SlideShare uma empresa Scribd logo
1 de 1
Introduction


This experiment was done to introduce young analysts to the use of electrochemical
instrumentation in analytical chemistry, specifically, potentiometric end-point detection.
The objective of the experiment is to analyse a mixed acid solution containing a strong
acid HCl and a weak acid CH3COOH. In the analysis of the solution by potentiometric
titration, it is possible to assess the appropriateness of the various end point detection
techniques – the Gran plot, the first derivative (δpH/δV) and the second derivative plot
(δ2pH/δV2).
Potentiometric titration involves the measurement of the potential of a suitable indicator
electrode as a function of titrant volume. The data provided by potentiometric titrations
are particularly more reliable than the data from titrations that use chemical indicators.
This is due to the fact that the procedure involves measuring and recording cell potential
(in pH) after each addition of reagent and the increments of addition shifting from large
to small as the end point is approached. The accuracy with which the end point can be
found by potentiometric titration depends upon the magnitude of the change in the
electromotive force (emf) in the region of the equivalence point. This depends upon the
concentration and strength of the reagents involved – acids and alkali in this case.




                                              2

Mais conteúdo relacionado

Mais procurados

Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...
Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...
Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...
Željko Penga
 
Latest enzyme edit
Latest enzyme editLatest enzyme edit
Latest enzyme edit
Umi Biee
 
Latest enzyme (2)
Latest enzyme (2)Latest enzyme (2)
Latest enzyme (2)
Umi Biee
 
Chap 1(a) molecular-diffusion_in_gas(2)
Chap 1(a) molecular-diffusion_in_gas(2)Chap 1(a) molecular-diffusion_in_gas(2)
Chap 1(a) molecular-diffusion_in_gas(2)
Charice Wan
 

Mais procurados (19)

Pielak_JACS
Pielak_JACSPielak_JACS
Pielak_JACS
 
Numerical Analysis of Inlet Gas-Mixture Flow Rate Effects on Carbon Nanotube ...
Numerical Analysis of Inlet Gas-Mixture Flow Rate Effects on Carbon Nanotube ...Numerical Analysis of Inlet Gas-Mixture Flow Rate Effects on Carbon Nanotube ...
Numerical Analysis of Inlet Gas-Mixture Flow Rate Effects on Carbon Nanotube ...
 
Abstract
AbstractAbstract
Abstract
 
Chapter 6
Chapter 6Chapter 6
Chapter 6
 
Conductivity measurement in CSTR water-base(according to temperature)
Conductivity measurement in CSTR water-base(according to temperature)Conductivity measurement in CSTR water-base(according to temperature)
Conductivity measurement in CSTR water-base(according to temperature)
 
Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...
Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...
Penga Ž, Tolj I, Barbir F, Computational fluid dynamics study of PEM fuel cel...
 
Reactor Design 3
Reactor Design 3Reactor Design 3
Reactor Design 3
 
GroupW _Kinetics
GroupW _KineticsGroupW _Kinetics
GroupW _Kinetics
 
3. Enhance DCM
3. Enhance DCM3. Enhance DCM
3. Enhance DCM
 
Experiment5 chem210
Experiment5 chem210Experiment5 chem210
Experiment5 chem210
 
Advanced Chemical Reaction Engineering-Part-1-10-Apr-2016
Advanced Chemical Reaction Engineering-Part-1-10-Apr-2016Advanced Chemical Reaction Engineering-Part-1-10-Apr-2016
Advanced Chemical Reaction Engineering-Part-1-10-Apr-2016
 
Electro kinetic fractal dimension for characterizing shajara reservoirs
Electro kinetic fractal dimension for characterizing shajara reservoirsElectro kinetic fractal dimension for characterizing shajara reservoirs
Electro kinetic fractal dimension for characterizing shajara reservoirs
 
Advanced Chemical Engineering Thermodynamics-31-July-2016
Advanced Chemical Engineering Thermodynamics-31-July-2016Advanced Chemical Engineering Thermodynamics-31-July-2016
Advanced Chemical Engineering Thermodynamics-31-July-2016
 
Latest enzyme edit
Latest enzyme editLatest enzyme edit
Latest enzyme edit
 
Latest enzyme (2)
Latest enzyme (2)Latest enzyme (2)
Latest enzyme (2)
 
Mathematical modeling of continuous stirred tank reactor systems (cstr)
Mathematical modeling of continuous stirred tank reactor systems (cstr)Mathematical modeling of continuous stirred tank reactor systems (cstr)
Mathematical modeling of continuous stirred tank reactor systems (cstr)
 
Space time and Space velocity, CSTR
Space time and Space velocity, CSTRSpace time and Space velocity, CSTR
Space time and Space velocity, CSTR
 
