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SNG: A Renewable,
 Regional Biofuel.
  Looking at Possible Markets



        Thomas Cheney
      cheney (at) unbc.ca
What is SNG
● SNG stands for synthetic natural gas created
  by anerobic digestion or methanization of
  gasified wood .

● Renewable Power Methane is a related
  product

● Can be used in existing natural gas
  infrastructure.
Objectives
                                           ● Introduce SNG
                                             production methods

                                           ● SNG uses

                                           ● SNGs role as energy
                                             currency in
                                             renewable energy
1 MW SNG production facility at Gussing,
Austria                                      system
How SNGis Made from
Wood
Feedstock        Gasification       Gas
                                Gasification
Pre-treatment                       Cleaning




                CO2               Gas Grid
   Methaniz     removal,
   ation        Compression
SNG Markets
                          ● Space and Water
                            Heating
                            ○ Existing gas furnaces
                            ○ Peak load for alternative
                              fuel systems
                          ● Power Generation
                            ○ intermittent
                            ○ peak load
www.energy.alberta.ca -
                          ● Vehicle Fuels
                            ○ Liquified bionatural gas
                            ○ Compressed bionatural gas
Energy Efficiency
              ● 60-70+% wood to SNG
                on LHV basis)
              ● ~ 90% including
                cogeneration (
              ● 10-15 % higher than
                biomass to liquids
                efficiency (GM2012)
              ● Potential for
                polygeneration
              ● Allothermal and
                autothermal
From ECN
              ● Low temperature
                gasification for efficient
              ~850 C
Allothermal vs Autothermal




gasification heat                         gasification heat
produced outside of the                   produced inside
gasifier                                  the gasifier
         Diagrams from Gassner and Marechal
         (2012)
Two Allothermal Design
philosophies
Swiss-Austrian                                 Dutch

● Steam Assisted                               ● Uses simple low-steam
    gasification                                     content, gasification
                                                     system
●   reforming tars in
    gasification                               ●     Needs better tar cleaning
                                                     system
●   Biodiesel gas cleaning
    requires cleaner gas                       ●     6% higher modeled SNG
    ○ less efficient process                         production efficiency.
        due to steam content

       http://www.ecn.nl/docs/library/report/2010/m10050.pdf
Allothermal Gasification
              ● Higher capital costs
                    ○ $927-$1755 /KWth
                    ○ complex system
                    ○ lower pressures to allow for
                      heat transfer by fluidization
                      medium
              ● Slightly lower efficiency
              ● Based on avoiding
                requirement for oxygen
                generation on site.

          Photo: www.aer-gas.de/index.php?l=C&m=A
Allothermal Gasification process in
Gassner and Marechal 2012
Autothermal CFB
Gasification
● Lower capital cost
   ○ $1240-$521/KWth
   ○ Simpler system
   ○ pressurized gasification and higher methanization
     pressure
● Requires oxygen supply
● Slightly higher efficiency than allothermal
  systems
Autothermal Gasifier




From Gassner and Marechal (2012)
SNG Production Prices $/GJ
               Low Wood Cost   High Wood Cost


5 MW CFB       $26.42          $33.23

20 MW CFB      $18.76          $25.56

100 MW CFB     $13.48          $19.62

5 MW FICFB     $32.42          $39.45

20 MW FICFB    $22.25          $29.28

100 MW FICFB   $18.08          $24.81

Larger and autothermal plants have lower
costs. Based on Gassner and Marechal (2012)
and adapted to British Columbian conditions
ButSNG is so expensive!
                                        A carbon price of
                                        $100 per tonne
                                        CO2 increases
                                        the cost of
                                        natural gas by $5
                                        per GJ




Only when the costs of the carbon dioxide climate damage are
ignored (Ackerman and Stanton, 2004)
SNG With Carbon Tax
$ emissions        low wood cost   High wood costs
mitigations cost

5 MW CFB           $388.49         $524.54

20 MW CFB          $235.12         $371.16

100 MW CFB         $129.51         $252.39

5 MW FICFB         $508.36         $648.95

20 MW FICFB        $305.09         $445.69

100 MW FICFB       $221.64         $356.11
Biofuels $/TCO2 Reduction

   SNG has
   competitive
   mitigation                                                                  S
                                                                               N
   costs                                                                       G




