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The rare earth
element potential
in Greenland




      No. 20 - November 2011
The rare earth element
20 / 2011




                      potential in Greenland
GEOLOGY AND ORE




                      Supply of rare earth elements (REE) is               demand is projected to rise to 180,000 t
                      complex. REE deposits are geographi-                 annually by 2012, and for neodymium,                 Highlights from the REE
                      cally unevenly distributed and the                   dysprosium, europium, terbium and yttri-             potential assessment workshop
                      content of individual REEs varies from               um in particular, forecasts show that sup-           A total of thirty-five areas were assessed
                      deposit to deposit; some deposits only               plies will become critical. In response to           by an expert panel during the REE work-
                      containing a few of the REEs in de-                  this rising global demand, Greenland has             shop.
                      mand. Greenland is endowed with                      experienced a strong international interest              Information compiled on known REE
                      several large REE deposits, related to               over the past decade in search of new REE            deposits and geological provinces in
                      various geological settings. Several                 deposits. The fact that Greenland is                 Greenland, as well as compilations of geo-
                      projects have reached advanced stages                endowed with geological environments                 chemical stream sediment data were treat-
                      of exploration. Additionally, Greenland              favourable to hosting REE accumulation               ed in conjunction with models for REE
                      also holds geological terrains favour-               makes Greenland attractive to the REE                deposits in order to assess the potential
                      able for hosting undiscovered REE                    exploration industry.                                for REE deposits in Greenland.
                      deposits, as concluded in a recent REE                   On this background the Geological                    An overview of the REE distribution
                      workshop.                                            Survey of Denmark and Greenland (GEUS)               based on geochemical information from
                                                                           and the Greenland Bureau of Minerals                 available stream sediment data is demon-
                                                                           and Petroleum (BMP), conducted a REE                 strated by the compilation map of stream
                      Introduction                                         potential workshop in 2010 to provide the            sediments.
                      Demand for REE is growing rapidly due to             REE mineral exploration sector with the                  The REE workshop assessed the follow-
                      innovation in the so-called ‘green tech-             scientific background and necessary data             ing REE-prone geological environments:
                      nologies’, electronic devices, defence sys-          to make qualified decisions. This magazine
                      tems and petroleum refining catalysts. The           highlights some of the results from this             • Carbonatite magmatism
                      global requirement for REEs in 2010 was              workshop.                                              REE accumulations are observed associ-
                      134,000 t, with global production around                                                                    ated with carbonatite complexes. In
                      124,000 t. The difference was covered by                                                                    Greenland the accumulation is often
                      utilising previously mined reserves. Global                                                                 related to late hydrothermal activity,




                      View of the Kringlerne multi-element deposit with the characteristic mountain Redekammen in the background. Photo: Bureau of Minerals and Petroleum.




                  2
R A R E         E A RT H           E L E M E N T                 P O T E N T I A L




                                                                                                           Licenced REE prospects with /
                                                                                                           without resource estimates
               Stream sediment samples with high REE
                                                                                                                  /      carbonatites
               (La>300 ppm, or Eu>10ppm or Yb>15 ppm)
                                                                                                                  /      alkaline complexes
                    La/Yb     Probable source environment
                        1 - 20 Pegmatite or placer                                                                       other
                       20 - 40                                                                             Other sites with REE potential
                       40 - 60 Alkaline or sedimentary                                                        carbonatites
                      60 - 120 Carbonatite, lamprophyre                                                       alkaline complexes
                        > 120 or monzonite
                                                                                                                                                            Kap Simpson
                              Stream sediment
                              sample location

                                                                                          Karrat

                                                                                                                        Inland Ice                           Milne Land




                                                                              Sarfartoq




                                                                               Qaqarssuk

                                                                                                                                                 Phanerozoic
                                                                                Tikiusaaq                                                        sedimentary,
                                                                                                               Skjoldungen
                                                                                                                                                 volcanic and
                                                             100 km                                            Alkaline
                                                                                                                                                 intrusive
                                                                                                               Province
                                                                                                                                                 rocks
                                                                                                                                              Caledonian mobile belt
                                                                                                        Qassiarsuk                            Palaeoproterozoic
                                                                                   Grønnedal-Ika                      Motzfeldt Sø            mobile belts
                                                                                                                                              Archaean craton
                                                                                               Kvanefjeld
                                                                                                  Kringlerne


Left figure: Plot of REE-anomalous stream sediment samples in Greenland reflecting the presence of known and unknown REE mineralisation or very REE-
enriched rocks. Symbol colour scale illustrates the variation in La/Yb ratio of the anomalies. Since fractionation among light and heavy REE shows consid-
erable and characteristic variation among diverse REE-rich lithologies, and since these characteristics are reflected in the stream sediments, the La/Yb ratio
can be used to indicate the probable source lithology of a stream sediment anomaly. Right figure: Simplified geological map with selected known REE
prospects and other sites with REE potential.




   where pathways in shear zones and                     • IOCG mineralising systems                                    The individual tracts assessed during the
   joints play an important role.                          REE accumulations are typical in miner-                      workshop are shown on page 7.
                                                           alising systems with low Ti - contents                          The potential areas outlined in the
• Alkaline intrusions                                      and where there are extensive Na and                         southern, eastern and southwestern part
  REE accumulations are typical during                     K - alterations, combined with                               of Greenland are due to the presence of
  igneous processes in layered intrusions                  increased contents of Co, Ag, U, Cu                          the Gardar intrusives, carbonatites and
  of strongly differentiated magmas with                   and P in coeval magmatism.                                   alkaline intrusions. In North Greenland,
  or without hydrothermal overprints.                                                                                   however, only a few areas were defined,
                                                         • Paleoplacer environments                                     due to the extensive carbonate platform
• Pegmatite settings                                       Placer deposits are a result of second-                      and sedimentary basins hiding possible
  In simple pegmatites related to gran-                    ary accumulation of heavy minerals,                          REE deposits.
  ites, the minerals allanite and monazite                 often REE bearing minerals like mon-                            A list of the 10 REE occurrences with
  are commonly enriched in light REEs,                     azite and xenotime.                                          the highest assessment score from the
  whereas a whole range of rare REE                                                                                     workshop assessment is given in table 1.
  minerals occurs in alkaline pegmatites.




                                                                                                                                                                          3
R A R E       E A RT H          E L E M E N T             P O T E N T I A L




    Tract name Location          Deposit model       Geological settings                                        Deposit size & grade*              Score

    A1           Kvanefjeld      Alkaline            Known deposit. High level of information.                  619 Mt                             50
                                                     Extensive drilling has been conducted on the deposit.      (6.6 Mt TREO including 0.24 Mt
                                                     Contains uranium above background level.                   heavy REO, 0.53 Mt Y2O3 + 350
                                                                                                                Mlbs U3O8 and 1.4 Mt Zn).

    A2           Kringlerne      Alkaline            Known deposit. High level of information. Extensive        1,000 Mt @ 2% ZrO2, 0.25%          50
                                                     drilling has been conducted on the deposit. Low            Nb2O5, 0.5% REO, 0.1% Y2O3 and
                                                     uranium content below or equal to background level.        0.025% Ta2O5.

    C3.1         Sarfartoq       Carbonatite         Known carbonatite showing. Kimberlites &                   14 Mt @ 1.53% TREO.                41
                                                     terraine boundary in the area = active pathways.

