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STRENGTHENING
STRUCTURES USING FRP
COMPOSITE MATERIALS
DAMIAN I. KACHLAKEV, Ph.D., P.E.
California Polytechnic State University
San Luis Obispo
WHY COMPOSITES?
• ADVANTAGES OVER TRADITIONAL
MATERIALS
• CORROSION RESISTANCE
• HIGH STRENGTH TO WEIGHT RATIO
• LOW MAINTENANCE
• EXTENDED SERVICE LIFE
• DESIGN FLEXIBILITY
COMPOSITES DEFINITION
• A combination of two or more materials (reinforcement,
resin, filler, etc.), differing in form or composition on a
macroscale. The constituents retain their identities, i.e..,
they do not dissolve or merge into each other, although
they act in concert. Normally, the components can be
physically identified and exhibit an interface between
each other.
DEFINITION
Fiber Reinforced Polymer (FRP) Composites
are defined as:
“A matrix of polymeric material that is
reinforced by fibers or other reinforcing
material”
COMPOSITES MARKETS
• TRANSPORTATION
• CONSTRUCTION
• MARINE
• CORROSION-RESISTANT
• CONSUMER
• ELECTRICAL/ELECTRONIC
• APPLIANCES/BUSINESS
• AIRCRAFT/DEFENSE
U.S. COMPOSITES SHIPMENTS - 1996 MARKET SHARE
SEMI-ANNUAL STATISTICAL REPORT - AUGUST 26, 1996
Includes reinforced thermoset and thermoplastic
resin composites, reinforcements and
fillers.
Includes reinforced thermoset and thermoplastic
resin composites, reinforcements and
fillers.
SOURCE: SPI Composites Institute
SOURCE: SPI Composites Institute
Transportation
30.6%
Other- 3.4%
Aircraft/Aerospace
0.7%
Appliance/Business
Equipment - 5.3%
Construction
20%
Consumer
Products - 6%
Marine - 11.6%
Electrical/
Electronic - 10%
Corrosion-Resistant
Equipment - 12.4%
Infrastructure Benefits
• HIGH STRENGTH/WEIGHT RATIO
• ORIENTATED STRENGTH
• DESIGN FLEXIBILITY
• LIGHTWEIGHT
• CORROSION RESISTANCE
• LOW MAINTENANCE/LONG-TERM DURABILITY
• LARGE PART SIZE POSSIBLE
• TAILORED AESTHETIC APPEARANCE
• DIMENSIONAL STABILITY
• LOW THERMAL CONDUCTIVITY
• LOW INSTALLED COSTS
FRP COMPOSITE
CONSTITUENTS
• RESINS (POLYMERS)
• REINFORCEMENTS
• FILLERS
• ADDITIVES
MATERIALS: RESINS
• PRIMARY FUNCTION:
“TO TRANSFER STRESS BETWEEN REINFORCING
FIBERS AND TO PROTECT THEM FROM
MECHANICAL AND ENVIRONMENTAL DAMAGE”
• TYPES:
– THERMOSET
– THERMOPLASTIC
RESINS
• THERMOSET
– POLYESTER
– VINYL ESTER
– EPOXY
– PHENOLIC
– POLYURETHANE
RESINS
• THERMOPLASTIC
– ACETAL
– ACRYRONITRILE BUTADIENE STYRENE
(ABS)
– NYLON
– POLYETHYLENE (PE)
– POLYPROPYLENE (PP)
– POLYETHYLENE TEREPHTHALATE (PET)
RESINS
• THERMOSET ADVANTAGES
– THERMAL STABILITY
– CHEMICAL RESISTANCE
– REDUCED CREEP AND STRESS RELAXATION
– LOW VISCOSITY- EXCELLENT FOR FIBER
ORIENTATION
– COMMON MATERIAL WITH FABRICATORS
RESINS
• THERMOPLASTIC ADVANTAGES
– ROOM TEMPERATURE MATERIAL STORAGE
– RAPID, LOW COST FORMING
– REFORMABLE
– FORMING PRESSURES AND TEMPERATURES
POLYESTERS
• LOW COST
• EXTREME PROCESSING VERSATILITY
• LONG HISTORY OF PERFORMANCE
• MAJOR USES:
–Transportation
– Construction
– Marine
VINYL ESTER
• SIMILAR TO POLYESTER
• EXCELLENT MECHANICAL & FATIGUE
PROPERTIES
• EXCELLENT CHEMICAL RESISTANCE
• MAJOR USES:
–Corrosion Applications - Pipes, Tanks, &
Ducts
EPOXY
• EXCELLENT MECHANICAL PROPERTIES
• GOOD FATIGUE RESISTANCE
• LOW SHRINKAGE
• GOOD HEAT AND CHEMICAL RESISTANCE
• MAJOR USES:
–FRP Strengthening Systems
–FRP Rebars
–FRP Stay-in-Place Forms
PHENOLICS
• EXCELLENT FIRE RETARDANCE
• LOW SMOKE & TOXICITY EMISSIONS
• HIGH STRENGTH AT HIGH TEMPERATURES
• MAJOR USES:
–Mass Transit - Fire Resistance & High
Temperature
–Ducting
POLYURETHANE
• TOUGH
• GOOD IMPACT RESISTANCE
• GOOD SURFACE QUALITY
• MAJOR USES:
–Bumper Beams, Automotive Panels
SUMMARY: POLYMERS
• WIDE VARIETY AVAILABLE
• SELECTION BASED ON:
– PHYSICAL AND MECHANICAL PROPERTIES
OF PRODUCT
– FABRICATION PROCESS REQUIREMENTS
Physical Properties of Thermosetting
Resins Used in Structural
Composites
Resin
Type
Density
(kg/m3
)
Tensile
Str.
(MPa)
Elong.
(%)
E-
Mod.
(GPa)
Long.
Term
t ,(C)
Polyester 1.2 50-65 2-3 3 120
Vinyl
Ester
1.15 70-80 4-6 3.5 140
Epoxy 1.1-1.4 50-90 2-8 3 120-
200
Phenolic 1.2 40-50 1-2 3 120-
150
MATERIAL: FIBER
REINFORCEMENTS
• PRIMARY FUNCTION:
“CARRY LOAD ALONG THE LENGTH OF THE
FIBER, PROVIDES STRENGTH AND OR STIFFNESS
IN ONE DIRECTION”
• CAN BE ORIENTED TO PROVIDE PROPERTIES IN
DIRECTIONS OF PRIMARY LOADS
REINFORCEMENTS
• NATURAL
• MAN-MADE
• MANY VARIETIES COMMERCIALLY
AVAILABLE
MAN-MADE FIBERS
• ARAMID
• BORON
• CARBON/GRAPHITE
• GLASS
• NYLON
• POLYESTER
• POLYETHYLENE
• POLYPROPYLENE
FIBER PROPERTIES
DENSITY (g/cm3
)
1.38
1.59
1.99
1.99
2.76
8
0 2 4 6 8 10
Aramid
Carbon
S-Glass
E-Glass
Alum
Steel
FIBER PROPERTIES
TENSILE STRENGTH
x103
psi
500
525
530
625
20
60
0 200 400 600 800
E-Glass
Aramid
Carbon
S-Glass
Steel
Alum
FIBER PROPERTIES
STRAIN TO FAILURE
(%)
1.4
2.8
4.8
5
0.2
0.16
0 1 2 3 4 5 6
Carbon
Aramid
E-Glass
S-Glass
Steel
Alum
FIBER PROPERTIES
TENSILE MODULUS
106
psi
10.5
12.6
19
33.5
29
10
0 10 20 30 40
E-Glass
S-Glass
Aramid
Carbon
Steel
Alum
FIBER PROPERTIES
CTE - Longitudinal
x10-6
/0
C
-2
0.5
2.9
5
6.5
12.6
-2
0
2
4
6
8
10
12
14
Aramid Carbon S-Glass E-Glass Steel Alum
FIBER PROPERTIES
THERMAL CONDUCTIVITY
x10-6
/0
C
BTU-in/hr-ft2
- 0
F
1.5
115
1500
7.5
0
200
400
600
800
1000
1200
1400
1600
FRP Steel Alum Concrete
FIBER REINFORCEMENT
• GLASS (E-GLASS)
– MOST COMMON FIBER USED
– HIGH STRENGTH
– GOOD WATER RESISTANCE
– GOOD ELECTRIC INSULATING PROPERTIES
– LOW STIFFNESS
GLASS TYPES
• E-GLASS
• S-GLASS
• C-GLASS
• ECR-GLASS
• AR-GLASS
FIBER REINFORCEMENT
• ARAMID (KEVLAR)
– SUPERIOR RESISTANCE TO DAMAGE
(ENERGY ABSORBER)
– GOOD IN TENSION APPLICATIONS (CABLES,
TENDONS)
– MODERATE STIFFNESS
– MORE EXPENSIVE THAN GLASS
FIBER REINFORCEMENT
• CARBON
– GOOD MODULUS AT HIGH TEMPERATURES
– EXCELLENT STIFFNESS
– MORE EXPENSIVE THAN GLASS
– BRITTLE
– LOW ELECTRIC INSULATING PROPERTIES
TYPICAL PROPERTIES OF
STRUCTURAL FIBERS
Fiber
Type
Density
(kg/m3
)
E-
Modulus
(GPa)
Tensile
Strength
(GPa)
Elong.
