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MATERIAL SAFETY DATA SHEET
                              KOALA AUTO KARE                                   Product: HAND SANITIZER
                             Date of Issue: JAN 2010                                 Page 1 of Total 7

SECTION 1 – STATEMENT OF CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
SUPPLIER:                              MOGA HOLDINGS PTY LTD T/as KOALA AUTO KARE
ADDRESS:                               P.O. Box 1071 Ashmore City, QLD 4214
Trade Name:                                                “HG4948E” HAND SANITIZER
TELEPHONE:                             07 3807 7400                 FAX:                         07 3807 7491
AH EMERGENCY TELEPHONE:                13 1126 in Australia         ABN:                         64 692 649 921
Substance:                             Alcohol based                Product Use:                 Hand sanitizer
Creation Date:                         JAN 2010                     Revision Date:               JAN 2015
Product Code:



SECTION 2 – HAZARDS IDENTIFICATION
   This product is classified as HAZARDOUS (FLAMMABLE) according to criteria of the National
          Occupational Health and Safety Commission Australia.
     This product is classified as Dangerous Goods according to the Australian Dangerous Goods (ADG)
          Code.
     This product is NOT classified as a Scheduled Poison according to the SUSDP.
Approved Criteria            R11 Highly Flammable.
Classification               S16 Keep away from sources of ignition – no smoking
                             S2 Keep out of reach of children
                             S7 Keep container tightly closed.
UN Number                    1193                            ADG Classification                  3
Shipping Name                                                Class
                             FLAMMABLE LIQUIDS,
                             N.O.S. (ETHANOL,
                             ISOPROPANOL)

Hazchem Code         3[Y]E                                        Packing Group                  II
SUSDP Classification None allocated                               ADG Subsidiary Risk            none allocated
EMERGENCY OVERVIEW
Colour               White milky                                  Odour                          Fragrant
Physical Description Liquid                                       Viscosity                      Non-viscous liquid
Major Health Hazards None known



SECTION 3 – COMPOSITION AND INFORMATION ON INGREDIENTS
Ingredients determined not to be hazardous are present in concentrations that do not exceed the relevant cut-off concentrations
as found from NOHSC publication “List of Designated Hazardous Substances” or have been found NOT to meet the criteria of a
hazardous substance as defined in the NOHSC publication “Approved Criteria for Classifying Hazardous Substances”.
Ingredients:                                           CAS              Proportion:         Exposure           Exposure
                                                      Number:                               Standards       Standards STEL
                                                                                               TWA
                                                                                             1000ppm
Ethanol                                                64-17-5          < 10% w/w                                 Not set
                                                                                           1880 mg/m3
                                                                                              400ppm             500ppm
Isopropyl alcohol                                       67-63-0         > 60 % w/w
                                                                                           (983 mg/m3)        (1230 mg/m3)
Ingredients determined not to be hazardous             Various          <10% w/w              Not set            Not set
Water                                                 7732-18-5        10 –30% w/w            Not set            Not set
 The TWA exposure value is the Time Weighted Average airborne concentration of a particular substance when calculated
 over a normal 8-hour working day for a 5-day working week. The STEL (Short Term Exposure Limit) is an exposure value that
 should not be exceeded for more than 15 minutes and should not be repeated for more than 4 times per day. There should be
MATERIAL SAFETY DATA SHEET
                            KOALA AUTO KARE                                  Product: HAND SANITIZER
                           Date of Issue: JAN 2010                                Page 2 of Total 7

 at least 60 minutes between successive exposures at the STEL. The term “peak” is used when the TWA limit, because of the
 rapid action of the substance, should never be exceeded, even briefly.
____________________________________________________________________________________________

