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Geologic Time
Correlation and Dating of the Rock
              Record
Time
• Relative
  – Order of deposition of a body of rock based on
    position
• Absolute
  – A number representing the time a body of rock
    was deposited
Relative Time
• Determining of sequence of events

• Which came first?
In what order did these events occur in
             American History?
A             B                 C




    D                       E
Relative Time
• Tools
  – Smith
     • Fossil Succession
  – Steno
     • Superposition
     • Original horizontality
  – Lyell
     • Cross-cutting relationships
     • Intrusions
     • Inclusions
Principle of fossil succession
• Fossils occur in a consistent vertical order in
  sedimentary rocks all over the world.
  (William"Strata Bill" Smith, late 1700's, England).

• This principle is valid and does not depend on any
  pre-existing ideas of evolution. (In fact, Charles
  Darwin's ideas on evolution did not appear until
  50 years later - 1858).
Principle of fossil succession
Geologists interpret fossil succession to be the result of
  evolution - the natural appearance and disappearance of
  species through time.


"Fossil species succeed one another in a definite and
  recognizable order"

Fossils at the base of a thick sequence of sediments
  (so older, by previous principles) are less like
  present-day species than those near the top
Principle of fossil succession
* Fossils unlike present-day species, but like
  each other, are found in widely separated
  sites
* A fossil species which is observed to occur
  above (and so younger than, by previous
  principles) a second fossil species in one
  locality will always occur above that second
  species, wherever found.
Principle of fossil succession
Unconformities
• Unconformities are buried surfaces of
  erosion or non-deposition
Unconformities
1.Angular unconformities
  Implies tectonic deformation and erosion of underlying
    strata.


2.Nonconformity
  Sedimentary strata overlying igneous or metamorphic
    rocks (in an erosional - not intrusive- contact)


3.Disconformity
  An irregular surface of erosion between two units of
   parallel strata
Disconformity
 Big Brook
Angular Unconformity
Nonconformity
               Brahma Schist underlies Tapeats Sandstone




http://www.physci.mc.maricopa.edu/Geology/FieldTrips/ColoradoRiver/ColoradoRiver_2006_Summer/ColoradoRiver_2006_Summer_Images_1024/DSC00512a_1024c.jpg
Nonconformity
               Brahma Schist underlies Tapeats Sandstone




http://www.physci.mc.maricopa.edu/Geology/FieldTrips/ColoradoRiver/ColoradoRiver_2006_Summer/ColoradoRiver_2006_Summer_Images_1024/DSC00512a_1024c.jpg
Siccar Point
Relative Dating
• Principle of Cross-cutting relationships

• Principle of Intrusions

• Principle of Inclusions
Principle of Cross-cutting
      relationships
Faulting
Principle of Inclusions




In which picture is the Granite older?
Principle of Intrusions
Intrusions vs Unconformities
• A xenolith is a fragment of country rocks
  which has been broken off during an
  intrusion, and has become surrounded by
  magma. The xenolith is older than the
  igneous rock which contains it.
• Through erosion and resedimentation,
  younger rocks will often have pieces of the
  older rock included (sedimentary).
Principle of Inclusions
Principle of
 Inclusions
Principle of Inclusions
Test Your Knowledge
f
g
e
b
d
c
a
History of
Geologic Time
• Geologic Systems
  – Body of rock that
    contains fossils of
    diverse animal life
  – Corresponds to
    geologic period
• Sedgewick
  – Named Cambrian
• Murchison
  – Named Silurian
Stratigraphy
• Study of stratified rocks, especially their
  geometric relations, compositions, origins, and
  age relations
• Stratigraphic units
   – Strata
      • Distinguished by some physical, chemical, or paleontological
        property
      • Units of time based on ages of strata
   – Geologic Systems
• Correlation
   – Demonstrate correspondence between geographically
     separated parts of a stratigraphic unit
      • Lithologic
      • Temporal
Units of Time
• Time-rock unit
   – Chronostratigraphic unit
   – All the strata in the world deposited during a particular interval
     of time
       • Erathem, System, Series, Stage
• Time unit
   – Geochronologic unit
   – Interval during which a time-rock unit is formed
       • Eras, Period, Epoch, Age
• Boundary stratotype
   – Boundary between two systems, series or stages, formally
     defined at a single locality
Geologic Time Scale
• Chronologic units - Time/Age