    O3           Karrat          Other               The REE prospect have been drilled which classifies it   26 Mt @ 1.36% TREO + Y.               35
                                                     as an undiscovered deposit. Lamprophyric dykes are
                                                     found in the area = active pathways. The deposition
                                                     model is not yet fully understood – more work required.

    C3.2         Qaqarssuk       Carbonatite         Known carbonatite showing. Lamprophyres are found          REE resource is currently          32
                                                     in the area = active pathways.                             beeing investigated.

    A3           Motzfeldt Sø    Alkaline            Known REE prospect. Micro syenites (which host the         REE resource is currently          31
                                                     REEs) not much investigated. Limited drilling – only Ta,   beeing investigated. Historical
                                                     Nb and U targets drilled. More work is needed to           data: 600 Mt @120 ppm Ta +
                                                     evaluate the REE potential.                                130 Mt grading 0.4 - 1.0% Nb205.

    A3.1         Qassiarsuk      Alkaline            Dyke with aegirine as prime mineral.                       Unknown. Showings of REE           22
                                                     The dyke is up to 4 m thick and can be followed for        known - up to 1%.
                                                     several kilometres. High Th content.

    C4           Tikiusaaq       Carbonatite         Known carbonatite showing. Lamprophyres and possible REE resource is currently                21
                                                     terraine boundary in the area = active pathways.     beeing investigated.

    A11.1        Kap Simpson     Alkaline            Alkali syenite complex. Malmbjerg type alteration (high    Unknown. Rock samples enriched     19
                                                     temp) seen via hyperspectral mapping. Several              in REEs (3%) & Nb (3.2%).
                                                     sources of mineralised rocks sampled from glaciers.

    C8.1         Overall tract Carbonatite           Known showing. Lamprophyres and ailikites are found        Unknown.                           19
                 around the                          in the area. Greisen alteration at Ivittuut. Radioactive
                 Grønnedal-Ika                       dykes (Ce enriched) are present in the area – radiates
                 carbonatite.                        from the Grønnedal-Ika carbonatite.

    Table 1. List of the 10 REE occurrences with the highest scores from the workshop assessment. Maximum score is 50.Tract name refers to the areas
    shown on map on page 7.
    * Deposit size and grade numbers are based on company announcements and available online data as of September 2011. For specific and updated
    information please refer to the company websites of the individual deposits.



                                                      tonic rift province consisting of sand-                province also includes the Igaliko
    Known REE deposits                                stones, and a variety of volcanic and plu-             Nepheline Syenite Complex, hosting the
    Eight REE deposits have been discovered           tonic igneous rocks. The plutonic rocks are            Motzfeldt Sø REE deposit.
    up to now in Greenland, of which two              alkaline to peralkaline and are hosted
    may well be amongst the 10 largest REE            within the Ilímaussaq intrusion (1160 Ma).             Kvanefjeld
    deposits in the world. The geological set-        The Ilímaussaq intrusion is largely                    The Kvanefjeld multi-element deposit,
    tings for these REE deposits vary, and the        implaced by block subsidence and formed                located a few kilometers north of Narsaq,
    ages cover a wide span. A brief introduc-         by three pulses, of which the third formed             South Greenland, is an accumulation of
    tion to these known deposits follows.             a layered series of nepheline syenites. The            various igneous rocks and supracrustals
                                                      Ilímaussaq intrusion is generally enriched             from the roof of the Ilímaussaq intrusion.
    The Gardar province hosts three large             in the elements U, Th, Nb, Ta, Be, Zr, Li, F,          Additionally rocks from the early phases of
    REE deposits: Kvanefjeld, Kringlerne              Zn and REE, and hosts two REE deposits                 the alkaline intrusion are also included,
    and Motzfeldt Sø                                  e.g. Kringlerne (dominated by the kakor-               forming blocks and sheets within the later
    The Meso-proterozoic Gardar province in           tokite bottom cumulates) and Kvanefjeld                agpaitic magma. The bulk of the REE (as
    South Greenland is designated as a cra-           (dominated by lujavrites). The Gardar                  well as U and Th) is associated with the




4
R A R E        E A RT H          E L E M E N T              P O T E N T I A L




View of the Narsaq Valley, Kvanefjeld and gravel road to the former test mine.
Photo: Greenland Minerals and Energy A/S.




lujavrite rocks hosting disseminated steen-             TREO, 404 ppm U3O8 (0.05% heavy                    townships of Narsaq and Qaqortoq in
strupine, which is the primary mineral host             REO, 0.12% Y2O3)                                   South Greenland. The kakortokite cumu-
of both REEs, U and Th. The deposit also                                                                   lates form a total of 29 cyclic, and regular
contains zinc, occurring mainly as dissemi-         Kringlerne                                             layers, with a total thicknes of about 200
nated sphalerite in the lujavrite, and fluo-        The multi-element deposit at Kringlerne is             m, made by units composed of black
rine hosted in the mineral villiaumite              hosted in the lower cumulates of the lay-              syenite (arfvedsonite dominated), reddish
(NaF). The Kvanefjeld deposit has previ-            ered agpaitic nephenline syenites, referred            syenite (eudialyte dominated) and whitish
ously been explored for the potential of U          to as kakortokite, and is situated near the            syenite (feldspar dominated) rocks. The
and Th.
    The Kvanefjeld REE deposit is dominat-
ed by Ce (approx. 40%), La (approx.
25%), Nd (approx. 15%), Y (approx.
10%), Pr (approx. 5%) and the remaining
HREE accounts for about 5%.
    Greenland Minerals and Energy A/S has
reported the following resource estimate
figures (based on 150 ppm U3O8 cut-off):

• Total JORC resource of 619 Mt
• Indicated JORC resources of 437 Mt
• Inferred resources of 182 Mt
• Contained metal inventory of 6.6 Mt
  TREO, including 0.24 Mt heavy REO
  and 0.53 Mt Y2O3 as well as 350 Mlbs
  U3O8 and 1.4 Mt Zn
• Near surface, higher grade zones                  The characteristic layering of the Karkortokite at the Kringlerne multi-element deposit. Note the campsite
  defined, including 122 Mt @ 1.4%                  in the lower left part of the image as scale. Photo: TANBREEZ Mining Greenland A/S.




                                                                                                                                                                 5
20 / 2011
GEOLOGY AND ORE                                        R A R E        E A RT H          E L E M E N T        P O T E N T I A L




                      Drill core logging at the Motzfeldt Sø camp in 2011. Photo: Ram Resources Ltd.



