the kiln
August 2013

15
Laboratory of Mineralogy – Microscopy of SCM

Calcium sulfate
Fly ash
Calcareous filler
Natural pozzolans

Determination of glass contents of ground
granulated blast furnace slag

August 2013

16
Laboratory of Mineralogy
Evaluation of sands for concrete aggregate

August 2013

17
Laboratory of Mineralogy – Scanning Electron Microscopy

Sputter coater ( gold)

SEM
August 2013

18
Laboratory of Mineralogy – Scanning Electron Microscopy

Ca
Ca
1500

S
1000

S

Al
Si

500

Ca
Fe

keV

0
0

5

10

Concrete microstruture
Sulfate attack
Alkali –aggregate reaction
Fire damage
Acid attack
August 2013

19
August 2013

20
Laboratory of Cement – Main facilities

Langavant calorimeter

Accelerated carbonation
chamber

ASTM flow table

Moisture chamber

Mortar compressive test machine

Setting Time apparatus

August 2013

21
Laboratory of Cement – Main facilities

Automatic Blaine apparatus

Mortar mixer

Cement densityLe Chatelier Flask

mini specimen compressive test
machine

August 2013

22
Laboratory of Cement – main tests



Performance of grinding aids



Bond grindability (clinker and raw feed)



Hardgroove grindability (coal and pet coke)



Durability tests



Accelerated carbonation tests



Phisico –mechanical tests



Autoclave expansion test



Heat of hydration



Cement test methods according to ASTM



Cement test methods according to EN and ISO



PSD by laser diffraction analysis

Accelerated carbonation tests

Alkali reactivity accelerated mortar
bar tests
August 2013

23
Laboratory of Cement- laser diffraction apparatus

August 2013

24
Importance of PSD (Particle Size Distribution)
Particles 3 - 30 µm
Particles < 2 µm
Particles > 50 µm

Mechanical performance and rheologycal
behaviour depend on PSD

100
90

CP II-Z-32

Porcentagem Passante

80
70

CP IV-32

60

CP V-ARI

50
40
30
20
10
0
0

1

10

100

Diâm etro das Partículas (µm )

August 2013

25
August 2013

26
Laboratory of Concrete- main tests

 Aggregates properties
 Workability, water demand
 Setting time
 Strength control
 Poison modulus of elasticity
 Concrete mix design
 Cement admixture compatibility
Self compacting concrete
August 2013

27
Laboratory of Concrete- Main tests

Cloride difusibility cell

DURABILITY TESTS
Concrete Ability to Resist Chloride Ion
Penetration

Concrete water permeability under pressure

Permeability apparatus

August 2013

28
Laboratory of Concrete

Examples of special reports for cement consumers companies
RESÍDUOS DE PERFURAÇÃO
DE POÇOS PETROLÍFEROS

CONCRETO DOSADO
CONCRETO

CONCRETO

EM CENTRAL

ESTUDO DE DOSAGEM DE
CONCRETOS CONVENCIONAIS E
BOMBEÁVEIS
ESTUDO DE VIABILIDADE DO USO DE
RESÍDUOS NA CONSTRUÇÃO CIVIL

ESPECIFICAÇÃO E APLICAÇÃO DO
CONCRETO EM OBRAS DE CÂMARA
TRANSFORMADORA SUBTERRÂNEA

ESTUDO DE DOSAGENS DE CONCRETO

JANEIRO 2003
JANEIRO 2003
Informações: 0800-555776 l dcc@abcp.org.brl www.abcp.org.br

DEZEMBRO 2003
DEZEMBRO 2003
Informações: 0800-555776 l dcc@abcp.org.brl www.abcp.org.br

DEZEMBRO 2003
DEZEMBRO 2003

Informações: 0800-555776 l dcc@abcp.org.br l www.abcp.org.br

Informações: 0800-555776 l dcc@abcp.org.br l www.abcp.org.br

Manual of concrete
Mix design of special
Evaluation of
concrete
wastes of oil well specification for underground
drilling for building concrete structure of eletrical
network
August 2013

29
Laboratory of Concrete- cement based products

Flexural test on concrete roof tiles

 concrete blocks and pavers
 mix design

 quality control
 technical support to manufacturers
Dimensional test on concrete block
August 2013

30
Laboratory of Concrete
Quality mark for concrete blocks
and pavers

August 2013

31
Laboratory of Concrete- Examples of Technical Support

Concrete Pavement :
Castello Branco Road
Imigrants Road
São Paulo Road Ring
BR101 (training for Army )

