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Silicate minerals

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Silicate minerals

  1. 1. SILICATE MINERALS Prepared by Dr. F. Clark, Department of Earth and Atmospheric Sciences, University of Alberta Sept. 05
  2. 2. ISOLATED SILICATES [Nesosilicates]In this group, silicon tetrahedra share no oxygen anions with other tetrahedra, and so have an excess negative charge of 4-. In the mineral olivine, this is balanced by the insertion of a pair of divalent cations in the crystal structure, either or both of Mg2+ and Fe2+. The chemical formula for olivine is written (Mg,Fe)2SiO4, which tells us that for every silicon, there are four oxygen and two cations, either or both of Mg and Fe. This option, which illustrates ionic substitution, is indicated by separating these elements by a comma within the parentheses. We have variation within fixed limits, those limits being 100% Mg and 100% Fe, or any proportion in between.
  3. 3. OLIVINEThese threespecimens areof an igneousrock consistingalmostexclusively ofcrystals ofolivine that areapproximately1mm across.Olivine exhibits its classic glassy, olive green appearance in thesespecimens, as well as its common granular [somewhat like sugar]habit. There is no cleavage, only conchoidal fracture, so that there areno plane surfaces reflecting light.
  4. 4. SINGLE CHAIN SILICATES [Inosilicates]In the single chain silicates, each silicon tetrahedron shares two oxygen anions, one with one neighbouring tetrahedron, and one with another, to produce long, strongly bonded chains. Each shared oxygen accounts for only 1- rather than the usual 2-, so that for each silicon tetrahedron, the excess negative charge is now only 2-, which still requires insertion of cations in the crystal structure. These cations are bonded to, and serve to link, the chains, but these bonds are weaker than those within the chains. The single chain silicates thus cleave parallel to the chains, along two planes that meet at approximately 90 degrees.
  5. 5. Pyroxene [e.g. augite]In these three views of two specimens, the upper face and left sidevertical face meet at right angles, a common characteristic of the singlechain silicates. Note how irregular the faces are on the two images onthe right, yet how these small steps are parallel to each other. Thehardness, around 5 ½ to 6, white streak, and typical dark colour makethis otherwise very similar to amphibole, a double chain silicate. Thesquare cross-sections of pyroxene crystals distinguishes them fromamphiboles.
  6. 6. DOUBLE CHAIN SILICATES [Inosilicates]As with single chain silicates, chains are constructed by sharing of two oxygen for each silicon tetrahedron. The double chains are constructed by having every second silicon along the chain share a third oxygen with a silicon from the facing chain. The net result is that on average, each silicon shares 2 ½ oxygen, so the excess negative charge per silicon is reduced to 1 ½. Cations serve to balance charge and link the strongly constructed double chains, whose extra width causes the cleavage planes to change orientation and meet at approximately 60 and 120 degrees, producing hexagonal cross sections.
  7. 7. Amphibole [e.g. hornblende]In the double chain silicates, the extra width of the double chain skewsthe intersection angle between cleavage faces, so that they meet toform hexagonal cross sections to the crystals, as highlighted by theyellow lines in the right-hand image. In this case, we are sighting alongthe length of the chains. Other major properties are as for pyroxene.
  8. 8. SHEET SILICATES [Phyllosilicates]In this group, each silicon tetrahedron shares three oxygen anions with neighbouring tetrahedra, so that the net negative charge per silicon is now 1-. This produces a kind of hexagonal honeycomb sheet, in which all tetrahedra point in the same direction. This enables these layers to bond with layers of cations at the centres of octahedra with oxygen as the apices. There is great variety in the combinations that are possible. However, there is an asymmetry to the charge distribution which leads to net surface charges on the sheets, which are then weakly bonded to each other by cations. This leads to the characteristic property of this group – one perfect cleavage, parallel to the sheets.
  9. 9. BiotiteAs with all mica group minerals within the sheet silicates, biotite cleavesreadily to produce flexible cleavage flakes whose surface has significantreflectance, such that small flakes or crystals within a rock typically glint.It is soft as well, and not readily confused with anything else. You mayrely on the colour to be this consistent, almost black or very dark brownshade, to distinguish from other micas, such as muscovite.
  10. 10. MuscoviteSoft, and with flexible, highly reflective cleavage flakes, the mica groupmineral muscovite is distinguished consistently and reliably from thedarker cousin biotite by its clear to silvery colour. Muscovite containsaluminum, whereas biotite has iron and/or magnesium in the same sitein the crystal struture, which accounts for the consistent colourdifference.
  11. 11. ChloriteBelonging to adifferent groupof sheetsilicates thanthe micas,chlorite hasbrittle ratherthan flexiblecleavageflakes.Chlorite is also soft and readily flakes along its perfect cleavage, and ishighly reflective as well. Its characteristic dark green colour imparts agreen tone to the rocks which most typically contain it – low grademetamorphic rocks that are called greenschists.