                      mineral eudialyte (Greek for ‘easily dis-          the 1980s is 600 Mt grading 120 ppm Ta.        Sarfartoq
                      solved’) is enriched in Ta-Nb-REE-Zr-Y and         High grade zones carry up to 426 ppm Ta.       The Sarfartoq carbonatite complex (564 Ma)
                      this is the main exploration target for REE        Additionally an Nb resource of at least        is well exposed, situated on the transition
                      by the licensee, Rimbal Pty Ltd. The kakor-        130 Mt grading 0.4-1.0% Nb205 is               zone between the Archaean craton and
                      tokites have been investigated for decades         known. The deposit is regarded as a ‘low       the Palaeoproterozoic Nagssugtoqidian
                      focusing in particular on Zr, Y, Nb, and           grade-large tonnage’ type of resource.         mobile belt. The host rocks are granodi-
                      REE.                                                   Ram Resources Ltd. is currently investi-   oritic gneisses.The complex was discov-
                          Current work by Rimbal Pty Ltd indi-           gating the intrusion for REEs. The 2010        ered by GGU in 1976 on the basis of a
                      cates a resource of no less than 1,000 Mt          work indicates that the known Ta-Nb min-       regional airborne radiometric survey and
                      grading 2% ZrO2, 0.25% Nb2O5, 0.5%                 eralisation is only weakly correlated with     later fieldwork. Subsequently, the complex
                      REO, 0.1% Y2O3 and 0.025% Ta2O5. The               the REE mineralisation. In the central part    has been the target of various exploration
                      distribution of light and heavy REEs in            of the intrusion, where the richest Ta-Nb      campaigns focusing on diamonds, P, Nb
                      eudialyte is reported to be 88% and 12%            mineralisation is found, the lithology is      and REE.
                      respectively.                                      predominantly altered syenite, with minor          The central core zone of the complex is
                                                                         pegmatite and diorite dykes. However,          surrounded by a series of ring-like layers
                      Motzfeldt Sø                                       high grade REE intersections are concen-       or dykes, containing innumerable intrusive
                      The Motzfeldt Sø REE deposit is part of            trated in the pegmatite intrusives at
                      the Motzfeldt Centre, which in turn is part        depth, but are also found scattered
                      of the Igaliko Nepheline Syenite Complex.          throughout the drill holes, gradually
                      Pyrochlore accumulations in the Motzfeldt          decreasing in grade towards the east.
                                                                                                                        Map showing the areas (tracts) used for the REE
                      Sø syenite show significant grades of              Estimated JORC resource figures are antici-    potential assessment workshop, grouped
                      Tantalum. The estimated resource based             pated at the beginning of 2012.                according to the type of geological environment
                      on investigations carried out by GEUS in                                                          of relevance to REE deposits.




                  6
R A R E                                           E A RT H        E L E M E N T                           P O T E N T I A L



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                                                                              C1
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                            C2                                                               P1
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                      Sisimiut




                                   C3.1
                                                                                             C3                                                               C12
                                                                                                                                                                                                 A6
                                       C3.2                                                                                                                                                                 Legend
                                                                                                                                                                                    P10
                                                                                                                                                              Tasiilaq




                                Nuuk
                                                P5                                                                                                       I2                                                              Alkaline tracts
                                                                                    C4
                                                                                                                                                                                                                         Carbonatite tracts
               C4.1                                                                                                                         C11
                                                                                                                                C11.1                                                                                    IOCG tracts
                                                                        C5
                                                                                                                                                 A5
                                                                                                                                           Skjoldungen

                                P6      C6   C9.1                                                                                                                                                                        Pegmatite tracts
                                       Paamiut

                                        A17     A3     C10
                                 C7        A3.1                                                                                                                                                                          Other tracts
                                 P7       A1      A15
                                  C8                   A4
                                 C8.1
                                   A16                P9                                                                                                                                                                                         Kilometers
                                         A2     P8
                                     C9                                                                                                                                                  0             125    250          375                 500
                                          C9.2



                                                                                                                                                                                                                                                              7
20 / 2011                                             R A R E         E A RT H        E L E M E N T            P O T E N T I A L




                      carbonate breccia veins. Substantial feniti-
GEOLOGY AND ORE




                      sation occurs around the core. Mineralisa-
                      tion of Nb and REE has been recorded from
                      separate zones in the outer fenitised zone.
                      The REE minerals are correlated with thorium
                      and are mainly bastnasite, synchysite and
                      monazite.
                          In 2010 Hudson Resources reported an
                      NI 43-101 compliant resources estimate
                      result over the ST1 site in the northern part
                      of the complex: 14 Mt inferred resources
                      avaraging 1.53% TREO at a cut-off grade
                      of 0.8% TREO. The REE distribution is
                      45% Ce, 20% La, 25% Nd, 6% Pr, 2%
                      Sm, and approx. 2% Gd, Dy and Y.

                      Qaqarssuk
                      The Qaqarssuk carbonatite complex (165
                      Ma), situated 60 km east of Maniitsoq,           View towards the well exposed outcrop at the ST1 site, part of the Sarfartoq carbonatite complex.
                      West Greenland, intruded the Archaean            The slope is c. 200 m high.
                      gneiss complex, along with kimberlite
                      dykes and alkaline intrusions. The compo-
                      sition of the carbonatite varies from sövite
                      to rauhaugite.
                                                                       Outcropping of vertical to subvertical, early stage carbonatite sheets of the Qaqarssuk carbonatite
                                                                       complex. Photo: NunaMinerals A/S.




                  8
R A R E         E A RT H           E L E M E N T            P O T E N T I A L




Aerial view of the Tikiussaq carbonatite complex with carbonatite sheets and fenites (yellowish areas) exposed in north walls of the gully. The extent of
the gully is c. 1-1.5 km. Photo: NunaMinerals A/S.




   In 2010 NunaMinerals A/S initiated REE            intruded by carbonate-rich ultramafic sili-           that the extension of the carbonatite dykes
exploration within the carbonatite. The              cate dykes. NunaMinerals A/S initiated                continues to a depth of at least 500 m.
main potential appears to lie in the core            exploration of the Tikiusaaq carbonatite in
of the complex concealed in carbonate                2010, and focussed on the aeromagneti-                The Niaqornakassak and
veins , and the company reports the aver-            cally defined ‘carbonatite core’. REEs are            Umiammakku Nunaa REE deposits
age grade for a 1.5 km2 area as 2.4%                 typically enriched in the latest phases of            The Niaqornakassak (NIAQ) REE deposit in
TREO, mainly hosted in ancylite (Sr-REE-             carbonatite magmatism, and the main REE               central West Greenland was discovered by
carbonate); the mineralisation is LREE               mineral is ancylite (Sr-REE carbonate). REE-          Avannaa Resources Ltd. in 2007 and in
dominated with 50% Ce, 27% La, 16%                   enriched carbonatite surface samples con-             2009, an extension of the deposit was dis-
Nd, and 5% Pr. The REE-mineralised veins             taining up to 9.6% TREO (predominantly                covered on the Umiammakku Nunaa
are generally less than one metre thick.             LREE), have been found in an area of                  (UMIA) peninsula 7 km along strike from
                                                     anomalous thorium counts. The REE distri-             the NIAQ site. The two deposits are jointly
Tikiusaaq                                            bution is 47% Ce, 33% La, 12% Nd, 4%                  named ‘Karrat’.
The Tikiusaaq carbonatite, discovered by             Pr and 4% other REEs. High phosphate                      Work conducted by Avannaa Resources
GEUS in 2005 by using regional stream                grades (up to 8.5% P2O5) were returned                Ltd. in 2010 on the NIAQ and UMIA
sediment data and regional airborne geo-             from surface samples within the magnetic              deposits included diamond drilling and
physical data, consists of massive                   core of the carbonatite.                              collecting 13 mini-bulk samples. The REE
dolomite-calcite carbonatite sheets intrud-              A recent interpretation of radiometric            accumulation is hosted in an amphibolite
ed along a ductile shear zone at approxi-            and magnetic data indicates a separate body           unit of the Palaeoproterozoic Karrat Group.
mately 158 Ma. The carbonatite is later              about 750 m long and 100 m wide and                   Strike length of NIAQ is 1.5 km but open




                                                                                                                                                            9
20 / 2011                                            R A R E       E A RT H       E L E M E N T        P O T E N T I A L




                       at both ends. The tabular NIAQ ore body
GEOLOGY AND ORE




                       has been found at a maximum elevation
                       of 56 m above sea level and down to 168 m
                       below sea level; the thickness varies
                       between approx. 10 m and 33 m. The
                       NIAQ bulk samples indicate an average of
                       TREO of 1.36%, of which the average
                       HREO content is approx. 13%. Preliminary
                       resource estimates of the NIAQ body are
                       26 Mt. The REE are mainly hosted by bast-
                       nasite, monazite and allanite related to
                       hydrothermal agents within the miner-
                       alised sequences. Very limited work has
                       been undertaken on the UMIA body.
                       Based on three drill holes the TREO of the
                       UMIA deposit is in the range of 0.08 -
                       0.12%.

