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AEEE –Past papers,[object Object],CHEMISTRY - UNSOLVED PAPER - 2006,[object Object]
SECTION – I,[object Object],Straight Objective Type,[object Object],This section contains  multiple choice questions numbered  55 . Each question has 4 choices (A), (B), (C) and (D), out of   which ONLY ONE is correct.,[object Object]
01,[object Object],Problem,[object Object],HBr reacts with CH2 = CH – OCH3 under anhydrous conditions at room temperature to give,[object Object],CH3CHO and CH3Br,[object Object], BrCH2CHO and CH3OH,[object Object],BrCH2 – CH2 – OCH3,[object Object], H3C – CHBr – OCH3,[object Object]
Problem,[object Object],02,[object Object],The IPUAC name of the compound shown below is :,[object Object], ,[object Object],2-bromo-6-chlorocyclohex-1-ene,[object Object],6-bromo-2-chlorocyclohexene,[object Object],3-bromo-1-chlorocyclohexene,[object Object],1-bromo-3-chlorocyclohexene,[object Object]
Problem,[object Object],03,[object Object],The increasing order of the rate of HCN addition to compounds A-D is : ,[object Object],HCHO,[object Object],CH3COCH3,[object Object],PhCOCH3,[object Object],PhCOPh,[object Object],A < B < C < D,[object Object],D < B < C < A,[object Object],D < C < B < A,[object Object],C < D < B < A,[object Object]
Problem,[object Object],04,[object Object],How many moles of magnesium phosphate, Mg3(PO4)2 will contain 0.25 mole of oxygen atoms ? ,[object Object], ,[object Object],0.02 ,[object Object],3.125 x 10-2,[object Object],1.25 x 10-2,[object Object],2.5 x 10-2,[object Object]
Problem,[object Object],05,[object Object],According to Bohr’s theory, he angular momentum of an electron in 5th orbit is : ,[object Object], ,[object Object],25,[object Object],b.   1.0 ,[object Object],c.   10 ,[object Object],d.  2.5,[object Object]
Problem,[object Object],06,[object Object],Which of the following molecules/ions does not contain unpaired electrons ? ,[object Object], ,[object Object],O ,[object Object],B2,[object Object],N ,[object Object],O2 ,[object Object]
Problem,[object Object],07,[object Object],Total volume of toms present in a face-centred cubic unit cell of metal is (r is atomic radius) :,[object Object],a.,[object Object],b.,[object Object],c.,[object Object],d.,[object Object]
Problem,[object Object],08,[object Object],A reaction was found to be second order with respect to the concentration of carbon monoxide. If the concentration of carbon monoxide. If the concentration of carbon monoxide is doubled, with everything else kept the same, the rate of reaction will: ,[object Object], ,[object Object],Remain unchanged ,[object Object],Triple ,[object Object],Increases by a factor of 4 ,[object Object],Double ,[object Object]
Problem,[object Object],09,[object Object],Which of the following chemical reactions depicts the oxidizing behaviour of H2SO4 ? ,[object Object], ,[object Object],2HI + H2SO4 I2 + SO2 + 2H2O,[object Object],Ca(OH)2 + H2SO4  CaSO4 + 2H2O,[object Object],NaCl + H2SO4  NaHSO4 + HCl,[object Object],2PCl5 + H2SO4  2POCl3 + 2HCl + SO2Cl2,[object Object]
Problem,[object Object],10,[object Object],The IUPAC name for he complex [Co(NO2)(NH3)5]Cl2 is : ,[object Object],Nitrite-N-pentaminecobalt (III) chloride,[object Object],Nitrite-N-pentamminecobalt (II) chloride,[object Object],Pentammine nitrite-N-cobalt (II) chloride,[object Object],Pentaamine nitrite-N-cobalt (III) chloride,[object Object]
Problem,[object Object],11,[object Object],The term anomers of glucose refers to : ,[object Object], Isomers of glucose that differ configuration at carbons one and four (C-1 and C - 4),[object Object],A mixture of (D)-glucose and  (L)- glucose ,[object Object],Enantiomers of glucose ,[object Object],Isomers of glucose that differ in configuration at carbon one (C - 1),[object Object]
Problem,[object Object],12,[object Object],In the transformation of                               if one emission is an -particle, what should be the other emission (s) ? ,[object Object], ,[object Object],Two -β,[object Object],Two -βand one + β,[object Object],One β and one ,[object Object],One β and one β,[object Object]
