1. Fate and Transport of Contaminants
(Hazardous Waste Management, LaGrega, M.D. vd, 2002) kitabından alınmıştır.
Hazırlayan: ABDUL WAHED AHMADI (218128001005)
Ders eğitmeni: Prof. Dr. Mehmet Emin Argun
Konya 2022-2023
T.C
KONYA TEKNİK ÜNİVERSİTESİ
MÜHENDİSLİK VE DOĞA BİLİMLERİ FAKÜLTESİ
ÇEVRE MÜHENDİSLİĞİ BÖLÜMÜ
2. Table of Contents
1. Contaminate Release
a. Air Emissions
b. Volatilization and Particular matter emission
c. Releases to Water
d. Landfill leachate
e. Contaminants
2. Transport of contaminants in the Subsurface
a. Hydrologic Cycle and Groundwater flow
b. Darcy`s Law and Hydraulic head
c. Hydraulic conductivity of geologic materials
d. Contaminates transportation mechanism
e. Groundwater modeling
3. Fate of contaminants in the Subsurface
a. Subsurface the Environment
b. Retardation process
c. Linear sorption model
d. Non-ideal sorption conditions
e. Ion exchange , Precipitation , filtration , chemical and biological oxidation reduction ,Hydrolysis,…..
4. Atmospheric transport and dispersion of contaminates
a. Transport and disoperation basic
b. Atmospheric turbulence and stability
c. The Gaussian equation
d. Source types and volume area sources
e. Estimation of contaminants concentration
f. Computer Modeling
g. Chemical transportation and deposition By Ab.W.Ahmadi
5. 1- Contaminate Release
By Ab.W.Ahmadi
Contaminate release introduces pollutants into the environment.
• An industrial facility discharges untreated wastewater containing chemicals into a
nearby river.
It determines the pathways through which contaminants spread.
• Pesticides sprayed on crops can be carried by rainwater runoff into nearby
streams, contaminating the water.
Contaminate release can lead to water, soil, and air pollution.
• Improperly dumped oil seeps into the soil, contaminating it and potentially
leaching into groundwater.
It influences the persistence and transformation of contaminants.
• Heavy metals released from industrial waste can persist in the environment for
long periods, accumulating in the food chain and posing health risks.
Understanding release is crucial for risk assessment and management.
• Understanding the release of toxic gases from a chemical plant enables authorities
to evacuate nearby residents and implement measures to prevent further
exposure.
7. Contaminate Release
By Ab.W.Ahmadi
Contaminant
Source
Release
Mechanism
Environmental
Media
Fate and Transport
Industrial Facility
Smokestack
emissions
Air
Dispersion modeling,
atmospheric transport
Agricultural
Activities
Runoff from
fields
Water
Water quality modeling,
transport in streams
Waste Disposal Site
Leachate
seepage
Soil, Groundwater
Soil adsorption modeling,
groundwater flow
Urban Traffic Vehicle exhaust Air
Traffic emissions modeling,
dispersion modeling
Chemical Spill
Accidental
release
Soil, Water
Spill modeling, transport in
soil and waterways
8. Air Emissions
By Ab.W.Ahmadi
Air emissions refer to the release of pollutants and contaminants into the
atmosphere. Here are some short examples related to air emissions:
Industrial smokestacks releasing sulfur dioxide (SO2) and nitrogen
oxides (NOx) from burning fossil fuels.
Vehicle exhaust emitting carbon monoxide (CO), nitrogen dioxide
(NO2), and particulate matter into the air.
Power plants emitting greenhouse gases such as carbon dioxide (CO2)
during the combustion of coal or natural gas.
Volatile organic compounds (VOCs) being released from industrial
processes, paints, and solvents.
Agricultural activities contributing to air emissions through the release
of ammonia from livestock waste or the use of fertilizers.
These examples demonstrate different sources of air emissions that can
have adverse effects on air quality, human health, and the environment.
