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Beyond the visible: A tour to
future of spectroscopy and
imaging
Barmak Heshmat
Dr. Ramesh Raskar
Dr. C. Barsi
1
The big picture
• Beyond the visible/IR spectrum (THz spec.)
– New hardware trends
– New computational trends
• Beyond the line of sight (multihop imaging)
– Seeing around the corners
– Seeing through the diffusers
• Beyond the resolvable (subwavelength imaging)
– New hardware trends(course p1)
– New computational trends(course p2)
2
Spectroscopy
• EM waves
• Many types of spectroscopy
3
Wave of spectrometers
• They were all there in the lab but
now they are entering consumer
market!
– Optical absorption 
diagnostic
– Raman  food analysis
– THz  skin, cosmetics,
pharm.
Electronics starting to become
portable
Optics starting to
become portable
Example
Just like super computers we still need the accurate lab spectrometers
but portable versions can be used in limited applications.
• Raman spectrometer from lab to
the key chain!
Tellspec
DeltaNu®
ReporteR™
Smiths Detection
RespondeR™ RCI
Microphazir™
Horiba T64000
?
Hyperspectral and multispectral imaging
6
http://www.markelowitz.com/Hyperspectral.html
7www.markelowitz.com
Measurement samples
8
asri.technion.ac.il
www.popularmechanics.com
www.neo.no
www.bayspec.com www.perception-park.com
Beating the diffraction limit
9
Superlensing Enhanced near
field probes
Fluorescence
imaging
Super oscillatory lenses
Diffraction limit has limited
our resolution in imaging
now we are learning ways
to go beyond this limit.
Seeking light after scattering
• Going from imaging for human to imaging for
computers (measurement in other mathematical spaces
and reconstructing the image)
• Going from single scattering imaging to multi-
scattering imaging.
10
2nd Bounce
1st
Bounce
3rd
Bounce
Beyond visible/IR spectrum
,
11
New hardware trends
• Introductions
• Applications
• PC Switches
– New Materials for THz
– Optimizing Excitation of PC Switches
– Nanoplasmonic Structures
• Summary
• Questions?
12
…THz
400
THz
Frequency(Hz)
800
THz
Unique spectroscopy
capabilities
Study of THz dynamics
Faster communication
Imaging and
inspection
13
Why THz
• Noninvasive
• Water in biological systems, protein folding, disease state of
tissue
• Vibrational modes for organic molecules
• Picosecond time scale dynamics
14
THz and tissues
• Can measure absorption and refraction index together through pulsed
imaging.
15
THz imaging
• Security apps, (mm wave <> THz)
• More inspection and analysis apps
16
See a whole gallery here: http://thznetwork.net/index.php/thz-images
Jefferson Lab Ken O, UT, Texas Startiger project
D. Mittleman Rice U
Q. Hu, MITBESSY, Germany- (100um res)
THz microscopy
17
R. Kersting, THz-ANSOM 150nmEpithelial tumor cell, A. Tredicuccii, ~15um
Diffractionlimit
Ordinary
imaging
Near field
imaging
Scanning
probes
D. Zimdars, Picometrix, Inc,
New trends in hardware
18
THz Generation Methods
19
PC Switches
20
Hamamatsu
Zomega
BATOP
Menlo System
T-Rays
TeraView
21
THzTHz
THz Transmitter
THzTHz
Emitting
THz
Receiving
THz
THz Receiver
22
Transmitter
Receiver
23
H2O,
Here is what is detected
Temporal profile Frequency composition
Math
24
Our ultimate
dream was!
Last 10 years
in our lab
This year
in our lab
Future, in our hand
The miniaturization process
25
It’s real!