                       Milne Land REE deposit
                       The Mesozoic Milne Land paleoplacer was
                       discovered in 1968 by Nordisk Mineselskab
                       A/S in connection with a heavy minerals
                       concentrate sampling programme and an
                       airborne radiometric survey. The placer is
                       in the basal part of the Charcot Bugt For-
                       mation, and the most anomalous locality,
                       "Hill 800" in Bays Fjelde, is around 500 m
                       in diameter and 40-50 m thick. The heavy
                       minerals are hosted by a 20 m thick basal
                       sandstone. The potential resources REE,Ti
                       and Th are mainly hosted in monazite.
                           In 1990, Coffs Harbour Rutile extracted
                       a 15-tonne selective bulk sample from 5
                       pits in the “Hill 800” area, and about 10
                       tonnes were investigated metallurgically.
                       Recoveries from a pilot scale study led to
                       the conclusion that it is feasable to extract
                       commercial products of monazite, zircon
                       and garnet, but not of anatase due to its
                       fine-grained and complex nature. Coff
                       Harbour Rutile estimates the resource for
                       “Hill 800” at 3.7 Mt with 1.1% zircon,
                       0.5% monazite, 2.6% anatase, 3.1% gar-
                       net and 0.03% xenotime. Sirius Minerals
                       Ltd. are currently exploring the REE poten-
                       tial of this placer deposit.
                                                                       aside from of the known deposits at      Among the known deposits are Sarfartoq,
                                                                       Kvanefjeld and Kringlerne. Among the     Qaqarssuk and Tikiussaq. Of these, Tikiussaq
                       Conclusions                                     more promising areas are around the      were only recently discovered in 2006.
                       Based on the conclusions of the recently        Grønnedal-Ika carbonatite and the           In the more remote and less investigated
                       conducted workshop at GEUS, South               Qassiarsuk carbonatite.                  areas of Greenland, the Kap Simpson
                       Greenland is believed to have the largest          West Greenland is highly prosperous   alkaline intrusion in central East Greenland
                       potential for hosting new REE deposits,         for carbonatite related REE deposits.    and the Skjoldungen Alkaline Province in




                  10
R A R E        E A RT H      E L E M E N T        P O T E N T I A L




                                                                                        Geological mapping and sampling of the NIAQ
                                                                                        REE deposit in 2010.
                                                                                        Photo: Avannaa Resources Ltd.
South East Greenland are believed to have    licences to move the projects towards
a good potential for hosting new REE         exploitation stage. Greenland has thus
deposits.                                    responded to the increased global demand
    Several of the known deposits are        and has a possibility to become a major
already covered by exploration licences      exporter of rare earth elements.
and extensive exploration and drilling is
currently being carried out on several




                                                                                                                                      11
20 / 2011




                                                                                                                                   Bureau of Minerals and Petroleum
                                                                                                                                                 (BMP)
                                                                                                                                       Government of Greenland
                                                                                                                                             P.O. Box 930
GEOLOGY AND ORE




                                                                                                                                            DK-3900 Nuuk
                                                                 NIAQ and UMIA REE deposits                                                    Greenland

                                                                                                                                           Tel: (+299) 34 68 00
                                                                                                                                           Fax: (+299) 32 43 02
                                                                                                                                            E-mail: bmp@gh.gl
                                                                                                                                          Internet: www.bmp.gl




                                 View of the NIAQ and UMIA REE deposits. The distance between the two deposits is 7 km.
                                                                                         Photo: Avannaa Resources Ltd.
                                                                                                                                     Geological Survey of Denmark
                                                                                                                                        and Greenland (GEUS)
                       Key references                                                                                                     Øster Voldgade 10
                       Grice, J. D., Gault, R.A., Rowe, R. & Johnsen, O.     Sørensen, H. 2006: The Ilímaussaq Alkaline                DK-1350 Copenhagen K
                                                                                                                                               Denmark
                        2006: Qaqarssukite -(Ce), a new barium-cerium         Complex, South Greenland – an Overview of
                        fluorcarbonate mineral species from Qaqarssuk,        200 years of research and outlook. Contribution
                                                                                                                                         Tel: (+45) 38 14 20 00
                        Greenland. Canadian Mineralogist 44, 1137-1146.       to the mineralogy of Ilímaussaq no. 130.
                                                                                                                                         Fax: (+45) 38 14 20 50
                       Harpøth, O., Pedersen, J.L., Schønwandt, H.K.          Meddelser om Grønland. Geoscience 45, 70 pp.                E-mail: geus@geus.dk
                        & Thomassen, B. 1986: The mineral occurrences        Sørensen, L. L., Kalvig, P., Hanghøj, K. 2011: Rare         Internet: www.geus.dk
                        of central East Greenland. Meddelelser om Grøn-       earth element potential in Greenland. Reporting
                        land. Geoscience 17, 138 pp.                          the BMP/GEUS mineral resource assessment work-
                       Knudsen, C. 1991: Petrology, geochemistry and          shop 29 November - 1 December 2010. 2. revised
                        economic geology of the Qaqarssuk carbonatite         version. Danmarks og Grønlands Geologiske
                        complex, southern West Greenland. Monograph           Undersøgelse Rapport 2011/80, 30 pp. + 1 DVD.
                        Series on Mineral Deposits 29, 110 pp.               Tappe, S., Steenfelt, A., Heaman, L. M. &
                       Secher, K. & Larsen, L.M. 1980: Geology and            Siminetti, A. 2009: The newly discovered Jurassic        Front cover photograph
                        mineralogy of the Sarfartôq complex, southern         Tikiusaaq carbonatite-aillikite occurrence, West     Front cover photograph: Hudson
                                                                                                                                   Resources Inc. drilling for REEs at its
                        West Greenland. Lithos 13, 199-212.                   Greenland, and some remarks on carbonatite-kim-
                                                                                                                                   ST19 target which is part of the
                       Secher, K., L. M. Heaman, Nielsen, T.F.D.,             berlite relationships. Lithos 112S, 385-399.         Sarfartoq carbonatite complex. Photo:
                        Jensen, S.M., Schjøth, F. & Creaser, R.A. 2009:      Tukiainen, T. 1988: Niobium-tantalum mineral-         Hudson Resources Inc.
                        Timing of kimberlite, carbonatite, and ultramafic     isation in the Motzfeldt Centre of the Igaliko
                        lamprophyre emplacement in the alkaline province      Nepheline Syenite Complex, South Greenland. In
                        located 64º– 67ºN in southern West Greenland.         Boissonnas, J. & Omenetto, P. (ed) Mineral
                        Lithos 112S: 400-406.                                 Deposits within the European Community.
                                                                                                                                                 Authors
                       Steenfelt, A. 2001: Geochemical atlas of Green-        SpringerVerlag Berlin & Heidelberg, 230-246.                Lars Lund Sørensen &
                        land – West and South Greenland. Danmarks og                                                                        Per Kalvig, GEUS
                        Grønlands Geologiske Undersøgelse Rapport
                        2001/46, 39 pp. + 1 CD-Rom.                                                                                              Editors
                       Steenfelt, A., Schjøth, F., Sand, K.K., Secher, K.,                                                                Lars Lund Sørensen &
                        Tappe, S., Moberg, E. & Tukiainen, T. 2007:                                                                       Karsten Secher, GEUS
                                                                              Usage of the term rare earth element
                        initial assessment of the geology and economic
                                                                              (REE) in this magazine is restricted to 16                 Graphic Production
                        potential of the Tikiusaaq carbonatite complex and
                                                                              elements including Y, La, and the lan-                   Carsten E. Thuesen, GEUS
                        ultramafic lamprophyre dykes. Mineral resource
                        assessment of the Archaean Craton (66° to             thanides.
                                                                                                                                           Photographs
                        63°30'N) SW Greenland Contribution no. 3. Dan-
                                                                                                                                     GEUS unless otherwise stated
                        marks og Grønlands Geologiske Undersøgelse            Given the fact that many REE deposits
                        Rapport 2007/64, 53 pp. + 1 DVD.                      also contain various amounts of U and                           Printed
                       Sørensen, H. 2001: The Ilímaussaq alkaline com-        Th, it should be stressed that the Green-                 November 2011 © GEUS
                        plex, South Greenland: status of mineralogical        land Government has introduced a zero-
                        research with new results. Geology of Green-          tolerance policy with regard to exploita-                       Printers
                        land Survey Bulletin 190, 167 pp.                     tion of radioactive minerals. Radioactive
                                                                                                                                    Rosendahls Schultz Grafisk a/s
                                                                                                                                                  •