  –   Eons (largest):
  –   Era
  –   Periods
  –   Epochs
  –   Ages
Geologic Time Scale
• Geochronologic Units = Place

  –   Eon (largest) = Eon
  –   Era = Era
  –   System = Period
  –   Series = Epoch
  –   Stage = Age
Biostratigraphy
• Biostratigraphic unit
   – Defined and characterized by their fossil content
• Stratigraphic range
   – Total vertical interval through which that species
     occurs in strata, from lowermost to uppermost
     occurrence
Biostratigraphy
• Index fossil
   – Abundant enough in the stratigraphic record to be
     found easily
   – Easily distinguished from other taxa
   – Geographically widespread and thus can be used to
     correlate rocks over a large area
   – Occurs in many kinds of sedimentary rocks and
     therefore can be found in many places
   – Has a narrow stratigraphic range, which allows for
     precise correlation if its mere presence is used to
     define a zone
Magnetic Stratigraphy
            • Use of magnetic
              properties of a rock to
              characterize and
              correlate rock units
            • Magnetic field
               – Reversals in polarity of
                 field are recorded in
                 rocks when they
                 crystallize or settle
                 from water
Magnetic
   Stratigraphy
• Chron
  – Polarity time-rock unit
  – Period of normal or
    reversed polarity
     • Normal interval
          – Same as today
          – Black
     • Reversed interval
          – Opposite to today
          – White
Lithostratigraphy
• Subdivision of the stratigraphic record on the basis of
  physical or chemical characteristics of rock
• Lithostratigraphic units
   – Formation
       • Local three-dimensional bodies of rock
            – Group
            – Member
• Stratigraphic section
   – Local outcrop of a formation that displays a continuous vertical
     sequence
• Type section
   – Locality where the unit is well exposed, that defines the unit
Lithologic Correlation
             • Cross-sections of
               strata
                – Establish geometric
                  relationships
                – Interpret mode of
                  origin
Lithologic Correlation
           • Grand Canyon
             – McKee
             – Used Trilobite
               biostratigraphy to
               determine age
               relationships
             – Eastern portion of
               units is younger than
               western
Facies
     • Transgression
         – Landward migration of
           shoreline
         – Grand Canyon
              • Cambrian transgression
     • Facies
         – Set of characteristics of a body
           of rock that presents a
           particular environment
     • Facies changes
         – Later changes in the
           characteristics of ancient strata
Absolute Age
• 4.6 billion years old
• Early estimates
   – Salts in the ocean
       • 90 million years old
   – Accumulation of sediment
       •   100 m.y. or less
       •   Gaps in stratigraphic record
       •   Unconformities represent large breaks in accumulation
       •   Didn’t include metamorphosed sedimentary rocks
   – Earth’s temperature
       • Kelvin
       • 20-40 million years old
Absolute Ages
• How old is the Earth?

• 4.6 billion years (4,600,000,000 years)

• Radiometric dating (Uranium, Thorium).
  Mass spectrometer.
Early Attempts
• 1654 Archbishop Usher (Ireland), genealogy
  in Bible Earth was created October 22, 4004
  BC,
• 9:00 am was added later
• Earth was 6000 years old.
• Led to the Doctrine of Catastrophism:
• Earth was shaped by series of giant disasters.
• Many processes fit into a short time scale.
Early Attempts
• 1770's, 1780's "Revolution"
• James Hutton, Father of Geology (Scotland)
  1726-1797.
• Published Theory of the Earth in 1785.
Hutton
• Hadrian's Wall built by Romans,
  after 1500 years no change.
  Suspected that Earth was much
  older.

• Slow processes shape earth.

• Mountains arise continuously as
  a balance against erosion and
  weathering
Hutton
• Doctrine of Uniformitarianism: "Present is key to
  the past".