Chap 1(a) molecular-diffusion_in_gas(2)
Chap 1(a) molecular-diffusion_in_gas(2)Chap 1(a) molecular-diffusion_in_gas(2)
Chap 1(a) molecular-diffusion_in_gas(2)
 
Jg3616071610
Jg3616071610Jg3616071610
Jg3616071610
 

Destaque (13)

Sensors
SensorsSensors
Sensors
 
Download-manuals-water quality-wq-manuals-32potentiometricanalysisofwaterqua...
 Download-manuals-water quality-wq-manuals-32potentiometricanalysisofwaterqua... Download-manuals-water quality-wq-manuals-32potentiometricanalysisofwaterqua...
Download-manuals-water quality-wq-manuals-32potentiometricanalysisofwaterqua...
 
Titration experiment report
Titration experiment reportTitration experiment report
Titration experiment report
 
Neutralization titrations
Neutralization titrationsNeutralization titrations
Neutralization titrations
 
Potentio lab report
Potentio lab reportPotentio lab report
Potentio lab report
 
Potentiometry new
Potentiometry newPotentiometry new
Potentiometry new
 
Titration Lab Report
Titration Lab ReportTitration Lab Report
Titration Lab Report
 
Potentiometry
PotentiometryPotentiometry
Potentiometry
 
Discussion exp 1
Discussion exp 1Discussion exp 1
Discussion exp 1
 
potentiometry & ion selective electode
potentiometry & ion selective electodepotentiometry & ion selective electode
potentiometry & ion selective electode
 
Unit 5 Potentiometry
Unit 5   PotentiometryUnit 5   Potentiometry
Unit 5 Potentiometry
 
potentiometry
potentiometrypotentiometry
potentiometry
 
Potentiometry
PotentiometryPotentiometry
Potentiometry
 

Semelhante a Introduction Det 3

Electrochemical method of analysis
Electrochemical method of analysisElectrochemical method of analysis
Electrochemical method of analysis
Siham Abdallaha
 
Kinetic of fast reaction
Kinetic of fast reactionKinetic of fast reaction
Kinetic of fast reaction
NITINOO
 
Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...
Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...
Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...
Fatemeh Sedaghatpour
 
2.2.21. Fluorimetry.pdf
2.2.21. Fluorimetry.pdf2.2.21. Fluorimetry.pdf
2.2.21. Fluorimetry.pdf
Arun Nt
 
Experiment 4 Electropolymerized Conducting Polymers. In.docx
Experiment 4 Electropolymerized Conducting Polymers.         In.docxExperiment 4 Electropolymerized Conducting Polymers.         In.docx
Experiment 4 Electropolymerized Conducting Polymers. In.docx
gitagrimston
 
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
eSAT Publishing House
 

Semelhante a Introduction Det 3 (20)

Electrochemical methods: Environmental Analysis
Electrochemical methods: Environmental Analysis Electrochemical methods: Environmental Analysis
Electrochemical methods: Environmental Analysis
 
Electrochemical method of analysis
Electrochemical method of analysisElectrochemical method of analysis
Electrochemical method of analysis
 
Use of sodium tetraphenylborate reagent for conductometric titration of Amlod...
Use of sodium tetraphenylborate reagent for conductometric titration of Amlod...Use of sodium tetraphenylborate reagent for conductometric titration of Amlod...
Use of sodium tetraphenylborate reagent for conductometric titration of Amlod...
 
Different techniques of pharmaceutical analysis
Different techniques of pharmaceutical analysisDifferent techniques of pharmaceutical analysis
Different techniques of pharmaceutical analysis
 
Kinetic of fast reaction
Kinetic of fast reactionKinetic of fast reaction
Kinetic of fast reaction
 
Mechanism of the Reaction of Plasma Albumin with Formaldehyde in Ethanol - Wa...
Mechanism of the Reaction of Plasma Albumin with Formaldehyde in Ethanol - Wa...Mechanism of the Reaction of Plasma Albumin with Formaldehyde in Ethanol - Wa...
Mechanism of the Reaction of Plasma Albumin with Formaldehyde in Ethanol - Wa...
 
Coulometry
CoulometryCoulometry
Coulometry
 
Coulometry.pptx presentation assignment copy
Coulometry.pptx presentation assignment   copyCoulometry.pptx presentation assignment   copy
Coulometry.pptx presentation assignment copy
 
Electrochemical method
Electrochemical methodElectrochemical method
Electrochemical method
 
Tecniques determine Rate of Reaction pdf.pdf
Tecniques  determine Rate of Reaction pdf.pdfTecniques  determine Rate of Reaction pdf.pdf
Tecniques determine Rate of Reaction pdf.pdf
 
Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...
Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...
Tensammetric Analysis of Nonionic Surfactant Mixtures by Artificial Neural Ne...
 
