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PRE-TREATMENT
IN THE DYEING AND FINISHING PROCESS

    Responsible Sourcing Initiative
   Natural Resources Defense Council
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
First, we will go through:            Woven Fabric
    Fiber                Yarn
                                      Knitted Fabric
                    Pre-treatment


      Dyeing          Bleaching       Printing

                       Finishing
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
WHAT IS PRE-TREATMENT?
• by damaging the fabric as little as possible, remove
all the impurities from the fabric
• make a semi-finished product that is clean, smooth,
soft, and water absorbent (hydrophilic)
• the preparation work in a dyeing and finishing
factory work, it can also be known as bleaching and
scouring
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
THE BASIC COMPONENTS OF PRE-TREATMENT:


SINGEING      DE-SIZING   SCOURING    BLEACHING   MERCERIZING



                    PRE-TREATMENT

           NOTE: THIS IS JUST AN EXAMPLE OF THE PRE-
           TREATMENT PROCESS FOR COTTON. PRE-TREATMENT
           PROCESSES CAN VARY FOR EACH TYPE OF
           SUBSTRATE.
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

 Let’s talk about singeing…

SINGEING    DE-SIZING    SCOURING     BLEACHING   MERCERIZING



                  PRE-TREATMENT
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

SINGEING REFERS TO THE BURNING
  OFF OF:
- LOOSE FIBERS NOT FIRMLY BOUND
  INTO THE YARN OR FABRIC
- LOOSE YARNS NOT BOUND INTO
  FABRIC
- PROTRUDING FIBER ENDS STICKING
  OUT OF THE YARN OR FABRIC
                                      Information: http://ara-texworld.com
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT




        BEFORE                                       AFTER
       SINGEING                                    SINGEING



                                 Photo: Osthoff Senge from http://ara-texworld.com/
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT



    This is fabric
    going through
    a singeing
    machine
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

 Onto de-sizing…

SINGEING    DE-SIZING    SCOURING     BLEACHING   MERCERIZING



                  PRE-TREATMENT
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
The reason for de-sizing because during the spinning
and weaving process, the fabric goes through sizing.


SIZING is when
SIZE is applied to
the fabric to protect
it from the abrasive
action of the loom.
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

WHAT IS SIZE?

Natural sizing agents
are mostly based on
starch and starch-
derivatives. There
are also synthetic
sizing agents such as
modified polyesters.

                                      close-up of starch under
                                      electron microscope
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT


De-sizing is the removal of sizing
agents from the fabric using
enzymes, acid, oxidative agents,
etc. Enzymatic de-sizing is the
most common.
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

Irrespective of what kind of de-sizing, the
process includes:
                 Impregnation of fabric with
            1         de-sizing agent

                Allowing the de-sizing agent to
            2   solubilize or degrade the size

                Washing out the degradation
            3            products
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
                                                                        WASH OUT
EXAMPLE OF A DE-SIZING PROCESS:                                         ENZYMES




F   AB
      RIC
                       +          ENZYMES




                     FOR EXAMPLE, CELLULASE, AN
                     ENZYME, BREAKS DOWN STARCH

                     Thanks to Prof. Michal Vik for all the information on de-sizing (from:
                     http://www.ft.tul.cz/depart/ktc/dokumenty/pte/2PTE%20Desizing.pdf)
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

 Now we will talk about scouring…

SINGEING    DE-SIZING    SCOURING     BLEACHING   MERCERIZING



                  PRE-TREATMENT
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
SCOURING is the treatment of textile materials in
aqueous or other solutions in order to remove:
      SIZING                          INORGANIC
   DEGRADATION           PECTINS      SUBSTNACES
     PRODUCTS



    ALUMINIUM             FATS
                                        SIZES
  AND IRON OXIDES       AND WAXES
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

SCOURING can be carried out as a separate
step of the process OR in combination with
other treatments (usually bleaching or desizing)
on all kind of substrates (fiber, woven fibers,
knitted fibers).



                Thanks to Dr. Schönberger and Dr. Schäfer from Best Available
                Techniques in Textile Industry for information on scouring
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
EXAMPLE OF SCOURING PROCESS:
                              ALKALI,

    AB
      RIC
                  +       WETTING AGENTS,
                                ETC.
F




                Thanks to Dr. Schönberger and Dr. Schäfer from Best Available
                Techniques in Textile Industry for information on scouring
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT



SINGEING    DE-SIZING    SCOURING     BLEACHING   MERCERIZING



                  PRE-TREATMENT
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

Bleaching increasing the whiteness of the
substrates, this is important for un-dyed fabrics
as well for fabrics dyed in light shades or with
a high brilliance.