9. Air Emissions
By Ab.W.Ahmadi
Emission Source Contaminants Fate and Transport Environmental Impacts
Industrial Facility
Sulfur dioxide (SO2)
Atmospheric dispersion,
chemical reactions
Acid rain, respiratory
irritation
Nitrogen oxides (NOx)
Atmospheric dispersion,
photochemical reactions
Smog formation,
respiratory issues
Particulate matter (PM)
Atmospheric dispersion,
deposition
Respiratory problems, air
pollution
Vehicle Exhaust
Carbon monoxide (CO)
Atmospheric dispersion,
chemical reactions
Carbon monoxide
poisoning
Volatile organic compounds
(VOCs)
Atmospheric dispersion,
photochemical reactions
Ground-level ozone
formation
Power Plant
Mercury (Hg)
Atmospheric dispersion,
deposition
Bioaccumulation,
ecosystem damage
Carbon dioxide (CO2)
Atmospheric dispersion,
greenhouse effect
Climate change, global
warming
Agricultural Activity
Ammonia (NH3)
Atmospheric dispersion,
deposition
Eutrophication, water
pollution
Pesticides
Atmospheric dispersion,
deposition
Ecological harm, human
health risks
Outlining different air emissions and their potential fate and transport processes:
10. Volatilization and Particular matter emission
By Ab.W.Ahmadi
Contaminant Volatilization Process Fate
Volatile Organic
Compounds (VOCs)
Evaporation from liquid or solid
surfaces
Atmospheric transport and dispersion
Sublimation from solid to gas phase
Dependent on specific VOC:
photochemical reactions, deposition, or
reaction with other compounds
Polycyclic Aromatic
Hydrocarbons (PAHs)
Sublimation from solid to gas phase
Atmospheric transport, deposition, or
reaction with other compounds
Desorption from contaminated soils or
sediments
Atmospheric transport, deposition, or
leaching into water bodies
Pesticides
Volatilization from treated surfaces or
soil
Atmospheric transport, deposition, or
reaction with other compounds
Vaporization from plant surfaces or
treated crops
Atmospheric transport, deposition, or
uptake by other organisms
Mercury
Evaporation from liquid surfaces Atmospheric transport and dispersion
Sublimation from solid to gas phase
Atmospheric transport, deposition, or
reaction with other compounds
Biomagnification through the food
chain
Accumulation in organisms, potential
for environmental contamination
11. Volatilization and Particular matter emission
By Ab.W.Ahmadi
Soil to Water:
Leaching: Contaminants dissolve in water, percolate through soil, and reach
groundwater or surface water bodies.
Runoff: Contaminants attached to sediment particles are transported via surface
water runoff, entering nearby water bodies.
Erosion: Soil erosion contributes to the transport of sediment-bound
contaminants, impacting water quality.
Soil to Air:
Volatilization: Contaminants evaporate from soil surfaces as volatile compounds,
entering the air.
Dust Emissions: Contaminants present in fine particles or dust become airborne
and can be transported over long distances.
Water to Air:
Evaporation: Contaminants dissolved in water bodies volatilize into the air
through the process of evaporation.
Aerosol Formation: Water bodies generate aerosols containing contaminants,
which can disperse through air currents.
12. Volatilization and Particular matter emission
By Ab.W.Ahmadi
shows a molecule of contaminant moving through different mediums,
including soil particles, water, liquid-air films, and atmospheric air.
Columns, labeled "Soil particle," "Pore water," "Liquid-air films," that the
contaminant can move through as it travels from the soil to the atmosphere.