• The physical and chemical laws that govern nature
  are uniform
•
• Unconformity at Siccar Point, Scotland

• "No vestige of a beginning, no prospect of an end"
Charles Lyell
• Charles Lyell 1800's compared amount of
  evolution shown by marine mollusks in the
  various series of the Tertiary System with the
  amount that had occurred since the beginning
  of the Pleistocene.

• Estimated 80 million years for the Cenozoic
  alone.
Various Geologists
• Thickness of total sedimentary record
  divided by average sedimentation rates (in
  mm/yr).

• In 1860, calculated to be about 3 million
  years old.

• In 1910, calculated to be about 1.6 billion
  years old.
Lord Kelvin
• In 1897, Lord Kelvin
  assumed that the Earth was
  originally molten and
  calculated a date based on
  cooling through conduction
  and radiation.

• Age of Earth was calculated
  to be about 24-40 million
  years.
Lord Kelvin
• Problem: Earth has an internal heat source
  (radioactive decay)

• Discovery of radioactivity by Henri
  Becquerel in 1896.
John Joly
• In 1899 - 1901, John Joly (Irish) calculated
  the rate of delivery of salt to the ocean. River
  water has only a small concentration of salts.
  Rivers flow to the sea.
• Evaporative concentration of salts.

• Age of Ocean = Total salt in oceans (in grams)
  divided by rate of salt added (grams per year)


• Age of Earth = 90-100 million years.
John Joly

• Problems: no way to account for recycled
  salt, salt incorporated into clay minerals, salt
  deposits.
von Helmholtz and Newcomb

The German physicist Hermann von Helmholtz and the American
astronomer Simon Newcomb joined in by independently
calculating the amount of time it would take for the Sun to
condense down to its current diameter and brightness from the
nebula of gas and dust from which it was born.

 100 million years, consistent with Thomson's calculations.
However, they assumed that the Sun was only glowing from the
heat of its gravitational contraction. They knew of no other ways
for it to produce its energy.
Rutherford and Boltwood

• In 1905, they used radioactive decay to
  measure the age of rocks and minerals.

• Uranium decay produces He, leading to a
  date of 500 million years.
Rutherford and Boltwood

In 1907, Boltwood suspected that lead was the
  stable end product of the decay of uranium.
  Published the age of a sample of urananite
  based on Uranium-Lead dating.

Date was 1.64 billion years.
Age of Earth
• So far, oldest dated Earth rocks are 3.96 billion
  years.
• Canadian Shield. (NW Territories near Great
  Slave Lake, 3.96 byr).
• Detrital Zircons in sedimentary rocks are 4.1 - 4.4
  byr
• Older rocks include meteorites and moon rocks
  with dates on the order of 4.6 billion years.
Geologic Time Scale.
 The age for the base of
   each division is in
    accordance with
recommendations of the
      International
    Commission on
  Stratigraphy for the
       year 2000.
Geologic
 Time
 Scale
The standard geologic
    time scale for the
Paleozoic and other eras
   developed without
benefit of a grand plan.
 Instead, it developed by
 the compilation of “type
 sections” for each of the
         systems.
Ordovician
Silurian

Murchison
Silurian   -   Murchison
Jurassic - Jura Mountains
• Cretaceous

• Kreta = Chalk

• White Cliffs of Dover
Absolute Age
• Radioactive decay
  – Becquerel, 1895
     • Uranium undergoes spontaneous decay
     • Atoms release subatomic particles and energy
     • Change to another element
  – Parent isotope decays/daughter isotope
    produced
Principles of Radiometric Dating
• Naturally-occurring radioactive materials
  break down into other materials at known
  rates. This is known as radioactive decay.

