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Historic Overview
of
DoD Sea Disposal Operations Involving Chemical
Warfare Material (CWM)
in
US Coastal Waters and Recent Studies
1st International Conference
Chemical and Conventional Munitions Dumped at Sea
Halifax, NS
October 2007
1
Highlights
• History of DoD sea disposal operations involving chemical
warfare material (CWM)
• Legislation
• Study requirements
• Ongoing studies
• Findings

2
History of US Sea Disposals
• Disposal options for CWM were limited, until recently
− Large quantities of CWM (US and captured) not needed
− Deteriorating condition of some CWM presented hazard
− Disposal at depths, beyond human reach, considered safe

• Disposals included:
− Bulk chemical agent (CA) containers (all types of CA)
− All types of chemical munitions
− Captured enemy CWM (WWII)

• Disposals operations often involved CWM and
conventional munitions

3
Timeline

4
When Did DoD CWM Sea Disposal
Operations Occur?
p

y

14,000
12,000
10,000

Net CA
in Tons

8,000
6,000
4,000
2,000
0
1911-1920 1921-1930 1931-1940 1941-1950 1951-1960 1961-1970

Year

5
What Type CWM Did DoD Sea Dispose?
N
erve
(VX, G & G )
A
B
1%

Mustard
56%

Lewisite
38%
U
specified agent
2%

B
lood
(AC & CK
)
1%

Arsenic
2%

Phosgene
0%

•Approximately 27,000 metric tons (30,000 tons) of chemical agent was
disposed in US waters
Data published in Defense Environmental Programs
FY06 Annual Report to Congress (ARC), Appendix R

6
Where Did DoD Conduct CWM Sea Disposal
Operations in US Coastal Waters?
West Coast
(1 site)
37%

Atlantic
(9 sites)
50%

Gulf of
Mexico
(2 sites)
1%

Hawaii
(3 sites)
9%

Alaska
(1 site)
3%

Graph based on net agent weight

7
CWM Sea Disposal Sites
Unknown
11%

(19)
Under 10
2%

(20 - 160)
11 - 100
12%

Percent of chemical agent disposal
by miles (km) from shore

(3,050)

Over 101 (over 161)
75%

Over 10,000
51%

Unknown
11%

Percent of chemical agent
disposal by depth in feet
(meters)

Under 1,000
2%
6,000-9,999
34%

1,000 - 5,999
2%

(1,850 - 3,049)

(300 – 1,849)

Graphs based on net agent weight

8
U.S. Coastal CWM Sea Disposals
Atlantic, Unknown
1919 August – 1958 August

USS Elinor
1919 February
Atlantic, Area A
1967 June – 1968 August

Pacific, CA, San Fran
1945 December & 1958 April

Atlantic, Unnamed 1
1960 June – 1964 August
Atlantic, Unnamed 2
1957 November
Atlantic, Area 1
1945 November – 1964 August
Atlantic, Unnamed 3
1945 Nov – 1964 August
Atlantic, Baker
1946
Atlantic, B-1
1946 June - October
Atlantic, Unnamed 4
1946 March – 1970 August

Pacific, HI, Oahu, Area 1
1945 October – 1946 March

Pacific, AK, Attu
1947 June

Pacific, HI, Oahu, Unnamed
1944 December

Gulf of Mexico, Alabama
1946 July
Mississippi River, Braithwaite LA
1946 March – 1970 August

Pacific, HI, Oahu, Area 2
1945 December
Pacific, HI, Oahu, Unknown
1943 May – 1944 June

9
• Locations:

Sea Disposal Sites

− Ranged from 5 to over 250 miles (10 to over 400 km) from shore
− Depths ranged from 50 to 16,000 feet (15 to 4,900 m)

• DoD disposal methods
− Loose or “over the side”
− Consolidated in ship hulks, with scuttling

• DoD used for:
− CWM
− Conventional munitions

• Designated sites
− Were generally 100 square miles (260 sq km)
− May also have been used by others for disposal of
industrial and municipal wastes

10
Public Law 109-364, Section 314 (NDAA)
Research on Effects of Ocean Disposal of Munitions
• Identify disposals sites located in US coastal waters
• Identify navigational and safety hazards
• Research effects of sea disposed munitions on oceans and those
that use them
− Determine effects of munitions on
environment
− Determine effects of sea water on munitions
− Analyze water and sediment from six
representative sites
− Investigate feasibility of removal or remediation
− Develop safety measures for dealing with these munitions

