SlideShare a Scribd company logo
1 of 12
Environmental
                   Problems
Chemical Order for mercury and mercury compound
   Mercury is a chemical element with the
    symbol Hg and atomic number 80. It is commonly
    known as quicksilver and was formerly named
    hydrargyrum . A heavy, silvery d-block element,
    mercury is the only metal that is liquid at standard
    conditions for temperature and pressure; the only
    other element that is liquid under these conditions
    is bromine, though metals such as caesium,gallium,
    and rubidum melt just above room temperature. With
    a freesing point of −38.83 °C and boiling point of
    356.73 °C, mercury has one of the narrowest ranges
    of its liquid state of any metal.




What is Mercury?
Mercury
   Mercury can affect not only our bodies but also the environment and wildlife.
    The toxic effects of mercury depend on its chemical form and the route of
    exposure. Methylmercury [CH3Hg] is the most toxic form. It affects the
    immune system, alters genetic and enzyme systems, and damages the
    nervous system, including coordination and the senses of touch, taste, and
    sight. Methylmercury is particularly damaging to developing embryos, which
    are five to ten times more sensitive than adults. Exposure to methylmercury is
    usually by ingestion, and it is absorbed more readily and excreted more slowly
    than other forms of mercury. Elemental mercury, Hg(0), the form released
    from broken thermometers, causes tremors, gingivitis, and excitability when
    vapors are inhaled over a long period of time. Although it is less toxic than
    methylmercury, elemental mercury may be found in higher concentrations in
    environments such as gold mine sites, where it has been used to extract gold.
    If elemental mercury is ingested, it is absorbed relatively slowly and may pass
    through the digestive system without causing damage. Ingestion of other
    common forms of mercury, such as the salt HgCl2, which damages the
    gastrointestinal tract and causes kidney failure, is unlikely from environmental
    sources.




Effects of Mercury
   People are exposed to methylmercury almost entirely by
    eating contaminated fish and wildlife that are at the top of
    aquatic foodchains. The National Research Council, in its
    2000 report on the toxicological effects of methylmercury,
    pointed out that the population at highest risk is the
    offspring of women who consume large amounts of fish
    and seafood. The report went on to estimate that more
    than 60,000 children are born each year at risk for adverse
    neurodevelopmental effects due to in utero exposure to
    methylmercury. In its 1997 Mercury Study Report to
    Congress, the U.S. Environmental Protection Agency
    concluded that mercury also may pose a risk to some
    adults and wildlife populations that consume large amounts
    of fish that is contaminated by mercury.




Effects of Mercury to people
   In several areas of the United States, concentrations of mercury in fish and wildlife are
    high enough to be a risk to wildlife. It is difficult to prove cause and effect in field studies,
    however, because other factors that may contribute to the biological effect under study (for
    example, reproductive success) are often impossible to control. Scientists have
    discovered toxic effects in the field at concentrations of mercury that are toxic in the lab,
    and controlled lab studies have found toxic effects at concentrations that are common in
    certain environments. In studies in Wisconsin, reductions in loon chick production has
    been found in lakes where mercury concentrations in eggs exceed concentrations that are
    toxic in laboratory studies. At dietary mercury concentrations that are typical of parts of the
    Everglades, the behavior of juvenile great egrets can be affected. Studies with mallards,
    great egrets, and other aquatic birds have shown that protective enzymes are less
    effective following exposure to mercury. Analyses of such biochemical indicators indicate
    that mercury is adversely affecting diving ducks from the San Francisco Bay, herons and
    egrets from the Carson River, Nevada, and heron embryos from colonies along the
    Mississippi River. Finally, other contaminants also affect the toxicity of mercury.
    Methylmercury can be more harmful to bird embryos when selenium, another potentially
    toxic element, is present in the diet.




Effects of Mercury to wildlife
   Mercury occurs uncombined in nature to a limited extent. It rarely
    occurs free in nature and is found mainly in cinnabar ore (HgS) in
    Spain, Russia, Italy, China and Slovenia. World production of
    mercury is around 8.000 tonnes per year. Mineable reserves are
    around 600.000 tonnes.
   Mercury is a compound that can be found naturally in the
    environment. It can be found in metal form, as mercury salts or as
    organic mercury compounds.