                                                                              resources are not dealt with in this issue.
                  12                                                                                                                              ISSN
                                                                                                                                                1602-818x

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Geology and Ore no. 20

  • 1. The rare earth element potential in Greenland No. 20 - November 2011
  • 2. The rare earth element 20 / 2011 potential in Greenland GEOLOGY AND ORE Supply of rare earth elements (REE) is demand is projected to rise to 180,000 t complex. REE deposits are geographi- annually by 2012, and for neodymium, Highlights from the REE cally unevenly distributed and the dysprosium, europium, terbium and yttri- potential assessment workshop content of individual REEs varies from um in particular, forecasts show that sup- A total of thirty-five areas were assessed deposit to deposit; some deposits only plies will become critical. In response to by an expert panel during the REE work- containing a few of the REEs in de- this rising global demand, Greenland has shop. mand. Greenland is endowed with experienced a strong international interest Information compiled on known REE several large REE deposits, related to over the past decade in search of new REE deposits and geological provinces in various geological settings. Several deposits. The fact that Greenland is Greenland, as well as compilations of geo- projects have reached advanced stages endowed with geological environments chemical stream sediment data were treat- of exploration. Additionally, Greenland favourable to hosting REE accumulation ed in conjunction with models for REE also holds geological terrains favour- makes Greenland attractive to the REE deposits in order to assess the potential able for hosting undiscovered REE exploration industry. for REE deposits in Greenland. deposits, as concluded in a recent REE On this background the Geological An overview of the REE distribution workshop. Survey of Denmark and Greenland (GEUS) based on geochemical information from and the Greenland Bureau of Minerals available stream sediment data is demon- and Petroleum (BMP), conducted a REE strated by the compilation map of stream Introduction potential workshop in 2010 to provide the sediments. Demand for REE is growing rapidly due to REE mineral exploration sector with the The REE workshop assessed the follow- innovation in the so-called ‘green tech- scientific background and necessary data ing REE-prone geological environments: nologies’, electronic devices, defence sys- to make qualified decisions. This magazine tems and petroleum refining catalysts. The highlights some of the results from this • Carbonatite magmatism global requirement for REEs in 2010 was workshop. REE accumulations are observed associ- 134,000 t, with global production around ated with carbonatite complexes. In 124,000 t. The difference was covered by Greenland the accumulation is often utilising previously mined reserves. Global related to late hydrothermal activity, View of the Kringlerne multi-element deposit with the characteristic mountain Redekammen in the background. Photo: Bureau of Minerals and Petroleum. 2
  • 3. R A R E E A RT H E L E M E N T P O T E N T I A L Licenced REE prospects with / without resource estimates Stream sediment samples with high REE / carbonatites (La>300 ppm, or Eu>10ppm or Yb>15 ppm) / alkaline complexes La/Yb Probable source environment 1 - 20 Pegmatite or placer other 20 - 40 Other sites with REE potential 40 - 60 Alkaline or sedimentary carbonatites 60 - 120 Carbonatite, lamprophyre alkaline complexes > 120 or monzonite Kap Simpson Stream sediment sample location Karrat Inland Ice Milne Land Sarfartoq Qaqarssuk Phanerozoic Tikiusaaq sedimentary, Skjoldungen volcanic and 100 km Alkaline intrusive Province rocks Caledonian mobile belt Qassiarsuk Palaeoproterozoic Grønnedal-Ika Motzfeldt Sø mobile belts Archaean craton Kvanefjeld Kringlerne Left figure: Plot of REE-anomalous stream sediment samples in Greenland reflecting the presence of known and unknown REE mineralisation or very REE- enriched rocks. Symbol colour scale illustrates the variation in La/Yb ratio of the anomalies. Since fractionation among light and heavy REE shows consid- erable and characteristic variation among diverse REE-rich lithologies, and since these characteristics are reflected in the stream sediments, the La/Yb ratio can be used to indicate the probable source lithology of a stream sediment anomaly. Right figure: Simplified geological map with selected known REE prospects and other sites with REE potential. where pathways in shear zones and • IOCG mineralising systems The individual tracts assessed during the joints play an important role. REE accumulations are typical in miner- workshop are shown on page 7. alising systems with low Ti - contents The potential areas outlined in the • Alkaline intrusions and where there are extensive Na and southern, eastern and southwestern part REE accumulations are typical during K - alterations, combined with of Greenland are due to the presence of igneous processes in layered intrusions increased contents of Co, Ag, U, Cu the Gardar intrusives, carbonatites and of strongly differentiated magmas with and P in coeval magmatism. alkaline intrusions. In North Greenland, or without hydrothermal overprints. however, only a few areas were defined, • Paleoplacer environments due to the extensive carbonate platform • Pegmatite settings Placer deposits are a result of second- and sedimentary basins hiding possible In simple pegmatites related to gran- ary accumulation of heavy minerals, REE deposits. ites, the minerals allanite and monazite often REE bearing minerals like mon- A list of the 10 REE occurrences with are commonly enriched in light REEs, azite and xenotime. the highest assessment score from the whereas a whole range of rare REE workshop assessment is given in table 1. minerals occurs in alkaline pegmatites. 3