Drilling of concrete core
Concrete placing monitoring
Troubleshooting inspection

August 2013

32
August 2013

33
Laboratory of industrialized mortars

Slipping test

Pull out test

Pull out tests
Open time tests
Quality Certification
Development of product
Litigation support


August 2013

34
Laboratory of industrialized mortars
Examples of reports for litigation support and Programs of
Quality
ARGAMASSA DE
REVESTIMENTO

ARGAMASSA DE
REVESTIMENTO

DESCOLAMENTO DE REVESTIMENTO DE
ARGAMASSA

ARGAMASSA DE
REVESTIMENTO

FISSURAÇÃO EM REVESTIMENTO DE ARGAMASSA
PATOLOGIA EM ARGAMASSA DE REVESTIMENTO

MAIO DE 2003
Informações: 0800
-555776l dcc@abcp.org.br www.abcp.org.br
l

SETEMBRO DE 2003

ABRIL DE 2003

Informações: 0800
-555776l dcc@abcp.org.br www.abcp.org.br
l

Cracking and fall of rendering
mortars

Informações: 0800
-555776l dcc@abcp.org.br www.abcp.org.br
l

Sectorial program of quality of
dry set mortars .

August 2013

35
August 2013

36
Laboratory of Environment

Materials tested
 wastes
 gas emissions
 dust emissions
 ordinary fuels
 alternative fuels

Net calorific values
Carbon, hydrogen e nitrogen
 Fluorides e clorides (selective ions )
Sulphur (SC apparatus)
 Heavy metals (atomic absortion) and ICP
Water content of liquids (Karl-Fischer apparatus)
 Emission analysis (SOx, NOx)

August 2013

37
Laboratory of Environment

AAS

ICP

Atomic Absortion spectrometry and ICP to detect heavy metal in industrial wastes

Cadmium, Arsenic,Selenium,Tellurium, Mercury, Lead, Cobalt,etc

August 2013

38
Laboratory of Environment

Calorimeter

Net calorific values of fuels

CHN apparatus

August 2013

39
Laboratory of Environment

Emission monitoring








Heavy metals
Dioxins and Furans
NOx and SOx
Particulate matter (dust)
Cyanides, fluorides
THC ( total hydrocarbons)

August 2013

40
August 2013

41
Laboratory of Chemistry

Chemical characterization



Reconstitution of the concrete mix



Chemical admixtures



Mixing water



Concrete durability



August 2013

42
Laboratory of Chemistry- facilities

.Sample Microwave Digester

.Apparaus for the Production of UltraPure Acids

.Water Purification System

August 2013

43
Laboratory of Chemistry

Sugar contamination detection: The formation of a dark pink halo in a solution of α naftol
suggests the presence of sugar .

August 2013

44
August 2013

45
Laboratory of Metrology


Accredited areas by INMETRO(Governmental Body for
Quality and Metrology)

FORCE

DIMENTIONAL

VOLUME

MASS

August 2013

46
Laboratory of Metrology

glassware

moulds

compression test
machines

balances

test sieves

August 2013

47
Laboratory of Metrology
Standard Reference Materials





SRM for Blaine apparatus calibration
SRM for sieve calibration
SEM (standard cement) for alkali aggregate tests
Concrete standard subsurface pieces for dry-set
Portland cement mortar tests