(%)
E-Glass 2.54 72.5 1.72-3.45 2.5
S-Glass 2.49 87 2.53-4.48 2.9
Kevlar 29 1.45 85 2.27-3.80 2.8
Kevlar 49 1.45 117 2.27-3.80 1.8
Carbon
(HS)
1.80 227 2.80-5.10 1.1
Carbon
(HM)
1.80-1.86 370 1.80 0.5
Carbon
(UHM)
1.86-2.10 350-520 1.00-1.75 0.2
ADVANTAGES AND
DISADVANTAGES OF
REINFORCING FIBERS
Fiber Type Advantages Disadvantages
E-Glass, S-Glass High Strength,
Low Cost
Low Stiffness,
Fatigue
Aramid High Strength,
Low Density
Low Compr.
Str., High
Moisture
Absorption
HS Carbon High Strength
and Stiffness
High Cost
UHM Carbon Very High
Stiffness
Low Strength,
High Cost
FIBER ORIENTATION
• ANISOTROPIC
• UNIDIRECTIONAL
• BIAS - TAILORED DIRECTION
– 0O
- flexural strengthening
– 90O
- column wraps
– + /- 45O
- shear strengthening
• ANGLE VARIES BY APPLICATION
DEGREE OF ANISOTROPY OF
FRP COMPOSITES
FRP Composite E1/E2 E1/G12 F1/F2t
Steel 1.00 2.58 1.00
Vinyl Ester 1.00 0.94 1.00
S-Glass/Epoxy 2.44 5.06 28
E-Glass/Epoxy 4.42 8.76 17.7
Carbon/Epoxy 13.64 19.1 41.4
UHM/Epoxy 40 70 90
Kevlar/Epoxy 15.3 27.8 260
PROPERTIES OF
UNIDIRECTIONAL
COMPOSITES
Property E-Glass/
Epoxy
S-Glass/
Epoxy
Aramid/
Epoxy
Carbon/
Epoxy
Fiber Volume 0.55 0.50 0.60 0.63
Longitudinal Modulus GPa 39 43 87 142
Transverse .Modulus,
GPa
8.6 8.9 5.5 10.3
Shear Modulus,
GPa
3.8 4.5 2.2 7.2
Poisson’s
Ratio
0.28 0.27 0.34 0.27
Long.Tensile Strength
MPa
1080 1280 1280 2280
Compressive Strength,
MPa
620 690 335 1440
ELASTIC AND SHEAR MODULI
OF FRP COMPOSITES
Material E1 E2 G12 G13 G23
Aluminum 10.40 10.40 3.38 3.38 3.38
Steel 29 29 11.24 11.24 11.24
Carbon/Epoxy 20 1.30 1.03 1.03 0.90
Glass/Epoxy 7.80 2.60 1.25 1.25 0.50
REINFORCEMENTS
SUMMARY
• TAILORING MECHANICAL PROPERTIES
– TYPE OF FIBER
– PERCENTAGE OF FIBER
– ORIENTATION OF FIBER
COMPARISON OF AXIAL AND
FLEXURAL EFFICIENCY OF FRP
SYSTEMS
AXIAL
EFFICIENCY
FLEXURAL
EFFICIENCY
Material E/ρ Rank E1/2
/ρ Rank
Carbon/Epoxy 113.1 1 8.4 1
Kevlar/Epoxy 52.1 2 6.0 2
E-Glass/Epoxy 21.4 4 3.5 3
Mild Steel 25.6 3 1.8 4
DESIGN VARIABLES
FOR COMPOSITES
• TYPE OF FIBER
• PERCENTAGE OF FIBER or FIBER VOLUME
• ORIENTATION OF FIBER
– 0o
, 90o
, +45o
, -45o
• TYPE OF POLYMER (RESIN)
• COST
• VOLUME OF PRODUCT - MANUFACTURING
METHOD
DESIGN VARIABLES
FOR COMPOSITES
• PHYSICAL:
– tensile strength
– compression strength
– stiffness
– weight, etc.