SECTION 4 – FIRST AID MEASURES
Scheduled Poisons           Poisons Information Centre in each Australian State capital city or in Christchurch, New
                            Zealand can provide additional assistance for scheduled poisons. (Phone Australia
                            131126 or New Zealand 03 474 7000).
First Aid Facilities        Normal washroom facilities.
Skin contact                Wash skin with plenty of water. Remove contaminated clothing and wash before re-use.
                            Seek medical advice (e.g. doctor) if irritation, burning or redness develops.
Eye contact                 Immediately irrigate with copious quantities of water for at least 20 minutes. Eyelids to be
                            held open. Seek medical advice (e.g. ophthalmologist).
Ingestion                   Do NOT induce vomiting. Do NOT attempt to give anything by mouth to an unconscious
                            person. Rinse mouth thoroughly with water immediately. Give water to drink. If vomiting
                            occurs, give further water to achieve effective dilution. Seek medical advice (e.g. doctor).
Inhalation                  Remove victim to fresh air away from exposure. Obtain medical attention if symptoms
                            occur.
Advice to Doctor            Treat symptomatically. All treatments should be based on observed signs and symptoms
                            of distress of the patient. Poisons Information Centre in each Australian State capital city
                            or in Christchurch, New Zealand can provide additional assistance for scheduled poisons.
Aggravated Medical
Conditions                  None known.



SECTION 5 – FIRE FIGHTING MEASURES
Fire and Explosion          Combustion products include oxides of carbon and unidentified organic and inorganic
Hazards                     compounds.
Extinguishing Media         Keep containers exposed to extreme heat cool with water spray. Use an extinguishing
                            media such as Carbon dioxide, foam or dry chemical, water fog/spray.
Fire Fighting               Combustion products include oxides of carbon and unidentified organic and inorganic
                            compounds. Fire fighters to wear self-contained breathing apparatus if risk of exposure
                            to products of combustion or decomposition.
Flash Point                 < 20 °C (literature value)



SECTION 6 – ACCIDENTAL RELEASE MEASURES
Emergency                   HAZCHEM code: 3[Y]E
Procedures                  3 = use FOAM to fight fires.
                            [Y] = Yes – risk of violent reaction, recommend-breathing apparatus for fire only, contain.
                                  Shut off engine and electrical equipment off.
                                  No smoking or naked lights within 50 metres.
                                  Move people from immediate area; keep upwind.
                                  Send messenger to notify fire brigade and police.
                                  Tell them location, material quantity, UN number and emergency contact.
                                  Indicate condition of vehicle and damage or injuries observed.
                                  Warn other traffic.
                            E = Consider evacuation.
Occupational Release        Minor spills do not normally need any special clean-up measures. In the event of a major
                            spill, prevent spillage from entering drains or watercourses. For large spills, or tank
MATERIAL SAFETY DATA SHEET
                          KOALA AUTO KARE                               Product: HAND SANITIZER
                         Date of Issue: JAN 2010                             Page 3 of Total 7

                         rupture, consider initial evacuation distance of 200 metres in all directions. Stop leak if
                         safe to do so. If available, use water spray to disperse vapour. Wear appropriate
                         protective equipment as in section 8 below to prevent skin and eye contamination. Spilt
                         material may result in a slip hazard and should be absorbed into dry, inert material (e.g.
                         sand, earth or vermiculite), which then can be put into appropriately labeled drums for
                         disposal by an approved agent according to local conditions. Residual deposits will
                         remain slippery. Wash area down with excess water. If contamination of sewers or
                         waterways has occurred advise the local emergency services. In the event of a large
                         spillage notify the local environment protection authority or emergency services.



SECTION 7 – HANDLING AND STORAGE
Handling                 Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke.
                         Keep containers closed at all times. Avoid physical damage to containers. Always wash
                         hands with water after handling.
                         Do not breathe vapour, spray, and mists.
                         Use local exhaust extraction.
                         Extinguish any naked flames. Remove ignition sources. Avoid sparks. Do not smoke.
                         Take precautionary measures against static discharges.
                         Earth all equipment.
                         Do not empty into drains.
Storage                  Store in a cool, dry, place with good ventilation. Store away from incompatible materials
                         (Section 10). Keep containers closed at all times – check regularly for leaks. Keep
                         container tightly closed and in a well-ventilated place.
                         Keep away from direct sunlight and other sources of heat or ignition.
                         Do not smoke in storage areas.