August 2013

48
Abcp labs   an overview 2013

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Abcp labs an overview 2013

  • 1. ABCP LABS - AN OVERVIEW- August- 2013
  • 2. Laboratory - aims and activities Technical services for impartial solution to the cement industry as well as to the civil construction industry     Raw material, cement and based-cement product tests Calibration services Conformity mark Environmental monitoring in cement plants August 2013 2
  • 3. Laboratory - Certifications  ISO 9001 by ABS – Quality Evaluation  Acreditation by INMETRO NBR ISO / IEC 17025 •RBC (calibration lab network) •RBLE (test method lab network) August 2013 3
  • 4. Laboratory- Awards  Quality Award Sinaprocim /Sinprocim 2010 Vitória Prize, for physical and mechanical tests – Prize indicated by means of an independ institute of public survey (IBOPE) Winner team ABCP President Renato Giusti August 2013 4
  • 5. Laboratory - Services         Technical assistance in production process Technical assistance to the cement consumers Development of products Development of analytical tests Concrete durability studies Calibration of equipaments Trainings Standard reference materials Raw materials Cement and SCM Clinker Mortars and concrete August 2013 5
  • 6. Laboratory - Expertise Metrology Industrialized mortars Cement Chemistry August 2013 6
  • 9. Laboratory of Mineralogy Raw materials  Selection and sampling  Mineralogycal Characterization  Dosage studies  Burnability  Calibration curves for XRFA August 2013 9
  • 10. Laboratory of Mineralogy Raw material characterization techniques XRFA XRDA DTA/ TG Fused beads preparation apparatus August 2013 10
  • 11. Laboratory of Mineralogy Burnability tests for raw meals High temperature furnace August 2013 11
  • 12. Laboratory of Mineralogy Cement characterization techniques Conduction calorimetry Cement pre hydration studies Anomalous setting time and strength evolution Cement – admixtures compatibility Determination of slag and fly ash contents Kiln system deposits Selective solution August 2013 12
  • 13. Laboratory of Mineralogy – Optical Microscopy  SCM quality evaluation  Clinker grindability  Manucfacturing process evaluation  Rocks and sands for concrete aggregates August 2013 13
  • 14. Laboratory of Mineralogy – clinker microscopy Detecting problems of Raw meal grinding... August 2013 14
  • 15. Laboratory of Mineralogy – clinker microscopy Reducing atmosphere inside the kiln August 2013 15
  • 16. Laboratory of Mineralogy – Microscopy of SCM Calcium sulfate Fly ash Calcareous filler Natural pozzolans Determination of glass contents of ground granulated blast furnace slag August 2013 16
  • 17. Laboratory of Mineralogy Evaluation of sands for concrete aggregate August 2013 17
  • 18. Laboratory of Mineralogy – Scanning Electron Microscopy Sputter coater ( gold) SEM August 2013 18
  • 19. Laboratory of Mineralogy – Scanning Electron Microscopy Ca Ca 1500 S 1000 S Al Si 500 Ca Fe keV 0 0 5 10 Concrete microstruture Sulfate attack Alkali –aggregate reaction Fire damage Acid attack August 2013 19
  • 21. Laboratory of Cement – Main facilities Langavant calorimeter Accelerated carbonation chamber ASTM flow table Moisture chamber Mortar compressive test machine Setting Time apparatus August 2013 21
  • 22. Laboratory of Cement – Main facilities Automatic Blaine apparatus Mortar mixer Cement densityLe Chatelier Flask mini specimen compressive test machine August 2013 22
  • 23. Laboratory of Cement – main tests  Performance of grinding aids  Bond grindability (clinker and raw feed)  Hardgroove grindability (coal and pet coke)  Durability tests  Accelerated carbonation tests  Phisico –mechanical tests  Autoclave expansion test  Heat of hydration  Cement test methods according to ASTM  Cement test methods according to EN and ISO  PSD by laser diffraction analysis Accelerated carbonation tests Alkali reactivity accelerated mortar bar tests August 2013 23
  • 24. Laboratory of Cement- laser diffraction apparatus August 2013 24
  • 25. Importance of PSD (Particle Size Distribution) Particles 3 - 30 µm Particles < 2 µm Particles > 50 µm Mechanical performance and rheologycal behaviour depend on PSD 100 90 CP II-Z-32 Porcentagem Passante 80 70 CP IV-32 60 CP V-ARI 50 40 30 20 10 0 0 1 10 100 Diâm etro das Partículas (µm ) August 2013 25
  • 27. Laboratory of Concrete- main tests  Aggregates properties  Workability, water demand  Setting time  Strength control  Poison modulus of elasticity  Concrete mix design  Cement admixture compatibility Self compacting concrete August 2013 27