• ENVIRONMENTAL:
– Fire
– UV
– Corrosion Resistance
TAILORING COMPOSITE
PROPERTIES
• MAJOR FEATURE
• PLACE MATERIALS WHERE NEEDED -
ORIENTED STRENGTH
– LONGITUDINAL
– TRANSVERSE
– or between
• STRENGTH
• STIFFNESS
• FIRE RETARDANCY
STRUCTURAL DESIGN
APPROACH FOR COMPOSITES
S t r u c t u r a l D e s ig n W it h F R P C o m p o s it e s
M a t r ix , F ib e r s
M ic r o m e c h a n ic s
L a m in a , L a m in a t e
M a c r o m e c h a n ic s
S t r u c t u r a l A n a ly s is
S t r e n g t h e n in g D e s ig n
S T R U C T U R E
F R P R e p a ir
SPECIFIC MODULUS AND STRENGTH
OF FRP COMPOSITE
FLOW CHART FOR DESIGN OF
FRP COMPOSITES
[ E ] x , y
T r a n s fo r m e d E n g . C o n s t a n t s
[ Q ] x , y
T r a n s fo r m e d M a t h . C o n s t a n t s
[ Q ] 1 , 2
M a t h e m a t ic a l C o n s t a n t s
[ F ib e r O r ie n t a t io n ]
[ E ] x , y
T r a n s fo r m e d E n g . C o n s t a n t s
[ S ] x , y
T r a n s fo r m e d M a t h . C o n s t a n t s
[ S ] 1 , 2
M a t h e m a t ic a l C o n s t a n t s
[ E ] 1 , 2
E n g in e e r in g C o n s t a n t s
MANUFACTURING
PROCESSES
• Hand Lay-up/Spray-up
• Resin Transfer Molding (RTM)
• Compression Molding
• Injection Molding
• Reinforced Reaction Injection Molding (RRIM)
• Pultrusion
• Filament Winding
• Vacuum Assisted RTM (Va-RTM)
• Centrifugal Casting
PROCESS CHARACTERISTICS
Hand Lay-up/Spray-up
• MAX SIZE: Unlimited
• PART GEOMETRY: Simple - Complex
• PRODUCTION VOLUME: Low - Med
• CYCLE TIME: Slow
• SURFACE FINISH: Good - Excellent
• TOOLING COST: Low
• EQUIPMENT COST: Low
PRODUCT CHARACTERISTICS
Pultrusion
• CONSTANT CROSS SECTION
• CONTINUOUS LENGTH
• HIGH ORIENTED STRENGTHS
• COMPLEX PROFILES POSSIBLE
• HYBRID REINFORCEMENTS
MATERIAL PROPERTIES
• PROPERTIES OF FRP COMPOSITES VARY
DEPENDING ON:
– TYPE OF FIBER & RESIN SELECTED
– FIBER CONTENT
– FIBER ORIENTATION
– MANUFACTURING PROCESS
REPAIR
• HYBRIDS (SUPER COMPOSITES): TRADITIONAL
MATERIALS ARE JOINED WITH FRP
COMPOSITES
– WOOD
– STEEL
– CONCRETE
– ALUMINUM
BENEFITS - SUMMARY
• LIGHT WEIGHT
• HIGH STRENGTH to WEIGHT RATIO
• COMPLEX PART GEOMETRY
• COMPOUND SURFACE SHAPE
• PARTS CONSOLIDATION
• DESIGN FLEXIBILITY
• LOW SPECIFIC GRAVITY
• LOW THERMAL CONDUCTIVITY
• HIGH DIELECTRIC STRENGTH
LIFE CYCLE ECONOMICS
• PLANNING/DESIGN/DEVELOPMENT
COST
• PURCHASE COST
• INSTALLATION COST
• MAINTENANCE COST
• LOSS/WEAR COST
• LIABILITY/INSURANCE COSTS
• DOWNTIME/LOST BUSINESS COST
• REPLACEMENT/DISPOSAL/RECYCLING
COST
LIFE CYCLE ECONOMICS
(Examples)
• IBACH BRIDGE (SWITZERLAND)
– CFRP LAMINATES- 50 TIMES MORE
EXPENSIVE THAN STEEL PER KILOGRAM
– CFRP LAMINATES- 9 TIMES MORE
EXPENSIVE THAN STEEL BY VOLUME
– REPAIR WORK REQUIREMENTS-175 KG
STEEL OR 6.2 KG CFRP
– MATERIAL COST-20 % OF THE TOTAL
PROJECT COST
LIFE CYCLE ECONOMICS
(Examples)
• HORSETAIL CREEK BRIDGE (OREGON)
– CONVENTIONAL REPAIR (SHEAR ONLY-ONE
BEAM)-$69,000
– FRP REPAIR (GFRP SHEAR ONLY-ONE BEAM)-
$1850
– FRP REPAIR [SHEAR (GFRP)+ FLEXURE(CFRP),
ONE BEAM]- $9850
CONCLUSIONS
• ECONOMICS ARE MORE THAN THE BASIC
ELEMENTS OF MATERIALS, LABOR,
EQUIPMENT, OVERHEAD, ETC.
• ENTIRE LIFE CYCLE ECONOMICS MUST BE
CONSIDERED AND COMPARED TO THAT OF
TRADITIONAL MATERIALS TO DETERMINE THE
BENEFITS OF COMPOSITES IN A GIVEN
APPLICATION
STRUCTURAL DESIGN WITH
FRP COMPOSITES
EXTERNAL REINFORCEMENT OF
RC BEAMS USING FRP
• BACKGROUND
• DESIGN MODELS
– LACK OF DUCTILITY
– FLEXURAL STRENGTHENING
– SHEAR STRENGTHENING
– PRESTRESSED FRP APPLICATION
• DESIGN METHODOLOGY AND
ANALYSIS
• OTHER ISSUES
– FATIGUE, CREEP, LOW TEMPERATURE FRP
PERFORMANCE
• DESIGN EXAMPLES
FRP STRENGTHENED BEAMS
BACKGROUND
• FRP VS. EXTERNALLY STEEL BONDED
PLATES
– CORROSION AT THE EPOXY-STEEL INTERFACE
– STEEL PLATES DO NOT INCREASE STRENGTH,
JUST STIFFNESS
– HIGH TEMPERATURES PERFORMANCE
DIFFICULTIES DUE TO HEAVY WEIGHT OF THE
STEEL PLATES
– STRENGTHENING DESIGN BASED ON MATERIAL
WEIGHT, NOT STRUCTURAL NEEDS
– CONSTRUCTION DIFFICULTIES
– TIME CONSUMING, HEAVY EQUIPMENT NEEDED
FRP STRENGTHENED BEAMS
LACK OF DUCTILITY
• LINEAR STRESS-STRAIN PROFILE
• DEFINITION OF DUCTILITY
– DEFLECTION AT ULTIMATE/DEFLECTION AT
YIELD- NOT APPLICABLE FOR FRP MATERIAL
– STRAIN-ENERGY ABSORPTION, I.E., AREA UNDER
LOAD-DEFLECTION CURVE- OK FOR FRP
COMPOSITES
– IN GENERAL- THE HIGHER THE FRP FRACTION
AREA, THE LOWER THE ENERGY ABSORPTION OF
THE STRENGTHENED CONCRETE BEAM
FRP STRENGTHENED BEAMS
TYPICAL LOAD-DEFLECTION
CURVE
FRP REINFORCED BEAMS-
FAILURE MODES
FRP REINFORCEMENT OF RC
COLUMNS
• Advantages of Strengthening Columns with
FRP Jackets
– Increased Ductility
– Increased Strength
– Low Dead Weight
– Reduced Construction Time
– Low Maintenance
FRP REINFORCEMENT OF RC
COLUMNS
• Factors Influencing the Behavior of FRP-
Retrofitted Columns
– Column composition
– Column geometry
– Current condition
– Type of loading
– Environmental conditions
DESIGN OF FRP RETROFIT OF
RC COLUMNS
• Shear Strengthening
• Flexural Hinge Confinement
• Lap Splice Clamping
LOAD-DISPLACEMENT CURVE
(Before Strengthening)
LOAD-DISPLACEMENT CURVE
(After Strengthening)
COLUMN DUCTILITY
FRP REINFORCEMENT OF RC
COLUMNS
• Advantages of Strengthening Columns with
FRP Jackets
– Increased Ductility
– Increased Strength
– Low Dead Weight
– Reduced Construction Time
– Low Maintenance
FRP REINFORCEMENT OF RC
COLUMNS
• Factors Influencing the Behavior of FRP-
Retrofitted Columns
– Column composition
– Column geometry
– Current condition
– Type of loading
– Environmental conditions
LOAD-DISPLACEMENT
CURVE
(Before Strengthening)
LOAD-DISPLACEMENT CURVE
(After Strengthening)
COLUMN DUCTILITY
CONSTRUCTION PROCESS
• Preparation of the Concrete Surface
• Mixing Epoxy, Putty, etc.
• Preparation of the FRP Composite System
• Application of the FRP Strengthening System
• Anchorage (if recommended)
• Curing the FRP Material
• Application of Finish System
CONCRETE SURFACE
PREPARATION
• Repair of the existing concrete in accordance to:
– ACI 546R-96 “Concrete Repair Guide”
– ICRI Guideline No. 03370 “Guide for Surface
Preparation for the Repair of Deteriorated
Concrete...”