Effects of Mercury to the
environment
 Mercury enters the environment as a result of normal breakdown of minerals in rocks and
  soil through exposure to wind and water. Release of mercury from natural sources has
  remained fairly the same over the years. Still mercury concentrations in the environment
  are increasing; this is ascribed to human activity.
  Most of the mercury released from human activities is released into air, through fossil fuel
  combustion, mining, smelting and solid waste combustion. Some forms of human activity
  release mercury directly into soil or water, for instance the application of agricultural
  fertilizers and industrial wastewater disposal. All mercury that is released in the
  environment will eventually end up in soils or surface waters.
 Mercury is not naturally found in foodstuffs, but it may turn up in food as it can be spread
  within food chains by smaller organisms that are consumed by humans, for instance
  through fish. Mercury concentrations in fish usually greatly exceed the concentrations in
  the water they live in. Cattle breeding products can also contain eminent quantities of
  mercury. Mercury is not commonly found in plant products, but it can enter human bodies
  through vegetables and other crops, when sprays that contain mercury are applied in
  agriculture.




Effects of Mercury to the
environment
   Alkali and metal processing, incineration of coal, and
    medical and other waste, and mining of gold and
    mercury contribute greatly to mercury concentrations
    in some areas, but atmospheric deposition is the
    dominant source of mercury over most of the
    landscape. Once in the atmosphere, mercury is
    widely disseminated and can circulate for years,
    accounting for its wide-spread distribution. Natural
    sources of atmospheric mercury include volcanoes,
    geologic deposits of mercury, and volatilization from
    the ocean. Although all rocks, sediments, water, and
    soils naturally contain small but varying amounts of
    mercury, scientists have found some local mineral
    occurrences and thermal springs that are naturally
    high in mercury.



Where can we find mercury?
   Although mercury is a globally dispersed
    contaminant, it is not a problem everywhere. Aside
    from grossly polluted environments, mercury is
    normally a problem only where the rate of natural
    formation of methylmercury from inorganic mercury
    is greater than the reverse reaction. Methylmercury is
    the only form of mercury that accumulates
    appreciably in fish. Environments that are known to
    favor the production of methylmercury include certain
    types of wetlands, dilute low-pH lakes in Northeast
    and Northcentral United States, parts of the Florida
    Everglades, newly flooded reservoirs, and coastal
    wetlands, particularly along the Gulf of Mexico,
    Atlantic Ocean, and San Francisco Bay.




Where can we find mercury?
 We can prevent by preventing mercury
  pollution from coming.
 Conserve Energy. Most mercury pollution
  comes from burning coal in power plants.
  Conserving energy will reduce mercury
  pollution along with greenhouse gases
  and other pollutants.


How can we prevent mercury from
destroying our environment and
wildlife?
   Don't Buy Mercury-Containing Products
    Unless Absolutely Necessary. Use digital
    thermometers instead of mercury
    thermometers. Use low-mercury bulbs
    instead of fluorescent lamps. There are
    many ways to get rid of mercury so it
    won’t affect us and the environment.


How can we prevent mercury from
destroying our environment and
wildlife?

More Related Content

What's hot

Bioavailability of heavy metals in sediment C.U.EBONG
Bioavailability of heavy metals  in sediment C.U.EBONGBioavailability of heavy metals  in sediment C.U.EBONG
Bioavailability of heavy metals in sediment C.U.EBONGUnyime Christopher
 
Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...
Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...
Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...Alexander Decker
 
Mercury Pollution
Mercury PollutionMercury Pollution
Mercury Pollutioniyaselex
 
Heavy metals in drinking water
Heavy metals in drinking waterHeavy metals in drinking water
Heavy metals in drinking waterAbdulJalil109
 
HEAVY METALS AND THEIR EFFECTS
HEAVY METALS AND THEIR EFFECTSHEAVY METALS AND THEIR EFFECTS
HEAVY METALS AND THEIR EFFECTSvirgo_az
 
Heavy metals and heavy metal in water and soil.
Heavy metals and heavy metal in water and soil.Heavy metals and heavy metal in water and soil.
Heavy metals and heavy metal in water and soil.17071561-007
 
project presentation on Bioaccumulation of Heavy metals
project presentation on Bioaccumulation of Heavy metalsproject presentation on Bioaccumulation of Heavy metals
project presentation on Bioaccumulation of Heavy metalscutiepie39
 