  • 28. Laboratory of Concrete- Main tests Cloride difusibility cell DURABILITY TESTS Concrete Ability to Resist Chloride Ion Penetration Concrete water permeability under pressure Permeability apparatus August 2013 28
  • 29. Laboratory of Concrete Examples of special reports for cement consumers companies RESÍDUOS DE PERFURAÇÃO DE POÇOS PETROLÍFEROS CONCRETO DOSADO CONCRETO CONCRETO EM CENTRAL ESTUDO DE DOSAGEM DE CONCRETOS CONVENCIONAIS E BOMBEÁVEIS ESTUDO DE VIABILIDADE DO USO DE RESÍDUOS NA CONSTRUÇÃO CIVIL ESPECIFICAÇÃO E APLICAÇÃO DO CONCRETO EM OBRAS DE CÂMARA TRANSFORMADORA SUBTERRÂNEA ESTUDO DE DOSAGENS DE CONCRETO JANEIRO 2003 JANEIRO 2003 Informações: 0800-555776 l dcc@abcp.org.brl www.abcp.org.br DEZEMBRO 2003 DEZEMBRO 2003 Informações: 0800-555776 l dcc@abcp.org.brl www.abcp.org.br DEZEMBRO 2003 DEZEMBRO 2003 Informações: 0800-555776 l dcc@abcp.org.br l www.abcp.org.br Informações: 0800-555776 l dcc@abcp.org.br l www.abcp.org.br Manual of concrete Mix design of special Evaluation of concrete wastes of oil well specification for underground drilling for building concrete structure of eletrical network August 2013 29
  • 30. Laboratory of Concrete- cement based products Flexural test on concrete roof tiles  concrete blocks and pavers  mix design  quality control  technical support to manufacturers Dimensional test on concrete block August 2013 30
  • 31. Laboratory of Concrete Quality mark for concrete blocks and pavers August 2013 31
  • 32. Laboratory of Concrete- Examples of Technical Support Concrete Pavement : Castello Branco Road Imigrants Road São Paulo Road Ring BR101 (training for Army ) Drilling of concrete core Concrete placing monitoring Troubleshooting inspection August 2013 32
  • 34. Laboratory of industrialized mortars Slipping test Pull out test Pull out tests Open time tests Quality Certification Development of product Litigation support  August 2013 34
  • 35. Laboratory of industrialized mortars Examples of reports for litigation support and Programs of Quality ARGAMASSA DE REVESTIMENTO ARGAMASSA DE REVESTIMENTO DESCOLAMENTO DE REVESTIMENTO DE ARGAMASSA ARGAMASSA DE REVESTIMENTO FISSURAÇÃO EM REVESTIMENTO DE ARGAMASSA PATOLOGIA EM ARGAMASSA DE REVESTIMENTO MAIO DE 2003 Informações: 0800 -555776l dcc@abcp.org.br www.abcp.org.br l SETEMBRO DE 2003 ABRIL DE 2003 Informações: 0800 -555776l dcc@abcp.org.br www.abcp.org.br l Cracking and fall of rendering mortars Informações: 0800 -555776l dcc@abcp.org.br www.abcp.org.br l Sectorial program of quality of dry set mortars . August 2013 35
  • 37. Laboratory of Environment Materials tested  wastes  gas emissions  dust emissions  ordinary fuels  alternative fuels Net calorific values Carbon, hydrogen e nitrogen  Fluorides e clorides (selective ions ) Sulphur (SC apparatus)  Heavy metals (atomic absortion) and ICP Water content of liquids (Karl-Fischer apparatus)  Emission analysis (SOx, NOx) August 2013 37
  • 38. Laboratory of Environment AAS ICP Atomic Absortion spectrometry and ICP to detect heavy metal in industrial wastes Cadmium, Arsenic,Selenium,Tellurium, Mercury, Lead, Cobalt,etc August 2013 38
  • 39. Laboratory of Environment Calorimeter Net calorific values of fuels CHN apparatus August 2013 39
  • 40. Laboratory of Environment Emission monitoring       Heavy metals Dioxins and Furans NOx and SOx Particulate matter (dust) Cyanides, fluorides THC ( total hydrocarbons) August 2013 40
  • 42. Laboratory of Chemistry Chemical characterization  Reconstitution of the concrete mix  Chemical admixtures  Mixing water  Concrete durability  August 2013 42
  • 43. Laboratory of Chemistry- facilities .Sample Microwave Digester .Apparaus for the Production of UltraPure Acids .Water Purification System August 2013 43
  • 44. Laboratory of Chemistry Sugar contamination detection: The formation of a dark pink halo in a solution of α naftol suggests the presence of sugar . August 2013 44
  • 46. Laboratory of Metrology  Accredited areas by INMETRO(Governmental Body for Quality and Metrology) FORCE DIMENTIONAL VOLUME MASS August 2013 46
  • 47. Laboratory of Metrology glassware moulds compression test machines balances test sieves August 2013 47
  • 48. Laboratory of Metrology Standard Reference Materials     SRM for Blaine apparatus calibration SRM for sieve calibration SEM (standard cement) for alkali aggregate tests Concrete standard subsurface pieces for dry-set Portland cement mortar tests August 2013 48