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Hafiz Akmal 1
                     CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


              SULPHURIC ACID



                                  In the pure, concentrated
sulphuric acid is a diprotic      form, sulphuric acid is an
  (dibasic) mineral acid             oily, colourless liquid
 which does not volatise.             which is dense and
                                             viscous.




                    It has high boiling
                   point, that is 270 ˚C
Hafiz Akmal 2
                      CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


      USES OF SULPHURIC ACID




             18%
1%
                                                  38%          making fertiliser

12%                                                            paints

                                                               chemicals

                                                               detergents
       18%
                                    13%                        removing dust from steel

                                                               other uses




       Figure 1:- Uses of Sulphuric Acid, H2SO4
Hafiz Akmal 3
                                              CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry




                          2H2SO4 (l) + Ca3(PO4)2 (s)                     Ca(H2PO4)2 (l) + 2CaSO4 (s)




                                                         superphosphate
                                                             fertilisers :-
                                                       - it is manufactured
                                                        from the reaction
                                                        between sulphuric
                                                         acid and calcium
                                                             phosphate.




                                                            sulphuric
                                                              acid:
                                                             making
                                                            fertiliser



                                                                                          Ammonia Sulphate
                 Potassium Sulphate:-
                                                                                                 fertiliser:-
                - It is manufactured by
                                                                                          - It is manufactured
                  the neutralisation of
                                                                                          by the neutralisation
                       sulphuric acid
                                                                                          of sulphuric acid and
                  potassium hydoxide
                                                                                                  ammonia




2KOH(aq) + H2SO4(aq)               K2SO4(aq) + 2H2O (l)                   2NH3(aq) + H2SO4(aq)                    (NH4)2SO4(aq)
Hafiz Akmal 4
                      CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


MANUFACTURE OF SULPHURIC ACID

The manufacture of sulphuric acid in industry is through the
contact process.
The raw materials used to manufacture the acid are sulphur, air
and water.
The acid is produced in 3 stages:-



   Stage 1: The production of sulphur dioxide


         Stage 2: Formation of sulphur trioxide


              Stage 3: Formation of sulphuric acid
Hafiz Akmal 5
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                           STAGE 1:
THE PRODUCTION OF SULPHUR DIOXIDE




 a) This can be obtained through two methods:-
      a) Heating liquid sulphur with hot air in a furnace.
          S (s) + O2 (g)     SO2 (g)
      b) Heating sulphides in air, for example:
          4FeS2 (s) + 11O2 (g)       2Fe2O3 (s) + 8SO2 (g)
          SO2 is a side-product in the extraction of the metal, iron.
          [Fe2O3 is reduced to iron with coke]
          Zinc pyrites can also be heated in air as follows:
          2ZnO (s) + 3O2 (g)      2SO2 (g) + 2ZnO (s)
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                       CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                        STAGE 2:
 FORMATION OF SULPHUR TRIOXIDE




a) Pure, dry sulphur dioxide is mixed with dry oxygen in excess and
   passed over vanadium(V) oxide, V2O5 as catalyst at a temperature
   of 450˚C - 550˚C and a pressure of 1 atmosphere. The conditions
   ensure the maximum production of sulphur trioxide:
   2SO2 (g) + O2 (g)     2SO3 (g)
b) The reaction takes place in a heat converter.
c) Excess air is used to ensure higher percentage of SO3 produced.
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                        CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                         STAGE 3:
    FORMATION OF SULPHURIC ACID




a) The sulphur trioxide is dissolved in concentrated sulphuric acid to
   form a product called oleum, H2S2O7. This is carried out until the
   concentrated sulphuric acid has reached a concentration of
   99.5%.
   SO3 (g) + H2SO4 (aq)         H2S2O7 (l)
b) The product, oleum will not show any property of an acid. This is
   because, oleum will ‘not ionise’ without the presence of water.
c) Water is then added to the oleum to produce concentrated
   sulphuric acid.
   H2S2O7 (l) + H2O (l)        2H2SO4 (l)
d) The reaction in (a) and (b) is equivalent to dissolving sulphur
   trioxide in water.
   SO3 (g) + H2O (l)       H2SO4 (aq)
e) However, this reaction is not carried out in industry. This is
   because the reaction is too vigorous.
f) It produces a large cloud of sulphuric acid mist. This mist is
   corrosive and pollutes the air.
Hafiz Akmal 8
                           CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


               CONTACT PROCESS:

                                               Water




                          Concentrated H2SO4




       O2 , V2O5, 450˚C, 1 atm
                                                                        concentated
                                                       Oleum            sulphuric
                                                       H2S2O7           acid, H2SO4
Burnt in air
                                     Sulphur
                                     trioxide SO3
                      Sulphur
                      dioxide SO2

         Sulphur




                 Figure 2:- Flow chart of Contact Process
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                                                               CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


The industrial process in the Manufactured of Sulphuric Acid
Hafiz Akmal 10
                      CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


USES OF AMMONIA IN INDUSTRY:
                        Examples are ammonium sulphate, ammonium nitrate and urea.
                        The first two are prepare through neuralisation but urea is
                        produced by the reaction of ammonia with carbon dioxide. The
         To             reaction involved are as the following:
    manufacture
    nitrogenous
                        a) 2NH3 (g) + H2SO4 (aq)       (NH4)2SO4 (s) ammonium sulphate
     fertilisers        b) NH3 (g) + HNO3 (aq)         NH4NO3 (aq)     ammonium nitrate
                        c) 2NH3 (g) + CO2 (g)       (NH2)2CO (s) + H2O (l) urea


                                      Having a low melting point,
                                      liquefied ammonia makes a good
               As a cooling           cooling agent in refrigerators and
                  agent
                                      air conditioners.


                                              It neutralizes the organic acids formed
                     To prevent the
                                              by microorganisms in latex, thereby
                      coagulation of          preventing coagulation and preserving
                       latex in the           the latex in liquid form.
                     rubber industry


                                         Ammonia is converted to nitric acid in the Ostwald process:

                                         1)     ammonia is first oxidised to nitrogen monoxide, NO, by
                                                oxygen in the presence of platinum as catalyst at 900˚C.
                   To manufacture               4NH3 (g) + 5O2 (g) Pt/900˚C 4NO (aq) + 6H2O (l)
                     nitric acid in      2)     nitrogen monoxide is further oxidised to nitrogen
                       industry
                                                dioxide.
                                                2NO (g) + O2 (g)        2NO2 (g)
                                         3)     Nitrogen dioxide and oxygen are dissolved in water to
                                                produced nitric acid.
                                                4NO2 (g) + O2 (g) + H2O (l)       4HNO3 (aq)


                                          a)     Nitric acid is manufactured from ammonia before
                    To manufacture               being used to make explosive like trinitrotoluene
                       explosive                 (TNT).
                                          b)     Nitric acid, in this case, is reacted with organic
                                                 substances like toluene.
Hafiz Akmal 11
                         CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


     EXPERIMENT TO INVESTIGATE THE
        PROPERTIES OF AMMONIA

Aim:-
    To investigate the properties of ammonia

Material:-
    0.1 mol dm ammonia solution, 0.1 mol dm sodium hydroxide
    solution, ammonia chloride, calcium hydroxide, concentrated
    hydrochloric acid, soda lime, distilled water, red litmus paper, Ph
    paper.

Apparatus:-
    Test tubes, beaker, U-tube, Bunsen burner, glass rod, delivery
    tube, stoppers.