Bleached products are usually treated with
hypochlorite or peroxide. Peroxide is more
commonly used for cotton whereas
hypochlorite is used for linen.
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT


This is fabric
coming out of
a scouring
and bleaching
machine
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT



SINGEING    DE-SIZING    SCOURING     BLEACHING   MERCERIZING



                  PRE-TREATMENT
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

Mercerizing is the treatment of cotton and
cotton blends with strong alkali under
tension.

Let’s see what it looks like…
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

                  ALKALI TREATING THE FABRIC




                       N
                T ENSIO
           NDER
  FA BRIC U
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
Mercerizing is possible before and after a lot of steps
in the dyeing and finishing process.
For example:
• on greige goods
• after desizing
• after de-sizing and scouring
• after bleaching
• after dyeing
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

MERCERIZING CAN:
             IMPROVE DYESTUFF ABSORPTION

                INCREASE TENSILE STRENGTH

                 MAKE A RESISTANT LUSTER


             IMPROVE DIMENSIONAL STABILITY
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
All the steps of the pre-treatment process can
take place in something like this:




This is a continuous dyeing machine.
                           Graphic from:
                           http://www.ineris.fr/ippc/sites/default/interactive/bref_text/breftext/a
                           nglais/bref/BREF_tex_gb55.html
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT

Now that we have looked at all the basic
components of the pre-treatment process, let’s
see what a pre-treatment process might look
like for various substrates.
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
                       GREIGE
                    PREPARATION


                                  SINGEING
For cotton and
                                                CAN BE
cotton-based fabrics,                           COMPLETED
the pre-treatment                 DE-SIZING     IN ONE-BATH
                                                DYEING
process might look
like this…
                                  MERCERIZING



                      SCOURING
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
                        GREIGE
                     PREPARATION

                                    CIRCULAR
                                    SINGEING
For knitted cotton
fabrics, the pre-
treatment process                   SCOURING    CAN BE
might look like                                 COMPLETED
                                                IN ONE-BATH
this…                               BLEACHING   DYEING

                   ALKALI MILLING
                       AND
                    MERCERIZING
2. THE DYEING AND FINISHING PROCESS
A. PRE-TREATMENT
                               QUALITIES:

                                        RELATIVELY CLEAN
 SYNTHETIC FIBERS
                                         FEW IMPURITIES

                                IN PRE-TREATMENT:

                                      GENERALLY DO NOT BLEACH


                                      WARM TEMPERATURE FOR
                                           PRE-TREATMENT
                                       (except for very white or
                                         bright colored fibers)