• Bond Between Concrete and FRP Materials
– Should satisfy ICRI “Guide for Selecting and
Specifying Materials for Repair of Concrete
Surfaces”
CONCRETE SURFACE
PREPARATION
• Repair Cracks 0.010 inches or Wider
– Epoxy pressure injected
– To satisfy Section 3.2 of the ACI 224.1R-93
“Causes, Evaluation and Repair of Cracks…”
• Concrete Surface Unevenness to be Less than 1
mm
• Concrete Corners- Minimum Radius of 30 mm
APPLICATION OF THE FRP
COMPOSITE
• In Accordance to Manufacturer’s and Designer's
Specifications
– Priming
– Putty Application
– Under-coating with Epoxy Resin
– Application of the FRP Laminate/ FRP Fiber Sheet
– Over-coating with Epoxy Resin
CURING OF THE FRP
COMPOSITES
• In Accordance to Manufacturer’s Specifications
– Temperature ranges and Curing Time- varies from
few hours to 15 days for different FRP systems
• Cured FRP Composite
– Uniform thickness and density
– Lack of porosity
CONSTRUCTION PROCESS
• Typical RC Beam in
Need for Repair
– corroded steel
– spalling concrete
CONSTRUCTION PROCESS
• Deteriorated Column /
Beam Connection
CONSTRUCTION PROCESS
• Concrete Surface
Preparation
– Smooth, free of dust and
foreign objects, oil, etc.
– Application of primer
and putty (if required by
the manufacturer)
CONSTRUCTION PROCESS
• Preparation of the FRP
Composites for
Application
– Follow
manufacturer’s
recommendations
CONSTRUCTION PROCESS
• Priming of the Concrete
Surface
• Application of the
Undercoating epoxy
Layer (adhesive when
FRP pultruded laminates
are used)
CONSTRUCTION PROCESS
• Application of CFRP
Fiber Sheet on a Beam-
Wet Lay-Up Process
• Similar for Application
of Pultruded Laminates
CONSTRUCTION PROCESS
• Column Wrapping with
Automated FRP
Application device
CONSTRUCTION PROCESS
• Robo Wrapper by Xxsys
Technologies
CONSTRUCTION PROCESS
• Column Wrapping
Device

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Frp materials

  • 1. STRENGTHENING STRUCTURES USING FRP COMPOSITE MATERIALS DAMIAN I. KACHLAKEV, Ph.D., P.E. California Polytechnic State University San Luis Obispo
  • 2. WHY COMPOSITES? • ADVANTAGES OVER TRADITIONAL MATERIALS • CORROSION RESISTANCE • HIGH STRENGTH TO WEIGHT RATIO • LOW MAINTENANCE • EXTENDED SERVICE LIFE • DESIGN FLEXIBILITY
  • 3. COMPOSITES DEFINITION • A combination of two or more materials (reinforcement, resin, filler, etc.), differing in form or composition on a macroscale. The constituents retain their identities, i.e.., they do not dissolve or merge into each other, although they act in concert. Normally, the components can be physically identified and exhibit an interface between each other.
  • 4. DEFINITION Fiber Reinforced Polymer (FRP) Composites are defined as: “A matrix of polymeric material that is reinforced by fibers or other reinforcing material”
  • 5. COMPOSITES MARKETS • TRANSPORTATION • CONSTRUCTION • MARINE • CORROSION-RESISTANT • CONSUMER • ELECTRICAL/ELECTRONIC • APPLIANCES/BUSINESS • AIRCRAFT/DEFENSE
  • 6. U.S. COMPOSITES SHIPMENTS - 1996 MARKET SHARE SEMI-ANNUAL STATISTICAL REPORT - AUGUST 26, 1996 Includes reinforced thermoset and thermoplastic resin composites, reinforcements and fillers. Includes reinforced thermoset and thermoplastic resin composites, reinforcements and fillers. SOURCE: SPI Composites Institute SOURCE: SPI Composites Institute Transportation 30.6% Other- 3.4% Aircraft/Aerospace 0.7% Appliance/Business Equipment - 5.3% Construction 20% Consumer Products - 6% Marine - 11.6% Electrical/ Electronic - 10% Corrosion-Resistant Equipment - 12.4%
  • 7. Infrastructure Benefits • HIGH STRENGTH/WEIGHT RATIO • ORIENTATED STRENGTH • DESIGN FLEXIBILITY • LIGHTWEIGHT • CORROSION RESISTANCE • LOW MAINTENANCE/LONG-TERM DURABILITY • LARGE PART SIZE POSSIBLE • TAILORED AESTHETIC APPEARANCE • DIMENSIONAL STABILITY • LOW THERMAL CONDUCTIVITY • LOW INSTALLED COSTS
  • 8. FRP COMPOSITE CONSTITUENTS • RESINS (POLYMERS) • REINFORCEMENTS • FILLERS • ADDITIVES
  • 9. MATERIALS: RESINS • PRIMARY FUNCTION: “TO TRANSFER STRESS BETWEEN REINFORCING FIBERS AND TO PROTECT THEM FROM MECHANICAL AND ENVIRONMENTAL DAMAGE” • TYPES: – THERMOSET – THERMOPLASTIC
  • 10. RESINS • THERMOSET – POLYESTER – VINYL ESTER – EPOXY – PHENOLIC – POLYURETHANE
  • 11. RESINS • THERMOPLASTIC – ACETAL – ACRYRONITRILE BUTADIENE STYRENE (ABS) – NYLON – POLYETHYLENE (PE) – POLYPROPYLENE (PP) – POLYETHYLENE TEREPHTHALATE (PET)
  • 12. RESINS • THERMOSET ADVANTAGES – THERMAL STABILITY – CHEMICAL RESISTANCE – REDUCED CREEP AND STRESS RELAXATION – LOW VISCOSITY- EXCELLENT FOR FIBER ORIENTATION – COMMON MATERIAL WITH FABRICATORS
  • 13. RESINS • THERMOPLASTIC ADVANTAGES – ROOM TEMPERATURE MATERIAL STORAGE – RAPID, LOW COST FORMING – REFORMABLE – FORMING PRESSURES AND TEMPERATURES
  • 14. POLYESTERS • LOW COST • EXTREME PROCESSING VERSATILITY • LONG HISTORY OF PERFORMANCE • MAJOR USES: –Transportation – Construction – Marine
  • 15. VINYL ESTER • SIMILAR TO POLYESTER • EXCELLENT MECHANICAL & FATIGUE PROPERTIES • EXCELLENT CHEMICAL RESISTANCE • MAJOR USES: –Corrosion Applications - Pipes, Tanks, & Ducts
  • 16. EPOXY • EXCELLENT MECHANICAL PROPERTIES • GOOD FATIGUE RESISTANCE • LOW SHRINKAGE • GOOD HEAT AND CHEMICAL RESISTANCE • MAJOR USES: –FRP Strengthening Systems –FRP Rebars –FRP Stay-in-Place Forms
  • 17. PHENOLICS • EXCELLENT FIRE RETARDANCE • LOW SMOKE & TOXICITY EMISSIONS • HIGH STRENGTH AT HIGH TEMPERATURES • MAJOR USES: –Mass Transit - Fire Resistance & High Temperature –Ducting
  • 18. POLYURETHANE • TOUGH • GOOD IMPACT RESISTANCE • GOOD SURFACE QUALITY • MAJOR USES: –Bumper Beams, Automotive Panels
  • 19. SUMMARY: POLYMERS • WIDE VARIETY AVAILABLE • SELECTION BASED ON: – PHYSICAL AND MECHANICAL PROPERTIES OF PRODUCT – FABRICATION PROCESS REQUIREMENTS
  • 20. Physical Properties of Thermosetting Resins Used in Structural Composites Resin Type Density (kg/m3 ) Tensile Str. (MPa) Elong. (%) E- Mod. (GPa) Long. Term t ,(C) Polyester 1.2 50-65 2-3 3 120 Vinyl Ester 1.15 70-80 4-6 3.5 140 Epoxy 1.1-1.4 50-90 2-8 3 120- 200 Phenolic 1.2 40-50 1-2 3 120- 150
  • 21. MATERIAL: FIBER REINFORCEMENTS • PRIMARY FUNCTION: “CARRY LOAD ALONG THE LENGTH OF THE FIBER, PROVIDES STRENGTH AND OR STIFFNESS IN ONE DIRECTION” • CAN BE ORIENTED TO PROVIDE PROPERTIES IN DIRECTIONS OF PRIMARY LOADS
  • 22. REINFORCEMENTS • NATURAL • MAN-MADE • MANY VARIETIES COMMERCIALLY AVAILABLE
