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what is? Effective collision? Collision theory? Factors affecting? Activation energy? Energy level diagram? Rate of reaction
AVERAGE RATE OF REACTION  For the whole exp From X min to Y min  On the X min (2 nd )  ( from 2 nd  to 1 st )  For  first x (3) min ( from 0 to 3rd )
b) Example from the graph, determine: ,[object Object],Total volume of gas  Total time taken
=  46  = 0.20 cm 3  s -1 210
b) Example from the graph, determine: ,[object Object],Total volume of gas at 3min -1 min Total time taken at 3min -1min
=  44-25  = 0.13 cm 3  s -1 180-60
b) Example from the graph, determine: ,[object Object],Total volume of gas at 3min – at 2min  Total time taken at 3min – at 2 min
=  44-38  = 0.10 cm 3  s -1 180-120
b) Example from the graph, determine: ,[object Object],Total volume of gas at 2min – at 0min  Total time taken at 2min – at 0 min
=  38-0  = 0.33 cm 3  s -1 120-0
INSTANTANEOUS RATE OF REACTION  ( rate of reaction at that time)  Draw tangent to the graph  Y X Rate = Y/X
b) Example from the graph, determine: ,[object Object],Instantaneous rate of reaction = Draw tangent to the graph
=  56 – 20   = 0.176 cm 3  s -1 222-18
 
 
 
II I III Volume of gas Time ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
Example: Sketch curve that would be obtained with the changes below: original Lower temp Volume of gas Time Lower temperature is used
Example: Sketch curve that would be obtained with the changes below: original higher temp Volume of gas Time Higher temperature
Example: Sketch curve that would be obtained with the changes below: original Bigger size Volume of gas Time Bigger size of reactant is used
Example: Sketch curve that would be obtained with the changes below: original Smaller size Volume of gas Time Smaller size of reactant
Example: Sketch curve that would be obtained with the changes below: original higher temp Volume of gas Time Higher temperature
Example: Sketch curve that would be obtained with the changes below: original With catalyst Volume of gas Time Catalyst was added
Changes to the FLAT part of graph
Example: Curve I represents the result of the experiment using excess zinc powder and 50cm 3  of 1.0 moldm -3  dilute hydrochloric acid   I Volume of gas/ cm 3 Time/s
Draw curves when condition change: ORIGINAL: 50cm 3  of 1.0 moldm -3  dilute hydrochloric acid Change  : 50cm 3  of 2.0 moldm -3  dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s Change
Draw curves when condition change: ORIGINAL: 50cm 3  of 1.0 moldm -3  dilute hydrochloric acid Change  : 50cm 3  of 0.5 moldm -3  dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s Change
Draw curves when condition change: ori  :50cm 3  of 1.0 moldm -3  dilute hydrochloric acid  change : 50cm 3  of 0.5 moldm -3  dilute hydrochloric acid  ori Volume of gas/ cm 3 Time/s change
Draw curves when condition change: ORI  :  50cm 3  of 1.0 moldm -3  dilute hydrochloric acid  change : 20cm 3  of 1.0 moldm -3  dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s change
Draw curves when condition change: ori: 50cm 3  of 1.0 moldm -3  dilute hydrochloric acid  change: 25cm 3  of 2.0 moldm -3  dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s change
1. The effect of size of reactant ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
2. The effect of temperature ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
3. The effect of concentration ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
4. The effect of catalyst ,[object Object],[object Object],[object Object],[object Object],[object Object],[object Object]
exothermic reaction
Activation energy with catalyst Activation energy no catalyst reactant
[object Object],[object Object]
[object Object],[object Object]
[object Object],[object Object]
What is the catalyst used in the decomposition hydrogen peroxide?(1m) Manganese (IV) oxide
Write ionic equation for Sodium thiosulphate and sulphuric acid (2m)
End

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Discussion on rate of reaction =for quiz 1 and 2

  • 1. what is? Effective collision? Collision theory? Factors affecting? Activation energy? Energy level diagram? Rate of reaction
  • 2. AVERAGE RATE OF REACTION For the whole exp From X min to Y min On the X min (2 nd ) ( from 2 nd to 1 st ) For first x (3) min ( from 0 to 3rd )
  • 3.
  • 4. = 46 = 0.20 cm 3 s -1 210
  • 5.
  • 6. = 44-25 = 0.13 cm 3 s -1 180-60
  • 7.
  • 8. = 44-38 = 0.10 cm 3 s -1 180-120
  • 9.
  • 10. = 38-0 = 0.33 cm 3 s -1 120-0
  • 11. INSTANTANEOUS RATE OF REACTION ( rate of reaction at that time) Draw tangent to the graph Y X Rate = Y/X
  • 12.
  • 13. = 56 – 20 = 0.176 cm 3 s -1 222-18
  • 14.  
  • 15.  
  • 16.  
  • 17.
  • 18. Example: Sketch curve that would be obtained with the changes below: original Lower temp Volume of gas Time Lower temperature is used
  • 19. Example: Sketch curve that would be obtained with the changes below: original higher temp Volume of gas Time Higher temperature
  • 20. Example: Sketch curve that would be obtained with the changes below: original Bigger size Volume of gas Time Bigger size of reactant is used
  • 21. Example: Sketch curve that would be obtained with the changes below: original Smaller size Volume of gas Time Smaller size of reactant
  • 22. Example: Sketch curve that would be obtained with the changes below: original higher temp Volume of gas Time Higher temperature
  • 23. Example: Sketch curve that would be obtained with the changes below: original With catalyst Volume of gas Time Catalyst was added
  • 24. Changes to the FLAT part of graph
  • 25. Example: Curve I represents the result of the experiment using excess zinc powder and 50cm 3 of 1.0 moldm -3 dilute hydrochloric acid I Volume of gas/ cm 3 Time/s
  • 26. Draw curves when condition change: ORIGINAL: 50cm 3 of 1.0 moldm -3 dilute hydrochloric acid Change : 50cm 3 of 2.0 moldm -3 dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s Change
  • 27. Draw curves when condition change: ORIGINAL: 50cm 3 of 1.0 moldm -3 dilute hydrochloric acid Change : 50cm 3 of 0.5 moldm -3 dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s Change
  • 28. Draw curves when condition change: ori :50cm 3 of 1.0 moldm -3 dilute hydrochloric acid change : 50cm 3 of 0.5 moldm -3 dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s change
  • 29. Draw curves when condition change: ORI : 50cm 3 of 1.0 moldm -3 dilute hydrochloric acid change : 20cm 3 of 1.0 moldm -3 dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s change
  • 30. Draw curves when condition change: ori: 50cm 3 of 1.0 moldm -3 dilute hydrochloric acid change: 25cm 3 of 2.0 moldm -3 dilute hydrochloric acid ori Volume of gas/ cm 3 Time/s change
  • 31.
  • 32.
  • 33.
  • 34.
  • 36. Activation energy with catalyst Activation energy no catalyst reactant
  • 37.
  • 38.
  • 39.
  • 40. What is the catalyst used in the decomposition hydrogen peroxide?(1m) Manganese (IV) oxide
  • 41. Write ionic equation for Sodium thiosulphate and sulphuric acid (2m)
  • 42. End