13. Volatilization and Particular matter emission
By Ab.W.Ahmadi
Contaminant Particulate Matter (PM) Fate
Heavy Metals PM2.5 and PM10
Deposition onto surfaces such as soil, water
bodies, and vegetation
Bioaccumulation in organisms through
inhalation or ingestion
Polycyclic Aromatic
Hydrocarbons
(PAHs)
PM2.5 and PM10
Adsorption onto PM surfaces
Atmospheric transport and deposition,
potentially contributing to regional or
global pollution
Organic
Compounds
PM2.5 and PM10
Adsorption onto PM surfaces
Potential for reactions with other
compounds in the atmosphere
Inhalation or ingestion by organisms
Contribution to air pollution, smog
formation, and health effects
15. Releases to Water
By Ab.W.Ahmadi
Model
Name
Source
Types
Activity Data
Required
Emission
Factors
Control Measures
Considered
Fate and Transport
Processes
Model A Industrial Yes Yes Yes
Advection, Dispersion,
Deposition
Model B Commercial Yes Yes No
Advection, Diffusion,
Volatilization
Model C Consumer Yes Yes Yes
Advection, Sorption,
Biodegradation
Model D Industrial No Yes Yes
Advection, Dispersion,
Deposition
Model E Industrial Yes No Yes
Advection, Diffusion,
Sorption
(volatile air emissions models)
16. Landfill leachate
By Ab.W.Ahmadi
Landfill leachate is the liquid that is produced when water comes into
contact with waste materials in a landfill. This liquid can contain a variety of
pollutants and can be harmful to the environment if not properly managed.
The sources of fluids that contribute to the generation of landfill leachate
include precipitation, surface water, and groundwater.
17. Landfill leachate
By Ab.W.Ahmadi
The HELP model is a hydrological model that is used to simulate the movement of water through the soil
and groundwater systems.
P is the precipitation, ET is the evapotranspiration, Q is the runoff, and ΔS is the change in storage
P = ET + Q + ΔS
18. Landfill leachate
By Ab.W.Ahmadi
Table shows the selected inorganic constituents detected in leachate from
hazardous waste landfills.
First row shows that arsenic was detected in concentrations ranging from 11
to 10,000,000 μg/L in 6 landfills in the 1981 report, and in concentrations
ranging from 30 to 5,800 μg/L in five landfills in the 1977 report.
19. Landfill leachate
By Ab.W.Ahmadi
Table provides a list of the organic compounds found in leachate from hazardous waste landfills,
along with their chemical formulas and names.
21. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Contaminants move through soil and groundwater in the
subsurface.
Groundwater flow carries contaminants along with it.
Contaminants can spread and mix due to variations in
groundwater flow velocities and subsurface heterogeneity.
Sorption can occur, where contaminants attach to soil particles.
Biodegradation by microorganisms can break down contaminants.
Preferential flow pathways can speed up contaminant transport.
Contaminant fate depends on their properties and interactions with
the subsurface materials.
Hydrologic Cycle and Groundwater flow
22. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Infiltration during precipitation events can introduce contaminants into the
subsurface.
Increased precipitation and groundwater recharge can dilute and disperse
contaminants in the subsurface.
The hydrological cycle creates and maintains transport pathways, such as preferential
flow channels, for contaminants to move through the subsurface.
Changes in groundwater flow due to the hydrological cycle can alter the direction
and velocity of contaminant transport.
Recharge and discharge zones play a role in the movement and fate of contaminants
in the subsurface.
Hydrologic Cycle and Groundwater flow
23. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Hydrologic Cycle and Groundwater flow
Aspect Description
Definition Water located beneath the Earth's surface in saturated zones called aquifers.
Source
Primarily comes from precipitation that infiltrates the ground. Can also be replenished
through surface water bodies via seepage or recharge.
Aquifers
Underground formations or layers of rock, gravel, sand, or other materials that hold and
transmit groundwater.
Water Availability
Essential water resource for human consumption, irrigation, industry, and sustaining
ecosystems like wetlands and springs.
Groundwater
Movement
Moves slowly through the subsurface under the influence of gravity, following the
hydraulic gradient from higher to lower elevation.
Recharge
Process of water entering the aquifer through infiltration, replenishing groundwater
reserves.
Discharge
Movement of groundwater back to the surface through springs, seeps, or interactions
with surface water bodies.
Groundwater Quality
Quality can vary based on geological conditions, land use practices, and the presence of
contaminants. Protection is crucial to ensure suitability for various uses.