  • 23. MAN-MADE FIBERS • ARAMID • BORON • CARBON/GRAPHITE • GLASS • NYLON • POLYESTER • POLYETHYLENE • POLYPROPYLENE
  • 24. FIBER PROPERTIES DENSITY (g/cm3 ) 1.38 1.59 1.99 1.99 2.76 8 0 2 4 6 8 10 Aramid Carbon S-Glass E-Glass Alum Steel
  • 25. FIBER PROPERTIES TENSILE STRENGTH x103 psi 500 525 530 625 20 60 0 200 400 600 800 E-Glass Aramid Carbon S-Glass Steel Alum
  • 26. FIBER PROPERTIES STRAIN TO FAILURE (%) 1.4 2.8 4.8 5 0.2 0.16 0 1 2 3 4 5 6 Carbon Aramid E-Glass S-Glass Steel Alum
  • 27. FIBER PROPERTIES TENSILE MODULUS 106 psi 10.5 12.6 19 33.5 29 10 0 10 20 30 40 E-Glass S-Glass Aramid Carbon Steel Alum
  • 28. FIBER PROPERTIES CTE - Longitudinal x10-6 /0 C -2 0.5 2.9 5 6.5 12.6 -2 0 2 4 6 8 10 12 14 Aramid Carbon S-Glass E-Glass Steel Alum
  • 29. FIBER PROPERTIES THERMAL CONDUCTIVITY x10-6 /0 C BTU-in/hr-ft2 - 0 F 1.5 115 1500 7.5 0 200 400 600 800 1000 1200 1400 1600 FRP Steel Alum Concrete
  • 30. FIBER REINFORCEMENT • GLASS (E-GLASS) – MOST COMMON FIBER USED – HIGH STRENGTH – GOOD WATER RESISTANCE – GOOD ELECTRIC INSULATING PROPERTIES – LOW STIFFNESS
  • 31. GLASS TYPES • E-GLASS • S-GLASS • C-GLASS • ECR-GLASS • AR-GLASS
  • 32. FIBER REINFORCEMENT • ARAMID (KEVLAR) – SUPERIOR RESISTANCE TO DAMAGE (ENERGY ABSORBER) – GOOD IN TENSION APPLICATIONS (CABLES, TENDONS) – MODERATE STIFFNESS – MORE EXPENSIVE THAN GLASS
  • 33. FIBER REINFORCEMENT • CARBON – GOOD MODULUS AT HIGH TEMPERATURES – EXCELLENT STIFFNESS – MORE EXPENSIVE THAN GLASS – BRITTLE – LOW ELECTRIC INSULATING PROPERTIES
  • 34. TYPICAL PROPERTIES OF STRUCTURAL FIBERS Fiber Type Density (kg/m3 ) E- Modulus (GPa) Tensile Strength (GPa) Elong. (%) E-Glass 2.54 72.5 1.72-3.45 2.5 S-Glass 2.49 87 2.53-4.48 2.9 Kevlar 29 1.45 85 2.27-3.80 2.8 Kevlar 49 1.45 117 2.27-3.80 1.8 Carbon (HS) 1.80 227 2.80-5.10 1.1 Carbon (HM) 1.80-1.86 370 1.80 0.5 Carbon (UHM) 1.86-2.10 350-520 1.00-1.75 0.2
  • 35. ADVANTAGES AND DISADVANTAGES OF REINFORCING FIBERS Fiber Type Advantages Disadvantages E-Glass, S-Glass High Strength, Low Cost Low Stiffness, Fatigue Aramid High Strength, Low Density Low Compr. Str., High Moisture Absorption HS Carbon High Strength and Stiffness High Cost UHM Carbon Very High Stiffness Low Strength, High Cost
  • 36. FIBER ORIENTATION • ANISOTROPIC • UNIDIRECTIONAL • BIAS - TAILORED DIRECTION – 0O - flexural strengthening – 90O - column wraps – + /- 45O - shear strengthening • ANGLE VARIES BY APPLICATION
  • 37. DEGREE OF ANISOTROPY OF FRP COMPOSITES FRP Composite E1/E2 E1/G12 F1/F2t Steel 1.00 2.58 1.00 Vinyl Ester 1.00 0.94 1.00 S-Glass/Epoxy 2.44 5.06 28 E-Glass/Epoxy 4.42 8.76 17.7 Carbon/Epoxy 13.64 19.1 41.4 UHM/Epoxy 40 70 90 Kevlar/Epoxy 15.3 27.8 260
  • 38. PROPERTIES OF UNIDIRECTIONAL COMPOSITES Property E-Glass/ Epoxy S-Glass/ Epoxy Aramid/ Epoxy Carbon/ Epoxy Fiber Volume 0.55 0.50 0.60 0.63 Longitudinal Modulus GPa 39 43 87 142 Transverse .Modulus, GPa 8.6 8.9 5.5 10.3 Shear Modulus, GPa 3.8 4.5 2.2 7.2 Poisson’s Ratio 0.28 0.27 0.34 0.27 Long.Tensile Strength MPa 1080 1280 1280 2280 Compressive Strength, MPa 620 690 335 1440
  • 39. ELASTIC AND SHEAR MODULI OF FRP COMPOSITES Material E1 E2 G12 G13 G23 Aluminum 10.40 10.40 3.38 3.38 3.38 Steel 29 29 11.24 11.24 11.24 Carbon/Epoxy 20 1.30 1.03 1.03 0.90 Glass/Epoxy 7.80 2.60 1.25 1.25 0.50
  • 40. REINFORCEMENTS SUMMARY • TAILORING MECHANICAL PROPERTIES – TYPE OF FIBER – PERCENTAGE OF FIBER – ORIENTATION OF FIBER
  • 41. COMPARISON OF AXIAL AND FLEXURAL EFFICIENCY OF FRP SYSTEMS AXIAL EFFICIENCY FLEXURAL EFFICIENCY Material E/ρ Rank E1/2 /ρ Rank Carbon/Epoxy 113.1 1 8.4 1 Kevlar/Epoxy 52.1 2 6.0 2 E-Glass/Epoxy 21.4 4 3.5 3 Mild Steel 25.6 3 1.8 4
  • 42. DESIGN VARIABLES FOR COMPOSITES • TYPE OF FIBER • PERCENTAGE OF FIBER or FIBER VOLUME • ORIENTATION OF FIBER – 0o , 90o , +45o , -45o • TYPE OF POLYMER (RESIN) • COST • VOLUME OF PRODUCT - MANUFACTURING METHOD
  • 43. DESIGN VARIABLES FOR COMPOSITES • PHYSICAL: – tensile strength – compression strength – stiffness – weight, etc. • ENVIRONMENTAL: – Fire – UV – Corrosion Resistance
  • 44. TAILORING COMPOSITE PROPERTIES • MAJOR FEATURE • PLACE MATERIALS WHERE NEEDED - ORIENTED STRENGTH – LONGITUDINAL – TRANSVERSE – or between • STRENGTH • STIFFNESS • FIRE RETARDANCY
  • 45. STRUCTURAL DESIGN APPROACH FOR COMPOSITES S t r u c t u r a l D e s ig n W it h F R P C o m p o s it e s M a t r ix , F ib e r s M ic r o m e c h a n ic s L a m in a , L a m in a t e M a c r o m e c h a n ic s S t r u c t u r a l A n a ly s is S t r e n g t h e n in g D e s ig n S T R U C T U R E F R P R e p a ir
  • 46. SPECIFIC MODULUS AND STRENGTH OF FRP COMPOSITE
  • 47. FLOW CHART FOR DESIGN OF FRP COMPOSITES [ E ] x , y T r a n s fo r m e d E n g . C o n s t a n t s [ Q ] x , y T r a n s fo r m e d M a t h . C o n s t a n t s [ Q ] 1 , 2 M a t h e m a t ic a l C o n s t a n t s [ F ib e r O r ie n t a t io n ] [ E ] x , y T r a n s fo r m e d E n g . C o n s t a n t s [ S ] x , y T r a n s fo r m e d M a t h . C o n s t a n t s [ S ] 1 , 2 M a t h e m a t ic a l C o n s t a n t s [ E ] 1 , 2 E n g in e e r in g C o n s t a n t s
  • 48. MANUFACTURING PROCESSES • Hand Lay-up/Spray-up • Resin Transfer Molding (RTM) • Compression Molding • Injection Molding • Reinforced Reaction Injection Molding (RRIM) • Pultrusion • Filament Winding • Vacuum Assisted RTM (Va-RTM) • Centrifugal Casting
  • 49. PROCESS CHARACTERISTICS Hand Lay-up/Spray-up • MAX SIZE: Unlimited • PART GEOMETRY: Simple - Complex • PRODUCTION VOLUME: Low - Med • CYCLE TIME: Slow • SURFACE FINISH: Good - Excellent • TOOLING COST: Low • EQUIPMENT COST: Low
  • 50. PRODUCT CHARACTERISTICS Pultrusion • CONSTANT CROSS SECTION • CONTINUOUS LENGTH • HIGH ORIENTED STRENGTHS • COMPLEX PROFILES POSSIBLE • HYBRID REINFORCEMENTS
  • 51. MATERIAL PROPERTIES • PROPERTIES OF FRP COMPOSITES VARY DEPENDING ON: – TYPE OF FIBER & RESIN SELECTED – FIBER CONTENT – FIBER ORIENTATION – MANUFACTURING PROCESS
  • 52. REPAIR • HYBRIDS (SUPER COMPOSITES): TRADITIONAL MATERIALS ARE JOINED WITH FRP COMPOSITES – WOOD – STEEL – CONCRETE – ALUMINUM
  • 53. BENEFITS - SUMMARY • LIGHT WEIGHT • HIGH STRENGTH to WEIGHT RATIO • COMPLEX PART GEOMETRY • COMPOUND SURFACE SHAPE • PARTS CONSOLIDATION • DESIGN FLEXIBILITY • LOW SPECIFIC GRAVITY • LOW THERMAL CONDUCTIVITY • HIGH DIELECTRIC STRENGTH