• Radioactive parent elements decay to stable
  daughter elements.
What is an Isotope?
• Nuclide of an element with different masses
Absolute Age
      • Three modes of decay
         – Loss of alpha particle
             • Convert parent into
               element that has nucleus
               containing two fewer
               protons
         – Loss of beta particle
             • Convert parent into
               element whose nucleus
               contains one more proton
               by losing an electron
         – Capture of beta particle
             • Convert parent into
               element whose nucleus
               has one less proton
Absolute Age
      • Radiometric dating
         – Radioactive isotopes
           decay at constant
           geometric rate
            • After a certain amount
              of time, half of the
              parent present will
              survive and half will
              decay to daughter
      • Half-life
         – Interval of time for half
           of parent to decay
Absolute Age
• Useful isotopes
   – Uranium 238 and thorium 232
      • Zircon grains
   – Uranium 238 and lead 206
      • Fission track dating
   – Rubidium-Strontium
   – Potassium-Argon, Argon-Argon
   – Radiocarbon dating
      •   Produced in upper atmosphere
      •   Half life = 5730 years
      •   Maximum age for dating: 70,000 years
      •   Bone, teeth, wood
Absolute Age
      • Fission-Track Dating
        – Measure decay of
          uranium 238 by
          counting number of
          tracks
        – Tracks formed by
          subatomic particles
          that fly apart upon
          decay
Radioactive parent isotopes and
 their stable daughter products
  Each radioactive isotope has its own
  unique half-life.

  A half-life is the time it takes for half
  of the parent radioactive element to
  decay to a daughter product.
Radioactive parent isotopes and
   their stable daughter products
Radioactive Parent   Stable Daughter   Half Life

Potassium 40         Argon 40          1.25 billion yrs

Rubidium 87          Strontium 87      48.8 billion yrs

Thorium 232          Lead 208          14 billion years

Uranium 235          Lead 207          704 million years

Uranium 238          Lead 206          4.47 billion years

Carbon 14            Nitrogen 14       5730 years
Radioactive Decay
Radioactive Decay
• Radioactive decay occurs by releasing
  particles and energy.

•   Alpha particles
•   Beta particles
•   Neutrons
•   Gamma rays (high energy X-rays) are also
    produced.
Radioactive Decay
• Alpha particles (He)
•     large, easily stopped by paper
•     charge = +2
•     mass = 4
Radioactive Decay
• Beta particles
• penetrate hundreds of times farther than
  alpha particles, but easily stopped compared
  with neutrons and gamma rays.
•     charge = -1
•     mass = negligible
Radioactive decay
series of uranium-
238 (238U) to lead-
    206 (206Pb).
Datable Minerals
• Most minerals which contain radioactive isotopes
  are in igneous rocks. The dates they give indicate
  the time the magma cooled.
• Potassium 40 is found in:
•          potassium feldspar (orthoclase)
•          muscovite
•          amphibole
•          glauconite (greensand; found in some
             sedimentary rocks; rare)
•
Datable Rocks
• Radioactive elements tend to become
  concentrated in the residual melt that
  forms during the crystallization of
  igneous rocks. More common in
  SIALIC rocks (granite, granite
  pegmatite) and continental crust.
Datable Rocks
• Radioactive isotopes don't tell much about
  the age of sedimentary rocks (or fossils).
  The radioactive minerals in sedimentary
  rocks are derived from the weathering of
  igneous rocks. If the sedimentary rock were
  dated, the age date would be the time of
  cooling of the magma that formed the
  igneous rock. The date would not tell
  anything about when the sedimentary rock
  formed.
Carbon 14
14
  How does Carbon dating work?

• Cosmic rays from the sun
  strike Nitrogen 14 atoms in
  the atmosphere and cause
  them to turn into
  radioactive 14C, which
  combines with oxygen to
  form radioactive CO2.
14
  How does Carbon dating work?

• Living things are in
  equilibrium with the
  atmosphere, and the
  radioactive CO2 is absorbed
  and used by plants. The
  radioactive CO2 gets into the
  food chain and the carbon
  cycle.
14
  How does Carbon dating work?
• All living things contain a constant ratio of 14C to 12C (1
  in a trillion).

• At death, 14C exchange ceases and any 14C in the tissues
  of the organism begins to decay to Nitrogen 14, and is
  not replenished by new 14C.
14
  How does Carbon dating work?
• The change in the 14C to 12C ratio is the basis for
  dating.

• The half-life is so short (5730 years) that this
  method can only be used on materials less than
  50,000 years old.