  12. 12. FRAMEWORK SILICATES [Tectosilicates]Finally, all four oxygen are shared, each one with a different silicon tetrahedron, which eliminates the excess negative charge, given the basic formula SiO2 (the two oxygen are in effect four ½ oxygen, each being shared). One might therefore expect the framework silicates to be the simplest group to deal with, but complexity is introduced in the feldspar group, as we shall soon see.
  13. 13. QuartzAmong the most common rock-forming minerals, quartz is also amongthe easiest to identify. With a hardness of 7, it is not scratched by aknife blade, but ends up with a thin streak of metal on its surface. Mostcommonly it has a somewhat dull, grey glassy appearance. It has nocleavages to produce plane reflecting surfaces when incorporated inrocks (see right image), but rather exhibits conchoidal fracture. Itscharacteristic habit is as hexagonal prismatic crystals (see left view)with pyramid terminations, seen in the specimen under the scale bar inthe left image, and in the middle image.
  14. 14. Feldspar Group – Potassium FeldsparIn the feldspars, we see coupled ionic substitution, rather than the simple substitution exhibited by olivine. By virtue of its size, Al3+ fits between the oxygen anions of the tetrahedra in place of Si4+. Of course, this introduces a positive charge deficiency. Statistically, either one out of every four tetrahedra, or two out of every four tetrahedra, may have a silicon cation replaced by aluminum (any more than that cannot be accommodated by the crystal structure). In the case of potassium feldspar, one out of every four tetrahedra has aluminum, and the charge deficiency is balanced by insertion of a potassium (K+) cation.
  15. 15. Potassium FeldsparThe most common variety of potassium feldspar is orthoclase, number6 on Mohs hardness scale. Although it is commonly a salmon pinkcolour, this is not a diagnostic feature (see plagioclase feldspar imagesto confirm this point). It has two cleavages that meet at right angles, toproduce square edges as seen in these specimens. Streak is white.This mineral may have simple twinning, but never exhibits the multipletwinning that plagioclase feldspar may show.
  16. 16. Potassium FeldsparThis specimen is included to emphasize the fact that one can not saywith confidence that potassium feldspar is pink, and plagioclase white,although this is often the case. In the left-hand image, the upper faceand lower left faces are cleavages, and in the right-hand image, theupper face and shaded lower right face are cleavages. Note again thatcleavages tend to be expressed in a somewhat discontinuous fashion.
  17. 17. Feldspar Group – Plagioclase FeldsparExplanation of the plagioclase feldspars carries on from potassium feldspar. The substitution of one Al3+ for Si4+ could also be balanced by Na+. This is albite, the sodium plagioclase feldspar. If we substitute two Al for Si out of every four Si, the charge deficiency of 2+ is balanced by Ca2+, and we have anorthite. The ionic radii of Na+ and Ca2+ are almost identical, so the two freely substitute, along with Al3+ for Si4+, to produce the plagioclase feldspar solid solution series. One might expect there to be free substitution between albite and potassium feldspar, but because the ionic radius of potassium is approximately 40% larger than that of sodium, such substitution is limited to elevated temperatures.
  18. 18. PlagioclaseFeldsparThis mineralhas manyproperties incommon withpotassiumfeldspar, whichwe emphasizeon this slide.The hardness is 6, colour is variable, including salmon pink as seenhere, and the streak is white. Two excellent cleavages meet at rightangles (upper and left-facing surfaces in the image above). However,plagioclase feldspar may have multiple (or polysynthetic) twinningstriations, as seen on the upper face parallel to the red arrow.
  19. 19. Plagioclase FeldsparThis reoriented specimen exhibits the twinning striations more clearly,parallel to the blue arrows. Resembling very fine scratches, theyrepresent the intersection between twin planes and the upper surface ofthe crystal, and are flush with that surface. They are not seen on thefaces marked with blue stars, because they are parallel to those faces,but could be seen on the faces highlighted by green arrows.
  20. 20. Plagioclase FeldsparThe same crystal yet again conveys the idea that the twinned crystalconsists of slices with alternating orientation of the crystal structure. Asa result, some slices catch the light in such a way as to reflect it, andothers do not, showing up salmon pink rather than being washed out.We stress that the striations are an optical effect produced by the factthat crystal structure controls the interaction of light with a specimen.
  21. 21. Plagioclase FeldsparThis specimen illustrates the variability in colour exhibited by feldspars.Twinning striations are visible on the upper surface, parallel to the redarrows. Because the twin planes are parallel to the right side face in theright side image, they could not be seen there, but hypothetically couldbe seen on the lower, shaded face in that image. The irregularity of thisfracture surface makes this most unlikely in practice.
  22. 22. Plagioclase FeldsparThis white specimen, with twinning striations running parallel to the redarrows, illustrates the fact that portions of the twinned crystal are notnecessarily all of the same thickness, although they tended to be nearlyso in the specimens in the earlier slides. Note the broad uniform band,almost 1 cm wide, sandwiched between twins whose planes are lessthan 1 mm apart.