  • 54. LIFE CYCLE ECONOMICS • PLANNING/DESIGN/DEVELOPMENT COST • PURCHASE COST • INSTALLATION COST • MAINTENANCE COST • LOSS/WEAR COST • LIABILITY/INSURANCE COSTS • DOWNTIME/LOST BUSINESS COST • REPLACEMENT/DISPOSAL/RECYCLING COST
  • 55. LIFE CYCLE ECONOMICS (Examples) • IBACH BRIDGE (SWITZERLAND) – CFRP LAMINATES- 50 TIMES MORE EXPENSIVE THAN STEEL PER KILOGRAM – CFRP LAMINATES- 9 TIMES MORE EXPENSIVE THAN STEEL BY VOLUME – REPAIR WORK REQUIREMENTS-175 KG STEEL OR 6.2 KG CFRP – MATERIAL COST-20 % OF THE TOTAL PROJECT COST
  • 56. LIFE CYCLE ECONOMICS (Examples) • HORSETAIL CREEK BRIDGE (OREGON) – CONVENTIONAL REPAIR (SHEAR ONLY-ONE BEAM)-$69,000 – FRP REPAIR (GFRP SHEAR ONLY-ONE BEAM)- $1850 – FRP REPAIR [SHEAR (GFRP)+ FLEXURE(CFRP), ONE BEAM]- $9850
  • 57. CONCLUSIONS • ECONOMICS ARE MORE THAN THE BASIC ELEMENTS OF MATERIALS, LABOR, EQUIPMENT, OVERHEAD, ETC. • ENTIRE LIFE CYCLE ECONOMICS MUST BE CONSIDERED AND COMPARED TO THAT OF TRADITIONAL MATERIALS TO DETERMINE THE BENEFITS OF COMPOSITES IN A GIVEN APPLICATION
  • 59. EXTERNAL REINFORCEMENT OF RC BEAMS USING FRP • BACKGROUND • DESIGN MODELS – LACK OF DUCTILITY – FLEXURAL STRENGTHENING – SHEAR STRENGTHENING – PRESTRESSED FRP APPLICATION • DESIGN METHODOLOGY AND ANALYSIS • OTHER ISSUES – FATIGUE, CREEP, LOW TEMPERATURE FRP PERFORMANCE • DESIGN EXAMPLES
  • 60. FRP STRENGTHENED BEAMS BACKGROUND • FRP VS. EXTERNALLY STEEL BONDED PLATES – CORROSION AT THE EPOXY-STEEL INTERFACE – STEEL PLATES DO NOT INCREASE STRENGTH, JUST STIFFNESS – HIGH TEMPERATURES PERFORMANCE DIFFICULTIES DUE TO HEAVY WEIGHT OF THE STEEL PLATES – STRENGTHENING DESIGN BASED ON MATERIAL WEIGHT, NOT STRUCTURAL NEEDS – CONSTRUCTION DIFFICULTIES – TIME CONSUMING, HEAVY EQUIPMENT NEEDED
  • 61. FRP STRENGTHENED BEAMS LACK OF DUCTILITY • LINEAR STRESS-STRAIN PROFILE • DEFINITION OF DUCTILITY – DEFLECTION AT ULTIMATE/DEFLECTION AT YIELD- NOT APPLICABLE FOR FRP MATERIAL – STRAIN-ENERGY ABSORPTION, I.E., AREA UNDER LOAD-DEFLECTION CURVE- OK FOR FRP COMPOSITES – IN GENERAL- THE HIGHER THE FRP FRACTION AREA, THE LOWER THE ENERGY ABSORPTION OF THE STRENGTHENED CONCRETE BEAM
  • 65. FRP REINFORCEMENT OF RC COLUMNS • Advantages of Strengthening Columns with FRP Jackets – Increased Ductility – Increased Strength – Low Dead Weight – Reduced Construction Time – Low Maintenance
  • 66. FRP REINFORCEMENT OF RC COLUMNS • Factors Influencing the Behavior of FRP- Retrofitted Columns – Column composition – Column geometry – Current condition – Type of loading – Environmental conditions
  • 67. DESIGN OF FRP RETROFIT OF RC COLUMNS • Shear Strengthening • Flexural Hinge Confinement • Lap Splice Clamping
  • 71. FRP REINFORCEMENT OF RC COLUMNS • Advantages of Strengthening Columns with FRP Jackets – Increased Ductility – Increased Strength – Low Dead Weight – Reduced Construction Time – Low Maintenance
  • 72. FRP REINFORCEMENT OF RC COLUMNS • Factors Influencing the Behavior of FRP- Retrofitted Columns – Column composition – Column geometry – Current condition – Type of loading – Environmental conditions
  • 76. CONSTRUCTION PROCESS • Preparation of the Concrete Surface • Mixing Epoxy, Putty, etc. • Preparation of the FRP Composite System • Application of the FRP Strengthening System • Anchorage (if recommended) • Curing the FRP Material • Application of Finish System
  • 77. CONCRETE SURFACE PREPARATION • Repair of the existing concrete in accordance to: – ACI 546R-96 “Concrete Repair Guide” – ICRI Guideline No. 03370 “Guide for Surface Preparation for the Repair of Deteriorated Concrete...” • Bond Between Concrete and FRP Materials – Should satisfy ICRI “Guide for Selecting and Specifying Materials for Repair of Concrete Surfaces”
  • 78. CONCRETE SURFACE PREPARATION • Repair Cracks 0.010 inches or Wider – Epoxy pressure injected – To satisfy Section 3.2 of the ACI 224.1R-93 “Causes, Evaluation and Repair of Cracks…” • Concrete Surface Unevenness to be Less than 1 mm • Concrete Corners- Minimum Radius of 30 mm
  • 79. APPLICATION OF THE FRP COMPOSITE • In Accordance to Manufacturer’s and Designer's Specifications – Priming – Putty Application – Under-coating with Epoxy Resin – Application of the FRP Laminate/ FRP Fiber Sheet – Over-coating with Epoxy Resin
  • 80. CURING OF THE FRP COMPOSITES • In Accordance to Manufacturer’s Specifications – Temperature ranges and Curing Time- varies from few hours to 15 days for different FRP systems • Cured FRP Composite – Uniform thickness and density – Lack of porosity
  • 81. CONSTRUCTION PROCESS • Typical RC Beam in Need for Repair – corroded steel – spalling concrete
  • 82. CONSTRUCTION PROCESS • Deteriorated Column / Beam Connection
  • 83. CONSTRUCTION PROCESS • Concrete Surface Preparation – Smooth, free of dust and foreign objects, oil, etc. – Application of primer and putty (if required by the manufacturer)
  • 84. CONSTRUCTION PROCESS • Preparation of the FRP Composites for Application – Follow manufacturer’s recommendations
  • 85. CONSTRUCTION PROCESS • Priming of the Concrete Surface • Application of the Undercoating epoxy Layer (adhesive when FRP pultruded laminates are used)
  • 86. CONSTRUCTION PROCESS • Application of CFRP Fiber Sheet on a Beam- Wet Lay-Up Process • Similar for Application of Pultruded Laminates
  • 87. CONSTRUCTION PROCESS • Column Wrapping with Automated FRP Application device
  • 88. CONSTRUCTION PROCESS • Robo Wrapper by Xxsys Technologies

Notas do Editor

  1. The Composites Institute identifies eight market segments (plus a ninth - miscellaneous) for composite applications. The are: transportation construction marine corrosion-resistant consumer electrical/electronic appliance/business aircraft/defense
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  3. Composites can provide infrastructure applications with many benefits as listed here. Infrastructure can have all these benefits an more when the proper materials and manufacturing process is selected. But I believe that in order to achieve these goals, the engineer must specifically know the performance of his product. This includes the physical, mechanical, installation, cost, and quality that identifies the minimum performance specifications.