2.2.21. Fluorimetry.pdf
2.2.21. Fluorimetry.pdf2.2.21. Fluorimetry.pdf
2.2.21. Fluorimetry.pdf
 
Reverse phase chromatography
Reverse phase chromatographyReverse phase chromatography
Reverse phase chromatography
 
Experiment 4 Electropolymerized Conducting Polymers. In.docx
Experiment 4 Electropolymerized Conducting Polymers.         In.docxExperiment 4 Electropolymerized Conducting Polymers.         In.docx
Experiment 4 Electropolymerized Conducting Polymers. In.docx
 
Reaction kinetics
Reaction kineticsReaction kinetics
Reaction kinetics
 
Ligand based drug design
Ligand based drug designLigand based drug design
Ligand based drug design
 
Experimental Methods in Chemical Kinetics - Amina Luthfa
Experimental Methods in Chemical Kinetics - Amina LuthfaExperimental Methods in Chemical Kinetics - Amina Luthfa
Experimental Methods in Chemical Kinetics - Amina Luthfa
 
Lect. 6 method of quantitative analysis
Lect. 6 method of quantitative analysisLect. 6 method of quantitative analysis
Lect. 6 method of quantitative analysis
 
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
 
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
Thermodynamic behavior of tetrahydrofuron in p dioxane, methylcyclohexane and...
 

Mais de guest0009aa

Mais de guest0009aa (8)

Results Det 3
Results   Det 3Results   Det 3
Results Det 3
 
Results Last Page
Results Last PageResults Last Page
Results Last Page
 
References Det 3
References   Det 3References   Det 3
References Det 3
 
Experimental Methods Det 3
Experimental Methods   Det 3Experimental Methods   Det 3
Experimental Methods Det 3
 
Data For Lab
Data For LabData For Lab
Data For Lab
 
Abstract Det 3
Abstract   Det 3Abstract   Det 3
Abstract Det 3
 
Discussion & Findingd Det 3
Discussion & Findingd   Det  3Discussion & Findingd   Det  3
Discussion & Findingd Det 3
 
Data For Lab Day 1
Data For Lab   Day 1Data For Lab   Day 1
Data For Lab Day 1
 

Último

The basics of sentences session 2pptx copy.pptx
The basics of sentences session 2pptx copy.pptxThe basics of sentences session 2pptx copy.pptx
The basics of sentences session 2pptx copy.pptx
heathfieldcps1
 
Gardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch LetterGardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch Letter
MateoGardella
 
Seal of Good Local Governance (SGLG) 2024Final.pptx
Seal of Good Local Governance (SGLG) 2024Final.pptxSeal of Good Local Governance (SGLG) 2024Final.pptx
Seal of Good Local Governance (SGLG) 2024Final.pptx
negromaestrong
 
Activity 01 - Artificial Culture (1).pdf
Activity 01 - Artificial Culture (1).pdfActivity 01 - Artificial Culture (1).pdf
Activity 01 - Artificial Culture (1).pdf
ciinovamais
 

Último (20)

Explore beautiful and ugly buildings. Mathematics helps us create beautiful d...
Explore beautiful and ugly buildings. Mathematics helps us create beautiful d...Explore beautiful and ugly buildings. Mathematics helps us create beautiful d...
Explore beautiful and ugly buildings. Mathematics helps us create beautiful d...
 
The basics of sentences session 2pptx copy.pptx
The basics of sentences session 2pptx copy.pptxThe basics of sentences session 2pptx copy.pptx
The basics of sentences session 2pptx copy.pptx
 
Gardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch LetterGardella_PRCampaignConclusion Pitch Letter
Gardella_PRCampaignConclusion Pitch Letter
 
Seal of Good Local Governance (SGLG) 2024Final.pptx
Seal of Good Local Governance (SGLG) 2024Final.pptxSeal of Good Local Governance (SGLG) 2024Final.pptx
Seal of Good Local Governance (SGLG) 2024Final.pptx
 
Z Score,T Score, Percential Rank and Box Plot Graph
Z Score,T Score, Percential Rank and Box Plot GraphZ Score,T Score, Percential Rank and Box Plot Graph
Z Score,T Score, Percential Rank and Box Plot Graph
 
This PowerPoint helps students to consider the concept of infinity.
This PowerPoint helps students to consider the concept of infinity.This PowerPoint helps students to consider the concept of infinity.
This PowerPoint helps students to consider the concept of infinity.
 