• Monitor sites as necessary
11
Historical Research
• Archival research ongoing
• Initial effort focused on CWM
• DoD Annual Report to Congress (ARC)
on Environmental Programs
− Initial effort’s result reported in FY06 ARC
− Interim updates reported annually in ARC
− Final report due for FY09 ARC

• Current effort is focused on conventional
munitions
• Report must include: number, size, and
probable locations of munitions

12
Navigation and Safety Hazards
• DoD and NOAA are working together
• Research and field work will be used to update nautical charts
• DoD developed explosives safety materials for commercial and
recreational activities (See www.denix.osd.mil/uxosafety)
• NOAA distributed explosives safety materials to permitted
vessels and public

13
Research
• DoD established a senior level Tiger Team to provide vision
and leadership to overall effort. Team is supported by:
− Underwater Technology Research and Development Work Group
− Inter-agency Technical Advisory Committee

• Strategic Environmental Research Development Program
(SERDP) workshop on research needs for improving detection
and remediation of underwater munitions
• Developing sampling, analysis and investigation survey
approach and procedures
− NOAA survey of Ordnance Reef provided basis for approach
− Hawaii Undersea Chemical Weapons Assessment Program to
refine approach
14
Research
• SERDP literature review of CA fate and transport in
seawater
• Modeling effects of sea disposal on one-ton containers
(July 2007, ARL-TR-3883)
• Examination of corrosion of recovered sea disposed CWM
• Modeling of munitions migration
• Review of marine military munitions (M3) sites that may
present a hazard during dredging or replenishment

15
Press Reports of CWM Disposals in US Waters

16
Contact Information
Plexus Scientific Corporation
9104 Guilford Road, Suite 1010
Columbia, MD 21046 USA
Geoff Carton
(410) 715-3865 x-109
gcarton@plexsci.com
Geoff Carton
CALIBRE Systems, Inc
Or
Alexandria, Virginia, USA
Geoff.carton@calibresys.com
glcarton@gmail.com

17

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2007 Historic Overview Sea Disposal of Chemical Warfare Materiel