  • 4. R A R E E A RT H E L E M E N T P O T E N T I A L Tract name Location Deposit model Geological settings Deposit size & grade* Score A1 Kvanefjeld Alkaline Known deposit. High level of information. 619 Mt 50 Extensive drilling has been conducted on the deposit. (6.6 Mt TREO including 0.24 Mt Contains uranium above background level. heavy REO, 0.53 Mt Y2O3 + 350 Mlbs U3O8 and 1.4 Mt Zn). A2 Kringlerne Alkaline Known deposit. High level of information. Extensive 1,000 Mt @ 2% ZrO2, 0.25% 50 drilling has been conducted on the deposit. Low Nb2O5, 0.5% REO, 0.1% Y2O3 and uranium content below or equal to background level. 0.025% Ta2O5. C3.1 Sarfartoq Carbonatite Known carbonatite showing. Kimberlites & 14 Mt @ 1.53% TREO. 41 terraine boundary in the area = active pathways. O3 Karrat Other The REE prospect have been drilled which classifies it 26 Mt @ 1.36% TREO + Y. 35 as an undiscovered deposit. Lamprophyric dykes are found in the area = active pathways. The deposition model is not yet fully understood – more work required. C3.2 Qaqarssuk Carbonatite Known carbonatite showing. Lamprophyres are found REE resource is currently 32 in the area = active pathways. beeing investigated. A3 Motzfeldt Sø Alkaline Known REE prospect. Micro syenites (which host the REE resource is currently 31 REEs) not much investigated. Limited drilling – only Ta, beeing investigated. Historical Nb and U targets drilled. More work is needed to data: 600 Mt @120 ppm Ta + evaluate the REE potential. 130 Mt grading 0.4 - 1.0% Nb205. A3.1 Qassiarsuk Alkaline Dyke with aegirine as prime mineral. Unknown. Showings of REE 22 The dyke is up to 4 m thick and can be followed for known - up to 1%. several kilometres. High Th content. C4 Tikiusaaq Carbonatite Known carbonatite showing. Lamprophyres and possible REE resource is currently 21 terraine boundary in the area = active pathways. beeing investigated. A11.1 Kap Simpson Alkaline Alkali syenite complex. Malmbjerg type alteration (high Unknown. Rock samples enriched 19 temp) seen via hyperspectral mapping. Several in REEs (3%) & Nb (3.2%). sources of mineralised rocks sampled from glaciers. C8.1 Overall tract Carbonatite Known showing. Lamprophyres and ailikites are found Unknown. 19 around the in the area. Greisen alteration at Ivittuut. Radioactive Grønnedal-Ika dykes (Ce enriched) are present in the area – radiates carbonatite. from the Grønnedal-Ika carbonatite. Table 1. List of the 10 REE occurrences with the highest scores from the workshop assessment. Maximum score is 50.Tract name refers to the areas shown on map on page 7. * Deposit size and grade numbers are based on company announcements and available online data as of September 2011. For specific and updated information please refer to the company websites of the individual deposits. tonic rift province consisting of sand- province also includes the Igaliko Known REE deposits stones, and a variety of volcanic and plu- Nepheline Syenite Complex, hosting the Eight REE deposits have been discovered tonic igneous rocks. The plutonic rocks are Motzfeldt Sø REE deposit. up to now in Greenland, of which two alkaline to peralkaline and are hosted may well be amongst the 10 largest REE within the Ilímaussaq intrusion (1160 Ma). Kvanefjeld deposits in the world. The geological set- The Ilímaussaq intrusion is largely The Kvanefjeld multi-element deposit, tings for these REE deposits vary, and the implaced by block subsidence and formed located a few kilometers north of Narsaq, ages cover a wide span. A brief introduc- by three pulses, of which the third formed South Greenland, is an accumulation of tion to these known deposits follows. a layered series of nepheline syenites. The various igneous rocks and supracrustals Ilímaussaq intrusion is generally enriched from the roof of the Ilímaussaq intrusion. The Gardar province hosts three large in the elements U, Th, Nb, Ta, Be, Zr, Li, F, Additionally rocks from the early phases of REE deposits: Kvanefjeld, Kringlerne Zn and REE, and hosts two REE deposits the alkaline intrusion are also included, and Motzfeldt Sø e.g. Kringlerne (dominated by the kakor- forming blocks and sheets within the later The Meso-proterozoic Gardar province in tokite bottom cumulates) and Kvanefjeld agpaitic magma. The bulk of the REE (as South Greenland is designated as a cra- (dominated by lujavrites). The Gardar well as U and Th) is associated with the 4
  • 5. R A R E E A RT H E L E M E N T P O T E N T I A L View of the Narsaq Valley, Kvanefjeld and gravel road to the former test mine. Photo: Greenland Minerals and Energy A/S. lujavrite rocks hosting disseminated steen- TREO, 404 ppm U3O8 (0.05% heavy townships of Narsaq and Qaqortoq in strupine, which is the primary mineral host REO, 0.12% Y2O3) South Greenland. The kakortokite cumu- of both REEs, U and Th. The deposit also lates form a total of 29 cyclic, and regular contains zinc, occurring mainly as dissemi- Kringlerne layers, with a total thicknes of about 200 nated sphalerite in the lujavrite, and fluo- The multi-element deposit at Kringlerne is m, made by units composed of black rine hosted in the mineral villiaumite hosted in the lower cumulates of the lay- syenite (arfvedsonite dominated), reddish (NaF). The Kvanefjeld deposit has previ- ered agpaitic nephenline syenites, referred syenite (eudialyte dominated) and whitish ously been explored for the potential of U to as kakortokite, and is situated near the syenite (feldspar dominated) rocks. The and Th. The Kvanefjeld REE deposit is dominat- ed by Ce (approx. 40%), La (approx. 25%), Nd (approx. 15%), Y (approx. 10%), Pr (approx. 5%) and the remaining HREE accounts for about 5%. Greenland Minerals and Energy A/S has reported the following resource estimate figures (based on 150 ppm U3O8 cut-off): • Total JORC resource of 619 Mt • Indicated JORC resources of 437 Mt • Inferred resources of 182 Mt • Contained metal inventory of 6.6 Mt TREO, including 0.24 Mt heavy REO and 0.53 Mt Y2O3 as well as 350 Mlbs U3O8 and 1.4 Mt Zn • Near surface, higher grade zones The characteristic layering of the Karkortokite at the Kringlerne multi-element deposit. Note the campsite defined, including 122 Mt @ 1.4% in the lower left part of the image as scale. Photo: TANBREEZ Mining Greenland A/S. 5