From Fulton et al. (2004) Biofuels for Transportation. http://www.cti2000.it/Bionett/All-2004-004%20IEA%20biofue
20report.pdf
GHG Effects of SNG
                     ● Carbo et al (2011)
                       found significant
                       potential to combine
                       CCS with carbon
                       capture and storage
                     ● Net negative CO2
                       when combined with
www.climate101.org
                       carbon capture and
                       storage
Methane Leakage
● Depends on the quality of the grid

● Life-cycle analysis of shale gas and natural
  gas suggests limited impact of methane
  emissions from transmission.
Natural gas has better than
GHG balance than coal!




Biomethane has even lower seeing role of
combustion GHG
SNG USES




  © Lasse Hejdenberg/Hejdlösabilder
With SNG any natural gas
bus can be a biogas bus
Buses
        ● Natural gas buses are
          widely used
        ● 150 units in Canada
        ● $45,000 Capital
          premium




        Source: Marbek (2010)
Truck
        ● 700- 900 miles range
        ● $70,000 more
          expensive capital costs
        ● Spark ignition and
          HPDI (natural
          gas/diesel mixture)
          ○ spark ignition 10% less fuel
            economy.
          ○ or 5% diesel mixture
Marine
    Traffic
                                             LNG MS Stavangerfjord




●   LNG becoming popular as a marine fuel due to large
    mobile "point" source of demand.
●   Ferry in operation in Norway
●   Considered by BC Ferries (BC ferries uses 118 Million
    liters of diesel p/.a) and Washington State Ferries
Norwegian LNG Ferry




http://baltictransportjournal.com/poland/last-of-four-lng-ferries-for-torghattan-nord,23.html
Rail LNG LOCOS




CN Rail exploring LNG propulsion
Biogas Train in Sweden




               Retrofit cost of 1 Million Euro
               1.3 Million $ Canadian


               fr.wikipedia.org
Power generation




www.ecomagination.com
SNG Electricity generation
● SNG works in existing natural gas generators
  and turbines
● Can provide flexible low capital cost biomass
  power
● Natural gas turbines cost 1.2 Mil Canadian
  per MW.

http://www.emr.gov.yk.ca/oilandgas/pdf/eagleplain_.pdf
Renewable Power Methane




http://www.iwes.fraunhofer.
de/de/publikationen/uebersicht/2010/towards_100_integrationofresimulationscenariosandstoragebylinkin/_jcr_cont
ent/pressrelease/linklistPar/download/file.res/2010-049_Towards-Integration_NREL.pdf
Peak Load Heating
                                  ● Technological and Economic
                                      barriers
                                  ●   Biomass boilers high capital
                                      costs
                                      ○ 5 MWth $ 600 per KWth
                                      ○ Nat Gas. $196 per KWth




https://encrypted-tbn3.gstatic.com/images?q=tbn:
ANd9GcRcml0wFkH4yJA2uYFq0Y546UUP55zcHFktcBeUARpm_v1CQ9uO
Challenges with biomass
 systems
                            ● Turndown Ratio
                              ○ Max prod: Min Prod


                            ● Typically 3:1
                              ○ Load variation much
                                greater
http://www.riebenbauer.at     ○ Long start up time for
                                solid biomass systems
                                makes load following by
                                start up and shutdown
                                unfeasible
Food vs Fuel?
Heat Pump System Limits
            ● High capital cost
            ● Air source units have
              much lower heat
              production at low
              temperatures
            ● natural gas backup and
              peaking
              ○ SNG can replace fossil
                natural gas
SNG Heating
        ● SNG Heating can work
          where natural gas works,
          due to quick start-up of
          boilers and furnaces
        ● SNG is expensive so other
          options will likely make
          sense for baseload!
Flying on Liquified NG?
XB-70




        Boeing SUGAR Freeze
LNG vs Hydrogen
    LBM greater energy storage density
·      Liquid Biomethane 22.2 MJ/L
·      Liquid Hydrogen 8.5 MJ/L
    Liquid hydrogen better energy KG/Mass
·      Liquid Biomethane 53.6 MJ/KG
·      Liquid Hydrogen 141.6 MJ/KG