• Assumes that the rate of 14C production (and
  hence the amount of cosmic rays striking the
  Earth) has been constant.
Deviation of carbon-14 ages to true ages from
  the present back to about 5000 B.C. Data are
 obtained from analysis of bristle cone pines from
the western United States. Calculations of carbon-
      14 are based on half-life of 5730 years.
(Adapted from Ralph, E. K., Michael, H. N., and Han, M. C. 1973. Radiocarbon
                 dates and reality. MASCA Newsletter 9:1.)
Absolute Age
        • Best candidates for
          most radiometric
          dating are igneous
           – Not necessarily useful
             for sediments
        • Error in age estimate
          can be sizable
Absolute Age
      • Absolute ages change
         – Error increases in older
           rocks
         – Techniques change
      • Biostratigraphic
        correlations are
        usually more accurate
         – Radiometric dates used
           when fossils not
           present
How old is the Old Red Sandstone?
a. Older than 425 myr
b. Younger than 370 myr
c. Between 425 and 370 myr
d. Have no idea

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03 time slides

  • 1. Geologic Time Correlation and Dating of the Rock Record
  • 2. Time • Relative – Order of deposition of a body of rock based on position • Absolute – A number representing the time a body of rock was deposited
  • 3. Relative Time • Determining of sequence of events • Which came first?
  • 4. In what order did these events occur in American History? A B C D E
  • 5. Relative Time • Tools – Smith • Fossil Succession – Steno • Superposition • Original horizontality – Lyell • Cross-cutting relationships • Intrusions • Inclusions
  • 6. Principle of fossil succession • Fossils occur in a consistent vertical order in sedimentary rocks all over the world. (William"Strata Bill" Smith, late 1700's, England). • This principle is valid and does not depend on any pre-existing ideas of evolution. (In fact, Charles Darwin's ideas on evolution did not appear until 50 years later - 1858).
  • 7. Principle of fossil succession Geologists interpret fossil succession to be the result of evolution - the natural appearance and disappearance of species through time. "Fossil species succeed one another in a definite and recognizable order" Fossils at the base of a thick sequence of sediments (so older, by previous principles) are less like present-day species than those near the top
  • 8. Principle of fossil succession * Fossils unlike present-day species, but like each other, are found in widely separated sites * A fossil species which is observed to occur above (and so younger than, by previous principles) a second fossil species in one locality will always occur above that second species, wherever found.
  • 9. Principle of fossil succession
  • 10. Unconformities • Unconformities are buried surfaces of erosion or non-deposition
  • 11. Unconformities 1.Angular unconformities Implies tectonic deformation and erosion of underlying strata. 2.Nonconformity Sedimentary strata overlying igneous or metamorphic rocks (in an erosional - not intrusive- contact) 3.Disconformity An irregular surface of erosion between two units of parallel strata
  • 14. Nonconformity Brahma Schist underlies Tapeats Sandstone http://www.physci.mc.maricopa.edu/Geology/FieldTrips/ColoradoRiver/ColoradoRiver_2006_Summer/ColoradoRiver_2006_Summer_Images_1024/DSC00512a_1024c.jpg
  • 15. Nonconformity Brahma Schist underlies Tapeats Sandstone http://www.physci.mc.maricopa.edu/Geology/FieldTrips/ColoradoRiver/ColoradoRiver_2006_Summer/ColoradoRiver_2006_Summer_Images_1024/DSC00512a_1024c.jpg
  • 17. Relative Dating • Principle of Cross-cutting relationships • Principle of Intrusions • Principle of Inclusions
  • 18. Principle of Cross-cutting relationships
  • 20. Principle of Inclusions In which picture is the Granite older?
  • 22. Intrusions vs Unconformities • A xenolith is a fragment of country rocks which has been broken off during an intrusion, and has become surrounded by magma. The xenolith is older than the igneous rock which contains it. • Through erosion and resedimentation, younger rocks will often have pieces of the older rock included (sedimentary).
  • 27. History of Geologic Time • Geologic Systems – Body of rock that contains fossils of diverse animal life – Corresponds to geologic period • Sedgewick – Named Cambrian • Murchison – Named Silurian