Activity 01 - Artificial Culture (1).pdf
Activity 01 - Artificial Culture (1).pdfActivity 01 - Artificial Culture (1).pdf
Activity 01 - Artificial Culture (1).pdf
 
Measures of Central Tendency: Mean, Median and Mode
Measures of Central Tendency: Mean, Median and ModeMeasures of Central Tendency: Mean, Median and Mode
Measures of Central Tendency: Mean, Median and Mode
 
Unit-V; Pricing (Pharma Marketing Management).pptx
Unit-V; Pricing (Pharma Marketing Management).pptxUnit-V; Pricing (Pharma Marketing Management).pptx
Unit-V; Pricing (Pharma Marketing Management).pptx
 
Ecological Succession. ( ECOSYSTEM, B. Pharmacy, 1st Year, Sem-II, Environmen...
Ecological Succession. ( ECOSYSTEM, B. Pharmacy, 1st Year, Sem-II, Environmen...Ecological Succession. ( ECOSYSTEM, B. Pharmacy, 1st Year, Sem-II, Environmen...
Ecological Succession. ( ECOSYSTEM, B. Pharmacy, 1st Year, Sem-II, Environmen...
 
Basic Civil Engineering first year Notes- Chapter 4 Building.pptx
Basic Civil Engineering first year Notes- Chapter 4 Building.pptxBasic Civil Engineering first year Notes- Chapter 4 Building.pptx
Basic Civil Engineering first year Notes- Chapter 4 Building.pptx
 
fourth grading exam for kindergarten in writing
fourth grading exam for kindergarten in writingfourth grading exam for kindergarten in writing
fourth grading exam for kindergarten in writing
 
microwave assisted reaction. General introduction
microwave assisted reaction. General introductionmicrowave assisted reaction. General introduction
microwave assisted reaction. General introduction
 
How to Give a Domain for a Field in Odoo 17
How to Give a Domain for a Field in Odoo 17How to Give a Domain for a Field in Odoo 17
How to Give a Domain for a Field in Odoo 17
 
Class 11th Physics NEET formula sheet pdf
Class 11th Physics NEET formula sheet pdfClass 11th Physics NEET formula sheet pdf
Class 11th Physics NEET formula sheet pdf
 
Unit-IV; Professional Sales Representative (PSR).pptx
Unit-IV; Professional Sales Representative (PSR).pptxUnit-IV; Professional Sales Representative (PSR).pptx
Unit-IV; Professional Sales Representative (PSR).pptx
 
SOCIAL AND HISTORICAL CONTEXT - LFTVD.pptx
SOCIAL AND HISTORICAL CONTEXT - LFTVD.pptxSOCIAL AND HISTORICAL CONTEXT - LFTVD.pptx
SOCIAL AND HISTORICAL CONTEXT - LFTVD.pptx
 
Unit-IV- Pharma. Marketing Channels.pptx
Unit-IV- Pharma. Marketing Channels.pptxUnit-IV- Pharma. Marketing Channels.pptx
Unit-IV- Pharma. Marketing Channels.pptx
 
Mattingly "AI & Prompt Design: Structured Data, Assistants, & RAG"
Mattingly "AI & Prompt Design: Structured Data, Assistants, & RAG"Mattingly "AI & Prompt Design: Structured Data, Assistants, & RAG"
Mattingly "AI & Prompt Design: Structured Data, Assistants, & RAG"
 
Mixin Classes in Odoo 17 How to Extend Models Using Mixin Classes
Mixin Classes in Odoo 17  How to Extend Models Using Mixin ClassesMixin Classes in Odoo 17  How to Extend Models Using Mixin Classes
Mixin Classes in Odoo 17 How to Extend Models Using Mixin Classes
 

Introduction Det 3

  • 1. Introduction This experiment was done to introduce young analysts to the use of electrochemical instrumentation in analytical chemistry, specifically, potentiometric end-point detection. The objective of the experiment is to analyse a mixed acid solution containing a strong acid HCl and a weak acid CH3COOH. In the analysis of the solution by potentiometric titration, it is possible to assess the appropriateness of the various end point detection techniques – the Gran plot, the first derivative (δpH/δV) and the second derivative plot (δ2pH/δV2). Potentiometric titration involves the measurement of the potential of a suitable indicator electrode as a function of titrant volume. The data provided by potentiometric titrations are particularly more reliable than the data from titrations that use chemical indicators. This is due to the fact that the procedure involves measuring and recording cell potential (in pH) after each addition of reagent and the increments of addition shifting from large to small as the end point is approached. The accuracy with which the end point can be found by potentiometric titration depends upon the magnitude of the change in the electromotive force (emf) in the region of the equivalence point. This depends upon the concentration and strength of the reagents involved – acids and alkali in this case. 2