Procedure:-
  a) Preparation of ammonia gas:
        1. Some ammonium chloride is mixed with some calcium
           hydroxide.
        2. The apparatus as shown in Figure 3 is set up
Hafiz Akmal 12
                        CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry

     3. The mixture is heated
     4. The ammonia gas produced is collected in a few test tubes.
        The test tubes containing ammonia gas must be closed with
        stoppers.



b) Alkalinity of ammonia:
      1. 5.0 cm of 1 mol ammonia solution and 5 cm of 0.1 mol dm
         sodium hydroxide solution are poured into two separate test
         tubes.
      2. A piece of pH paper is dipped into the solution in each test
         tube.
      3. The pH values of both solution are recorded.



c) Colour, physical state, smell and solubility of ammonia:
     1. The colour and physical state of ammonia are observed.
     2. The stopper of a test tube containing ammonia gas is
        removed and the smell of the gas is identified.
     3. A test tube containing ammonia gas is inverted into a beaker
        of water.
     4. All observation are recorded.
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                        CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry

d) Density of ammonia:
     1. A test tube containing ammonia gas is held upright and
        another test rube containing ammonia gas is held upside
        down.
     2. The stopper of the two test tubes are removed.
     3. After 20 seconds, a piece of moist red litmus paper is put at
        the mouth of each test tube as shown in figure 5.
     4. The colour of the red litmus paper is recorded.




e) Chemical property of ammonia:
     1. One end of a glass rod is dipped into concentrated
        hydrochloric acid.
     2. The glass rod is then put on top of a test tube of ammonia
        gas.
     3. Any change taking place is observed.
Hafiz Akmal 14
                 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Observation :-

      Section       Observation                      Inference
                 pH of ammonia
                                                 ammonia is weak
                 solution is 10
                                                 alkali
        b)       pH of sodium
                                                 sodium hydroxide
                 hydroxide solution
                                                 is a strong alkali
                 is 14
                 colourless gas                  ammonia is a
                 pungent smell                   colourless gas with
         c)      water rushed up                 a pungent smell
                 and fills up the                ammonia is very
                 whole test tube                 soluble in water
                 moist red litmus
                 paper on top of the
                 upright test tube               Ammonia gas has
                 does not change                 escaped from the
        d)       colour.                         upright test tube
                 Moist red litmus                and thus is slightly
                 paper under the                 less dense than air
                 inverted test tube
                 turns blue
                                                 Ammonia react
                                                 with hydrogen
                 Dense white fumes
        e)       are formed
                                                 chloride gas to
                                                 form ammonium
                                                 chloride
Hafiz Akmal 15
                         CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Discussion:-
    Ammonia is a weak alkali and has a pH of 10
    Ammonia is a colourless gas with a pungent smell
    Ammonia is very soluble in water, ionize partially in water to form
    ammonium ions and hydroxide
    NH3 (g) + H2O (l) = NH4+ (aq) + OH- (aq)
    Ammonia is slightly less dense than air
    Ammonia react with hydrogen chloride gas to form ammonium
    chloride
    NH3 (g) + HCl (g) = NH4Cl (s)



Conclusion:-
    Ammonia is an alkaline, colourless gas with a pungent smell. It is
    very soluble in water and is less dense in than air. It react with
    hydrogen chloride gas to form dense white fumes of ammonium
    chloride
Hafiz Akmal 16
  CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


HABER PROCESS
Hafiz Akmal 17
                                                       CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


The manufacture of ammonia through the Haber Process
Hafiz Akmal 18
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


PREPARATION OF AMMONIA FERTILISER


Aim:-
    To prepare ammonium sulphate.

Material:-
    1 mol dm-2 sulphuric acid, 2 mol dm-3 ammonia solution, methyl
    orange, filter paper

Apparatus:-
    25.0 cm pipette, burette, conical flask, white tile, retort stand and
    clamp, beaker, glass rod, evaporating dish, filter funnel, Bunsen
    burner, tripod stand, wire gauze.

Procedure:-
  a) Determining the volume of sulphuric acid that will neutralize 25.0
     cm of ammonia solution:-
       1. 25.0 cm of 2 mol dm-3 ammonia solution is transferred by a
          pipette to a clean conical flask.
       2. Three drops of methyl orange indicator are added to the
          alkali. The solution turns yellow.
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                   CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry

3. A clean burette is filled with 1 mol dm-2 sulphuric acid and
   clamped to a retort stand. The initial burette reading is
   recorded.
4. The conical flask with its content is placed on a white tile
   below the burette as shown in figure 6 below.




5. The sulphuric acid is added slowly into the conical flask. The
   conical flask is swirled gently throughout the titration.
6. The addition of sulphuric acid is stopped when the indicator
   changes from yellow to orange. The final burette reading is
   recorded.
7. The volume of acid needed to completely neutralize the 25.0
   cm of 2 mol dm-3 ammonia solution is calculated. Let this
   volume V cm.
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                         CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry

  b) Preparation ammonium sulphate salt:-




       1. 25.0 cm of 2 mol dm-3 ammonia solution is pipetted into a
          clean conical flask. No indicator is added.
       2. V cm of 1 mol sulphuric acid is added from the burette to the
          ammonia solution.
       3. The mixture in the conical flask is transferred to an
          evaporating dish and heated until a saturated solution is
          formed.
       4. The hot, saturated salt solution is left to cool for
          crystallization to occur.
       5. The crystal of ammonium sulphate formed are filtered,
          ashed and dried between sheets of filter paper.



Observation:-
    A colourless solution is formed when sulphuric acid is added to
    ammonia solution.
    The crystal obtained are white in colour
Hafiz Akmal 21
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Discussion:-
    The equation for the reaction is:
    H2SO4 (aq) + 2NH4OH (aq)           (NH4)2SO4 (aq) + 2H2O (l)
    Methyl orange is an acid-base indicator used to determine the
    end point of the titration.
    The first titration is carried out to determine the exact volume of
    sulphuric acid required to completely neutralize the 25.0 cm of
    ammonia solution.
    The salt solution in the first titration is discarded because it is
    contaminated by methyl orange.
    The ammonium sulphate solution should not be heated until
    dryness because ammonium sulphate decomposes when it is
    overheated.
    The weight of ammonium sulphate obtained from the activity is
    always less than the theorical value. This is because some of the
    salt is not fully crystallized out and still remains in the solution.
    Other ammonium salt such as ammonium nitrate can be prepared
    from the reaction between nitric acid and ammonium solution.

Conclusion:-
    Ammonium sulphate and other ammonium fertilizers can be
    prepared by neutralizing ammonia solution with the respective
    acids.
Hafiz Akmal 22
           CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


THE PHYSICAL PROPERTIES OF PURE
             METAL
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                                            CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                       PROPERTIES OF AMMONIA


                                           Ammonia turns
                                           the damp red
                                           litmus paper
                                           blue.
                                           The gas is less
                                           dense than air
                                                                             +      -
                                                               NH3 + H2O   NH4 OH



                                                         alkaline
An inverted filter funnel is used                      gas, colurless
                                                       and pungent
to prevent sucking back of water                            gas                               Aqueous solutions of ammonia
                                                                                              react with metal ions (except
                                                                                              Na+, K+, and Ca2+) to produce
                                                                                              precipitate of metal hydroxide




                                                                                        Ammonia is weak alkali which
                                                                                        reacts with dilute acids in
                                                                                        neutralization to produce salt.
                   Ammonia gas burns in oxygen to                                        2NH3 + H2SO4     (NH4)2SO4
                   produce nitrogen monoxide gas

                   4NH3 + 5O2       4NO + 6H2O
Hafiz Akmal 24
                            CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                                ALLOY


Meaning and purpose of making alloy:-
    Alloying is a process of mixing two or more metals (or mixing
    metals with element such carbon) which cannot be separated
    using physical way

Arrangement of atoms in alloys:-




             Pure metal A                       Pure metal B




                                   Alloys
Hafiz Akmal 25
                           CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


  COMPARE THE HARDNESS OF A PURE
      METAL AND ITS ALLOYS

Aim:-
     To compare the hardness of a pure metal and its alloy.

