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Thermal Management in Electronic Components –
  Can Polymers Replace Metals or Ceramics?



     Aravind Chander, Senior Research Analyst,
            Technical Insights, Chennai,
                   June 3, 2008
Focus Points
•   Introduction to Thermally Conductive Polymers (TCPs)

•   Technology Challenges and Drivers

•   Current Trends and Future Trends

•   Material Technologies Analysis

•   Technological Innovations in this Arena

•   Key Industry Participants




                                                           2
Introduction


•   Electronic devices are getting smaller and thinner

•   Conventional plastic components overheat often and develop
    localized quot;hot spotsquot;

•   Development of TCP’s has paved way to significant breakthrough
    for thermal management applications as they carry the same
    heat transfer capacity as metals or ceramics

•   TCP’s have good chemical resistance and give up heat faster
    during molding than conventional plastics



                                                                     3
Challenges – Thermally Conductive Polymers
                                                           There is a demand for newer compounds
                                                             that could compete with the existing
                                                                 thermoplastic compositions.      Concern for Passive
                                                                                                  Component Manufacturers
                                                  Thermal                                        high-temperature conditions
         Manufacturing                          Fatigue and                                        for a long period of time
             Cost                                   Heat                                             can damage or change
                                                                             Lack of New            their organic properties.
                                                Dissipation
                                                                               Polymer
                                                                             Compounds
                                                                                                       Elevated
                                                                                                     Temperature
                                             Due to the polymer properties
                                              such as High CTE and Low
  High initial cost is the biggest              Thermal Conductivities.
 obstacle to wider acceptance of                                                    Demand for
thermally conductive compounds.                                                     More Power




                                                                                     The increase in activities of the
  Note: Size of the ball is not related to                                   components has led to demand for more power
   importance or weight of the factor                                         in order to maintain the existing performance.

                                                                                                                          4
Drivers – Thermal Conductive Polymers
 Compounds can be used as
                                                    Polymers can be more easily custom manufactured to a wider range
        encapsulates in
                                                      of sizes and shapes when compared to conventional materials.
     electronic component
                                                   This enables them to be deployed for a broader range of applications.
 packaging making it suitable
for smaller and thinner without              Easy material
        compromising on                      process ability                 Polymers, particularly bio-based polymeric
    mechanical properties.                                                    compounds are gaining importance which
                                                                             can be effectively recycled with no harmful
                                                                                     effect on the environment.
  Miniaturization
  of electronic
  components

                                   Continued
                                    focus on                                                        Recyclability
                                     Weight                           Excellent
                                   Reduction                          Mechanical
                                                                      Properties




     Weight reduction by means of
 using plastics for manufacturing safer,
 lighter and high performance devices.                            Thermally Conductive Polymers
                                                               possess higher flexural strength, tensile
  Note: Size of the ball is not related to                       stiffness, and low-impact strengths.
   importance or weight of the factor

                                                                                                                           5
Current Trends


                            Thermally conductive adhesives
                                for lighting application




                                                             High viscosities make molding
   Custom-molded heat                                           over a large surface area
  sinks on circuit boards                                                difficult

                                       Current
                                       Trends



  Carbon nanofibers and boron
   nitride filler is gaining more                    Laser Diode Encapsulation is in
              attraction                                the developmental phase



                                                                                             6
Future Trends


                            Composites will target flip chips
                             and solder joint applications




  New compounds from                                              Tailorable CTEs with low
  natural resources high                                            manufacturing cost
   temperature stability

                                         Future
                                         Trends




  PCB itself can act as heat sink                        Elastomers is expected to get
                                                               more treatment



                                                                                             7
Parameters for Technology Performance


                            CTE




 Chemical resistance                       Mechanical Strength

                         Technology
                         Performance




   Processing ease and                 Temperature range
       Workability


                                                                 8
Parameters for Application Potential


                      Light Weighted ness




                                            Miniaturization of
  Thermal Stability                           components
                          Application
                          Potential




         Design                             Cost



                                                                 9
Technology Performance Vs Application Potential
              (Present Scenario)

                                    Electronics Sector- Present Scenario

                           10


                                                                                    Carbon Nanofibres

                                                                       Silicone
   Application Potential




                                                                          Epoxies
                                                           Urethanes
                                                                              Acrylics
                            5




                            0
                                0                      5                                          10
                                             Technology Performance




                                                                                                        10
Technology Performance Vs Application Potential
            (7- 10 years from Now)

                                   Electronics Sector-10 years from now

                          10




                                                                                   Carbon Nanofibres
  Application Potential




                                                                 Epoxies         Acrylics
                                                             Silicones
                                                                     Urethanes
                           5




                           0
                               0                      5                                       10

                                            Technology Performance




                                                                                                       11
Noteworthy Innovations
   Development of a polycarbonate compound (Nemcon- H) by Ovation
   Polymers Inc.

   National Starch and Chemical Company, NJ, USA have
   demonstrated fusible particles can enhance thermal conductivity.

    A broad range of Vectra liquid crystal polymer (LCP) grades using
   several polymer systems with various fillers and reinforcements was
   developed by Ticona Technical Polymers, KY, US

   Development of a new thermally conductive line of compound by
   Dow Corning Corporation, US.

   Development of a series of boron nitride filler grades under the name
   PolarTherm by Momentive Performance Materials GmbH.