Management
Involves monitoring and controlling groundwater extraction, implementing recharge
measures, and preventing pollution to sustain availability and
24. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Darcy`s Law and Hydraulic head
Describes groundwater flow through porous media.
Relates flow rate to hydraulic gradient and hydraulic conductivity.
Used in groundwater hydrology and engineering.
Assumptions: steady-state flow and homogeneous medium.
Important for well design, velocity estimation, and contaminant transport.
Limitations in complex flow situations.
Q = -K * A * (dh/dl)
where:
Q is the discharge or flow rate of groundwater,
K is the hydraulic conductivity of the porous medium,
A is the cross-sectional area through which groundwater flows, dh/dl is the hydraulic
gradient or the change in hydraulic head per unit distance.
25. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Hydraulic conductivity of geologic materials
The experiment involved measuring the flow rate of water through a column of sand of
known length and cross-sectional area, under a constant pressure gradient.
Darcy's law states that the flow rate of a fluid through a porous medium is proportional to
the pressure gradient and the cross-sectional area of the medium, and inversely
proportional to the length of the medium and the viscosity of the fluid
A is the cross-sectional area of the flow path, Δh is the difference in hydraulic head between the two
ends of the flow path, and L is the length of the flow path
Darcy's law, which describes the flow of water
through a porous medium, is:
26. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Hydraulic conductivity of geologic materials
Displays the values of hydraulic head obtained from
Darcy's experiment.
27. 2-Transport of contaminants in the
Subsurface
By Ab.W.Ahmadi
Hydraulic conductivity of geologic materials
This is a typical ranges of hydraulic conductivity for various types of soils.
Hydraulic conductivity is a measure of how easily water can flow through
a soil. It is expressed in units of cm/s (centimeters per second).
28. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Hydraulic conductivity of geologic materials
Refers to the effect of dispersion on
contaminant transport, which is an
important concept in environmental
engineering and science. Such as a
contaminant, as it moves through a
medium, such as soil or water. This
spreading out can occur due to
various factors, such as diffusion,
turbulence, and mixing.
30. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Hydraulic conductivity of geologic materials
Section heading that refers to the transport of contaminants in the subsurface. This section
is divided into two parts, (a) Continuous point source and (b) One-time point source.
32. 2-Transport of contaminants in the Subsurface
By Ab.W.Ahmadi
Groundwater Modeling
Groundwater modeling plays a crucial role in the management of hazardous waste
Groundwater Flow Analysis
Understanding flow patterns and velocities Assessing potential migration pathways
Contaminant Transport Modeling
Simulating the movement of hazardous waste contaminants
Source Identification and Remediation Design
- Identifying the source of contamination- and designing effective remediation strategies
Risk Assessment and Mitigation
- Assessing potential risks to human health and the environment Evaluating the magnitude and
extent of contamination Guiding risk-based decision-making
Regulatory Compliance and Permitting
- Supporting regulatory agencies in evaluating permit applications Providing data for compliance
with environmental regulation
Data Validation and Continuous Monitoring
• Monitoring groundwater quality and refining models over time
33. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
How the contaminates moved to the subsurface in response to advection ,
Hydrodynamic dispersion and molecular diffusion.
34. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Subsurface the Environment
Classification Particle Size Range Texture Examples
Gravel > 2 mm Coarse
Pebbles, cobbles,
boulders
Sand 0.05 mm - 2 mm Gritty
Quartz sand, feldspar
sand, volcanic sand
Silt
0.002 mm - 0.05
mm
Smooth Fine silt particles
Clay < 0.002 mm
Sticky,
Plastic
Kaolinite,
montmorillonite, illite
Organic
Matter
Variable Variable
Decomposed remains
of plants, animals,
microorganisms
Classification of mineral grains in soil
35. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Retardation process
Sorption or adsorption is the primary mechanism responsible for retardation,
where contaminants adhere to solid surfaces in the subsurface.