    LBM is a better fuel choice when volume is limited.
The decarbonization Triangle
          e-
              Various energy
              currencies    CO2

                            H2O
                            O2




CH4                                                  H2
              4H2 + CO2                      CH4 + 2H2O
 Muradov (2013),   DOI: 10.1039/c3ee22879g
Conclusion
SNG offers
● energy efficient biofuel production
● Second generation biofuel
● Transportation, heating and power
  generation fuel
● Low emissions
● Existing infrastructure
● Integration with Wind, Water Solar sources
  through Renewable Power Methane.
Future Gas Well?
     Fu




     Thanks!

www.us.all.biz -

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SNG: A Renewable, Regional Biofuel

  • 1. SNG: A Renewable, Regional Biofuel. Looking at Possible Markets Thomas Cheney cheney (at) unbc.ca
  • 2. What is SNG ● SNG stands for synthetic natural gas created by anerobic digestion or methanization of gasified wood . ● Renewable Power Methane is a related product ● Can be used in existing natural gas infrastructure.
  • 3. Objectives ● Introduce SNG production methods ● SNG uses ● SNGs role as energy currency in renewable energy 1 MW SNG production facility at Gussing, Austria system
  • 4. How SNGis Made from Wood Feedstock Gasification Gas Gasification Pre-treatment Cleaning CO2 Gas Grid Methaniz removal, ation Compression
  • 5. SNG Markets ● Space and Water Heating ○ Existing gas furnaces ○ Peak load for alternative fuel systems ● Power Generation ○ intermittent ○ peak load www.energy.alberta.ca - ● Vehicle Fuels ○ Liquified bionatural gas ○ Compressed bionatural gas
  • 6. Energy Efficiency ● 60-70+% wood to SNG on LHV basis) ● ~ 90% including cogeneration ( ● 10-15 % higher than biomass to liquids efficiency (GM2012) ● Potential for polygeneration ● Allothermal and autothermal From ECN ● Low temperature gasification for efficient ~850 C
  • 7. Allothermal vs Autothermal gasification heat gasification heat produced outside of the produced inside gasifier the gasifier Diagrams from Gassner and Marechal (2012)
  • 8. Two Allothermal Design philosophies Swiss-Austrian Dutch ● Steam Assisted ● Uses simple low-steam gasification content, gasification system ● reforming tars in gasification ● Needs better tar cleaning system ● Biodiesel gas cleaning requires cleaner gas ● 6% higher modeled SNG ○ less efficient process production efficiency. due to steam content http://www.ecn.nl/docs/library/report/2010/m10050.pdf
  • 9. Allothermal Gasification ● Higher capital costs ○ $927-$1755 /KWth ○ complex system ○ lower pressures to allow for heat transfer by fluidization medium ● Slightly lower efficiency ● Based on avoiding requirement for oxygen generation on site. Photo: www.aer-gas.de/index.php?l=C&m=A
  • 10. Allothermal Gasification process in Gassner and Marechal 2012
  • 11. Autothermal CFB Gasification ● Lower capital cost ○ $1240-$521/KWth ○ Simpler system ○ pressurized gasification and higher methanization pressure ● Requires oxygen supply ● Slightly higher efficiency than allothermal systems
  • 12. Autothermal Gasifier From Gassner and Marechal (2012)
  • 13. SNG Production Prices $/GJ Low Wood Cost High Wood Cost 5 MW CFB $26.42 $33.23 20 MW CFB $18.76 $25.56 100 MW CFB $13.48 $19.62 5 MW FICFB $32.42 $39.45 20 MW FICFB $22.25 $29.28 100 MW FICFB $18.08 $24.81 Larger and autothermal plants have lower costs. Based on Gassner and Marechal (2012) and adapted to British Columbian conditions
  • 14. ButSNG is so expensive! A carbon price of $100 per tonne CO2 increases the cost of natural gas by $5 per GJ Only when the costs of the carbon dioxide climate damage are ignored (Ackerman and Stanton, 2004)