                                                                           12
Key Industry Participants




 Cool Polymers Inc      Momentive
 Ovation Polymers       Performance Materials
 Fujipoly American      Kunze Folien GmbH
 Corporation                                    Shin-Etsu
 CYTEC Inc                     Pronat
 Cast-Coat Inc                 Industries       Chemical
 Timtronics                    Ltd.             Co. Ltd
 Diemat Inc.
 Ticona     Technical
 Polymers




                                                            13
Your Feedback is Important to Us

          What would you like to see from Frost & Sullivan?

Growth Forecasts?

Competitive Structure?

Emerging Trends?

Strategic Recommendations?

Other?


                Please inform us by taking our survey.

                                                              14
For Additional Information



 Steve Lee
 Strategic Account Manager
 Chemicals, Materials and Food, Asia Pacific
 (65) 6890 0914
 steve.lee@frost.com




                                               15

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Thermal Management In Electronic Components – Can Polymers Replace Metals Or Ceramics Jun08

  • 1. Thermal Management in Electronic Components – Can Polymers Replace Metals or Ceramics? Aravind Chander, Senior Research Analyst, Technical Insights, Chennai, June 3, 2008
  • 2. Focus Points • Introduction to Thermally Conductive Polymers (TCPs) • Technology Challenges and Drivers • Current Trends and Future Trends • Material Technologies Analysis • Technological Innovations in this Arena • Key Industry Participants 2
  • 3. Introduction • Electronic devices are getting smaller and thinner • Conventional plastic components overheat often and develop localized quot;hot spotsquot; • Development of TCP’s has paved way to significant breakthrough for thermal management applications as they carry the same heat transfer capacity as metals or ceramics • TCP’s have good chemical resistance and give up heat faster during molding than conventional plastics 3
  • 4. Challenges – Thermally Conductive Polymers There is a demand for newer compounds that could compete with the existing thermoplastic compositions. Concern for Passive Component Manufacturers Thermal high-temperature conditions Manufacturing Fatigue and for a long period of time Cost Heat can damage or change Lack of New their organic properties. Dissipation Polymer Compounds Elevated Temperature Due to the polymer properties such as High CTE and Low High initial cost is the biggest Thermal Conductivities. obstacle to wider acceptance of Demand for thermally conductive compounds. More Power The increase in activities of the Note: Size of the ball is not related to components has led to demand for more power importance or weight of the factor in order to maintain the existing performance. 4
  • 5. Drivers – Thermal Conductive Polymers Compounds can be used as Polymers can be more easily custom manufactured to a wider range encapsulates in of sizes and shapes when compared to conventional materials. electronic component This enables them to be deployed for a broader range of applications. packaging making it suitable for smaller and thinner without Easy material compromising on process ability Polymers, particularly bio-based polymeric mechanical properties. compounds are gaining importance which can be effectively recycled with no harmful effect on the environment. Miniaturization of electronic components Continued focus on Recyclability Weight Excellent Reduction Mechanical Properties Weight reduction by means of using plastics for manufacturing safer, lighter and high performance devices. Thermally Conductive Polymers possess higher flexural strength, tensile Note: Size of the ball is not related to stiffness, and low-impact strengths. importance or weight of the factor 5
  • 6. Current Trends Thermally conductive adhesives for lighting application High viscosities make molding Custom-molded heat over a large surface area sinks on circuit boards difficult Current Trends Carbon nanofibers and boron nitride filler is gaining more Laser Diode Encapsulation is in attraction the developmental phase 6
  • 7. Future Trends Composites will target flip chips and solder joint applications New compounds from Tailorable CTEs with low natural resources high manufacturing cost temperature stability Future Trends PCB itself can act as heat sink Elastomers is expected to get more treatment 7
  • 8. Parameters for Technology Performance CTE Chemical resistance Mechanical Strength Technology Performance Processing ease and Temperature range Workability 8
  • 9. Parameters for Application Potential Light Weighted ness Miniaturization of Thermal Stability components Application Potential Design Cost 9
  • 10. Technology Performance Vs Application Potential (Present Scenario) Electronics Sector- Present Scenario 10 Carbon Nanofibres Silicone Application Potential Epoxies Urethanes Acrylics 5 0 0 5 10 Technology Performance 10
  • 11. Technology Performance Vs Application Potential (7- 10 years from Now) Electronics Sector-10 years from now 10 Carbon Nanofibres Application Potential Epoxies Acrylics Silicones Urethanes 5 0 0 5 10 Technology Performance 11
  • 12. Noteworthy Innovations Development of a polycarbonate compound (Nemcon- H) by Ovation Polymers Inc. National Starch and Chemical Company, NJ, USA have demonstrated fusible particles can enhance thermal conductivity. A broad range of Vectra liquid crystal polymer (LCP) grades using several polymer systems with various fillers and reinforcements was developed by Ticona Technical Polymers, KY, US Development of a new thermally conductive line of compound by Dow Corning Corporation, US. Development of a series of boron nitride filler grades under the name PolarTherm by Momentive Performance Materials GmbH. 12
  • 13. Key Industry Participants Cool Polymers Inc Momentive Ovation Polymers Performance Materials Fujipoly American Kunze Folien GmbH Corporation Shin-Etsu CYTEC Inc Pronat Cast-Coat Inc Industries Chemical Timtronics Ltd. Co. Ltd Diemat Inc. Ticona Technical Polymers 13
  • 14. Your Feedback is Important to Us What would you like to see from Frost & Sullivan? Growth Forecasts? Competitive Structure? Emerging Trends? Strategic Recommendations? Other? Please inform us by taking our survey. 14
  • 15. For Additional Information Steve Lee Strategic Account Manager Chemicals, Materials and Food, Asia Pacific (65) 6890 0914 steve.lee@frost.com 15