26
Skin
quality
Lung
cancer
agents
Blood
sugar
Drunk
Really
Hungry
Cold
Sampletransmittance(Arb.units)
Frequency (Terahertz)
27
New Materials for THz
28
Conventional Materials
The philosophy of an optical switch defines the desired properties
of the substrate material. highest level of fast
photoconductivity modulations:
• high optical density
• high thermal breakdown limit
• high mobility, and Vb and Vsat
• short carrier lifetime (sub-picosecond)
• low dark conductance
• PC switching started by Austin on Si in 1975 (D.H. Auston, Appl. Phys. Lett., 26 (3) 101
(1975))
• C.H. Lee used GaAs in 1977(C.H. Lee, Appl. Phys. Lett., 30 (2) 84 (1977))
• M.Y. Frankel used LT-GaAs in 1990 (M.Y. Frankel, et al, IEEE Trans on Elec. Devices, 37, 2493, 1990).
29
LT-GaAs
• LT-GaAs has short carrier lifetime (<1ps)
• It has low mobility as well  GaAsBi
• Bi is a group V poor metal GaAsBi is
shrinking bandgap material
30
GaAsBi Results
• 500 GHz bandwidth improvement
• Interesting emissions!
31
Effect of GaAsBi growth condition
• THz emission with variation of different parameters
32
Carbon
nanotubes
Increasing the performance
with carbon nanotubes
between the gold electrodes
of the chip
33
So we made samples.
34
Nanoplasmonic Structures
35
Nanoplasmonics
• Engineering surface
electron density waves
in the metallic
nanostructures to
achieve an enhanced
optical response.
• A key property of
nanoplasmonics is its
capability to efficiently
couple light into
subwavelength
structures.
36
Nanoplasmonics: An Example
Tuning annular nano-
apertures
B. Heshmat, D. Li, T. E. Darcie, R. Gordon, " Tuning plasmonic resonances of an annular aperture in
metal plate "Optics Express, Vol. 19, Iss. 7, pp. 5912–5923 (2011). 37
Nanoplasmoincs for THz PC Switches
38
Nanoplasmoincs in THz PC switches
B. Heshmat, H. Pahlevaninezhad,Y. Pang, M. Masnadi, R. Lewis, T. Tiedje, R. Gordon and T. E.
Darcie "Nanoplasmonic Terahertz Photoconductive Switch" Nano letter, accepted. 39
Results of Using Nanoplasmonic
Structures
Peak-to-peak response enhancements of 40×,
10×, and 2×, compared to GaAs, LT-GaAs and
Commerical device.
40
Past, Present, Future
41
Challenges
• THz waves have long wavelength; biological structures, many
important ones, are small…
• Living things need water: THz radiation and water are not
“best friends”…
• Unless you work hard, no clear spectroscopic features at THz
are visible for many samples.
• Some solutions to above problems are coming out.
42
Summary of new trends in hardware
• 100 GHz to 10THz region of EM waves are called THz,
have been unexplored, but we are finally closing the
gap.
• Main challenge is detection and generation.
• Major sources and QCLs, schottky diodes, PC switches
and nonlinear crystals.
• There is room for enhancement through material,
optics and nanoplasmonics.
• Many exciting applications from early cancer detection
to inspection of organic materials and faster
telecommunication. 43
New computational trends
44
• They also investigated the difference between a random mask and an optimized one.
https://www.youtube.com/watch?v=CWlCa3qbzU0
The optimal block size for the block-based CS is a function of the local image
characteristics, and different block sizes can be assigned to different regions.
Summary of computational trends
• Compressive measurements, where you
measure the minimum amount of points to
reconstruct an image with known priors.
• Layer separation based on pulse features
• Reference-free measurements in THz imaging
• Here is a demo:
55
Beyond the line of sight
56
Time-of-flight
In Situ remote sensing
Require direct path between objects sensor
JPL
Hyperspectral Imaging
Spectroscopic
Monterrey Bay Aquarium Research Institute
http://www.mbari.org/coastal/
http://earthobservatory.nasa.gov/Features/Lidar/
http://aviris.jpl.nasa.gov/html/aviris.freedata.html
Optical remote sensing
What if there is no direct path?
Receiver
Source
?