  • 15. SNG With Carbon Tax $ emissions low wood cost High wood costs mitigations cost 5 MW CFB $388.49 $524.54 20 MW CFB $235.12 $371.16 100 MW CFB $129.51 $252.39 5 MW FICFB $508.36 $648.95 20 MW FICFB $305.09 $445.69 100 MW FICFB $221.64 $356.11
  • 16. Biofuels $/TCO2 Reduction SNG has competitive mitigation S N costs G From Fulton et al. (2004) Biofuels for Transportation. http://www.cti2000.it/Bionett/All-2004-004%20IEA%20biofue 20report.pdf
  • 17. GHG Effects of SNG ● Carbo et al (2011) found significant potential to combine CCS with carbon capture and storage ● Net negative CO2 when combined with www.climate101.org carbon capture and storage
  • 18. Methane Leakage ● Depends on the quality of the grid ● Life-cycle analysis of shale gas and natural gas suggests limited impact of methane emissions from transmission.
  • 19. Natural gas has better than GHG balance than coal! Biomethane has even lower seeing role of combustion GHG
  • 20. SNG USES © Lasse Hejdenberg/Hejdlösabilder
  • 21. With SNG any natural gas bus can be a biogas bus
  • 22. Buses ● Natural gas buses are widely used ● 150 units in Canada ● $45,000 Capital premium Source: Marbek (2010)
  • 23. Truck ● 700- 900 miles range ● $70,000 more expensive capital costs ● Spark ignition and HPDI (natural gas/diesel mixture) ○ spark ignition 10% less fuel economy. ○ or 5% diesel mixture
  • 24. Marine Traffic LNG MS Stavangerfjord ● LNG becoming popular as a marine fuel due to large mobile "point" source of demand. ● Ferry in operation in Norway ● Considered by BC Ferries (BC ferries uses 118 Million liters of diesel p/.a) and Washington State Ferries
  • 26. Rail LNG LOCOS CN Rail exploring LNG propulsion
  • 27. Biogas Train in Sweden Retrofit cost of 1 Million Euro 1.3 Million $ Canadian fr.wikipedia.org
  • 29. SNG Electricity generation ● SNG works in existing natural gas generators and turbines ● Can provide flexible low capital cost biomass power ● Natural gas turbines cost 1.2 Mil Canadian per MW. http://www.emr.gov.yk.ca/oilandgas/pdf/eagleplain_.pdf
  • 31. Peak Load Heating ● Technological and Economic barriers ● Biomass boilers high capital costs ○ 5 MWth $ 600 per KWth ○ Nat Gas. $196 per KWth https://encrypted-tbn3.gstatic.com/images?q=tbn: ANd9GcRcml0wFkH4yJA2uYFq0Y546UUP55zcHFktcBeUARpm_v1CQ9uO
  • 32. Challenges with biomass systems ● Turndown Ratio ○ Max prod: Min Prod ● Typically 3:1 ○ Load variation much greater http://www.riebenbauer.at ○ Long start up time for solid biomass systems makes load following by start up and shutdown unfeasible
  • 34. Heat Pump System Limits ● High capital cost ● Air source units have much lower heat production at low temperatures ● natural gas backup and peaking ○ SNG can replace fossil natural gas
  • 35. SNG Heating ● SNG Heating can work where natural gas works, due to quick start-up of boilers and furnaces ● SNG is expensive so other options will likely make sense for baseload!
  • 36. Flying on Liquified NG? XB-70 Boeing SUGAR Freeze
  • 37. LNG vs Hydrogen LBM greater energy storage density · Liquid Biomethane 22.2 MJ/L · Liquid Hydrogen 8.5 MJ/L Liquid hydrogen better energy KG/Mass · Liquid Biomethane 53.6 MJ/KG · Liquid Hydrogen 141.6 MJ/KG LBM is a better fuel choice when volume is limited.
  • 38. The decarbonization Triangle e- Various energy currencies CO2 H2O O2 CH4 H2 4H2 + CO2 CH4 + 2H2O Muradov (2013), DOI: 10.1039/c3ee22879g
  • 39. Conclusion SNG offers ● energy efficient biofuel production ● Second generation biofuel ● Transportation, heating and power generation fuel ● Low emissions ● Existing infrastructure ● Integration with Wind, Water Solar sources through Renewable Power Methane.
  • 40. Future Gas Well? Fu Thanks! www.us.all.biz -