Problem Statement:-
     Are alloys harder than pure metal ?

Hypothesis:-
     Bronze is harder than cooper.

Variables:-
     Manipulated: Different types of materials (cooper & bronze)
     Responding: diameter of the dent
     Controlled: diameter of steel ball bearing, height of the weight,
     mass of the weight.

Operational definition:-
  1) If the diameter of the dent is smaller, then the material is harder

Materials:-
  2) Cooper block, bronze block, cellophane tape
Hafiz Akmal 26
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Apparatus:-
  3) Retort stand and clamp, 1-kg weight, metre ruler, steel ball
     bearing, thread.

Procedure:-
  1) A steel ball bearing is taped onto a cooper block using cellophane
     tape.
  2) A 1-kg weight is hung at a height of 50 cm above the cooper block
     as shown in the figure 8.




  3) The weight is allowed to drop onto the ball bearing.
  4) The diameter of the dent made by the ball bearing on the cooper
     block is measured.
  5) Steps 1-4 are repeated twice on the other parts of the cooper
     block in order to obtain an average value for the diameter of
     dents formed.
  6) Steps 1-5 are repeated using a bronze block to replace the cooper
     block.
  7) The reading are recorded in the table.
Hafiz Akmal 27
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Results:-



                            DIAMETER OF THE DENT (mm)
  METAL
                    1            2            3                        average
  Cooper           2.9              2.8                2.9                2.9
  Bronze           2.1              2.2                2.2                2.2


Discussion:-
  1) The smaller the diameter of the dent, the harder and stronger is
     the material.
  2) The average diameter of the dent made on the surface on the
     cooper block is bigger than the bronze block.
  3) Based on the result, bronze is harder than cooper.



Conclusion:-
     The hypothesis is accepted.
Hafiz Akmal 28
            CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


   EXAMPLE OF ALLOYS




                      Brass




                                            Stainless
 Bronze
                                              Steel


Bronze                                                  steel
                  EXAMPLE
                  OF ALLOY


Manganese
  Steel


Pewter
                                          Stainless steel
                   Manganese
                     steel
Hafiz Akmal 29
                           CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


 THE RATE OF RUSTING OF IRON, STEEL,
        AND STAINLESS STEEL


Aim:-
     To compare the rate of rusting of iron, steel and stainless steel.

Problem statement:-
     How does the rate of rusting of iron, steel and stainless steel
     differ?

Hypothesis:-
     Iron rust faster than steel, and steel rust faster than stainless
     steel.

Variables:-
     Manipulated variable: Different types of nails
     Responding variable: Intensity & amount of blue colour
     Controlled variable: Size of nails, concentration of solution used,
     durations for rusting.

Operational definition:-
     The more intense the blue colour formed, the higher is the rate of
     rusting.
Hafiz Akmal 30
                           CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Materials:-
    Iron nail, steel nail, stainless steel nail, jelly solution, potassium
    hexacyanoferrate(lll) solution, water, sandpaper.

Apparatus:-
    Test tubes, test tube rack.

Procedure:-
  1) The nails are rubbed using sandpaper to remove the rust from the
     surface of the nails.
  2) The iron nail placed in the test tube A, the steel nail in test tube B
     and the stainless steel nail in test tube C.
  3) A 5% jelly solution is prepared by adding 5 g of jelly into 100 cm of
     boiling water. A few drops of potassium hexacyanoferrate(lll)
     solution are then added to the jelly solution.
  4) The hot jelly solution is poured into the three test tubes until all
     the nails are fully immersed.




  5) The test tubes are placed in a test tube rack and left aside for
     three days. The intensity of the blue colour is observed.
  6) All observation are recorded in the table.
Hafiz Akmal 31
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


Observation:-

Test tube   Intensity of blue colour                  Inference
    A              Very High                   Rusting occurs very fast
    B                 Low                       Rusting occurs slowly
    C                  Nil                       No rusting occurs


Discussion:-
  1) When iron rust, each iron atom loses two electrons to form an
     iron(ll) ion, Fe2+.
     Fe (s) = Fe2+ (aq) + 2e- (aq)
  2) Potassium hexacyanoferrate(lll) solution is added to the jelly
     solution as an indicator to detect iron(ll) ions.
  3) When there is iron(ll) ion, potassium hexacyanoferrate(lll)
     solution will form dark blue colouration.
  4) The higher the intensity of the blue colour, the higher is the rate
     of rusting.
  5) Solidified jelly solution is used to trap and see the blue
     colouration clearly. This is because diffusions occurs the slowest
     in solids.
  6) Based on the observation, iron rust faster than steel. Stainless
     steel does not rust.
  7) The nail made from stainless steel does not rust. This is because
     this nail is an alloy of iron with carbon, chromium and nickel.
Hafiz Akmal 32
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry

  8) The nail made from steel will rust slowly. The presence of carbon
     atoms will make the steel stronger than iron but does not prevent
     it from rusting.
  9) Rusting of iron is an example of corrosion. When corrosion occurs,
     the metal loses electrons to form metal iron.

Conclusion:-
    Iron rust faster than steel. Stainless steel does not rust.
    Hypothesis is accepted.
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                            CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


COMPOSITONS OF ALLOYS & THEIR USES


   Alloy      Composition       Properties                         Uses
                Cu 75%        Hard, strong,
Cupronickel                                          Coins
                Ni 25%        resist corrosion
                Al 95%
                                                     Aeroplane part, electric cables
Duralumin       Cu 4%         Light, strong
                                                     racing bicycles
                Mg 1%
                Fe 99%        Hard, strong,
Steel                                                Vehicles, bridges, buildings
                 C 1%         cheap
                Fe 73%
                                                     Kitchen appliance, watches,
Stainless       Cr 18%        Hard, rust
                                                     knifes, fork, spoons, machine
steel            Ni 8%        resistant
                                                     parts
                 C 1%
                Cu 90%        Hard, strong,          Decorative items, medals,
bronze
                Sn 10%        shining                artwork, pots & pans
                Cu 70%        Harder and             Musical instrument, bell, nails,
Brass
                Zn 30%        cheaper than Cu        screw, and pots
                Pb 50%        Low melting
Solder                                               Welding, soldering work
                Sn 50%        point, strong
                Sn 91%        Malleable,
Pewter           Sb 7%        ductile, rust          Decorative items,souvenirs
                Cu 2%         resistant
                Al 70%                               Tyre rim of racing car, skeletal
Magnalium                     Light, strong
                Mg 30%                               body of aeroplane
Hafiz Akmal 34
                     CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                     POLYMER


                            large molicule
                          that is in the form
                          of long chain with
                              high RMM




                        POLYMER
                                                made up of many
   two types:-                                  monomers which
                                                  join together
- natural polymer
                                                through process
- syntetic polymer                                    called
                                                 polymerisation
Hafiz Akmal 35
                          CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                    NATURAL POLYMER




Monomer        acid         Monomer        glucose            Monomer      isoprene
amino                       Eg: in starch and                 (2-methylbuta-1,3
Eg: in muscle, skin,        cellulose                         diene)
silk, hairs, wools, and                                       Eg: in latex
furs
Hafiz Akmal 36
                                      CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


     SYNTHETIC POLYMER & IT USES
Synthetic polymers are polymers made in industry from chemical
substances.
Many of the raw materials for synthetic polymers are obtained from
petroleum, after refining and cracking process.