  • 1. Historic Overview of DoD Sea Disposal Operations Involving Chemical Warfare Material (CWM) in US Coastal Waters and Recent Studies 1st International Conference Chemical and Conventional Munitions Dumped at Sea Halifax, NS October 2007 1
  • 2. Highlights • History of DoD sea disposal operations involving chemical warfare material (CWM) • Legislation • Study requirements • Ongoing studies • Findings 2
  • 3. History of US Sea Disposals • Disposal options for CWM were limited, until recently − Large quantities of CWM (US and captured) not needed − Deteriorating condition of some CWM presented hazard − Disposal at depths, beyond human reach, considered safe • Disposals included: − Bulk chemical agent (CA) containers (all types of CA) − All types of chemical munitions − Captured enemy CWM (WWII) • Disposals operations often involved CWM and conventional munitions 3
  • 5. When Did DoD CWM Sea Disposal Operations Occur? p y 14,000 12,000 10,000 Net CA in Tons 8,000 6,000 4,000 2,000 0 1911-1920 1921-1930 1931-1940 1941-1950 1951-1960 1961-1970 Year 5
  • 6. What Type CWM Did DoD Sea Dispose? N erve (VX, G & G ) A B 1% Mustard 56% Lewisite 38% U specified agent 2% B lood (AC & CK ) 1% Arsenic 2% Phosgene 0% •Approximately 27,000 metric tons (30,000 tons) of chemical agent was disposed in US waters Data published in Defense Environmental Programs FY06 Annual Report to Congress (ARC), Appendix R 6
  • 7. Where Did DoD Conduct CWM Sea Disposal Operations in US Coastal Waters? West Coast (1 site) 37% Atlantic (9 sites) 50% Gulf of Mexico (2 sites) 1% Hawaii (3 sites) 9% Alaska (1 site) 3% Graph based on net agent weight 7
  • 8. CWM Sea Disposal Sites Unknown 11% (19) Under 10 2% (20 - 160) 11 - 100 12% Percent of chemical agent disposal by miles (km) from shore (3,050) Over 101 (over 161) 75% Over 10,000 51% Unknown 11% Percent of chemical agent disposal by depth in feet (meters) Under 1,000 2% 6,000-9,999 34% 1,000 - 5,999 2% (1,850 - 3,049) (300 – 1,849) Graphs based on net agent weight 8
  • 9. U.S. Coastal CWM Sea Disposals Atlantic, Unknown 1919 August – 1958 August USS Elinor 1919 February Atlantic, Area A 1967 June – 1968 August Pacific, CA, San Fran 1945 December & 1958 April Atlantic, Unnamed 1 1960 June – 1964 August Atlantic, Unnamed 2 1957 November Atlantic, Area 1 1945 November – 1964 August Atlantic, Unnamed 3 1945 Nov – 1964 August Atlantic, Baker 1946 Atlantic, B-1 1946 June - October Atlantic, Unnamed 4 1946 March – 1970 August Pacific, HI, Oahu, Area 1 1945 October – 1946 March Pacific, AK, Attu 1947 June Pacific, HI, Oahu, Unnamed 1944 December Gulf of Mexico, Alabama 1946 July Mississippi River, Braithwaite LA 1946 March – 1970 August Pacific, HI, Oahu, Area 2 1945 December Pacific, HI, Oahu, Unknown 1943 May – 1944 June 9
  • 10. • Locations: Sea Disposal Sites − Ranged from 5 to over 250 miles (10 to over 400 km) from shore − Depths ranged from 50 to 16,000 feet (15 to 4,900 m) • DoD disposal methods − Loose or “over the side” − Consolidated in ship hulks, with scuttling • DoD used for: − CWM − Conventional munitions • Designated sites − Were generally 100 square miles (260 sq km) − May also have been used by others for disposal of industrial and municipal wastes 10
  • 11. Public Law 109-364, Section 314 (NDAA) Research on Effects of Ocean Disposal of Munitions • Identify disposals sites located in US coastal waters • Identify navigational and safety hazards • Research effects of sea disposed munitions on oceans and those that use them − Determine effects of munitions on environment − Determine effects of sea water on munitions − Analyze water and sediment from six representative sites − Investigate feasibility of removal or remediation − Develop safety measures for dealing with these munitions • Monitor sites as necessary 11
  • 12. Historical Research • Archival research ongoing • Initial effort focused on CWM • DoD Annual Report to Congress (ARC) on Environmental Programs − Initial effort’s result reported in FY06 ARC − Interim updates reported annually in ARC − Final report due for FY09 ARC • Current effort is focused on conventional munitions • Report must include: number, size, and probable locations of munitions 12
  • 13. Navigation and Safety Hazards • DoD and NOAA are working together • Research and field work will be used to update nautical charts • DoD developed explosives safety materials for commercial and recreational activities (See www.denix.osd.mil/uxosafety) • NOAA distributed explosives safety materials to permitted vessels and public 13
  • 14. Research • DoD established a senior level Tiger Team to provide vision and leadership to overall effort. Team is supported by: − Underwater Technology Research and Development Work Group − Inter-agency Technical Advisory Committee • Strategic Environmental Research Development Program (SERDP) workshop on research needs for improving detection and remediation of underwater munitions • Developing sampling, analysis and investigation survey approach and procedures − NOAA survey of Ordnance Reef provided basis for approach − Hawaii Undersea Chemical Weapons Assessment Program to refine approach 14
  • 15. Research • SERDP literature review of CA fate and transport in seawater • Modeling effects of sea disposal on one-ton containers (July 2007, ARL-TR-3883) • Examination of corrosion of recovered sea disposed CWM • Modeling of munitions migration • Review of marine military munitions (M3) sites that may present a hazard during dredging or replenishment 15
  • 16. Press Reports of CWM Disposals in US Waters 16
  • 17. Contact Information Plexus Scientific Corporation 9104 Guilford Road, Suite 1010 Columbia, MD 21046 USA Geoff Carton (410) 715-3865 x-109 gcarton@plexsci.com Geoff Carton CALIBRE Systems, Inc Or Alexandria, Virginia, USA Geoff.carton@calibresys.com glcarton@gmail.com 17