  4. Composites are composed of polymers, reinforcing fibers, fillers, and other additives. Each of these ingredients play an important role in the processing and final performance of the end product. In general terms, you could say that: The polymer is the “glue” that holds the composite and influence the physical properties of the composite end product. The reinforcement provides the mechanical strength properties to the end product. The fillers and additives are processing aids and also impart “special” properties to the end product. Other materials that we will cover include core materials. Depending on you application, core materials provide stiffness while being lightweight.
  5. Polymers are generally petrochemical or natural gas derivatives and can be either thermoplastic or thermosetting. Both types of polymers are used in composites and can benefit when combined with reinforcing fibers. However, the major volume of thermoplastic polymers are not used in composite form. In contrast to thermoplastics, thermosetting polymers generally require reinforcing fibers of high filler loading in order to be used. Properties required are usually dominated by strength, stiffness, toughness, and durability. The end-user must take into account the type of application, service temperature, environment, method of fabrication, and the mechanical propeties needed. Proper curing of the resin is essential for obtaining optimum mechanical properties, preventing heat softening, limiting creep, and reducing moisture impact.
  6. Thermosetting polymers are used for the major portion of the composites industry.
  7. Unsaturated polyester have the dominant share of this market because of their relatively low cost, fabrication flexibility and good performance. These polyesters are different than the thermoplastic polyesters used for textile fibers. Polyesters are available in many different varieties based on their special attributes or processing characteristics. Table 2.1 on page 13 of the handbook provides a handy selection guide that relates these characteristics to composite performance properties and typical end product uses.
  8. Vinyl esters are epoxy/polyester hybrids that combine some of the better characteristics of each system. They have good structural performance and dynamic properties. Vinyl esters should be considered for higher performance applications than isophthalic polyesters because they have superior chemical and water resistant properties, better retention of strength and stiffness at elevated temperatures and greater toughness. They process like polyesters. Their higher cost is offset by performance improvements.
  9. Epoxy polymers have higher mechanical properties, particularly dynamic and fatigue resistant properties, and water resistance than polyesters,. They exhibit low shrinkage during cure. They also have excellent adhesion characteristics. They have good heat and chemical resistance, good electrical properties. Epoxies generally have a slower cure. Epoxy resins should be considered where higher shear strength than is available with polyesters, and the application requires good mechanical properties at elevated temperatures or durability. Epoxies are used automated manufacturing such as pultrusion, filament winding, resin transfer molding, and compression molding. Some epoxies have low ultra-violet resistance and may need special surface protection.
  10. Phenolics are experiencing a resurgence of interest in composites because of their fire resistance. They have low creep and good dimensional stability. Phenolic resins should be considered when the goal is performance under heat, retention of properties under fire conditions or low emission of toxic fumes. Characteristics of phenolics include low flammability, low spread of flame and little smoke. Mechanical properties are comparable to orthophthalic polyesters. Low shrinkage compared with polyesters is as characteristic of this resin. Phenolics are available in liquid form or as molding compounds. Cure at room temperature is possible, however an elevated post cure above 80 0 C is needed ot obtain dimensionally stable materials. Development efforts by the resin producers have resulted in liquid systems for filament winding, pultrusion, and spray-up. This has greatly broadened the market opportunity for phenolics in the composites industry. Their excellent ablative characteristics have been used in rocket nozzle applications.
  11. Urethane’s are available as either thermoplastic or thermosets. Broad compounding capability cover the range from flexible to rigid systems. Both foams and solid forms are in use. They process rapidly, and although higher in cost, are gaining in usage based on cost/performance. Polyurethanes are used primarily in Reinforced Reaction Injection Molding, for items such as automotive bumpers and fascia.
  12. To summarize the discussion on polymers: A wide variety of polymers are available that can satisfy virtually every conceivable end use application. Proper selection requires knowledge of the physical and mechanical properties of the application and the fabrication process to be used to produce the end products.
  13. There are many reinforcing fibers commercially available for use in composites. They are of both natural and synthetic or man-made origin.
  14. The most prominent reinforcing fibers in terms of both quantity consumed and product sales value would be aramid, boron, carbon/graphite, glass, nylon, polyester, and polyethylene. Of these, glass fiber represents the predominant reinforcement because of its relatively low cost, good balance of properties, and a 40 year experience base. Materials such as boron are very expensive and only used in the most demanding performance applications.
  15. Glass has very good impact resistance due to their high strain to failure, when compared to other fibers. Aramid also has excellent impact resistance, particularly to ballistic impact. Not shown on this chart is steels ability to have a strain to failure up to 20%. The value shown is the strain at yield.
  16. I want to point out that in this graph, carbon can be shown with several different modulus. For example, 12K carbon fibers are available with standard or low (33-35 MSI), intermediate (40-50 MSI), high (50-70 MSI), and ultra high (70-140 MSI) modulus. The higher you go, the more expensive it gets. The higher modulus is more suitable for aircraft and spacecraft where performance is the main objective, not cost.