Water pollution & control by Muhammad Fahad Ansari 12IEEM14
Water pollution & control by Muhammad Fahad Ansari 12IEEM14Water pollution & control by Muhammad Fahad Ansari 12IEEM14
Water pollution & control by Muhammad Fahad Ansari 12IEEM14fahadansari131
 
Heavy metal pollution
Heavy metal pollutionHeavy metal pollution
Heavy metal pollutionHadia Khadija
 
Water pollution ppt
Water pollution pptWater pollution ppt
Water pollution pptsahinlaskar1
 
Ocean pollution
Ocean pollutionOcean pollution
Ocean pollutionCarlo Roa
 
Chemical parameters of soil & water on fish health
Chemical parameters of soil & water on fish healthChemical parameters of soil & water on fish health
Chemical parameters of soil & water on fish healthRajive Brahmchari
 
Seminar presentation
Seminar presentationSeminar presentation
Seminar presentationravi8492
 

What's hot (20)

Heavy metals
Heavy metalsHeavy metals
Heavy metals
 
Bioavailability of heavy metals in sediment C.U.EBONG
Bioavailability of heavy metals  in sediment C.U.EBONGBioavailability of heavy metals  in sediment C.U.EBONG
Bioavailability of heavy metals in sediment C.U.EBONG
 
Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...
Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...
Dangers of bioaccumulation of some heavy metals consumed in sardine and macke...
 
Mercury Pollution
Mercury PollutionMercury Pollution
Mercury Pollution
 
The Bio accumulation of heavy metals
The Bio accumulation of heavy metalsThe Bio accumulation of heavy metals
The Bio accumulation of heavy metals
 
Heavy metals in drinking water
Heavy metals in drinking waterHeavy metals in drinking water
Heavy metals in drinking water
 
HEAVY METALS AND THEIR EFFECTS
HEAVY METALS AND THEIR EFFECTSHEAVY METALS AND THEIR EFFECTS
HEAVY METALS AND THEIR EFFECTS
 
Heavy metals and heavy metal in water and soil.
Heavy metals and heavy metal in water and soil.Heavy metals and heavy metal in water and soil.
Heavy metals and heavy metal in water and soil.
 
project presentation on Bioaccumulation of Heavy metals
project presentation on Bioaccumulation of Heavy metalsproject presentation on Bioaccumulation of Heavy metals
project presentation on Bioaccumulation of Heavy metals
 
Water pollution & control by Muhammad Fahad Ansari 12IEEM14
Water pollution & control by Muhammad Fahad Ansari 12IEEM14Water pollution & control by Muhammad Fahad Ansari 12IEEM14
Water pollution & control by Muhammad Fahad Ansari 12IEEM14
 
Esu4 ao s1 hm x heavy metals
Esu4 ao s1 hm x heavy metalsEsu4 ao s1 hm x heavy metals
Esu4 ao s1 hm x heavy metals
 
heavy metal
heavy metalheavy metal
heavy metal
 
Marine pollution
Marine pollutionMarine pollution
Marine pollution
 
Heavy metal pollution
Heavy metal pollutionHeavy metal pollution
Heavy metal pollution
 
Water pollution ppt
Water pollution pptWater pollution ppt
Water pollution ppt
 
Heavy metal and human health
Heavy metal and human healthHeavy metal and human health
Heavy metal and human health
 
Ocean pollution
Ocean pollutionOcean pollution
Ocean pollution
 
Chemical parameters of soil & water on fish health
Chemical parameters of soil & water on fish healthChemical parameters of soil & water on fish health
Chemical parameters of soil & water on fish health
 
Seminar presentation
Seminar presentationSeminar presentation
Seminar presentation
 
Sea water pollution
Sea water pollutionSea water pollution
Sea water pollution
 

Viewers also liked

Viewers also liked (8)

Mercury Contamination
Mercury ContaminationMercury Contamination
Mercury Contamination
 
2015_SETAC_Chuan_10262015
2015_SETAC_Chuan_102620152015_SETAC_Chuan_10262015
2015_SETAC_Chuan_10262015
 
Inorganic and methylmercury do they transfer along a tropical coastal food ...
Inorganic and methylmercury   do they transfer along a tropical coastal food ...Inorganic and methylmercury   do they transfer along a tropical coastal food ...
Inorganic and methylmercury do they transfer along a tropical coastal food ...
 