  • 28. Stratigraphy • Study of stratified rocks, especially their geometric relations, compositions, origins, and age relations • Stratigraphic units – Strata • Distinguished by some physical, chemical, or paleontological property • Units of time based on ages of strata – Geologic Systems • Correlation – Demonstrate correspondence between geographically separated parts of a stratigraphic unit • Lithologic • Temporal
  • 29. Units of Time • Time-rock unit – Chronostratigraphic unit – All the strata in the world deposited during a particular interval of time • Erathem, System, Series, Stage • Time unit – Geochronologic unit – Interval during which a time-rock unit is formed • Eras, Period, Epoch, Age • Boundary stratotype – Boundary between two systems, series or stages, formally defined at a single locality
  • 30. Geologic Time Scale • Chronologic units - Time/Age – Eons (largest): – Era – Periods – Epochs – Ages
  • 31. Geologic Time Scale • Geochronologic Units = Place – Eon (largest) = Eon – Era = Era – System = Period – Series = Epoch – Stage = Age
  • 32. Biostratigraphy • Biostratigraphic unit – Defined and characterized by their fossil content • Stratigraphic range – Total vertical interval through which that species occurs in strata, from lowermost to uppermost occurrence
  • 33. Biostratigraphy • Index fossil – Abundant enough in the stratigraphic record to be found easily – Easily distinguished from other taxa – Geographically widespread and thus can be used to correlate rocks over a large area – Occurs in many kinds of sedimentary rocks and therefore can be found in many places – Has a narrow stratigraphic range, which allows for precise correlation if its mere presence is used to define a zone
  • 34. Magnetic Stratigraphy • Use of magnetic properties of a rock to characterize and correlate rock units • Magnetic field – Reversals in polarity of field are recorded in rocks when they crystallize or settle from water
  • 35. Magnetic Stratigraphy • Chron – Polarity time-rock unit – Period of normal or reversed polarity • Normal interval – Same as today – Black • Reversed interval – Opposite to today – White
  • 36. Lithostratigraphy • Subdivision of the stratigraphic record on the basis of physical or chemical characteristics of rock • Lithostratigraphic units – Formation • Local three-dimensional bodies of rock – Group – Member • Stratigraphic section – Local outcrop of a formation that displays a continuous vertical sequence • Type section – Locality where the unit is well exposed, that defines the unit
  • 37. Lithologic Correlation • Cross-sections of strata – Establish geometric relationships – Interpret mode of origin
  • 38. Lithologic Correlation • Grand Canyon – McKee – Used Trilobite biostratigraphy to determine age relationships – Eastern portion of units is younger than western
  • 39. Facies • Transgression – Landward migration of shoreline – Grand Canyon • Cambrian transgression • Facies – Set of characteristics of a body of rock that presents a particular environment • Facies changes – Later changes in the characteristics of ancient strata
  • 40. Absolute Age • 4.6 billion years old • Early estimates – Salts in the ocean • 90 million years old – Accumulation of sediment • 100 m.y. or less • Gaps in stratigraphic record • Unconformities represent large breaks in accumulation • Didn’t include metamorphosed sedimentary rocks – Earth’s temperature • Kelvin • 20-40 million years old
  • 41. Absolute Ages • How old is the Earth? • 4.6 billion years (4,600,000,000 years) • Radiometric dating (Uranium, Thorium). Mass spectrometer.
  • 42. Early Attempts • 1654 Archbishop Usher (Ireland), genealogy in Bible Earth was created October 22, 4004 BC, • 9:00 am was added later • Earth was 6000 years old. • Led to the Doctrine of Catastrophism: • Earth was shaped by series of giant disasters. • Many processes fit into a short time scale.
  • 43. Early Attempts • 1770's, 1780's "Revolution" • James Hutton, Father of Geology (Scotland) 1726-1797. • Published Theory of the Earth in 1785.
  • 44. Hutton • Hadrian's Wall built by Romans, after 1500 years no change. Suspected that Earth was much older. • Slow processes shape earth. • Mountains arise continuously as a balance against erosion and weathering