        Synthetic                        Synthetic fibres
                                                                                 Thermoplastic
         rubber                           (long chained polymer that withstand
                                                        streching)




                                                   Nylon (monomers:                 Polyvinyl chloride(PVC)
            Styrene- butadlene
                                                diamine and dicarboxylic                 (monomers:
         rubber (SBR) (monomers:
                                                          acid)                         chloroethene)
           styrene & butadlene.
                                                       eg:- synthetic               eg:- rain clothes, water
          eg:- shoe soles & tyres
                                                       textile, string                        pipes



          Neoprene (monomers:                     Terrylene (monomers:                   Polythene
              chloroprene)                         diol and dicarboxylic             (monomers: ethene)
         eg:- gloves, electric wire                        acid)                         eg:- battery
          insulator, water pipes                      eg:- fishing net             cases, pails, plastic bags



                                                                                         Polystytrene
         Butyl rubber (monomers:
                                                                                         (monomers:
          isobutylene & isoprene)
                                                                                        phenylethene)
            eg:- inner tubing of
                                                                                   eg:- toys, disposable cup
          tyre, hoses, shoe soles
                                                                                           and plates



           Perspex (monomers:                                                          Polypropene
           methyl metacrylate)                                                      (monomers: propene)
         eg:- spectacles, car lamps                                                   eg:- plastic bottles
Hafiz Akmal 37
                   CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


WHY USE SYNTETIC POLYMERS IN
         DAILY LIFE?



                            Strong &
                              light



       easily                                can be made
    moulded or                                 to have
    shaped & be                                 special
      coloured      Synthetic                 properties


                    polymers

           able to resist
                                        cheap
            corrosion
Hafiz Akmal 38
                                     CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


  ENVIRONMENTAL POLLUTION
RESULTING FROM THE DISPOSAL OF
     SYNTHETIC POLYMERS


                                            AIR POLLUTION
                                      - caused by burning of plastic
                                         eg: burning of PVC will
                                       produce dioxin. (dioxin will
                                        destroy human immune
                                      system, reproductive system
                                           & nervous system




                                           Effects of
                                           improper
                                          Disposal of
                                           Synthetic
         SOIL POLLUTION                     Polymer
  - plastic thrown on land fill up                                         WATER POLLUTION
          our living spaces                                            - plastic will stop the flow of
      - destroy the beauty of                                           river water and drains. this
             environment                                                   will cause flash floods.
  -plastic also cause the soil not                                     - plastic also cause the death
   suitable for planting because                                         of marine organism if they
    plastic inhibit the growth of                                      mistaken the plastic as food.
                 root
Hafiz Akmal 39
                                 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                                     GLASS
Glass:-
     The major component of glass is silica or silicon dioxide, SiO2
     which found in sand.ri




                                         Impermeable
                                           to liquid



                                                           Electrical
                     Transparent
                                                           insulator



                                          Properties
                                           of glass



                      hard but
                                                         Heat insulator
                       brittle



                                          Chemically
                                            inert
Hafiz Akmal 40
                                CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


TYPES, COMPOSITION, PROPERTIES, AND
           USES OF GLASS


      GLASS            COMPOSITION            PROPERTIES                     USES
                                           Low melting point           Glass container
                        SiO2 – 70%         Mouldable into shapes       Glass panes
                        Na2O – 15%         Cheap                       Mirror
 Soda lime glass
                        CaO – 10%          Breakable                   Lamps and bulbs
                        Others – 4%        Can withstand high          Plates and bowls
                                           heat                        Bottles
                                           High density and            Containers for drinks
                                           refractive index            and food
                        SiO2 – 70%
                                           Glittering surface          Decorative glass
Lead glass (crystal)    Na2O – 20%
                                           Soft                        Crystal glassware
                        PbO – 10%
                                           Low melting point           Lens for spectacles
                                           (600˚C)
                                           Resistant to high heat      Glass apparatus in lab
                        SiO2 – 80%
                                           &chemical reaction          Cooking utensils
Borosilicate glass      B2O3 – 13%
                                           Does not break easily
    (Pyrex)             Na2O – 4%
                                           Allow infra-red rays
                        Al2O3 – 2%
                                           but no ultra-violet rays
                                           High melting point          Scientific apparatus
                                           (1700˚C)                    like lens on
                                           Expensive                   spectrometer
                         SiO2 – 99%
Fused silicate glass                       Allow ultraviolet to        Optical lens
                         B2O3 – 1%
                                           pass through                Lab apparatus
                                           Difficult to melt or
                                           mould into shape
Hafiz Akmal 41
                              CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


                              CERAMICS
Ceramics:-
    Ceramic is manufactured substances made from clay that is dried,
    and heated in a kiln at a very high temperature
    The main component of clay is aluminosilicate (aluminum oxide
    and silicon dioxide) with small quantities of sand and feldspar.
    Unlike glass, ceramic cannot be recycled.
    Kaolinite is a high quality white clay that contains hydrated
    aluminosilicate, Al2O3•2SiO2•2H2O.



                                    extremely
                                      hard &
                                    strong but
                                      brittle


              able to                                    has a very
             withstand                                     high
             and resist                                   melting
             corrosion              Properties             point
                                        of
                                     ceramics



                         good
                     insulator of                 inert to
                      electricity                chemicals
                       and heat
Hafiz Akmal 42
                        CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


THE DIFFERENT CLASES OF CERAMIC

       GROUP                             COMPOSITION
Mineral                    Quartz – SiO2
                           Calcite – CaCO3
Cement material            Mixture of CaSiO3 and ammonium silicate
Oxide of ceramic           Aluminium oxide – Al2O3
                           Silicon dioxide – SiO2
                           Magnesium oxide – MgO
Non-oxides of ceramic      Silicon nitride – Si3N4
                           Silicon carbide – SiC
                           Boron nitride – BN
                           Boron carbide – B4C3
Hafiz Akmal 43
                                                                     CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


          THE USES OF IMPROVED GLASS AND
          CERAMICS FOR SPECIFIC PURPOSES



GLASS OPTICAL FIBRE                   CONDUCTING GLASS                      GLASS-CERAMIC                         CERAMIC                            PHOTOCHROMIC GLASS
• A pure silica glass thread that     • a type of glass that can conduct    • Rearrange its atoms into regular    SUPERCONUCTOR                      • sensitive to light intensity
  conducts light.                       electricity.                          patterns by heating glass to form   • superconductor can conduct       • the glass darken when exposed
• this fibres can transmit messages   • produce by embedding a thin           strong material                       electricity at low temoerature     to sunlight but became clear
  modulated onto light waves.           layer of conducting material in     • it can withstand high                 without resistance, loss of        when light intensity decresase.
• used inmedical instrument, LAN        glass.                                temperature, chemical attacks         electrical energy as heat        • used in windows, sunglasses ad
                                      • adding a layer of indium tin(iv)    • used in                             • used to make light                 instrument control
                                        oxide (ITO) acts as an electrical     tile, cookware, rockets, engine       magnet, electric
                                        conductor.                            blocks                                motors, electrical generators
                                      • used in the making of LCD
Hafiz Akmal 44
                      CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry


           COMPOSITE MATERIALS
A composite material is structural material formed by
combining two or more materials with different physical
properties, producing a complex mixture.
They are used to make various substances in daily life
because of the following reasons:-
  a) Metals corrode and are ductile and malleable
  b) Glass and ceramic break easily
  c) Metal are good conductors but have high resistant,
     leading to loss of electrical energy as heat.
  d) Plastic and glass can withstand heat to a certain level
     only
Hafiz Akmal 45
                                         CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry



  COMPOSITE                               PROPERTIES OF           PROPERTIES OF
                      COMPONENT                                                                    USES
   MATERIAL                                COMPONENT               COMPOSITE
                      concrete              hard but brittle      stronger                  construction of road
                                            low tensile strengh   higher tensile strength   rocket launching pads
                                                                  does not corrode          high-rise buildings
                                                                  easily
                                                                  cheaper
Reinforced concrete                                               can be moulded into
                                                                  shape
                      steel                 strong in tensile     can withstand very
                                            strength              high applied force
                                            expensive             can support very
                                            can corrode           heavy load

                      Cooper(ll) oxide      Insulator of          Conducts electricity      Magnetically levitated
                      Yttrium oxide         electricity           without resistance        train
 Superconductor       Barium oxide                                when cooled by liquid     Transformer
                                                                  nitrogen                  Electric cable
                                                                                            Computer parts
                      Glass                 Transparent           Reduce refraction of      Information display
                                            Not sensitive to      light                     panels
                                            light                 Control the amount of     Light detector device
                                                                  light passed through it   Car windshields
                                                                  auto.                     Optical lens
Photochromic glass
                      Silver chloride       Sensitive to light    Has the ability to
                      or silver                                   change colour and
                      bromide                                     become darker when
                                                                  exposed to ultraviolet
                                                                  light
                      Glass with low        Transparent           Low material cost         Transmit data using
                      refraction index      Does not reflect      Reflect light rays and    light waves in
                                            light rays            allow to travel along     telecommunications
                                                                  the fibre
    Fibre optics                                                  Can transmit
                                                                  electronic data or
                      Glass with
                                                                  signal, voice and
                      higher
                                                                  image
                      refractive index

                      glass                 high density          high tensile strength     car bodies
                                            strong but brittle    moulded and shaped        helmets
                                            non-flexible          inert to chemicals        skies
                                                                  light, strong, tough      rackets
    Fibre glass       polyester             light
                                                                  non-flammable             furniture
                      plastic               flexible
                                                                  impermeable to water
                                            inflammable
                                                                  resilient
                                            elastic but weak
                                                                  flexible
Hafiz Akmal 46
                 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry




                          in the medical
                         field: to replace
                       organs in the form
                             of plastic
                        composite organ




                        Uses of
                       composite
                        material
 car part now use
composite material
                                              sronger buildings
  instead iron and
                                              are built by using
steel. this increase
                                             reinforce concrete
  the speed of the
 car and fuel saver

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15102759 chemistry-folio-chapter-9-spm