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Pre treatment test

  • 1. PRE-TREATMENT IN THE DYEING AND FINISHING PROCESS Responsible Sourcing Initiative Natural Resources Defense Council
  • 2. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT First, we will go through: Woven Fabric Fiber Yarn Knitted Fabric Pre-treatment Dyeing Bleaching Printing Finishing
  • 3. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT WHAT IS PRE-TREATMENT? • by damaging the fabric as little as possible, remove all the impurities from the fabric • make a semi-finished product that is clean, smooth, soft, and water absorbent (hydrophilic) • the preparation work in a dyeing and finishing factory work, it can also be known as bleaching and scouring
  • 4. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT THE BASIC COMPONENTS OF PRE-TREATMENT: SINGEING DE-SIZING SCOURING BLEACHING MERCERIZING PRE-TREATMENT NOTE: THIS IS JUST AN EXAMPLE OF THE PRE- TREATMENT PROCESS FOR COTTON. PRE-TREATMENT PROCESSES CAN VARY FOR EACH TYPE OF SUBSTRATE.
  • 5. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Let’s talk about singeing… SINGEING DE-SIZING SCOURING BLEACHING MERCERIZING PRE-TREATMENT
  • 6. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT SINGEING REFERS TO THE BURNING OFF OF: - LOOSE FIBERS NOT FIRMLY BOUND INTO THE YARN OR FABRIC - LOOSE YARNS NOT BOUND INTO FABRIC - PROTRUDING FIBER ENDS STICKING OUT OF THE YARN OR FABRIC Information: http://ara-texworld.com
  • 7. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT BEFORE AFTER SINGEING SINGEING Photo: Osthoff Senge from http://ara-texworld.com/
  • 8. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT This is fabric going through a singeing machine
  • 9. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Onto de-sizing… SINGEING DE-SIZING SCOURING BLEACHING MERCERIZING PRE-TREATMENT
  • 10. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT The reason for de-sizing because during the spinning and weaving process, the fabric goes through sizing. SIZING is when SIZE is applied to the fabric to protect it from the abrasive action of the loom.
  • 11. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT WHAT IS SIZE? Natural sizing agents are mostly based on starch and starch- derivatives. There are also synthetic sizing agents such as modified polyesters. close-up of starch under electron microscope
  • 12. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT De-sizing is the removal of sizing agents from the fabric using enzymes, acid, oxidative agents, etc. Enzymatic de-sizing is the most common.
  • 13. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Irrespective of what kind of de-sizing, the process includes: Impregnation of fabric with 1 de-sizing agent Allowing the de-sizing agent to 2 solubilize or degrade the size Washing out the degradation 3 products
  • 14. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT WASH OUT EXAMPLE OF A DE-SIZING PROCESS: ENZYMES F AB RIC + ENZYMES FOR EXAMPLE, CELLULASE, AN ENZYME, BREAKS DOWN STARCH Thanks to Prof. Michal Vik for all the information on de-sizing (from: http://www.ft.tul.cz/depart/ktc/dokumenty/pte/2PTE%20Desizing.pdf)
  • 15. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Now we will talk about scouring… SINGEING DE-SIZING SCOURING BLEACHING MERCERIZING PRE-TREATMENT
  • 16. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT SCOURING is the treatment of textile materials in aqueous or other solutions in order to remove: SIZING INORGANIC DEGRADATION PECTINS SUBSTNACES PRODUCTS ALUMINIUM FATS SIZES AND IRON OXIDES AND WAXES
  • 17. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT SCOURING can be carried out as a separate step of the process OR in combination with other treatments (usually bleaching or desizing) on all kind of substrates (fiber, woven fibers, knitted fibers). Thanks to Dr. Schönberger and Dr. Schäfer from Best Available Techniques in Textile Industry for information on scouring
  • 18. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT EXAMPLE OF SCOURING PROCESS: ALKALI, AB RIC + WETTING AGENTS, ETC. F Thanks to Dr. Schönberger and Dr. Schäfer from Best Available Techniques in Textile Industry for information on scouring
  • 19. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT SINGEING DE-SIZING SCOURING BLEACHING MERCERIZING PRE-TREATMENT
  • 20. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Bleaching increasing the whiteness of the substrates, this is important for un-dyed fabrics as well for fabrics dyed in light shades or with a high brilliance. Bleached products are usually treated with hypochlorite or peroxide. Peroxide is more commonly used for cotton whereas hypochlorite is used for linen.
  • 21. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT This is fabric coming out of a scouring and bleaching machine
  • 22. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT SINGEING DE-SIZING SCOURING BLEACHING MERCERIZING PRE-TREATMENT
  • 23. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Mercerizing is the treatment of cotton and cotton blends with strong alkali under tension. Let’s see what it looks like…
  • 24. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT ALKALI TREATING THE FABRIC N T ENSIO NDER FA BRIC U
  • 25. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Mercerizing is possible before and after a lot of steps in the dyeing and finishing process. For example: • on greige goods • after desizing • after de-sizing and scouring • after bleaching • after dyeing
  • 26. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT MERCERIZING CAN: IMPROVE DYESTUFF ABSORPTION INCREASE TENSILE STRENGTH MAKE A RESISTANT LUSTER IMPROVE DIMENSIONAL STABILITY
  • 27. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT All the steps of the pre-treatment process can take place in something like this: This is a continuous dyeing machine. Graphic from: http://www.ineris.fr/ippc/sites/default/interactive/bref_text/breftext/a nglais/bref/BREF_tex_gb55.html
  • 28. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT Now that we have looked at all the basic components of the pre-treatment process, let’s see what a pre-treatment process might look like for various substrates.
  • 29. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT GREIGE PREPARATION SINGEING For cotton and CAN BE cotton-based fabrics, COMPLETED the pre-treatment DE-SIZING IN ONE-BATH DYEING process might look like this… MERCERIZING SCOURING
  • 30. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT GREIGE PREPARATION CIRCULAR SINGEING For knitted cotton fabrics, the pre- treatment process SCOURING CAN BE might look like COMPLETED IN ONE-BATH this… BLEACHING DYEING ALKALI MILLING AND MERCERIZING
  • 31. 2. THE DYEING AND FINISHING PROCESS A. PRE-TREATMENT QUALITIES: RELATIVELY CLEAN SYNTHETIC FIBERS FEW IMPURITIES IN PRE-TREATMENT: GENERALLY DO NOT BLEACH WARM TEMPERATURE FOR PRE-TREATMENT (except for very white or bright colored fibers)