Problem,[object Object],13,[object Object],Phenyl magnesium bromide reacts with methanol to give :,[object Object],A mixture of anisol and Mg(OH)Br,[object Object],A mixture of benzene and Mg(OMe)Br,[object Object],A mixture of toluence and Mg(OH)Br,[object Object],A mixture Phenol and Mg (Me)Br,[object Object]
Problem,[object Object],14,[object Object],                                                  The decreasing order of the rate of the above reaction with nucleophiles (Nu-) A to D is :  [Nu- = (A) PhO-, (B)AcO-, (C) HO-, (D) CH3O-],[object Object], ,[object Object],D > C > A < B,[object Object],D > C > B > A,[object Object],A > B > C > D,[object Object],B > D > C > A,[object Object]
Problem,[object Object],15,[object Object],The pyrimidine bases present in DNA are : ,[object Object], ,[object Object],Cytosine and adenine ,[object Object],Cytosine and guanine ,[object Object],Cytosine and thymine ,[object Object],Cytosine and uracil,[object Object]
Problem,[object Object],16,[object Object],Among the following the one that gives positive iodoform test upon reaction with I2 and NaOH is : ,[object Object],a. CH3CH2CH(OH)CH2CH3,[object Object],b.  C6H5CH2CH2OH ,[object Object],PhCHOHCH3,[object Object],  ,[object Object]
Problem,[object Object],17,[object Object],The increasing order of stability of the following free radicals is : ,[object Object], ,[object Object],(CH3)2     H < (CH3)3 < (C6H5)2     H  < (C6H5)3,[object Object],(C6H5)3 (C6H5)2     H< (CH3)3  < (CH3)2     H,[object Object],(C6H5)2     H<(C6H5)3 <(CH3)3  < (CH3)2    H,[object Object],(CH3)2      H < (CH3)3 < (C6H5)3  < (C6H5)2     H,[object Object]
Problem,[object Object],18,[object Object],Uncertainty in the position of an electron (mass  = 9.1 x 10-31 kg) moving with a velocity 300 ms-1, accurate upon 0.001% will be : ,[object Object], ,[object Object],19.2 x 10-2 m,[object Object],5.76 x 10-2 m,[object Object],1.92 x 10-2 m,[object Object],3.84 x 10-2 m,[object Object],(h= 6.63 x 10-34 Js),[object Object]
Problem,[object Object],19,[object Object],Phosphorus pentachloride dissociates as follows, in a closed reaction vessel,          ,[object Object],                                                                  If total pressure at equilibrium of the reaction mixture is P and degree of dissociation of PCl5 is x, the partial pressure of PCl3 will be: ,[object Object],a.,[object Object],b.,[object Object],c.,[object Object],d.,[object Object]
Problem,[object Object],20,[object Object],The standard enthalpy of formation                at 298 K for methane, CH4(g), is -78.4 kJ mol-1. The additional information required to determine the average energy for C-H bond formation would be: ,[object Object], ,[object Object],The dissociation energy of H2 and enthalpy of sublimation of carbon ,[object Object],Latent heat of vaporization of methane ,[object Object],The first four ionization energies of carbon and electron gain enthalpy of hydrogen ,[object Object],The dissociation energy of hydrogen molecule, H2,[object Object]
Problem,[object Object],21,[object Object],Among the following mixtures, dipole-dipole as the major interaction, is present in: ,[object Object], ,[object Object],Benzene and ethanol ,[object Object],Acetonitrile and acetone ,[object Object],KCl and water ,[object Object],Benzene and carbon tetrachloride ,[object Object]
Problem,[object Object],22,[object Object],Fluorobenzene (C6H5F) can be synthesized in the laboratory: ,[object Object], ,[object Object],By heating phenol with HF and KF,[object Object],From aniline by diazotization followed by heating the diazonium salt with HBF4,[object Object],By direct fluorination of benzene with F2 gas ,[object Object],By reacting bromobenzene with NaF solution ,[object Object]