Computation + optics
J. Bertolotti, et al. Nature 491 (2012).S. M. Popoff, et al. Nat. Commun. 1 (2010)
• Relies on coherence/correlation
• Small field of view
• Short standoff distance
60Nature Photonics 6, 549–553 (2012)
A. Velten, et al. Nat. Commun. 3 (2012).
Time is a parameter for imaging
x
t Hyperbola
x
Laser
Streak
camera
Diffuser
Object
Time-resolved image formation
Source: Ti:Sapph (λ0 =795nm, but could use other wavelengths)
Detector: Streak Camera (δt ≈2ps)
Different ray paths register at different times  hyperbolic impulse response (x – ct)
Il (x,t)= I0 G(xl, x, ¢x )N(qin )N(qout )R( ¢x )d ct -(rl ( ¢x )+rc ( ¢x ))( )d ¢xò
Time-resolved image formation
Geometry Diffuser Object
Reflectance
Time
constraint
Il R(x), N(qin,out ){ }
1)(0for,ˆˆ1
minarg
1
2(.)),(
 
xRII
L
L
l
num
ll
meas
l
NxR

Inverse problem
Given a set of streak images
Find the unknown reflectance R(x)
Streak Image
Experimental setup
66
Visible volume
Experimental setup
• Need to know something about diffuser
Unknown reflectance
Unknown reflectance
• Assume object geometry known (can get from previous work)
• Wide field reconstruction
• Works for incoherent light
Moving on to the miniaturization
Time of flight camera
• Continuous wave instead of pulsed
• Cheaper, safer, more compact, but less accurate.
R. Raskar, et al., “Coded Time of Flight Cameras: Sparse Deconvolution to Address Multipath Interference and Recover Time Profiles”, SIGGRAPH
Asia 2013.
3d imaging through
turbulence
Solving occlusion
problems
www.picassodreams.com/photos/nyc_skyscrapers/
http://www.nasa.gov/vision/earth/lookingatearth/h2005_katrina.html
http://www.fjellandfjord.com/article.php?id=166
http://www.soest.hawaii.edu/GG/HCV/loihi.html
Generalizations for remote imaging
Summary of time of flight imaging
• Moving from single scattering to multiscattering
(multihop) imaging
• Different reconstruction techniques that rely on
previous optimization techniques can be used.
• Moving from expensive ultrafast hardware to
cheaper slow hardware that operates on modulated
light
• Now we can recover what is in the visible volume
of these cameras
N. Naik, C. Barsi, A. Velten, R. Raskar.
“Estimating spatially varying reflectance through scattering layers using time-resolve inversion.” JOSA A.
Two picosecond time resolution
Streak camera details

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Course entry t hz and ultrafast

  • 1. Beyond the visible: A tour to future of spectroscopy and imaging Barmak Heshmat Dr. Ramesh Raskar Dr. C. Barsi 1
  • 2. The big picture • Beyond the visible/IR spectrum (THz spec.) – New hardware trends – New computational trends • Beyond the line of sight (multihop imaging) – Seeing around the corners – Seeing through the diffusers • Beyond the resolvable (subwavelength imaging) – New hardware trends(course p1) – New computational trends(course p2) 2
  • 3. Spectroscopy • EM waves • Many types of spectroscopy 3
  • 4. Wave of spectrometers • They were all there in the lab but now they are entering consumer market! – Optical absorption  diagnostic – Raman  food analysis – THz  skin, cosmetics, pharm. Electronics starting to become portable Optics starting to become portable
  • 5. Example Just like super computers we still need the accurate lab spectrometers but portable versions can be used in limited applications. • Raman spectrometer from lab to the key chain! Tellspec DeltaNu® ReporteR™ Smiths Detection RespondeR™ RCI Microphazir™ Horiba T64000 ?
  • 6. Hyperspectral and multispectral imaging 6 http://www.markelowitz.com/Hyperspectral.html
  • 9. Beating the diffraction limit 9 Superlensing Enhanced near field probes Fluorescence imaging Super oscillatory lenses Diffraction limit has limited our resolution in imaging now we are learning ways to go beyond this limit.