  • 6. 20 / 2011 GEOLOGY AND ORE R A R E E A RT H E L E M E N T P O T E N T I A L Drill core logging at the Motzfeldt Sø camp in 2011. Photo: Ram Resources Ltd. mineral eudialyte (Greek for ‘easily dis- the 1980s is 600 Mt grading 120 ppm Ta. Sarfartoq solved’) is enriched in Ta-Nb-REE-Zr-Y and High grade zones carry up to 426 ppm Ta. The Sarfartoq carbonatite complex (564 Ma) this is the main exploration target for REE Additionally an Nb resource of at least is well exposed, situated on the transition by the licensee, Rimbal Pty Ltd. The kakor- 130 Mt grading 0.4-1.0% Nb205 is zone between the Archaean craton and tokites have been investigated for decades known. The deposit is regarded as a ‘low the Palaeoproterozoic Nagssugtoqidian focusing in particular on Zr, Y, Nb, and grade-large tonnage’ type of resource. mobile belt. The host rocks are granodi- REE. Ram Resources Ltd. is currently investi- oritic gneisses.The complex was discov- Current work by Rimbal Pty Ltd indi- gating the intrusion for REEs. The 2010 ered by GGU in 1976 on the basis of a cates a resource of no less than 1,000 Mt work indicates that the known Ta-Nb min- regional airborne radiometric survey and grading 2% ZrO2, 0.25% Nb2O5, 0.5% eralisation is only weakly correlated with later fieldwork. Subsequently, the complex REO, 0.1% Y2O3 and 0.025% Ta2O5. The the REE mineralisation. In the central part has been the target of various exploration distribution of light and heavy REEs in of the intrusion, where the richest Ta-Nb campaigns focusing on diamonds, P, Nb eudialyte is reported to be 88% and 12% mineralisation is found, the lithology is and REE. respectively. predominantly altered syenite, with minor The central core zone of the complex is pegmatite and diorite dykes. However, surrounded by a series of ring-like layers Motzfeldt Sø high grade REE intersections are concen- or dykes, containing innumerable intrusive The Motzfeldt Sø REE deposit is part of trated in the pegmatite intrusives at the Motzfeldt Centre, which in turn is part depth, but are also found scattered of the Igaliko Nepheline Syenite Complex. throughout the drill holes, gradually Pyrochlore accumulations in the Motzfeldt decreasing in grade towards the east. Map showing the areas (tracts) used for the REE Sø syenite show significant grades of Estimated JORC resource figures are antici- potential assessment workshop, grouped Tantalum. The estimated resource based pated at the beginning of 2012. according to the type of geological environment on investigations carried out by GEUS in of relevance to REE deposits. 6
  • 7. R A R E E A RT H E L E M E N T P O T E N T I A L D N A L I S E R E M S E D L L Y LAN E PEAR and nL nd nse La riste n . Ch E gt o J. C in D sh Æ Wa R T S Kane Bassin S E N A R I3 P13 O2 Pituffik A? Store Koldeway LA UG E KO CH KY P12 Me ST lv ill e B u gt P11 C14 A12 P14 A13 C15 A11.1 BAFF P15 IN Svartenhuk A10 BUGT Halvø O3.1 A11 Ubekendt Ejland O3 A14 Va A9 Illoqqortoormiut iga t DE O1 S ull STRÆ ors ua q Disko Anap Nunaa DAV IS C1 P2 Aasiaat C13 A8 C2 P1 Attu P3 I1 P4 A7 Sisimiut C3.1 C3 C12 A6 C3.2 Legend P10 Tasiilaq Nuuk P5 I2 Alkaline tracts C4 Carbonatite tracts C4.1 C11 C11.1 IOCG tracts C5 A5 Skjoldungen P6 C6 C9.1 Pegmatite tracts Paamiut A17 A3 C10 C7 A3.1 Other tracts P7 A1 A15 C8 A4 C8.1 A16 P9 Kilometers A2 P8 C9 0 125 250 375 500 C9.2 7
  • 8. 20 / 2011 R A R E E A RT H E L E M E N T P O T E N T I A L carbonate breccia veins. Substantial feniti- GEOLOGY AND ORE sation occurs around the core. Mineralisa- tion of Nb and REE has been recorded from separate zones in the outer fenitised zone. The REE minerals are correlated with thorium and are mainly bastnasite, synchysite and monazite. In 2010 Hudson Resources reported an NI 43-101 compliant resources estimate result over the ST1 site in the northern part of the complex: 14 Mt inferred resources avaraging 1.53% TREO at a cut-off grade of 0.8% TREO. The REE distribution is 45% Ce, 20% La, 25% Nd, 6% Pr, 2% Sm, and approx. 2% Gd, Dy and Y. Qaqarssuk The Qaqarssuk carbonatite complex (165 Ma), situated 60 km east of Maniitsoq, View towards the well exposed outcrop at the ST1 site, part of the Sarfartoq carbonatite complex. West Greenland, intruded the Archaean The slope is c. 200 m high. gneiss complex, along with kimberlite dykes and alkaline intrusions. The compo- sition of the carbonatite varies from sövite to rauhaugite. Outcropping of vertical to subvertical, early stage carbonatite sheets of the Qaqarssuk carbonatite complex. Photo: NunaMinerals A/S. 8
  • 9. R A R E E A RT H E L E M E N T P O T E N T I A L Aerial view of the Tikiussaq carbonatite complex with carbonatite sheets and fenites (yellowish areas) exposed in north walls of the gully. The extent of the gully is c. 1-1.5 km. Photo: NunaMinerals A/S. In 2010 NunaMinerals A/S initiated REE intruded by carbonate-rich ultramafic sili- that the extension of the carbonatite dykes exploration within the carbonatite. The cate dykes. NunaMinerals A/S initiated continues to a depth of at least 500 m. main potential appears to lie in the core exploration of the Tikiusaaq carbonatite in of the complex concealed in carbonate 2010, and focussed on the aeromagneti- The Niaqornakassak and veins , and the company reports the aver- cally defined ‘carbonatite core’. REEs are Umiammakku Nunaa REE deposits age grade for a 1.5 km2 area as 2.4% typically enriched in the latest phases of The Niaqornakassak (NIAQ) REE deposit in TREO, mainly hosted in ancylite (Sr-REE- carbonatite magmatism, and the main REE central West Greenland was discovered by carbonate); the mineralisation is LREE mineral is ancylite (Sr-REE carbonate). REE- Avannaa Resources Ltd. in 2007 and in dominated with 50% Ce, 27% La, 16% enriched carbonatite surface samples con- 2009, an extension of the deposit was dis- Nd, and 5% Pr. The REE-mineralised veins taining up to 9.6% TREO (predominantly covered on the Umiammakku Nunaa are generally less than one metre thick. LREE), have been found in an area of (UMIA) peninsula 7 km along strike from anomalous thorium counts. The REE distri- the NIAQ site. The two deposits are jointly Tikiusaaq bution is 47% Ce, 33% La, 12% Nd, 4% named ‘Karrat’. The Tikiusaaq carbonatite, discovered by Pr and 4% other REEs. High phosphate Work conducted by Avannaa Resources GEUS in 2005 by using regional stream grades (up to 8.5% P2O5) were returned Ltd. in 2010 on the NIAQ and UMIA sediment data and regional airborne geo- from surface samples within the magnetic deposits included diamond drilling and physical data, consists of massive core of the carbonatite. collecting 13 mini-bulk samples. The REE dolomite-calcite carbonatite sheets intrud- A recent interpretation of radiometric accumulation is hosted in an amphibolite ed along a ductile shear zone at approxi- and magnetic data indicates a separate body unit of the Palaeoproterozoic Karrat Group. mately 158 Ma. The carbonatite is later about 750 m long and 100 m wide and Strike length of NIAQ is 1.5 km but open 9