  • 1. Hafiz Akmal 1 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry SULPHURIC ACID In the pure, concentrated sulphuric acid is a diprotic form, sulphuric acid is an (dibasic) mineral acid oily, colourless liquid which does not volatise. which is dense and viscous. It has high boiling point, that is 270 ˚C
  • 2. Hafiz Akmal 2 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry USES OF SULPHURIC ACID 18% 1% 38% making fertiliser 12% paints chemicals detergents 18% 13% removing dust from steel other uses Figure 1:- Uses of Sulphuric Acid, H2SO4
  • 3. Hafiz Akmal 3 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry 2H2SO4 (l) + Ca3(PO4)2 (s) Ca(H2PO4)2 (l) + 2CaSO4 (s) superphosphate fertilisers :- - it is manufactured from the reaction between sulphuric acid and calcium phosphate. sulphuric acid: making fertiliser Ammonia Sulphate Potassium Sulphate:- fertiliser:- - It is manufactured by - It is manufactured the neutralisation of by the neutralisation sulphuric acid of sulphuric acid and potassium hydoxide ammonia 2KOH(aq) + H2SO4(aq) K2SO4(aq) + 2H2O (l) 2NH3(aq) + H2SO4(aq) (NH4)2SO4(aq)
  • 4. Hafiz Akmal 4 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry MANUFACTURE OF SULPHURIC ACID The manufacture of sulphuric acid in industry is through the contact process. The raw materials used to manufacture the acid are sulphur, air and water. The acid is produced in 3 stages:- Stage 1: The production of sulphur dioxide Stage 2: Formation of sulphur trioxide Stage 3: Formation of sulphuric acid
  • 5. Hafiz Akmal 5 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry STAGE 1: THE PRODUCTION OF SULPHUR DIOXIDE a) This can be obtained through two methods:- a) Heating liquid sulphur with hot air in a furnace. S (s) + O2 (g) SO2 (g) b) Heating sulphides in air, for example: 4FeS2 (s) + 11O2 (g) 2Fe2O3 (s) + 8SO2 (g) SO2 is a side-product in the extraction of the metal, iron. [Fe2O3 is reduced to iron with coke] Zinc pyrites can also be heated in air as follows: 2ZnO (s) + 3O2 (g) 2SO2 (g) + 2ZnO (s)
  • 6. Hafiz Akmal 6 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry STAGE 2: FORMATION OF SULPHUR TRIOXIDE a) Pure, dry sulphur dioxide is mixed with dry oxygen in excess and passed over vanadium(V) oxide, V2O5 as catalyst at a temperature of 450˚C - 550˚C and a pressure of 1 atmosphere. The conditions ensure the maximum production of sulphur trioxide: 2SO2 (g) + O2 (g) 2SO3 (g) b) The reaction takes place in a heat converter. c) Excess air is used to ensure higher percentage of SO3 produced.
  • 7. Hafiz Akmal 7 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry STAGE 3: FORMATION OF SULPHURIC ACID a) The sulphur trioxide is dissolved in concentrated sulphuric acid to form a product called oleum, H2S2O7. This is carried out until the concentrated sulphuric acid has reached a concentration of 99.5%. SO3 (g) + H2SO4 (aq) H2S2O7 (l) b) The product, oleum will not show any property of an acid. This is because, oleum will ‘not ionise’ without the presence of water. c) Water is then added to the oleum to produce concentrated sulphuric acid. H2S2O7 (l) + H2O (l) 2H2SO4 (l) d) The reaction in (a) and (b) is equivalent to dissolving sulphur trioxide in water. SO3 (g) + H2O (l) H2SO4 (aq) e) However, this reaction is not carried out in industry. This is because the reaction is too vigorous. f) It produces a large cloud of sulphuric acid mist. This mist is corrosive and pollutes the air.
  • 8. Hafiz Akmal 8 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry CONTACT PROCESS: Water Concentrated H2SO4 O2 , V2O5, 450˚C, 1 atm concentated Oleum sulphuric H2S2O7 acid, H2SO4 Burnt in air Sulphur trioxide SO3 Sulphur dioxide SO2 Sulphur Figure 2:- Flow chart of Contact Process
  • 9. Hafiz Akmal 9 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry The industrial process in the Manufactured of Sulphuric Acid
  • 10. Hafiz Akmal 10 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry USES OF AMMONIA IN INDUSTRY: Examples are ammonium sulphate, ammonium nitrate and urea. The first two are prepare through neuralisation but urea is produced by the reaction of ammonia with carbon dioxide. The To reaction involved are as the following: manufacture nitrogenous a) 2NH3 (g) + H2SO4 (aq) (NH4)2SO4 (s) ammonium sulphate fertilisers b) NH3 (g) + HNO3 (aq) NH4NO3 (aq) ammonium nitrate c) 2NH3 (g) + CO2 (g) (NH2)2CO (s) + H2O (l) urea Having a low melting point, liquefied ammonia makes a good As a cooling cooling agent in refrigerators and agent air conditioners. It neutralizes the organic acids formed To prevent the by microorganisms in latex, thereby coagulation of preventing coagulation and preserving latex in the the latex in liquid form. rubber industry Ammonia is converted to nitric acid in the Ostwald process: 1) ammonia is first oxidised to nitrogen monoxide, NO, by oxygen in the presence of platinum as catalyst at 900˚C. To manufacture 4NH3 (g) + 5O2 (g) Pt/900˚C 4NO (aq) + 6H2O (l) nitric acid in 2) nitrogen monoxide is further oxidised to nitrogen industry dioxide. 2NO (g) + O2 (g) 2NO2 (g) 3) Nitrogen dioxide and oxygen are dissolved in water to produced nitric acid. 4NO2 (g) + O2 (g) + H2O (l) 4HNO3 (aq) a) Nitric acid is manufactured from ammonia before To manufacture being used to make explosive like trinitrotoluene explosive (TNT). b) Nitric acid, in this case, is reacted with organic substances like toluene.
  • 11. Hafiz Akmal 11 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry EXPERIMENT TO INVESTIGATE THE PROPERTIES OF AMMONIA Aim:- To investigate the properties of ammonia Material:- 0.1 mol dm ammonia solution, 0.1 mol dm sodium hydroxide solution, ammonia chloride, calcium hydroxide, concentrated hydrochloric acid, soda lime, distilled water, red litmus paper, Ph paper. Apparatus:- Test tubes, beaker, U-tube, Bunsen burner, glass rod, delivery tube, stoppers. Procedure:- a) Preparation of ammonia gas: 1. Some ammonium chloride is mixed with some calcium hydroxide. 2. The apparatus as shown in Figure 3 is set up
  • 12. Hafiz Akmal 12 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry 3. The mixture is heated 4. The ammonia gas produced is collected in a few test tubes. The test tubes containing ammonia gas must be closed with stoppers. b) Alkalinity of ammonia: 1. 5.0 cm of 1 mol ammonia solution and 5 cm of 0.1 mol dm sodium hydroxide solution are poured into two separate test tubes. 2. A piece of pH paper is dipped into the solution in each test tube. 3. The pH values of both solution are recorded. c) Colour, physical state, smell and solubility of ammonia: 1. The colour and physical state of ammonia are observed. 2. The stopper of a test tube containing ammonia gas is removed and the smell of the gas is identified. 3. A test tube containing ammonia gas is inverted into a beaker of water. 4. All observation are recorded.
  • 13. Hafiz Akmal 13 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry d) Density of ammonia: 1. A test tube containing ammonia gas is held upright and another test rube containing ammonia gas is held upside down. 2. The stopper of the two test tubes are removed. 3. After 20 seconds, a piece of moist red litmus paper is put at the mouth of each test tube as shown in figure 5. 4. The colour of the red litmus paper is recorded. e) Chemical property of ammonia: 1. One end of a glass rod is dipped into concentrated hydrochloric acid. 2. The glass rod is then put on top of a test tube of ammonia gas. 3. Any change taking place is observed.
  • 14. Hafiz Akmal 14 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Observation :- Section Observation Inference pH of ammonia ammonia is weak solution is 10 alkali b) pH of sodium sodium hydroxide hydroxide solution is a strong alkali is 14 colourless gas ammonia is a pungent smell colourless gas with c) water rushed up a pungent smell and fills up the ammonia is very whole test tube soluble in water moist red litmus paper on top of the upright test tube Ammonia gas has does not change escaped from the d) colour. upright test tube Moist red litmus and thus is slightly paper under the less dense than air inverted test tube turns blue Ammonia react with hydrogen Dense white fumes e) are formed chloride gas to form ammonium chloride
  • 15. Hafiz Akmal 15 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Discussion:- Ammonia is a weak alkali and has a pH of 10 Ammonia is a colourless gas with a pungent smell Ammonia is very soluble in water, ionize partially in water to form ammonium ions and hydroxide NH3 (g) + H2O (l) = NH4+ (aq) + OH- (aq) Ammonia is slightly less dense than air Ammonia react with hydrogen chloride gas to form ammonium chloride NH3 (g) + HCl (g) = NH4Cl (s) Conclusion:- Ammonia is an alkaline, colourless gas with a pungent smell. It is very soluble in water and is less dense in than air. It react with hydrogen chloride gas to form dense white fumes of ammonium chloride
  • 16. Hafiz Akmal 16 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry HABER PROCESS
  • 17. Hafiz Akmal 17 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry The manufacture of ammonia through the Haber Process
