This chapter discusses various theories of capital structure and how it relates to the value of the firm and cost of capital. It outlines the Modigliani-Miller view that capital structure does not affect firm value versus the traditional view that moderate debt can lower costs. It also discusses how interest tax shields, bankruptcy costs, and agency costs factor into the optimal capital structure based on a trade-off theory. The chapter further examines pecking order theory and approaches for establishing an appropriate capital structure including cash flow analysis.