Arsenic and manganese poisoning
Arsenic and manganese poisoningArsenic and manganese poisoning
Arsenic and manganese poisoning
 
Minamata disaster
Minamata disasterMinamata disaster
Minamata disaster
 
arsenic & mercury
arsenic & mercuryarsenic & mercury
arsenic & mercury
 
Arsenic Final Presentation
Arsenic Final PresentationArsenic Final Presentation
Arsenic Final Presentation
 
bioaccumulation and
bioaccumulation and bioaccumulation and
bioaccumulation and
 

Similar to Environmental problems

heavy metal toxicity.pptx
heavy metal toxicity.pptxheavy metal toxicity.pptx
heavy metal toxicity.pptxLinaSaadi2
 
Ayush biomagnification
Ayush biomagnificationAyush biomagnification
Ayush biomagnificationChamanGupta14
 
Mercury justin
Mercury justinMercury justin
Mercury justinjuco00207
 
Mercury poisoning
Mercury poisoningMercury poisoning
Mercury poisoningninarose85
 
Heavy metals in drinking water
Heavy metals in drinking waterHeavy metals in drinking water
Heavy metals in drinking waterAbdulJalil109
 
Pollution mercury and heavy metals
Pollution  mercury and heavy metals Pollution  mercury and heavy metals
Pollution mercury and heavy metals Ghassan Hadi
 
Heavy Metal toxicology in environment science
Heavy Metal toxicology in environment scienceHeavy Metal toxicology in environment science
Heavy Metal toxicology in environment sciencearchanaagarwal35
 
Heavy metals toxicity (1)
Heavy metals  toxicity (1)Heavy metals  toxicity (1)
Heavy metals toxicity (1)mallikaswathi
 
chronic mercury intoxication
chronic mercury intoxicationchronic mercury intoxication
chronic mercury intoxicationMDArif149
 
Trace metals and mercury
Trace metals and mercuryTrace metals and mercury
Trace metals and mercuryAlfahadFarwa
 
Heavy metal toxicity aman
Heavy metal toxicity amanHeavy metal toxicity aman
Heavy metal toxicity amanaman singh
 
bioaccomulation of heavy metals.pptx
bioaccomulation of heavy metals.pptxbioaccomulation of heavy metals.pptx
bioaccomulation of heavy metals.pptximtiazahmad682057
 
Table of Contents Introduction, Purpose & Scope Issue 1 I.docx
Table of Contents Introduction, Purpose & Scope Issue 1 I.docxTable of Contents Introduction, Purpose & Scope Issue 1 I.docx
Table of Contents Introduction, Purpose & Scope Issue 1 I.docxperryk1
 
CSE364_Handout_doc.pdf
CSE364_Handout_doc.pdfCSE364_Handout_doc.pdf
CSE364_Handout_doc.pdfAmmar475682
 

Similar to Environmental problems (20)

Soil science-1.pptx
Soil science-1.pptxSoil science-1.pptx
Soil science-1.pptx
 
heavy metal toxicity.pptx
heavy metal toxicity.pptxheavy metal toxicity.pptx
heavy metal toxicity.pptx
 
Sulfur cycle PERIOD 4
Sulfur cycle PERIOD 4Sulfur cycle PERIOD 4
Sulfur cycle PERIOD 4
 
Metals 3 (heavy_metals)
Metals 3 (heavy_metals)Metals 3 (heavy_metals)
Metals 3 (heavy_metals)
 
Ayush biomagnification
Ayush biomagnificationAyush biomagnification
Ayush biomagnification
 
Soil science.pptx
Soil science.pptxSoil science.pptx
Soil science.pptx
 
Mercury justin
Mercury justinMercury justin
Mercury justin
 
Mercury poisoning
Mercury poisoningMercury poisoning
Mercury poisoning
 
Heavy metals in drinking water
Heavy metals in drinking waterHeavy metals in drinking water
Heavy metals in drinking water
 