  • 18. Hafiz Akmal 18 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry PREPARATION OF AMMONIA FERTILISER Aim:- To prepare ammonium sulphate. Material:- 1 mol dm-2 sulphuric acid, 2 mol dm-3 ammonia solution, methyl orange, filter paper Apparatus:- 25.0 cm pipette, burette, conical flask, white tile, retort stand and clamp, beaker, glass rod, evaporating dish, filter funnel, Bunsen burner, tripod stand, wire gauze. Procedure:- a) Determining the volume of sulphuric acid that will neutralize 25.0 cm of ammonia solution:- 1. 25.0 cm of 2 mol dm-3 ammonia solution is transferred by a pipette to a clean conical flask. 2. Three drops of methyl orange indicator are added to the alkali. The solution turns yellow.
  • 19. Hafiz Akmal 19 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry 3. A clean burette is filled with 1 mol dm-2 sulphuric acid and clamped to a retort stand. The initial burette reading is recorded. 4. The conical flask with its content is placed on a white tile below the burette as shown in figure 6 below. 5. The sulphuric acid is added slowly into the conical flask. The conical flask is swirled gently throughout the titration. 6. The addition of sulphuric acid is stopped when the indicator changes from yellow to orange. The final burette reading is recorded. 7. The volume of acid needed to completely neutralize the 25.0 cm of 2 mol dm-3 ammonia solution is calculated. Let this volume V cm.
  • 20. Hafiz Akmal 20 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry b) Preparation ammonium sulphate salt:- 1. 25.0 cm of 2 mol dm-3 ammonia solution is pipetted into a clean conical flask. No indicator is added. 2. V cm of 1 mol sulphuric acid is added from the burette to the ammonia solution. 3. The mixture in the conical flask is transferred to an evaporating dish and heated until a saturated solution is formed. 4. The hot, saturated salt solution is left to cool for crystallization to occur. 5. The crystal of ammonium sulphate formed are filtered, ashed and dried between sheets of filter paper. Observation:- A colourless solution is formed when sulphuric acid is added to ammonia solution. The crystal obtained are white in colour
  • 21. Hafiz Akmal 21 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Discussion:- The equation for the reaction is: H2SO4 (aq) + 2NH4OH (aq) (NH4)2SO4 (aq) + 2H2O (l) Methyl orange is an acid-base indicator used to determine the end point of the titration. The first titration is carried out to determine the exact volume of sulphuric acid required to completely neutralize the 25.0 cm of ammonia solution. The salt solution in the first titration is discarded because it is contaminated by methyl orange. The ammonium sulphate solution should not be heated until dryness because ammonium sulphate decomposes when it is overheated. The weight of ammonium sulphate obtained from the activity is always less than the theorical value. This is because some of the salt is not fully crystallized out and still remains in the solution. Other ammonium salt such as ammonium nitrate can be prepared from the reaction between nitric acid and ammonium solution. Conclusion:- Ammonium sulphate and other ammonium fertilizers can be prepared by neutralizing ammonia solution with the respective acids.
  • 22. Hafiz Akmal 22 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry THE PHYSICAL PROPERTIES OF PURE METAL
  • 23. Hafiz Akmal 23 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry PROPERTIES OF AMMONIA Ammonia turns the damp red litmus paper blue. The gas is less dense than air + - NH3 + H2O NH4 OH alkaline An inverted filter funnel is used gas, colurless and pungent to prevent sucking back of water gas Aqueous solutions of ammonia react with metal ions (except Na+, K+, and Ca2+) to produce precipitate of metal hydroxide Ammonia is weak alkali which reacts with dilute acids in neutralization to produce salt. Ammonia gas burns in oxygen to 2NH3 + H2SO4 (NH4)2SO4 produce nitrogen monoxide gas 4NH3 + 5O2 4NO + 6H2O
  • 24. Hafiz Akmal 24 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry ALLOY Meaning and purpose of making alloy:- Alloying is a process of mixing two or more metals (or mixing metals with element such carbon) which cannot be separated using physical way Arrangement of atoms in alloys:- Pure metal A Pure metal B Alloys
  • 25. Hafiz Akmal 25 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry COMPARE THE HARDNESS OF A PURE METAL AND ITS ALLOYS Aim:- To compare the hardness of a pure metal and its alloy. Problem Statement:- Are alloys harder than pure metal ? Hypothesis:- Bronze is harder than cooper. Variables:- Manipulated: Different types of materials (cooper & bronze) Responding: diameter of the dent Controlled: diameter of steel ball bearing, height of the weight, mass of the weight. Operational definition:- 1) If the diameter of the dent is smaller, then the material is harder Materials:- 2) Cooper block, bronze block, cellophane tape
  • 26. Hafiz Akmal 26 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Apparatus:- 3) Retort stand and clamp, 1-kg weight, metre ruler, steel ball bearing, thread. Procedure:- 1) A steel ball bearing is taped onto a cooper block using cellophane tape. 2) A 1-kg weight is hung at a height of 50 cm above the cooper block as shown in the figure 8. 3) The weight is allowed to drop onto the ball bearing. 4) The diameter of the dent made by the ball bearing on the cooper block is measured. 5) Steps 1-4 are repeated twice on the other parts of the cooper block in order to obtain an average value for the diameter of dents formed. 6) Steps 1-5 are repeated using a bronze block to replace the cooper block. 7) The reading are recorded in the table.
  • 27. Hafiz Akmal 27 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Results:- DIAMETER OF THE DENT (mm) METAL 1 2 3 average Cooper 2.9 2.8 2.9 2.9 Bronze 2.1 2.2 2.2 2.2 Discussion:- 1) The smaller the diameter of the dent, the harder and stronger is the material. 2) The average diameter of the dent made on the surface on the cooper block is bigger than the bronze block. 3) Based on the result, bronze is harder than cooper. Conclusion:- The hypothesis is accepted.
  • 28. Hafiz Akmal 28 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry EXAMPLE OF ALLOYS Brass Stainless Bronze Steel Bronze steel EXAMPLE OF ALLOY Manganese Steel Pewter Stainless steel Manganese steel
  • 29. Hafiz Akmal 29 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry THE RATE OF RUSTING OF IRON, STEEL, AND STAINLESS STEEL Aim:- To compare the rate of rusting of iron, steel and stainless steel. Problem statement:- How does the rate of rusting of iron, steel and stainless steel differ? Hypothesis:- Iron rust faster than steel, and steel rust faster than stainless steel. Variables:- Manipulated variable: Different types of nails Responding variable: Intensity & amount of blue colour Controlled variable: Size of nails, concentration of solution used, durations for rusting. Operational definition:- The more intense the blue colour formed, the higher is the rate of rusting.
  • 30. Hafiz Akmal 30 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Materials:- Iron nail, steel nail, stainless steel nail, jelly solution, potassium hexacyanoferrate(lll) solution, water, sandpaper. Apparatus:- Test tubes, test tube rack. Procedure:- 1) The nails are rubbed using sandpaper to remove the rust from the surface of the nails. 2) The iron nail placed in the test tube A, the steel nail in test tube B and the stainless steel nail in test tube C. 3) A 5% jelly solution is prepared by adding 5 g of jelly into 100 cm of boiling water. A few drops of potassium hexacyanoferrate(lll) solution are then added to the jelly solution. 4) The hot jelly solution is poured into the three test tubes until all the nails are fully immersed. 5) The test tubes are placed in a test tube rack and left aside for three days. The intensity of the blue colour is observed. 6) All observation are recorded in the table.
  • 31. Hafiz Akmal 31 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry Observation:- Test tube Intensity of blue colour Inference A Very High Rusting occurs very fast B Low Rusting occurs slowly C Nil No rusting occurs Discussion:- 1) When iron rust, each iron atom loses two electrons to form an iron(ll) ion, Fe2+. Fe (s) = Fe2+ (aq) + 2e- (aq) 2) Potassium hexacyanoferrate(lll) solution is added to the jelly solution as an indicator to detect iron(ll) ions. 3) When there is iron(ll) ion, potassium hexacyanoferrate(lll) solution will form dark blue colouration. 4) The higher the intensity of the blue colour, the higher is the rate of rusting. 5) Solidified jelly solution is used to trap and see the blue colouration clearly. This is because diffusions occurs the slowest in solids. 6) Based on the observation, iron rust faster than steel. Stainless steel does not rust. 7) The nail made from stainless steel does not rust. This is because this nail is an alloy of iron with carbon, chromium and nickel.
  • 32. Hafiz Akmal 32 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry 8) The nail made from steel will rust slowly. The presence of carbon atoms will make the steel stronger than iron but does not prevent it from rusting. 9) Rusting of iron is an example of corrosion. When corrosion occurs, the metal loses electrons to form metal iron. Conclusion:- Iron rust faster than steel. Stainless steel does not rust. Hypothesis is accepted.