Problem,[object Object],23,[object Object],A metal, M forms chlorides in its + 2 and  + 4 oxidation states. Which of the following statements about these chlorides is correct? ,[object Object], ,[object Object],MCl2 is more volatile than MCl4,[object Object],MCl2 is more soluble in anhydrous ethanol than MCl4,[object Object],MCl2 is more ionic than MCl4,[object Object],MCl2 is more easily hydrolysed than MCl4,[object Object]
Problem,[object Object],24,[object Object],Which of the following statement is true ? ,[object Object], ,[object Object],H3PO3 is stronger acid than H2SO3­,[object Object],In aqueous medium HF is a stronger acid than HCl,[object Object],HClO4 is a weaker acid than HClO3,[object Object],HNO3 is a stronger acid than HNO2,[object Object]
Problem,[object Object],25,[object Object],The molar conductivities                                   at infinite dilution in water at 250C are 91.0 and 426.2 S cm2/ mol respectively. To calculate                 the additional value required is: ,[object Object],a.,[object Object],b.,[object Object],c.,[object Object],d.,[object Object]
Problem,[object Object],26,[object Object],Which one of the following sets of ions represents a collection of isoelectronic species ? ,[object Object], ,[object Object],K+, Cl-, Ca2+, Sc3+,[object Object],Ba2+, Sr2+, K+, S2-,[object Object],N3-, O2-, F-, S2-,[object Object],Li+, Na+, Mg2+, Ca2+,[object Object]
Problem,[object Object],27,[object Object],The correct order of increasing acid strength of the compounds: ,[object Object],CH2CO2H,[object Object],MeOCH2CO2H,[object Object],CF3CO2H,[object Object], ,[object Object],B < D < A < C,[object Object],D < A < C < B,[object Object],D < A < B < C,[object Object],A < D < C < B,[object Object]
Problem,[object Object],28,[object Object],In which of the following molecules/ions all the bonds are not equal? ,[object Object], ,[object Object],SF4,[object Object],SiF4,[object Object],XeF4,[object Object],BF4,[object Object]
Problem,[object Object],29,[object Object],What products are expected from the disproportionation reaction of hypochlorous acid? ,[object Object], ,[object Object],HClO3 and Cl2O,[object Object],HClO2 and HClO4,[object Object],HCl and Cl2O,[object Object],HCl and HClO3,[object Object]
Problem,[object Object],30,[object Object],Nickel (Z = 28) combines with a uninegativemonodentateligand X- to form a paramagnetic complex [NiX4]2-. The number of unpaired electron(s) in the nickel and geometry of this complex ion are respectively : ,[object Object], ,[object Object],One, tetrahedral ,[object Object],Two, tetrahedral,[object Object],One, square planar ,[object Object],Two, square planar ,[object Object]
Problem,[object Object],31,[object Object],In Fe(CO)s, the Fe-C bond possesses:,[object Object], ,[object Object],    Character only ,[object Object],Both     and     characters ,[object Object],Ionic character ,[object Object],    Character only ,[object Object]
Problem,[object Object],32,[object Object],The increasing order of the first ionization enthalpies of the elements B, P, S and F (lowest first) is : ,[object Object], ,[object Object],F < S < P < B,[object Object],P < S < B < F,[object Object],B < P < S < F,[object Object],B < S < P < F,[object Object]
Problem,[object Object],33,[object Object],An ideal gas is allowed to expand both reversibly and irreversibly in an isolated system, If Ti is the initial temperature and Tf is the final temperature, which of the following statements is correct ? ,[object Object], ,[object Object],(Tf)irrev > (Tf)rev,[object Object],Tf > Ti for reversible process but Tf = Ti for irreversible process ,[object Object],(Tf)rev = (Tf)irrev,[object Object],Tf = Ti for both reversible and irreversible ,[object Object]
Problem,[object Object],34,[object Object],In languir’s model of adsorption of a gas on a solid surface : ,[object Object], ,[object Object],The rate of dissociation of adsorbed molecules from the surface does not depend on the surface covered ,[object Object],The adorption at a single site on the surface may involve multiple molecules at the same time ,[object Object],The mass of gas striking a given area of surface is proportional to the pressure of the gas ,[object Object],The mass of gas striking a given area of surface is independent of the pressure of the gas ,[object Object]
