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The Origin of Precious Metals on Earth



Tim Elliott
Bristol Isotope Group, School of Earth Sciences, University of Bristol
Precious Metals




              PGE
Highly siderophile elements (HSE)
Geochemical Reservoirs


                Bulk Silicate
                Earth

 Bulk Earth
 (Chondritic)


                Core
Highly Siderophile Element (HSE) Abundances




                                     Walker 2009
Depletion of Siderophile Elements




                              Drake and Righter 02
Geochemical Reservoirs


                      Bulk Silicate
                      Earth

      Bulk Earth
      (Chondritic)
                                      Dmetal-silicate

                      Core



Most HSE compatible during mantle melting
Surprisingly Abundant Precious Metals




                                Drake and Righter 02
Deep, high temperature core formation?




                                  Wood et al 06
Higher P experiments




                       Mann et al 11
Late Veneer

• Addition of chondritic material post core
  formation

• Requires ~0.5% by mass of Earth by
  such late meteorite bombardment
Siderophile element abundances




                            Drake and Righter 02
NASA image
Fessler and Spudis LPI
Timing of Core Formation




                           Rudge et al 2010
‘Late’ Bombardment




                     Image from Elements Magazine
Late Veneer

• Material certainly added post core formation

• Need ~20:1 Earth:Moon accretion

• Can this amount of material be delivered
  without being added to core?
Late Veneer vs High T core

• Internal or external source of precious
  metals

• Sample Earth before Late Veneer?
The oldest part of the planet




Jack Hills,
Yilgarn Block, W. Australia

                                Wilde et al 01
Zircon ages
              Wilde et al 01
Archaean Greenland




                     Kamber et al 02
Istaq Gneisses, Greenland
Istaq Gneisses, Greenland




                            Kamber et al 02
Extinct     146
                               Sm

     146
           Sm -    142
                      Nd (t1/2 ~ 103 67Ma)

                               Sample
             142
                   Nd/144Nd
ε142Nd =                       Ames Nd
                                         -1 x10000
             142
                   Nd/144Nd
Oldest Terrestrial Rocks


                       Isua,
                       Greenland
                       ~3.8Ga




          ε
                           Caro et al 2006
Precious Metal Content of Earliest
               Mantle?
• Need to see through melting, crystallisation and
  metamorphism
• Hard to constrain moden mantle Platinum Group
  Elements (PGE) contents even with samples of
  mantle
• Need a robust proxy for PGE
• Isotopic tracer of terrestrial vs extra-terrestrial
  PGE?
W proxy of Precious Metals




          PGE
Extinct      182
                                Hf

     182
          Hf –      W (t1/2 ~ 8.9Ma)
                  182




                            Sample
            182
                 W/184W
ε182W =                     NIST SRM 3163
                                            -1 x10000
             182
                   W/184W
Earth’s Core
(today)




Jacobsen 06
Influence of Late Veneer on ε182W
W isotopic measurements




•Multi-collector inductively coupled plasma mass spectrometer
(MC-ICPMS), Thermo Finnigan Neptune
ε182W variability in modern mantle?

 • Entrainment of core material into mantle via
   plumes may lower ε182W
 • High 186Os/188Os of Hawaiian plume attributed to
   core component (Walker and Brandon)
 • Outer core should have low ε182W ~-1.9 and
   much W
Earth’s Core
(today)




Jacobsen 06
Large Igneous Provinces




                          Coffin 2006
Deep-seated plumes




Montelli et al 2006
Mantle ε182W
        variability


‘Deep rooted’ OIB




Large Igneous Provinces
Istaq Gneisses, Greenland
Mantle W isotope evolution
                   ε182W




 3.8Ga Greenland
          (Isua)




        Modern
                           2Ga Granitoid
Influence of Late Veneer on ε182W
Origin of Precious Metals

• Homogeneity of ε182W of modern mantle leaves no room
  for precious metal deliver from core to mantle

• Contrast of 0.15 ε182W between modern and Isua rocks
  entirely compatible with Late Veneer

• Current inventory of precious metals delivered to Earth by
  meteorite bombardment post core formation

• 20x higher flux to Earth compared to Moon a lucky
  chance of the random nature of accretion (Botke et al
  2011)

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The Origin of Precious Metals on Earth

Notas do Editor

  1. Confusing 143 referenced to chur (chondrite) as assumed the same, for 142 clearly not the case and for covenience refed to Earth
  2. Half life on 103Ma so the signature must have been imparted before formation at 3.8
  3. Confusing 143 referenced to chur (chondrite) as assumed the same, for 142 clearly not the case and for covenience refed to Earth
  4. Have checked strongest current plume, but is a tail. Worth checking out heads- most head on continents and very prone to contamination, however W. Pacific LIPs oceanic and mark major pulse of volcanism, strongly argued to be from lower mantle. Worth looking at other plumes. Notably deep root of hawaii still not especially clear, whereas as other less vigorous volcanoes aparently have (or did when we started)
  5. Montelli 2004 banana doughnutCanaries and Azores w resolved, deep rooted origins- (Canaries ‘Robust merge with Canaries?) Cape Verde, clearest topographic and geoid anom (Montelli ‘deep’ plume merging with Canaries/Azores. NB Hawaii and Iceland not so defined