  • 10. 20 / 2011 R A R E E A RT H E L E M E N T P O T E N T I A L at both ends. The tabular NIAQ ore body GEOLOGY AND ORE has been found at a maximum elevation of 56 m above sea level and down to 168 m below sea level; the thickness varies between approx. 10 m and 33 m. The NIAQ bulk samples indicate an average of TREO of 1.36%, of which the average HREO content is approx. 13%. Preliminary resource estimates of the NIAQ body are 26 Mt. The REE are mainly hosted by bast- nasite, monazite and allanite related to hydrothermal agents within the miner- alised sequences. Very limited work has been undertaken on the UMIA body. Based on three drill holes the TREO of the UMIA deposit is in the range of 0.08 - 0.12%. Milne Land REE deposit The Mesozoic Milne Land paleoplacer was discovered in 1968 by Nordisk Mineselskab A/S in connection with a heavy minerals concentrate sampling programme and an airborne radiometric survey. The placer is in the basal part of the Charcot Bugt For- mation, and the most anomalous locality, "Hill 800" in Bays Fjelde, is around 500 m in diameter and 40-50 m thick. The heavy minerals are hosted by a 20 m thick basal sandstone. The potential resources REE,Ti and Th are mainly hosted in monazite. In 1990, Coffs Harbour Rutile extracted a 15-tonne selective bulk sample from 5 pits in the “Hill 800” area, and about 10 tonnes were investigated metallurgically. Recoveries from a pilot scale study led to the conclusion that it is feasable to extract commercial products of monazite, zircon and garnet, but not of anatase due to its fine-grained and complex nature. Coff Harbour Rutile estimates the resource for “Hill 800” at 3.7 Mt with 1.1% zircon, 0.5% monazite, 2.6% anatase, 3.1% gar- net and 0.03% xenotime. Sirius Minerals Ltd. are currently exploring the REE poten- tial of this placer deposit. aside from of the known deposits at Among the known deposits are Sarfartoq, Kvanefjeld and Kringlerne. Among the Qaqarssuk and Tikiussaq. Of these, Tikiussaq Conclusions more promising areas are around the were only recently discovered in 2006. Based on the conclusions of the recently Grønnedal-Ika carbonatite and the In the more remote and less investigated conducted workshop at GEUS, South Qassiarsuk carbonatite. areas of Greenland, the Kap Simpson Greenland is believed to have the largest West Greenland is highly prosperous alkaline intrusion in central East Greenland potential for hosting new REE deposits, for carbonatite related REE deposits. and the Skjoldungen Alkaline Province in 10
  • 11. R A R E E A RT H E L E M E N T P O T E N T I A L Geological mapping and sampling of the NIAQ REE deposit in 2010. Photo: Avannaa Resources Ltd. South East Greenland are believed to have licences to move the projects towards a good potential for hosting new REE exploitation stage. Greenland has thus deposits. responded to the increased global demand Several of the known deposits are and has a possibility to become a major already covered by exploration licences exporter of rare earth elements. and extensive exploration and drilling is currently being carried out on several 11
  • 12. 20 / 2011 Bureau of Minerals and Petroleum (BMP) Government of Greenland P.O. Box 930 GEOLOGY AND ORE DK-3900 Nuuk NIAQ and UMIA REE deposits Greenland Tel: (+299) 34 68 00 Fax: (+299) 32 43 02 E-mail: bmp@gh.gl Internet: www.bmp.gl View of the NIAQ and UMIA REE deposits. The distance between the two deposits is 7 km. Photo: Avannaa Resources Ltd. Geological Survey of Denmark and Greenland (GEUS) Key references Øster Voldgade 10 Grice, J. D., Gault, R.A., Rowe, R. & Johnsen, O. Sørensen, H. 2006: The Ilímaussaq Alkaline DK-1350 Copenhagen K Denmark 2006: Qaqarssukite -(Ce), a new barium-cerium Complex, South Greenland – an Overview of fluorcarbonate mineral species from Qaqarssuk, 200 years of research and outlook. Contribution Tel: (+45) 38 14 20 00 Greenland. Canadian Mineralogist 44, 1137-1146. to the mineralogy of Ilímaussaq no. 130. Fax: (+45) 38 14 20 50 Harpøth, O., Pedersen, J.L., Schønwandt, H.K. Meddelser om Grønland. Geoscience 45, 70 pp. E-mail: geus@geus.dk & Thomassen, B. 1986: The mineral occurrences Sørensen, L. L., Kalvig, P., Hanghøj, K. 2011: Rare Internet: www.geus.dk of central East Greenland. Meddelelser om Grøn- earth element potential in Greenland. Reporting land. Geoscience 17, 138 pp. the BMP/GEUS mineral resource assessment work- Knudsen, C. 1991: Petrology, geochemistry and shop 29 November - 1 December 2010. 2. revised economic geology of the Qaqarssuk carbonatite version. Danmarks og Grønlands Geologiske complex, southern West Greenland. Monograph Undersøgelse Rapport 2011/80, 30 pp. + 1 DVD. Series on Mineral Deposits 29, 110 pp. Tappe, S., Steenfelt, A., Heaman, L. M. & Secher, K. & Larsen, L.M. 1980: Geology and Siminetti, A. 2009: The newly discovered Jurassic Front cover photograph mineralogy of the Sarfartôq complex, southern Tikiusaaq carbonatite-aillikite occurrence, West Front cover photograph: Hudson Resources Inc. drilling for REEs at its West Greenland. Lithos 13, 199-212. Greenland, and some remarks on carbonatite-kim- ST19 target which is part of the Secher, K., L. M. Heaman, Nielsen, T.F.D., berlite relationships. Lithos 112S, 385-399. Sarfartoq carbonatite complex. Photo: Jensen, S.M., Schjøth, F. & Creaser, R.A. 2009: Tukiainen, T. 1988: Niobium-tantalum mineral- Hudson Resources Inc. Timing of kimberlite, carbonatite, and ultramafic isation in the Motzfeldt Centre of the Igaliko lamprophyre emplacement in the alkaline province Nepheline Syenite Complex, South Greenland. In located 64º– 67ºN in southern West Greenland. Boissonnas, J. & Omenetto, P. (ed) Mineral Lithos 112S: 400-406. Deposits within the European Community. Authors Steenfelt, A. 2001: Geochemical atlas of Green- SpringerVerlag Berlin & Heidelberg, 230-246. Lars Lund Sørensen & land – West and South Greenland. Danmarks og Per Kalvig, GEUS Grønlands Geologiske Undersøgelse Rapport 2001/46, 39 pp. + 1 CD-Rom. Editors Steenfelt, A., Schjøth, F., Sand, K.K., Secher, K., Lars Lund Sørensen & Tappe, S., Moberg, E. & Tukiainen, T. 2007: Karsten Secher, GEUS Usage of the term rare earth element initial assessment of the geology and economic (REE) in this magazine is restricted to 16 Graphic Production potential of the Tikiusaaq carbonatite complex and elements including Y, La, and the lan- Carsten E. Thuesen, GEUS ultramafic lamprophyre dykes. Mineral resource assessment of the Archaean Craton (66° to thanides. Photographs 63°30'N) SW Greenland Contribution no. 3. Dan- GEUS unless otherwise stated marks og Grønlands Geologiske Undersøgelse Given the fact that many REE deposits Rapport 2007/64, 53 pp. + 1 DVD. also contain various amounts of U and Printed Sørensen, H. 2001: The Ilímaussaq alkaline com- Th, it should be stressed that the Green- November 2011 © GEUS plex, South Greenland: status of mineralogical land Government has introduced a zero- research with new results. Geology of Green- tolerance policy with regard to exploita- Printers land Survey Bulletin 190, 167 pp. tion of radioactive minerals. Radioactive Rosendahls Schultz Grafisk a/s • resources are not dealt with in this issue. 12 ISSN 1602-818x