SECTION 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION
Exposure Limits          National Occupational Exposure Limits, as published by National Occupational Health &
                         Safety Commission:
                         Time-weighted Average (TWA): None established for specific product.
                         See SECTION 3 for Exposure Limits of individual ingredients.
                         Short Term Exposure Limit (STEL): None established for specific product.
                         See SECTION 3 for Exposure Limits of individual ingredients.
Biological Limit Value   None established for product.
Engineering Controls     Ensure ventilation is adequate to maintain air concentrations below exposure standards.
                         Avoid generating mists of the product. Use only in a well-ventilated area. Ensure airflow,
                         where this product is used, is directed away from the operators.
Personal Protective      Use good occupational work practice. The use of protective clothing and equipment
Equipment                depends upon the degree and nature of exposure. Final choice of appropriate protection
                         will vary according to individual circumstances i.e. methods of handling or engineering
                         controls and according to risk assessments undertaken. The following protective
                         equipment should be available;
Eye Protection
                         Generally not required to handle the product as per label directions.
                         The use of safety glasses with side shield protection, goggles or face shield is
                         recommended to handle in quantity, cleaning up spills, decanting, etc. Contact lenses
                         pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them.
Skin Protection          Generally not required to handle the product as per label directions – hand
                         cleaner/sanitizer.
                         Overalls, work boots and gloves are recommended for handling the concentrated product
MATERIAL SAFETY DATA SHEET
                          KOALA AUTO KARE                                Product: HAND SANITIZER
                         Date of Issue: JAN 2010                              Page 4 of Total 7

                          (as per AS/NZS 2161, or as recommended by supplier) to handle in quantity, cleaning up
                          spills, decanting, etc.


Protective Material       Material suitable for detergent contact – Butyl rubber, Natural Latex, Neoprene, PVC, and
Types                     Nitrile.
Respirator                Generally not required to handle the product as per label directions.
                          If engineering controls are not effective in controlling airborne exposure then respiratory
                          protective equipment should be used suitable for protecting against airborne
                          contaminants. Final choice of appropriate breathing protection is dependant upon actual
                          airborne concentrations and the type of breathing protection required will vary according
                          to individual circumstances. Expert advice may be required to make this decision.
                          Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and
                          maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory
                          Protective Devices.



SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES
Physical State           Liquid gel                      Colour                        Clear to slightly hazy liquid
Odour                    Citrus odour                    Specific Gravity              < 1.0 @ 25 °C
Boiling Point            Approximately 70 °C             Freezing Point                Not available
Vapour Pressure          Not available                   Vapour Density                Not available
Flash Point              < 20 °C                         Flammable Limits              LEL: 2.2%v, UEL: 12.7%v
Water Solubility         Miscible in all proportions     pH                            6.0 – 8.0 neat
Volatile Organic                                         Coefficient of Water/Oil
                         Not available
Compounds (VOC)                                          Distribution                  Not available
Viscosity                Not available                   Odour Threshold               Not available
Evaporation Rate         Not available                   Per Cent Volatile             Ca 96 % v/v



SECTION 10 – STABILITY AND REACTIVITY
Chemical Stability        Stable at normal temperatures and pressure.
Conditions to Avoid       Excessive heat, sources of ignition.
Incompatible Materials    Strong oxidizing agents.
Hazardous                 Product can decompose on combustion to form Carbon Monoxide, Carbon Dioxide, and
Decomposition             other possibly toxic gases and vapours.
Hazardous Reactions       None known.



SECTION 11 – TOXICOLOGICAL INFORMATION
PRODUCT MIXTURE INFORMATION
Local Effects        Mild irritant: eye, skin, inhalation and ingestion.
Target Organs        Eyes, mucous membranes, skin, lungs.
POTENTIAL HEALTH EFFECTS
Ingestion
Short term exposure  Swallowing large amounts of this product can cause stomach irritation, nausea and
                     diarrhea. Aspiration of liquid into the lungs can produce chemical pneumonia.
Long term exposure   No information available.
Skin contact
Short term exposure  Properly used wash solutions not expected to be irritating. Prolonged contact with
                     concentrated solutions may have a degreasing effect on skin.
MATERIAL SAFETY DATA SHEET
                           KOALA AUTO KARE                              Product: HAND SANITIZER
                          Date of Issue: JAN 2010                            Page 5 of Total 7