  • 33. Hafiz Akmal 33 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry COMPOSITONS OF ALLOYS & THEIR USES Alloy Composition Properties Uses Cu 75% Hard, strong, Cupronickel Coins Ni 25% resist corrosion Al 95% Aeroplane part, electric cables Duralumin Cu 4% Light, strong racing bicycles Mg 1% Fe 99% Hard, strong, Steel Vehicles, bridges, buildings C 1% cheap Fe 73% Kitchen appliance, watches, Stainless Cr 18% Hard, rust knifes, fork, spoons, machine steel Ni 8% resistant parts C 1% Cu 90% Hard, strong, Decorative items, medals, bronze Sn 10% shining artwork, pots & pans Cu 70% Harder and Musical instrument, bell, nails, Brass Zn 30% cheaper than Cu screw, and pots Pb 50% Low melting Solder Welding, soldering work Sn 50% point, strong Sn 91% Malleable, Pewter Sb 7% ductile, rust Decorative items,souvenirs Cu 2% resistant Al 70% Tyre rim of racing car, skeletal Magnalium Light, strong Mg 30% body of aeroplane
  • 34. Hafiz Akmal 34 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry POLYMER large molicule that is in the form of long chain with high RMM POLYMER made up of many two types:- monomers which join together - natural polymer through process - syntetic polymer called polymerisation
  • 35. Hafiz Akmal 35 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry NATURAL POLYMER Monomer acid Monomer glucose Monomer isoprene amino Eg: in starch and (2-methylbuta-1,3 Eg: in muscle, skin, cellulose diene) silk, hairs, wools, and Eg: in latex furs
  • 36. Hafiz Akmal 36 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry SYNTHETIC POLYMER & IT USES Synthetic polymers are polymers made in industry from chemical substances. Many of the raw materials for synthetic polymers are obtained from petroleum, after refining and cracking process. Synthetic Synthetic fibres Thermoplastic rubber (long chained polymer that withstand streching) Nylon (monomers: Polyvinyl chloride(PVC) Styrene- butadlene diamine and dicarboxylic (monomers: rubber (SBR) (monomers: acid) chloroethene) styrene & butadlene. eg:- synthetic eg:- rain clothes, water eg:- shoe soles & tyres textile, string pipes Neoprene (monomers: Terrylene (monomers: Polythene chloroprene) diol and dicarboxylic (monomers: ethene) eg:- gloves, electric wire acid) eg:- battery insulator, water pipes eg:- fishing net cases, pails, plastic bags Polystytrene Butyl rubber (monomers: (monomers: isobutylene & isoprene) phenylethene) eg:- inner tubing of eg:- toys, disposable cup tyre, hoses, shoe soles and plates Perspex (monomers: Polypropene methyl metacrylate) (monomers: propene) eg:- spectacles, car lamps eg:- plastic bottles
  • 37. Hafiz Akmal 37 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry WHY USE SYNTETIC POLYMERS IN DAILY LIFE? Strong & light easily can be made moulded or to have shaped & be special coloured Synthetic properties polymers able to resist cheap corrosion
  • 38. Hafiz Akmal 38 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry ENVIRONMENTAL POLLUTION RESULTING FROM THE DISPOSAL OF SYNTHETIC POLYMERS AIR POLLUTION - caused by burning of plastic eg: burning of PVC will produce dioxin. (dioxin will destroy human immune system, reproductive system & nervous system Effects of improper Disposal of Synthetic SOIL POLLUTION Polymer - plastic thrown on land fill up WATER POLLUTION our living spaces - plastic will stop the flow of - destroy the beauty of river water and drains. this environment will cause flash floods. -plastic also cause the soil not - plastic also cause the death suitable for planting because of marine organism if they plastic inhibit the growth of mistaken the plastic as food. root
  • 39. Hafiz Akmal 39 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry GLASS Glass:- The major component of glass is silica or silicon dioxide, SiO2 which found in sand.ri Impermeable to liquid Electrical Transparent insulator Properties of glass hard but Heat insulator brittle Chemically inert
  • 40. Hafiz Akmal 40 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry TYPES, COMPOSITION, PROPERTIES, AND USES OF GLASS GLASS COMPOSITION PROPERTIES USES Low melting point Glass container SiO2 – 70% Mouldable into shapes Glass panes Na2O – 15% Cheap Mirror Soda lime glass CaO – 10% Breakable Lamps and bulbs Others – 4% Can withstand high Plates and bowls heat Bottles High density and Containers for drinks refractive index and food SiO2 – 70% Glittering surface Decorative glass Lead glass (crystal) Na2O – 20% Soft Crystal glassware PbO – 10% Low melting point Lens for spectacles (600˚C) Resistant to high heat Glass apparatus in lab SiO2 – 80% &chemical reaction Cooking utensils Borosilicate glass B2O3 – 13% Does not break easily (Pyrex) Na2O – 4% Allow infra-red rays Al2O3 – 2% but no ultra-violet rays High melting point Scientific apparatus (1700˚C) like lens on Expensive spectrometer SiO2 – 99% Fused silicate glass Allow ultraviolet to Optical lens B2O3 – 1% pass through Lab apparatus Difficult to melt or mould into shape
  • 41. Hafiz Akmal 41 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry CERAMICS Ceramics:- Ceramic is manufactured substances made from clay that is dried, and heated in a kiln at a very high temperature The main component of clay is aluminosilicate (aluminum oxide and silicon dioxide) with small quantities of sand and feldspar. Unlike glass, ceramic cannot be recycled. Kaolinite is a high quality white clay that contains hydrated aluminosilicate, Al2O3•2SiO2•2H2O. extremely hard & strong but brittle able to has a very withstand high and resist melting corrosion Properties point of ceramics good insulator of inert to electricity chemicals and heat
  • 42. Hafiz Akmal 42 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry THE DIFFERENT CLASES OF CERAMIC GROUP COMPOSITION Mineral Quartz – SiO2 Calcite – CaCO3 Cement material Mixture of CaSiO3 and ammonium silicate Oxide of ceramic Aluminium oxide – Al2O3 Silicon dioxide – SiO2 Magnesium oxide – MgO Non-oxides of ceramic Silicon nitride – Si3N4 Silicon carbide – SiC Boron nitride – BN Boron carbide – B4C3
  • 43. Hafiz Akmal 43 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry THE USES OF IMPROVED GLASS AND CERAMICS FOR SPECIFIC PURPOSES GLASS OPTICAL FIBRE CONDUCTING GLASS GLASS-CERAMIC CERAMIC PHOTOCHROMIC GLASS • A pure silica glass thread that • a type of glass that can conduct • Rearrange its atoms into regular SUPERCONUCTOR • sensitive to light intensity conducts light. electricity. patterns by heating glass to form • superconductor can conduct • the glass darken when exposed • this fibres can transmit messages • produce by embedding a thin strong material electricity at low temoerature to sunlight but became clear modulated onto light waves. layer of conducting material in • it can withstand high without resistance, loss of when light intensity decresase. • used inmedical instrument, LAN glass. temperature, chemical attacks electrical energy as heat • used in windows, sunglasses ad • adding a layer of indium tin(iv) • used in • used to make light instrument control oxide (ITO) acts as an electrical tile, cookware, rockets, engine magnet, electric conductor. blocks motors, electrical generators • used in the making of LCD
  • 44. Hafiz Akmal 44 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry COMPOSITE MATERIALS A composite material is structural material formed by combining two or more materials with different physical properties, producing a complex mixture. They are used to make various substances in daily life because of the following reasons:- a) Metals corrode and are ductile and malleable b) Glass and ceramic break easily c) Metal are good conductors but have high resistant, leading to loss of electrical energy as heat. d) Plastic and glass can withstand heat to a certain level only
  • 45. Hafiz Akmal 45 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry COMPOSITE PROPERTIES OF PROPERTIES OF COMPONENT USES MATERIAL COMPONENT COMPOSITE concrete hard but brittle stronger construction of road low tensile strengh higher tensile strength rocket launching pads does not corrode high-rise buildings easily cheaper Reinforced concrete can be moulded into shape steel strong in tensile can withstand very strength high applied force expensive can support very can corrode heavy load Cooper(ll) oxide Insulator of Conducts electricity Magnetically levitated Yttrium oxide electricity without resistance train Superconductor Barium oxide when cooled by liquid Transformer nitrogen Electric cable Computer parts Glass Transparent Reduce refraction of Information display Not sensitive to light panels light Control the amount of Light detector device light passed through it Car windshields auto. Optical lens Photochromic glass Silver chloride Sensitive to light Has the ability to or silver change colour and bromide become darker when exposed to ultraviolet light Glass with low Transparent Low material cost Transmit data using refraction index Does not reflect Reflect light rays and light waves in light rays allow to travel along telecommunications the fibre Fibre optics Can transmit electronic data or Glass with signal, voice and higher image refractive index glass high density high tensile strength car bodies strong but brittle moulded and shaped helmets non-flexible inert to chemicals skies light, strong, tough rackets Fibre glass polyester light non-flammable furniture plastic flexible impermeable to water inflammable resilient elastic but weak flexible
  • 46. Hafiz Akmal 46 CHEMISTRY FOLIO chapter 9: Manufacture Substances in industry in the medical field: to replace organs in the form of plastic composite organ Uses of composite material car part now use composite material sronger buildings instead iron and are built by using steel. this increase reinforce concrete the speed of the car and fuel saver