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Solar Thermal Hybrids
STEP:
A different solar energy conversion process
The Solar Thermal Electrochemical Production
          of energetic molecules


                             Stuart Licht
                              slicht@gwu.edu




                          14:15
The Solar Thermal Generation of Electricity is evolving rapidly




                                       STEP is our new hybrid solar
                                       thermal process.
                                       Its synergy is fundamentally
                                       capable of higher solar energy
                                       efficiency.
                                       Rather than electricity, STEP
                                       produces as a product staples,
                                       such as fuel, metals and bleach.




                                                 14:15
14:15
14:15
STEP (Solar Thermal, Electrochemical Production) is a process to




                                                    14:15
The STEP (Solar Thermal, Electrochemical Production) Process




                                                  14:15
STEP hydrogen generation




Weʼve been interested in solar H2
       "(solar electrochemical water splitting)   "       "
                                                               14:15
       " as an alternative to fossil fuels"
STEP hydrogen generation




             Today with our friends at Lynntech, Inc.,
             a STEP type hydrogen generator is in
             development for the US Air Force.




                                    14:15
14:15
Could STEP replace today’s alkali chlor process for bleach production?

                                                  The alkali chlor process consumes
                                                  ~1% of the world's generated
                                                  electricity, thereby releasing CO2, to
                                                  make chlorine for bleach.
                                                  Instead STEP uses the decrease of
                                                  chloride  electrolysis  potentials,
                                                  which are on the order of volts per
                                                  1000°C temperature change.


  Envisioning a Renewable Chemical Economy
  Ex: Can we scale STEP for solar seawater desalinization forming bleach & metals?
                                        Excess solar thermal maintains a molten
                                              chloride bath; which in tandem:
                                        1)  Vaporizes seawater for desalinization,
                                              or water splitting.
                                        2)  Provides for molten chloride electrolysis.
                                        Seawater is 3.5 wt %
                                             in dissolved salt,
                                         principally 0.5 M
                                             NaCl, and 0.05
                                             M MgCl2.               14:15
14:15
Goal: Efficient, low cost, high rate iron
production without carbon dioxide emission.




                                              14:15
STEP is a new process using well established components




                                         14:15
14:15
14:15
14:15
STEP (Solar Thermal, Electrochemical Production) is a process to




                                                    14:15

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Stuart Licht | GW Chemistry

  • 1. Solar Thermal Hybrids STEP: A different solar energy conversion process The Solar Thermal Electrochemical Production of energetic molecules Stuart Licht slicht@gwu.edu 14:15
  • 2. The Solar Thermal Generation of Electricity is evolving rapidly STEP is our new hybrid solar thermal process. Its synergy is fundamentally capable of higher solar energy efficiency. Rather than electricity, STEP produces as a product staples, such as fuel, metals and bleach. 14:15
  • 5. STEP (Solar Thermal, Electrochemical Production) is a process to 14:15
  • 6. The STEP (Solar Thermal, Electrochemical Production) Process 14:15
  • 7. STEP hydrogen generation Weʼve been interested in solar H2 "(solar electrochemical water splitting) " " 14:15 " as an alternative to fossil fuels"
  • 8. STEP hydrogen generation Today with our friends at Lynntech, Inc., a STEP type hydrogen generator is in development for the US Air Force. 14:15
  • 10. Could STEP replace today’s alkali chlor process for bleach production? The alkali chlor process consumes ~1% of the world's generated electricity, thereby releasing CO2, to make chlorine for bleach. Instead STEP uses the decrease of chloride electrolysis potentials, which are on the order of volts per 1000°C temperature change. Envisioning a Renewable Chemical Economy Ex: Can we scale STEP for solar seawater desalinization forming bleach & metals? Excess solar thermal maintains a molten chloride bath; which in tandem: 1)  Vaporizes seawater for desalinization, or water splitting. 2)  Provides for molten chloride electrolysis. Seawater is 3.5 wt % in dissolved salt, principally 0.5 M NaCl, and 0.05 M MgCl2. 14:15
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  • 12. Goal: Efficient, low cost, high rate iron production without carbon dioxide emission. 14:15
  • 13. STEP is a new process using well established components 14:15
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  • 17. STEP (Solar Thermal, Electrochemical Production) is a process to 14:15