Pollution mercury and heavy metals
Pollution  mercury and heavy metals Pollution  mercury and heavy metals
Pollution mercury and heavy metals
 
Contaminants
ContaminantsContaminants
Contaminants
 
Heavy Metal toxicology in environment science
Heavy Metal toxicology in environment scienceHeavy Metal toxicology in environment science
Heavy Metal toxicology in environment science
 
Presentation(abhyuday)
Presentation(abhyuday)Presentation(abhyuday)
Presentation(abhyuday)
 
Heavy metals toxicity (1)
Heavy metals  toxicity (1)Heavy metals  toxicity (1)
Heavy metals toxicity (1)
 
chronic mercury intoxication
chronic mercury intoxicationchronic mercury intoxication
chronic mercury intoxication
 
Trace metals and mercury
Trace metals and mercuryTrace metals and mercury
Trace metals and mercury
 
Heavy metal toxicity aman
Heavy metal toxicity amanHeavy metal toxicity aman
Heavy metal toxicity aman
 
bioaccomulation of heavy metals.pptx
bioaccomulation of heavy metals.pptxbioaccomulation of heavy metals.pptx
bioaccomulation of heavy metals.pptx
 
Table of Contents Introduction, Purpose & Scope Issue 1 I.docx
Table of Contents Introduction, Purpose & Scope Issue 1 I.docxTable of Contents Introduction, Purpose & Scope Issue 1 I.docx
Table of Contents Introduction, Purpose & Scope Issue 1 I.docx
 
CSE364_Handout_doc.pdf
CSE364_Handout_doc.pdfCSE364_Handout_doc.pdf
CSE364_Handout_doc.pdf
 

