Cannizaro reaction it is an organic name reaction.

6. Synthesis

13. Mechanism

14. In case Dianion form

15. In Aromatic aldehyde

17. In case of aldehydes that do have α-hydrogens, the aldol condensation reaction takes place preferentially.

19. The Biological Analogue of the Cannizzaro Reaction

28. 4 ) When a mixture of Formaldehyde and a non Enolizable aldehyde is treated with a strong base, the later is preferentially reduced to alcohol while formaldehyde is oxidized to formic acid. This variant is known as crossed Cannizzaro reaction . ILLUSTRATIONS

34. Intramolecular Cannizaro Reaction

35. Mechanism Step 1 Step 2 Step 3

48. Tishchenko reaction A variant of the Cannizzaro reaction, known as the Tischenko reaction is a disproportionate reaction of an Aldehyde lacking a hydrogen atom in the alpha position in the presence of an Alcoxide. Catalyst are aluminium alkoxides or sodium alkoxides . In this reaction the alcohol and acid products combine to form an ester .

49. Tishchenko reaction Para Benzaldehyde

51. Mechanism

55. Recent Literature

56. A convenient disproportionation or reduction of aldehydes is promoted by lithium bromide and triethylamine in a solvent-free environment at room temperature. Recent Literature

57. Recent Literature

59. Meerwein-Ponndorf-Verley reaction

62. One-Pot Oxidation-Cannizzaro Reaction of Aryl Methyl Ketones

64. One-Pot Oxidation-Cannizzaro Reaction of Aryl Methyl Ketones

70. Cannnizzaro Reaction by Marvi jabbar

71. Thank you