  • 10. Seeking light after scattering • Going from imaging for human to imaging for computers (measurement in other mathematical spaces and reconstructing the image) • Going from single scattering imaging to multi- scattering imaging. 10 2nd Bounce 1st Bounce 3rd Bounce
  • 12. New hardware trends • Introductions • Applications • PC Switches – New Materials for THz – Optimizing Excitation of PC Switches – Nanoplasmonic Structures • Summary • Questions? 12
  • 13. …THz 400 THz Frequency(Hz) 800 THz Unique spectroscopy capabilities Study of THz dynamics Faster communication Imaging and inspection 13
  • 14. Why THz • Noninvasive • Water in biological systems, protein folding, disease state of tissue • Vibrational modes for organic molecules • Picosecond time scale dynamics 14
  • 15. THz and tissues • Can measure absorption and refraction index together through pulsed imaging. 15
  • 16. THz imaging • Security apps, (mm wave <> THz) • More inspection and analysis apps 16 See a whole gallery here: http://thznetwork.net/index.php/thz-images Jefferson Lab Ken O, UT, Texas Startiger project D. Mittleman Rice U Q. Hu, MITBESSY, Germany- (100um res)
  • 17. THz microscopy 17 R. Kersting, THz-ANSOM 150nmEpithelial tumor cell, A. Tredicuccii, ~15um Diffractionlimit Ordinary imaging Near field imaging Scanning probes D. Zimdars, Picometrix, Inc,
  • 18. New trends in hardware 18
  • 24. H2O, Here is what is detected Temporal profile Frequency composition Math 24
  • 25. Our ultimate dream was! Last 10 years in our lab This year in our lab Future, in our hand The miniaturization process 25
  • 29. Conventional Materials The philosophy of an optical switch defines the desired properties of the substrate material. highest level of fast photoconductivity modulations: • high optical density • high thermal breakdown limit • high mobility, and Vb and Vsat • short carrier lifetime (sub-picosecond) • low dark conductance • PC switching started by Austin on Si in 1975 (D.H. Auston, Appl. Phys. Lett., 26 (3) 101 (1975)) • C.H. Lee used GaAs in 1977(C.H. Lee, Appl. Phys. Lett., 30 (2) 84 (1977)) • M.Y. Frankel used LT-GaAs in 1990 (M.Y. Frankel, et al, IEEE Trans on Elec. Devices, 37, 2493, 1990). 29
  • 30. LT-GaAs • LT-GaAs has short carrier lifetime (<1ps) • It has low mobility as well  GaAsBi • Bi is a group V poor metal GaAsBi is shrinking bandgap material 30
  • 31. GaAsBi Results • 500 GHz bandwidth improvement • Interesting emissions! 31
  • 32. Effect of GaAsBi growth condition • THz emission with variation of different parameters 32
  • 33. Carbon nanotubes Increasing the performance with carbon nanotubes between the gold electrodes of the chip 33
  • 34. So we made samples. 34
  • 36. Nanoplasmonics • Engineering surface electron density waves in the metallic nanostructures to achieve an enhanced optical response. • A key property of nanoplasmonics is its capability to efficiently couple light into subwavelength structures. 36
  • 37. Nanoplasmonics: An Example Tuning annular nano- apertures B. Heshmat, D. Li, T. E. Darcie, R. Gordon, " Tuning plasmonic resonances of an annular aperture in metal plate "Optics Express, Vol. 19, Iss. 7, pp. 5912–5923 (2011). 37
  • 38. Nanoplasmoincs for THz PC Switches 38
  • 39. Nanoplasmoincs in THz PC switches B. Heshmat, H. Pahlevaninezhad,Y. Pang, M. Masnadi, R. Lewis, T. Tiedje, R. Gordon and T. E. Darcie "Nanoplasmonic Terahertz Photoconductive Switch" Nano letter, accepted. 39
  • 40. Results of Using Nanoplasmonic Structures Peak-to-peak response enhancements of 40×, 10×, and 2×, compared to GaAs, LT-GaAs and Commerical device. 40
  • 42. Challenges • THz waves have long wavelength; biological structures, many important ones, are small… • Living things need water: THz radiation and water are not “best friends”… • Unless you work hard, no clear spectroscopic features at THz are visible for many samples. • Some solutions to above problems are coming out. 42
  • 43. Summary of new trends in hardware • 100 GHz to 10THz region of EM waves are called THz, have been unexplored, but we are finally closing the gap. • Main challenge is detection and generation. • Major sources and QCLs, schottky diodes, PC switches and nonlinear crystals. • There is room for enhancement through material, optics and nanoplasmonics. • Many exciting applications from early cancer detection to inspection of organic materials and faster telecommunication. 43
  • 45.