The retardation factor (R) quantifies the extent of retardation, with higher
values indicating greater retardation and slower contaminant movement.
Sorption isotherms describe the relationship between contaminant
concentrations in groundwater and their sorbed concentrations on solid
surfaces, providing insights into sorption capacity and affinity.
Retardation is an important factor to consider in assessing the transport and
fate of contaminants in the subsurface, as it affects their potential migration,
exposure, and remediation options.
36. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Retardation process
Refers to the process of desorption of sorbate. Sorbate refers to the substance that is
adsorbed onto a surface. Adsorption is the process by which molecules or particles adhere to
a surface. Desorption, on the other hand, is the process by which the adsorbed substance is
released from the surface.
37. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Retardation process
38. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Linear sorption model
Commonly used concept in the field of fate and transport of contaminants.
It is a simplified representation of the process of sorption, which refers to
the attachment or adsorption of contaminants to solid surfaces in soil,
sediment, or other porous media.
it is assumed that the sorption process is linearly proportional to the
concentration of the contaminant in the aqueous phase.
Mathematically, it can be represented as:
S = Kd × C
S is the amount of contaminant sorbed (mass or moles per unit mass of the sorbent)
Kd is the distribution coefficient or the partitioning coefficient, which represents the
sorption capacity of the sorbent (unit: volume of sorbent per unit volume of solution)
C is the concentration of the contaminant in the aqueous phase (mass or moles per unit
volume of the liquid phase)
39. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Non-ideal sorption conditions
Non-ideal sorption conditions often exhibit nonlinear behavior, where the
relationship between sorption and contaminant concentration is not linear.
This means that the rate of sorption may change non-proportionally with
varying contaminant concentrations, deviating from the assumptions of the
linear sorption model.
Heterogeneity: Non-ideal sorption conditions can arise due to spatial
heterogeneity within the sorbent material.
Non-ideal sorption conditions are influenced by various environmental
factors such as pH, temperature, ionic strength, and the presence of other
solutes. Changes in these factors can significantly impact sorption behavior
by altering the sorption affinity and capacity of the sorbent, causing
deviations from the linear sorption model.
40. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Ion exchange , Precipitation , filtration , chemical and biological oxidation
reduction ,Hydrolysis,…..
Process Role in Fate of Contaminants in the Subsurface
Ion Exchange
- Sorption and sequestration of contaminants
- Transformation of contaminants
- Remediation and selective removal of contaminants
Precipitation
- Removal of contaminants from solution
- Particle aggregation and immobilization
- Transformation and alteration of contaminants
Filtration
- Contaminant removal from fluids or gases
- Particle size selectivity
- Treatment, purification, and pre-treatment
- Reduction of contaminant transport
Chemical and Biological - Oxidation and reduction reactions
Oxidation-Reduction
- Transformation of contaminants
- Degradation and conversion of contaminants
- Reduction of contaminant toxicity and mobility
Hydrolysis
- Transformation and breakdown of contaminants
- Conversion of contaminants into different compounds
- Reduction of contaminant mobility
41. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Ion exchange , Precipitation , filtration , chemical and biological oxidation
reduction ,Hydrolysis,…..
42. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Ion exchange , Precipitation , filtration , chemical and biological oxidation
reduction ,Hydrolysis,…..
This equation indicates that the rate of hydrolysis is directly proportional to the
concentration of the contaminant (c).
dc/dt represents the rate of change of the concentration of the contaminant over
time,
c represents the concentration of the contaminant,
k is the rate constant for the hydrolysis reaction.
43. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Ion exchange , Precipitation , filtration , chemical and biological oxidation
reduction ,Hydrolysis,…..
Shows a diagram or graph related to the hydrolysis of chlorinated alkyl compounds.
Hydrolysis is a chemical reaction in which water is used to break down a compound into
smaller molecules. Chlorinated alkyl compounds are organic compounds that contain both
chlorine and alkyl groups. These compounds are often used in industrial processes and can
be harmful to the environment if not properly disposed of.
44. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Ion exchange , Precipitation , filtration , chemical and biological oxidation
reduction ,Hydrolysis,…..
shows the reduction of sorption by
cosolvation. Sorption is the process
of a substance being absorbed or
adsorbed by another substance. In
this case, it refers to the adsorption
of a solute (the substance being
dissolved) onto a solid surface.
Cosolvation is the process of adding
a second solvent to a solution to
change its properties.
45. 3- Fate of contaminants in the Subsurface
By Ab.W.Ahmadi
Ion exchange , Precipitation , filtration , chemical and biological oxidation
reduction ,Hydrolysis,…..
Information about the effect of the distribution coefficient on contaminant retardation
during transport in a shallow groundwater flow system. The distribution coefficient,
denoted by
46. 4- Atmospheric transport and dispersion of cont..
By Ab.W.Ahmadi
The atmospheric transport and dispersion of contaminants refers to the movement
and spreading of pollutants or contaminants in the Earth's atmosphere.
Emission: Contaminants are released into the atmosphere through various
sources, including industrial emissions, vehicular exhaust, combustion
processes, and natural sources such as volcanoes or forest fires.
Atmospheric Transport: Contaminants can be transported over long distances
by wind currents and atmospheric circulation patterns.
Atmospheric Chemistry: During atmospheric transport, contaminants may
undergo chemical reactions. For example, volatile organic compounds (VOCs)
can react with other atmospheric constituents, leading to the formation of
secondary pollutants such as ozone or aerosols.
Environmental Impacts: .It can have environmental impacts, such as air
pollution, degradation of air quality, and deposition of contaminants onto land
or water bodies. These impacts can affect ecosystems, human health, and the
overall environmental balance.
47. 4- Atmospheric transport and dispersion of cont..
By Ab.W.Ahmadi
The Gaussian equation is commonly used in air quality modeling and assessment to estimate
the impact of pollutants released from point sources on surrounding areas.
The Gaussian equation
48. 4- Atmospheric transport and dispersion of cont..
By Ab.W.Ahmadi
Source types and volume area sources
The calculation of plume rise
involves estimating the
vertical dispersion and
elevation of a pollutant
plume released from a
source.
The plume rise is influenced
by various factors, including
the release characteristics,
meteorological conditions,
and the physical properties
of the pollutant.
Step 2 step of estimating dispersion, the focus is on calculating the dispersion of
contaminants in the environment.
This involves using meteorological data and dispersion models to determine how
pollutants disperse and spread in the surrounding area.
49. 4- Atmospheric transport and dispersion of cont..
By Ab.W.Ahmadi
Estimation of contaminants concentration
50. 4- Atmospheric transport and dispersion of cont..
By Ab.W.Ahmadi
Computer Modeling and Chemical transportation and deposition
Computer modeling allows us to estimate the behavior of
pollutants in the air.
Using computer models, we can estimate the concentrations of
pollutants at different locations in the atmosphere.
Models help us identify areas and hotspots that are particularly
affected by pollution.
Computer modeling is used in assessing the impacts of air
pollution on human health and the environment.
With computer models, we can examine and evaluate strategies
for air pollution control.
51. Conclusion
By Ab.W.Ahmadi
1. The fate and transport of contaminants play a crucial role in understanding
their behavior and potential impacts on the environment and human health.
2. Various processes such as sorption, precipitation, hydrolysis, and biological
transformation influence the fate of contaminants, determining their
distribution and persistence in different environmental compartments.
3. Transport mechanisms, including advection, diffusion, and dispersion,
govern the movement of contaminants in air, water, and soil, affecting their
spatial and temporal distribution.
4. Computer modeling provides a valuable tool for estimating and predicting
the fate and transport of contaminants, allowing for better risk assessment
and informed decision-making in pollution management.
5. It is essential to study and monitor the fate and transport of contaminants to
develop effective strategies for pollution prevention, remediation, and the
protection of ecosystems and human populations.