Environmental problems

  • 1. Environmental Problems Chemical Order for mercury and mercury compound
  • 2. Mercury is a chemical element with the symbol Hg and atomic number 80. It is commonly known as quicksilver and was formerly named hydrargyrum . A heavy, silvery d-block element, mercury is the only metal that is liquid at standard conditions for temperature and pressure; the only other element that is liquid under these conditions is bromine, though metals such as caesium,gallium, and rubidum melt just above room temperature. With a freesing point of −38.83 °C and boiling point of 356.73 °C, mercury has one of the narrowest ranges of its liquid state of any metal. What is Mercury?
  • 4. Mercury can affect not only our bodies but also the environment and wildlife. The toxic effects of mercury depend on its chemical form and the route of exposure. Methylmercury [CH3Hg] is the most toxic form. It affects the immune system, alters genetic and enzyme systems, and damages the nervous system, including coordination and the senses of touch, taste, and sight. Methylmercury is particularly damaging to developing embryos, which are five to ten times more sensitive than adults. Exposure to methylmercury is usually by ingestion, and it is absorbed more readily and excreted more slowly than other forms of mercury. Elemental mercury, Hg(0), the form released from broken thermometers, causes tremors, gingivitis, and excitability when vapors are inhaled over a long period of time. Although it is less toxic than methylmercury, elemental mercury may be found in higher concentrations in environments such as gold mine sites, where it has been used to extract gold. If elemental mercury is ingested, it is absorbed relatively slowly and may pass through the digestive system without causing damage. Ingestion of other common forms of mercury, such as the salt HgCl2, which damages the gastrointestinal tract and causes kidney failure, is unlikely from environmental sources. Effects of Mercury
  • 5. People are exposed to methylmercury almost entirely by eating contaminated fish and wildlife that are at the top of aquatic foodchains. The National Research Council, in its 2000 report on the toxicological effects of methylmercury, pointed out that the population at highest risk is the offspring of women who consume large amounts of fish and seafood. The report went on to estimate that more than 60,000 children are born each year at risk for adverse neurodevelopmental effects due to in utero exposure to methylmercury. In its 1997 Mercury Study Report to Congress, the U.S. Environmental Protection Agency concluded that mercury also may pose a risk to some adults and wildlife populations that consume large amounts of fish that is contaminated by mercury. Effects of Mercury to people
  • 6. In several areas of the United States, concentrations of mercury in fish and wildlife are high enough to be a risk to wildlife. It is difficult to prove cause and effect in field studies, however, because other factors that may contribute to the biological effect under study (for example, reproductive success) are often impossible to control. Scientists have discovered toxic effects in the field at concentrations of mercury that are toxic in the lab, and controlled lab studies have found toxic effects at concentrations that are common in certain environments. In studies in Wisconsin, reductions in loon chick production has been found in lakes where mercury concentrations in eggs exceed concentrations that are toxic in laboratory studies. At dietary mercury concentrations that are typical of parts of the Everglades, the behavior of juvenile great egrets can be affected. Studies with mallards, great egrets, and other aquatic birds have shown that protective enzymes are less effective following exposure to mercury. Analyses of such biochemical indicators indicate that mercury is adversely affecting diving ducks from the San Francisco Bay, herons and egrets from the Carson River, Nevada, and heron embryos from colonies along the Mississippi River. Finally, other contaminants also affect the toxicity of mercury. Methylmercury can be more harmful to bird embryos when selenium, another potentially toxic element, is present in the diet. Effects of Mercury to wildlife
  • 7. Mercury occurs uncombined in nature to a limited extent. It rarely occurs free in nature and is found mainly in cinnabar ore (HgS) in Spain, Russia, Italy, China and Slovenia. World production of mercury is around 8.000 tonnes per year. Mineable reserves are around 600.000 tonnes.  Mercury is a compound that can be found naturally in the environment. It can be found in metal form, as mercury salts or as organic mercury compounds.  Effects of Mercury to the environment
  • 8.  Mercury enters the environment as a result of normal breakdown of minerals in rocks and soil through exposure to wind and water. Release of mercury from natural sources has remained fairly the same over the years. Still mercury concentrations in the environment are increasing; this is ascribed to human activity. Most of the mercury released from human activities is released into air, through fossil fuel combustion, mining, smelting and solid waste combustion. Some forms of human activity release mercury directly into soil or water, for instance the application of agricultural fertilizers and industrial wastewater disposal. All mercury that is released in the environment will eventually end up in soils or surface waters.  Mercury is not naturally found in foodstuffs, but it may turn up in food as it can be spread within food chains by smaller organisms that are consumed by humans, for instance through fish. Mercury concentrations in fish usually greatly exceed the concentrations in the water they live in. Cattle breeding products can also contain eminent quantities of mercury. Mercury is not commonly found in plant products, but it can enter human bodies through vegetables and other crops, when sprays that contain mercury are applied in agriculture. Effects of Mercury to the environment
  • 9. Alkali and metal processing, incineration of coal, and medical and other waste, and mining of gold and mercury contribute greatly to mercury concentrations in some areas, but atmospheric deposition is the dominant source of mercury over most of the landscape. Once in the atmosphere, mercury is widely disseminated and can circulate for years, accounting for its wide-spread distribution. Natural sources of atmospheric mercury include volcanoes, geologic deposits of mercury, and volatilization from the ocean. Although all rocks, sediments, water, and soils naturally contain small but varying amounts of mercury, scientists have found some local mineral occurrences and thermal springs that are naturally high in mercury. Where can we find mercury?
  • 10. Although mercury is a globally dispersed contaminant, it is not a problem everywhere. Aside from grossly polluted environments, mercury is normally a problem only where the rate of natural formation of methylmercury from inorganic mercury is greater than the reverse reaction. Methylmercury is the only form of mercury that accumulates appreciably in fish. Environments that are known to favor the production of methylmercury include certain types of wetlands, dilute low-pH lakes in Northeast and Northcentral United States, parts of the Florida Everglades, newly flooded reservoirs, and coastal wetlands, particularly along the Gulf of Mexico, Atlantic Ocean, and San Francisco Bay. Where can we find mercury?
  • 11.  We can prevent by preventing mercury pollution from coming.  Conserve Energy. Most mercury pollution comes from burning coal in power plants. Conserving energy will reduce mercury pollution along with greenhouse gases and other pollutants. How can we prevent mercury from destroying our environment and wildlife?
  • 12. Don't Buy Mercury-Containing Products Unless Absolutely Necessary. Use digital thermometers instead of mercury thermometers. Use low-mercury bulbs instead of fluorescent lamps. There are many ways to get rid of mercury so it won’t affect us and the environment. How can we prevent mercury from destroying our environment and wildlife?