Problem,[object Object],35,[object Object],Rate of a reaction can be expressed by Arrhenius equation as: k = A e−E /RT  In this equation, E represents,[object Object],the energy above which all the colliding molecules will react,[object Object],the energy below which colliding molecules will not react,[object Object],the total energy of the reacting molecules at a temperature, T,[object Object],the fraction of molecules with energy greater than the activation energy of the reaction,[object Object]
Problem,[object Object],36,[object Object],The structure of the major product formed in the following reaction is : ,[object Object],a.,[object Object],b.,[object Object],c.,[object Object],d.,[object Object]
Problem,[object Object],37,[object Object],Reaction of  trans-2-phenyl-1-bromocyclopentane on reaction with alcoholic KOH produces:  ,[object Object],4-phenylcyclopentene,[object Object],2-phenylcylocpentene ,[object Object],1-phenylcylopentene ,[object Object],3-phenylcylopentene,[object Object]
Problem,[object Object],38,[object Object],Increasing order of stability among the three main conformations (i.e., Eclipse, Anti, Gauche) of 2-fluoroethanol is : ,[object Object], ,[object Object],Eclipse, Gauche, Anti ,[object Object],Gauche, Eclipse, Anti,[object Object],Eclipse, Anti, Gauche,[object Object],Anti, Gauche, Eclipse ,[object Object]
Problem,[object Object],39,[object Object],The structure of the compound that gives a tribromo derivative on treatment with bromine water is,[object Object],a.,[object Object],b.,[object Object],c.,[object Object],d.,[object Object]
Problem,[object Object],40,[object Object],The decreasing values of bond angles form NH3(1060) to SbH3(1010) down group-15 of the periodic table is due to: ,[object Object], ,[object Object],Increasing bp-bp repulsion ,[object Object],Increasing p-orbital character in sp3,[object Object],Decreasing lp-bp repulsion ,[object Object],Decreasing electronegativity ,[object Object]
Problem,[object Object],41,[object Object],The alkene formed as a major product in the above elimination reaction is ,[object Object], The ‘spin-only’ magnetic moment [in units of Bohr magneton, ( )] of Ni2+ in aqueous solution would be (Atomic number of Ni  = 28) :,[object Object],a.				b.,[object Object],c.				d.,[object Object], ,[object Object]
Problem,[object Object],42,[object Object],The ‘spin – only’ magnetic moment in uints of Bohr magneton, of Ni2+ in aueous solution would be (automatic number of Ni =28):,[object Object],2.84,[object Object],4.90,[object Object],0,[object Object],1.73,[object Object]
Problem,[object Object],43,[object Object],The equilibrium constant for the reaction                                                           is ,[object Object],Kc= 4.9 x 10-2. The value of Kc for the reaction                                            will be: ,[object Object], ,[object Object],416,[object Object],2.40 x 10-3,[object Object],9.8 x 10-2,[object Object],4.9 x 10-2,[object Object]
Problem,[object Object],44,[object Object],Following statements regarding the periodic trends of chemical reactivity of the alkali metals and the halogens are given. Which of these statements gives the correct picture? ,[object Object], ,[object Object],The reactivity decreases in the alkali metals but increases in the halogens with increase in atomic number down the group ,[object Object],In both the alkali metals and the halogens the chemical reactivity decreases with increase in atomic number down the group ,[object Object],Chemical reactivity increases with increase in atomic number down the group in both the alkali metals and halogens ,[object Object],In alkali metals the reactivity increases but in the halogens it decreases with increase in atomic number down the group,[object Object]
Problem,[object Object],45,[object Object],Given the data at 250C,,[object Object],Ag + I-AgI + e-	; 		E0 = 0.152 V,[object Object],Ag  Ag+ +  e - 	; 		E0 = - 0.800 V,[object Object],What is the value of log Ksp for AgI ?  ,[object Object],-8.12,[object Object],+ 8.612,[object Object],- 37.83,[object Object],- 16.13,[object Object]