  • 45. Hutton • Doctrine of Uniformitarianism: "Present is key to the past". • The physical and chemical laws that govern nature are uniform • • Unconformity at Siccar Point, Scotland • "No vestige of a beginning, no prospect of an end"
  • 46. Charles Lyell • Charles Lyell 1800's compared amount of evolution shown by marine mollusks in the various series of the Tertiary System with the amount that had occurred since the beginning of the Pleistocene. • Estimated 80 million years for the Cenozoic alone.
  • 47. Various Geologists • Thickness of total sedimentary record divided by average sedimentation rates (in mm/yr). • In 1860, calculated to be about 3 million years old. • In 1910, calculated to be about 1.6 billion years old.
  • 48. Lord Kelvin • In 1897, Lord Kelvin assumed that the Earth was originally molten and calculated a date based on cooling through conduction and radiation. • Age of Earth was calculated to be about 24-40 million years.
  • 49. Lord Kelvin • Problem: Earth has an internal heat source (radioactive decay) • Discovery of radioactivity by Henri Becquerel in 1896.
  • 50. John Joly • In 1899 - 1901, John Joly (Irish) calculated the rate of delivery of salt to the ocean. River water has only a small concentration of salts. Rivers flow to the sea. • Evaporative concentration of salts. • Age of Ocean = Total salt in oceans (in grams) divided by rate of salt added (grams per year) • Age of Earth = 90-100 million years.
  • 51. John Joly • Problems: no way to account for recycled salt, salt incorporated into clay minerals, salt deposits.
  • 52. von Helmholtz and Newcomb The German physicist Hermann von Helmholtz and the American astronomer Simon Newcomb joined in by independently calculating the amount of time it would take for the Sun to condense down to its current diameter and brightness from the nebula of gas and dust from which it was born. 100 million years, consistent with Thomson's calculations. However, they assumed that the Sun was only glowing from the heat of its gravitational contraction. They knew of no other ways for it to produce its energy.
  • 53. Rutherford and Boltwood • In 1905, they used radioactive decay to measure the age of rocks and minerals. • Uranium decay produces He, leading to a date of 500 million years.
  • 54. Rutherford and Boltwood In 1907, Boltwood suspected that lead was the stable end product of the decay of uranium. Published the age of a sample of urananite based on Uranium-Lead dating. Date was 1.64 billion years.
  • 55. Age of Earth • So far, oldest dated Earth rocks are 3.96 billion years. • Canadian Shield. (NW Territories near Great Slave Lake, 3.96 byr). • Detrital Zircons in sedimentary rocks are 4.1 - 4.4 byr • Older rocks include meteorites and moon rocks with dates on the order of 4.6 billion years.
  • 56. Geologic Time Scale. The age for the base of each division is in accordance with recommendations of the International Commission on Stratigraphy for the year 2000.
  • 58. The standard geologic time scale for the Paleozoic and other eras developed without benefit of a grand plan. Instead, it developed by the compilation of “type sections” for each of the systems.
  • 61. Silurian - Murchison
  • 62. Jurassic - Jura Mountains
  • 63. • Cretaceous • Kreta = Chalk • White Cliffs of Dover
  • 64. Absolute Age • Radioactive decay – Becquerel, 1895 • Uranium undergoes spontaneous decay • Atoms release subatomic particles and energy • Change to another element – Parent isotope decays/daughter isotope produced
  • 65. Principles of Radiometric Dating • Naturally-occurring radioactive materials break down into other materials at known rates. This is known as radioactive decay. • Radioactive parent elements decay to stable daughter elements.
  • 66. What is an Isotope? • Nuclide of an element with different masses
  • 67. Absolute Age • Three modes of decay – Loss of alpha particle • Convert parent into element that has nucleus containing two fewer protons – Loss of beta particle • Convert parent into element whose nucleus contains one more proton by losing an electron – Capture of beta particle • Convert parent into element whose nucleus has one less proton
  • 68. Absolute Age • Radiometric dating – Radioactive isotopes decay at constant geometric rate • After a certain amount of time, half of the parent present will survive and half will decay to daughter • Half-life – Interval of time for half of parent to decay