  17. Carbon and aramid fibers can have small or negative coefficients of thermal expansion. It should be noted that the matrix has a much higher CTE than the reinforcement. The thermal expansion of the composite depends not only on the type of reinforcement and the type of matrix, but also the geometry of the reinforcement, its volume fraction, and the amount and type of filler used.
  18. As shown in the video, many raw materials are used to produce glass. silica sand is the primary ingredient, accounting for more than 50 percent of the raw materials. Additional materials that may be used include limestone, flourspar, boric acid, and clay, in addition to a variety of metal oxides. The combination and amounts depends on which type of glass is being produced. Glass is generally the most impact resistant fiber but also weighs more than carbon or aramid. Glass fibers have excellent strength characteristics, equal and higher than steel in certain forms. The lower modulus requires special design treatment in applications where stiffness is critical. Processing characteristics required of glass fibers include: choppability, low static buildup, good fiber matrix adhesion. Glass fibers are insulators of both electricity and heat and thus their composites exhibit very good electrical and thermal insulation properties. They are transparent to radio frequency radiation, therefore they are used extensively in radar antenna applications. Glass filaments are extremely fragile, and are supplied in bundles called strands, rovings or yarns. Strands are a collection of continuous filaments. A roving refers to a collection of untwisted strands or yarns. Yarns are collections of filaments or strands that are twisted together.
  19. E-Glass is electrical resistant glass providing good overall strength at low cost. It accounts for about 90% of all glass fiber reinforcements. It has good electrical resistance, and it is used in radomes and antennas because of its radio frequency transparency. It is also used in computer circuit boards to provide stiffness and electrical resistance. S-Glass is a high strength, high stiffness glass with good performance in high temperature and corrosive environments. This type of glass is stronger and stiffer than E-Glass and is used in more demanding applications were their extra cost can be justified. This type of glass is referred to R-Glass in Europe and T-Glass in Japan. A lower cost version, S-2 glass is approximately 40-70% stronger than E-Glass. S-2 Glass is used in golf club shafts because is provides flexibility and accuracy for long ball hitting, and it is less expensive than carbon. C-Glass is a calcium borosilicate glass providing good resistance to corrosive acid environments such as hydrochloric and sulfuric acid. It is also noted that E-Glass and S-2 Glass have a much better resistance to basic solutions such as sodium carbonate, compared to C-Glass. C-Glass has poor high-temperature performance, therefore either E-Glass or S-Glass is used. ECR-Glass , used in Europe is an alternative to E-Glass in a corrosive environment. They have similar properties to E-Glass, very resistant to chemical attack and are boron free. AR-Glass is a alkali resistant glass formulated for use in cement substrates and concrete.
  20. Aramid fiber, is an aromatic polyimide, organic man made fiber. There are three major commercial suppliers: DuPont produces a product called Kevlar, Akzo produces a product called Twaron, and Teijin produces a product called Technora. Kevlar is produced in two distinct types of aramid fibe: Kevlar 29 and and a higher modulus Kevlar 49. Both types have a tensile stress/strain curve which is essentially linear to failure. Aramid fibers offer good mechanical properties at a low density with the added advantage of toughness or damage resistance. They are characterized as having reasonably high tensile strength, a medium modulus, and a very low density. There is a significant cost difference compare with glass fibers. Since aramids are lightweight, they have an advantage in their strength/weight and stiffness to weight ratios. It should be noted that they have relatively low compressive strengths. Aramid fibers are insulators of both electricity and heat. They are resistant to organic solvents, fuels, and lubricants. Fibers without resin are tough and used as cables or ropes because they do not behave in a brittle manner as do both carbon and arramid. “ hybrids” of the two fibers may be used in specific applications such as high performance boats.
  21. Carbon/graphite fibers combine high modulus with low density and make them very attractive for aircraft and other applications where weight saved” can be directly translated to cost savings and, therefore, justify their higher material cost. Carbon fiber is created using polyacrylonitrile (PAN), pitch or rayon fiber precursors. PAN based fibers offer good strength and modulus values up to 85-90 Msi. They also offer excellent compression strength for structural applications. Pitch fibers are made from petroleum or coal tar pitch. Their extremely high modulus values (up to 140 Msi) and favorable CTE make them the material used in spacecraft applications. It should be noted that Carbon fiber composites are more brittle than glass or aramid and can show galvanic corrosion when used next to metal. A barrier material, such as glass, and sometimes epoxy, must be used.
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  23. To summarize the discussion about reinforcements, one should remember that with composites, the mechanical strength properties are dependent on the type, amount, and orientation of the reinforcement that is selected for the particular product. With the variety and many different forms of reinforcements that are commercially available, an almost limitless number of composite systems are available to meet the strength requirements of any applications. Additionally, the ability to orient the composite strength characteristics to the specific performance requirements of the application, provides a unique advantage for composites that translates to weight and cost advantage as compared to traditional homogeneous structural materials.
  24. Reinforcing fibers contribute to the mechanical strength characteristics of the composite. The strength is dependent on: - the type or species of fiber - the amount of fiber - the orientation of the fiber - the fiber surface treatment - and its compatibility with the matrix polymer. By varying these parameters, a broad range of mechanical properties are possible. For example, a composite which has all the fibers aligned in one direction, it is stiff and strong in that direction, but in the transverse direction, it will have a lower modulus and low strength. Also, the fiber volume fraction heavily depends on the method of manufacture. Generally, The higher the fiber content the stronger the composite.
  25. These same parameters allow the tailoring of the mechanical properties of the composite to the specific property requirements of the end product application. This is a major feature of composite materials that allows their efficient use in highly stressed applications.
  26. By carefully selecting the fiber, resin and manufacturing process, designers can tailor composites to meet final product requirements that could not be achieved using other materials. Fiber orientation can maximize strength in one or more directions. This allows wall thickness variations, complex-contoured parts, and various degrees of stiffness or strengths. Composite laminates may be designed to be isotropic (uniform properties in all directions, independent of applied load) or anisotropic (properties only apparent in the direction of the applied load), balanced or unbalanced, symmetric or asymmetric depending on the forces from the application. Understanding layered or laminate structures behavior is very important in designing effective composite parts or structures.
  27. We will discuss the various types of manufacturing processes. They include.....
  28. Both processes are characterized by relatively low equipment and tooling costs, low to medium production volumes, high level of worker dependence, and the requirement for emissions control techniques because of the styrene fumes that come from the polyester resins that are typically used.
  29. - Pultruded parts naturally have a high degree of reinforcement orientation in the continuous direction. - Cross direction reinforcement is achieved by woven tapes or mats, or process attachments that wind reinforcements around the reinforcing system. - The process, once operating, uses very low labor. Long continuous runs can be economically produced. - Tooling and capital equipment costs are moderate and depend on the size and complexity of the profiles to be produced. - Long production runs with minimum number of profile changes provide the best economics. - Very large, complex profiles have been produced. Hollow and encapsulated core structures are routinely produced. Hybrid reinforcing systems are easily incorporated into a pultruded product to maximize the strength of a particular profile.
  30. To summarize, FRP composites material properties vary depending on the type of fiber and resin selected, the fiber content, the fiber orientation, and the manufacturing process. This is very important in order for composites to be used in the proper applications.
  31. Repair of the infrastructure using FRP composites promises to have a huge impact for the civil engineer. FRP composites, used in conjunction with traditional construction materials such as wood, steel, concrete, and aluminum, will create SUPER COMPOSITES, where both materials complement each other in the performance of a structure. For example, both glass and aramid have demonstrated major benefits when applied in wood glulam beams. A thin layer of FRP composites used on the tensile face of glulam beams nearly doubles the length of that beam without increasing the depth of the beam. Some of you may be familiar with the use of carbon and glass FRP composites to repair, strengthen, and seismically upgrade reinforced concrete structures, particularly in California.