Long term exposure         Prolonged and repeated skin contact with solutions may induce eczematoid dermatitis
                           in certain individuals.
Eye contact
Short term exposure        This product may cause eye irritation, watering, and redness.
Long term exposure         No information available.
Inhalation
short term exposure        Irritating to respiratory system, drowsiness. Vapor may cause dizziness and headache.
                           Mist may cause breathing problems.
long term exposure         No information available.
Carcinogen Status
NOHSC                      No significant ingredient is classified as carcinogenic by NOHSC.
NTP                        No significant ingredient is classified as carcinogenic by NTP.
IARC                       No significant ingredient is classified as carcinogenic by IARC.
Medical conditions
aggravated by exposure No information available.
CLASSIFICATION OF INDIVIDUAL INGREDIENTS
NOTE : This information relates to each individual ingredient, when evaluated as pure undiluted chemical.
See SECTION 3 for actual proportions of ingredients present in this product.
Ingredients                                                 R-Phrases.
Isopropanol                                                 R11 Highly flammable. R36 Irritating to eyes.
Ethanol                                                     R11
INDIVIDUAL INGREDIENT INFORMATION
ETHANOL 100%
Irritation Data         Moderately irritating to skin – may cause redness. Moderately irritating to eyes – may
                        injure tissue. Moderately irritating to respiratory system and mucous membranes.
Toxicity Data           Excessive chronic absorption may result in liver damage.
                        LD50 oral (rat) : 2080 mg/kg. LD50 oral (rat) : 13.9 g/kg
Local Effects           Absorbed into the body by inhalation and ingestion. Irritant of sensitive tissues, eg eyes
                        and mucous membranes. Central nervous system depression.
Target Organs           Eyes, mucous membranes, liver, central nervous system.
Acute Toxicity Level    Mild toxicity. Narcotic properties: ingestion.
Mutagenic Data          No available information.
Reproductive Effects    No available information.
ISOPROPYL ALCOHOL 100%
Irritation Data          Vapour concentrations above recommended exposure levels may be irritating to the eyes
                         and the respiratory tract, may cause headaches and dizziness could be anesthetic and
                         may have other central nervous system effects. Negligible hazard at ambient
                         temperature (-18 to 38°C). Skin irritation test (rabbit): Slight irritations.
Toxicity Data            Acute oral toxicity: LD50 = 5045 mg/kg (rat). Acute dermal toxicity: LD50= 12500 mg/kg
                         (rabbit). Acute toxicity of the vapour: LC50= 16970 ppm 4hrs (rat). Chronic effects on
                         humans: developmental toxicity – Proven – the substance is toxic to kidneys, lungs, the
                         nervous system, the reproductive system, liver, immune system, eyes, skin.
Local Effects            Irritant: inhalation, skin, eye.
Mutagenic Data           Mutagenicity (test of mammal cells): negative. Bacterian Mutagenicity: Salmonella
                         typhimurium: negative. Bacterian Mutagenicity: Ames-Test: negative
Reproductive Data        There were no indications of developmental toxicity in the rabbits at any exposure
                         level. Findings from a multigeneration oral reproduction study indicate that infant and
                         immature rats are more sensitive than their parents to the acute oral toxicity induced by
                         high (1000 mg/kg/day) doses of Isopropanol. The effect levels for rats and rabbits were
                         at several times the maximum exposure that would occur at the TLV.
MATERIAL SAFETY DATA SHEET
                          KOALA AUTO KARE                                   Product: HAND SANITIZER
                         Date of Issue: JAN 2010                                 Page 6 of Total 7