  • 69. Absolute Age • Useful isotopes – Uranium 238 and thorium 232 • Zircon grains – Uranium 238 and lead 206 • Fission track dating – Rubidium-Strontium – Potassium-Argon, Argon-Argon – Radiocarbon dating • Produced in upper atmosphere • Half life = 5730 years • Maximum age for dating: 70,000 years • Bone, teeth, wood
  • 70. Absolute Age • Fission-Track Dating – Measure decay of uranium 238 by counting number of tracks – Tracks formed by subatomic particles that fly apart upon decay
  • 71. Radioactive parent isotopes and their stable daughter products Each radioactive isotope has its own unique half-life. A half-life is the time it takes for half of the parent radioactive element to decay to a daughter product.
  • 72. Radioactive parent isotopes and their stable daughter products Radioactive Parent Stable Daughter Half Life Potassium 40 Argon 40 1.25 billion yrs Rubidium 87 Strontium 87 48.8 billion yrs Thorium 232 Lead 208 14 billion years Uranium 235 Lead 207 704 million years Uranium 238 Lead 206 4.47 billion years Carbon 14 Nitrogen 14 5730 years
  • 74. Radioactive Decay • Radioactive decay occurs by releasing particles and energy. • Alpha particles • Beta particles • Neutrons • Gamma rays (high energy X-rays) are also produced.
  • 75. Radioactive Decay • Alpha particles (He) • large, easily stopped by paper • charge = +2 • mass = 4
  • 76. Radioactive Decay • Beta particles • penetrate hundreds of times farther than alpha particles, but easily stopped compared with neutrons and gamma rays. • charge = -1 • mass = negligible
  • 77. Radioactive decay series of uranium- 238 (238U) to lead- 206 (206Pb).
  • 78. Datable Minerals • Most minerals which contain radioactive isotopes are in igneous rocks. The dates they give indicate the time the magma cooled. • Potassium 40 is found in: • potassium feldspar (orthoclase) • muscovite • amphibole • glauconite (greensand; found in some sedimentary rocks; rare) •
  • 79. Datable Rocks • Radioactive elements tend to become concentrated in the residual melt that forms during the crystallization of igneous rocks. More common in SIALIC rocks (granite, granite pegmatite) and continental crust.
  • 80. Datable Rocks • Radioactive isotopes don't tell much about the age of sedimentary rocks (or fossils). The radioactive minerals in sedimentary rocks are derived from the weathering of igneous rocks. If the sedimentary rock were dated, the age date would be the time of cooling of the magma that formed the igneous rock. The date would not tell anything about when the sedimentary rock formed.
  • 82. 14 How does Carbon dating work? • Cosmic rays from the sun strike Nitrogen 14 atoms in the atmosphere and cause them to turn into radioactive 14C, which combines with oxygen to form radioactive CO2.
  • 83. 14 How does Carbon dating work? • Living things are in equilibrium with the atmosphere, and the radioactive CO2 is absorbed and used by plants. The radioactive CO2 gets into the food chain and the carbon cycle.
  • 84. 14 How does Carbon dating work? • All living things contain a constant ratio of 14C to 12C (1 in a trillion). • At death, 14C exchange ceases and any 14C in the tissues of the organism begins to decay to Nitrogen 14, and is not replenished by new 14C.
  • 85. 14 How does Carbon dating work? • The change in the 14C to 12C ratio is the basis for dating. • The half-life is so short (5730 years) that this method can only be used on materials less than 50,000 years old. • Assumes that the rate of 14C production (and hence the amount of cosmic rays striking the Earth) has been constant.
  • 86. Deviation of carbon-14 ages to true ages from the present back to about 5000 B.C. Data are obtained from analysis of bristle cone pines from the western United States. Calculations of carbon- 14 are based on half-life of 5730 years. (Adapted from Ralph, E. K., Michael, H. N., and Han, M. C. 1973. Radiocarbon dates and reality. MASCA Newsletter 9:1.)
  • 87. Absolute Age • Best candidates for most radiometric dating are igneous – Not necessarily useful for sediments • Error in age estimate can be sizable
  • 88. Absolute Age • Absolute ages change – Error increases in older rocks – Techniques change • Biostratigraphic correlations are usually more accurate – Radiometric dates used when fossils not present
  • 89. How old is the Old Red Sandstone? a. Older than 425 myr b. Younger than 370 myr c. Between 425 and 370 myr d. Have no idea