Problem,[object Object],46,[object Object],The following mechanism has been proposed for the reaction of NO with Br2 to form NOBr: ,[object Object],NO(g) + Br2(g)             NOBr2 (g),[object Object],NOBr2 (g) + NO (g)         2NOBr(g),[object Object],If the second step is the rate determining step, the order of the reaction with respect to NO (g) is :,[object Object], ,[object Object],1,[object Object],0,[object Object],3,[object Object],2,[object Object]
Problem,[object Object],47,[object Object],Lanthanoid contraction is caused due to : ,[object Object], ,[object Object],The appreciable shielding on outer electrons by 4f electrons from the nuclear charge ,[object Object],The appreciable shielding on outer electrons by 5d electrons from the nuclear charge ,[object Object],The same effective nuclear charge from Ce to Lu,[object Object],The imperfect shielding on outer electrons by 4f electrons from the nuclear charge,[object Object]
Problem,[object Object],48,[object Object],Resistance of a conductivity cell filled with a solution of an electrolyte of concentration 0.01 M is 100 . The conductivity of this solution is 1.29 S m-1. Resistance of the same cell when filled with 0.2 M of the same solution is 520 . The molar conductivity of 0.02 M solution of the electrolyte will be : ,[object Object], ,[object Object],124 x 10-4 S m2 mol-1,[object Object],1240 x 10-4 S m2 mol-1,[object Object],1.24 x 10-4 S m2 mol-1,[object Object],12.4 x 10-4 S m2 mol-1,[object Object]
Problem,[object Object],49,[object Object],The ionic mobility of alkali metal ions in aqueous solution is maximum for : ,[object Object], ,[object Object],K+,[object Object],Rb+,[object Object],Li+,[object Object],Na+,[object Object]
Problem,[object Object],50,[object Object],Density of a 2.05 M solution of acetic acid in water is 1.02 g/ml. The molality of the solution is  : ,[object Object], ,[object Object],1.14 mol kg-1,[object Object],3.28 mol kg-1,[object Object],2.28 mol kg-1,[object Object],0.44 mol kg-1,[object Object]
Problem,[object Object],51,[object Object],The enthalpy changes for the following processes are listed below :,[object Object],Cl2(g)  = 2Cl(g),  242.3 kJ mol-1,[object Object],I2(g)  = 2I (g), 151.0 kJ mol-1,[object Object],ICl (g) = I (g) + Cl (g), 211.3 kJ mol-1,[object Object],I2(s) = I2 (g), 62.76 kJ mol-1,[object Object],Given that the standard states for iodine and chlorine are I2(s) and Cl2(g), the standard enthalpy of formation of ICI (g) is : ,[object Object], ,[object Object],- 14.6 kJ mol-1,[object Object],-16.8 kJ mol-1,[object Object],+ 16.8 kJ mol-1,[object Object],+ 244.8 kJ mol-1,[object Object]
Problem,[object Object],52,[object Object],How many EDTA (ethylenediaminetetra acetic acid) molecules are required to make an octanhedral complex with a Ca2+ ion? ,[object Object], ,[object Object],Six ,[object Object],Three,[object Object],One ,[object Object],Two ,[object Object]
Problem,[object Object],53,[object Object],The electrophile involved in the above reaction is :,[object Object], ,[object Object],Dichloromethylcation ( HCl2),[object Object],Dichlorocarbene (: CCl2),[object Object],Trichloromethyl anion (    Cl2),[object Object],Formylcation ( HO),[object Object]
Problem,[object Object],54,[object Object],18 g of glucose (C6H12O6) is added to 178.2 g of water. The vapour pressure of water for this aqueous solution at 1000C is : ,[object Object], ,[object Object],759.00 torr,[object Object],7.60 torr,[object Object],76.00 torr,[object Object],752.40 torr,[object Object]
Problem,[object Object],55,[object Object],                             for the formation of carbon monoxide (CO) from its elements at 298 K is :  (R = 8.314 JK-1 mol-1),[object Object], ,[object Object],-1238.78 J mol-1,[object Object],1238.78 J mol-1,[object Object],-2477.57 J mol‑1,[object Object],2477.57 J mol-1,[object Object]
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