  • 46.
  • 47.
  • 48. • They also investigated the difference between a random mask and an optimized one.
  • 50.
  • 51. The optimal block size for the block-based CS is a function of the local image characteristics, and different block sizes can be assigned to different regions.
  • 52.
  • 53.
  • 54.
  • 55. Summary of computational trends • Compressive measurements, where you measure the minimum amount of points to reconstruct an image with known priors. • Layer separation based on pulse features • Reference-free measurements in THz imaging • Here is a demo: 55
  • 56. Beyond the line of sight 56
  • 57. Time-of-flight In Situ remote sensing Require direct path between objects sensor JPL Hyperspectral Imaging Spectroscopic Monterrey Bay Aquarium Research Institute http://www.mbari.org/coastal/ http://earthobservatory.nasa.gov/Features/Lidar/ http://aviris.jpl.nasa.gov/html/aviris.freedata.html Optical remote sensing
  • 58. What if there is no direct path? Receiver Source ?
  • 59. Computation + optics J. Bertolotti, et al. Nature 491 (2012).S. M. Popoff, et al. Nat. Commun. 1 (2010) • Relies on coherence/correlation • Small field of view • Short standoff distance
  • 60. 60Nature Photonics 6, 549–553 (2012)
  • 61. A. Velten, et al. Nat. Commun. 3 (2012). Time is a parameter for imaging
  • 62. x t Hyperbola x Laser Streak camera Diffuser Object Time-resolved image formation Source: Ti:Sapph (λ0 =795nm, but could use other wavelengths) Detector: Streak Camera (δt ≈2ps) Different ray paths register at different times  hyperbolic impulse response (x – ct)
  • 63. Il (x,t)= I0 G(xl, x, ¢x )N(qin )N(qout )R( ¢x )d ct -(rl ( ¢x )+rc ( ¢x ))( )d ¢xò Time-resolved image formation Geometry Diffuser Object Reflectance Time constraint
  • 64. Il R(x), N(qin,out ){ } 1)(0for,ˆˆ1 minarg 1 2(.)),(   xRII L L l num ll meas l NxR  Inverse problem Given a set of streak images Find the unknown reflectance R(x)
  • 67. Experimental setup • Need to know something about diffuser
  • 69. Unknown reflectance • Assume object geometry known (can get from previous work) • Wide field reconstruction • Works for incoherent light
  • 70. Moving on to the miniaturization
  • 71. Time of flight camera • Continuous wave instead of pulsed • Cheaper, safer, more compact, but less accurate. R. Raskar, et al., “Coded Time of Flight Cameras: Sparse Deconvolution to Address Multipath Interference and Recover Time Profiles”, SIGGRAPH Asia 2013.
  • 72. 3d imaging through turbulence Solving occlusion problems www.picassodreams.com/photos/nyc_skyscrapers/ http://www.nasa.gov/vision/earth/lookingatearth/h2005_katrina.html http://www.fjellandfjord.com/article.php?id=166 http://www.soest.hawaii.edu/GG/HCV/loihi.html Generalizations for remote imaging
  • 73. Summary of time of flight imaging • Moving from single scattering to multiscattering (multihop) imaging • Different reconstruction techniques that rely on previous optimization techniques can be used. • Moving from expensive ultrafast hardware to cheaper slow hardware that operates on modulated light • Now we can recover what is in the visible volume of these cameras N. Naik, C. Barsi, A. Velten, R. Raskar. “Estimating spatially varying reflectance through scattering layers using time-resolve inversion.” JOSA A.
  • 74. Two picosecond time resolution Streak camera details