SECTION 12 – ECOLOGICAL INFORMATION
Fish toxicity            None available for specific product. For major ingredient ISOPROPANOL:
                         P. Promelas CL50 : 9640 mg/l /96h.
Algae toxicity           None available for specific product. For major ingredient ISOPROPANOL:
                         Desmodesmus subspicatus IC50 : > 1000 mg/l /72h.
Invertebrates toxicity   None available for specific product. For major ingredient ISOPROPANOL:
                         Daphnia magna EC50: 13299 mg/l /48h.
Toxicity to Bacteria     None available for specific product. For major ingredient ISOPROPANOL:
                         Photobacterium phosphoreum CE50 : 22000 mg/l /15min. Microtox test.
                         Bacterial toxic concentration limit:
                         Ps. putida CE5 : 1050 mg/l /16h.
                         M. Aeruginosa CE5: 1000mg/l /8d.
OECD Biological          Biological degradability: 95% /21d.
degradation              Biological degradability: good
                         Individual components stated to be biodegradable.
General                  Product miscible in all proportions with water. AS WITH ANY CHEMICAL PRODUCT, DO
                         NOT DISCHARGE BULK QUANTITIES INTO DRAINS, WATERWAYS, SEWER OR
                         ENVIRONMENT. Inform local authorities if this occurs. When introduced properly, no
                         impairments in the function of adapted biological waste-water-treatment plants are to be
                         expected. No ecological problems are to be expected when the product is handled and
                         used with due care and attention.



SECTION 13 – DISPOSAL CONSIDERATIONS
Disposal                 To dispose of quantities of undiluted product, refer to State Land Waste Management
                         Authority. Transfer product residues to a labelled, sealed container for disposal or
                         recovery. Waste disposal must be by an accredited contractor. As with any chemical, do
                         not put down the drain in quantity. The small quantities contained in wash solutions (when
                         used as directed) can generally be handled by conventional sewage systems, septics,
                         and grey water systems. For larger scale use, eg. Commercial laundry operations, a
                         recycled water system is often recommended, or Trade Waste License obtained for
                         disposal to sewer.



SECTION 14 – TRANSPORT INFORMATION
UN Number                1193                               ADG Classification              3
Shipping Name                                               Class
                         FLAMMABLE LIQUIDS,
                         N.O.S. (ETHANOL,
                         ISOPROPANOL)
Hazchem Code             3[Y]E                              Packing Group                   II
SUSDP Classification     None allocated                     ADG Subsidiary Risk             None allocated
Packaging Method         3.8.3 RT1                          Special Provisions              SP109, SP129, SP274
Segregation              Class 3 – Flammable liquid shall not be loaded in the same vehicle or packed in the same freight
                         container with:
                              Class 1, Explosives
                              Class 2.1, Flammable Gases, if both the Class 3 and Class 2.1 dangerous goods are in
                                  bulk
                              Class 2.3, Toxic Gases
                              Class 4.2 Spontaneously Combustible Substances
                              Class 5.1 Oxidizing Agents and Class 5.2, Organic Peroxides
                              Class 6 Toxic Substances (where the flammable liquid is nitro methane)
                              Class 7 Radioactive Substances.
MATERIAL SAFETY DATA SHEET
                              KOALA AUTO KARE                                    Product: HAND SANITIZER
                             Date of Issue: JAN 2010                                  Page 7 of Total 7

                                     Foodstuff and foodstuff empties



SECTION 15 – REGULATORY INFORMATION
AICS                         All ingredients present on AICS.
Labeling Details
HAZARD                       FLAMMABLE
RISK PHRASES                 R11 – Highly flammable.
SAFETY PHRASES               S2 - Keep out of reach of children.
                             S16 - Keep away from sources of ignition.
                             S 45 - In case of accident, or if you feel unwell, seek medical advice immediately (show
                             the label wherever possible).
SUSDP                        Not scheduled
ADG Code                     Class 3 Flammable



SECTION 16 – OTHER INFORMATION
Acronyms
SUSDP                        Standard for the Uniform Scheduling of Drugs and Poisons.
ADG Code                     Australian Code for the Transport of Dangerous Goods by Road and Rail.
CAS Number                   Chemical Abstracts Service Registry Number.
UN Number                    United Nations Number.
R-Phrases                    Risk Phrases.
HAZCHEM                      An emergency action code of numbers and letters, which gives information to emergency
                             services.
NOHSC                        National Occupational Health and Safety Commission.
NTP                          National Toxicology Program (USA).
IARC                         International Agency for Research on Cancer.
AICS                         Australian Inventory of Chemical Substances.
TWA                          Time Weighted Average
STEL                         Short Term Exposure Limit
Literature References        List of Designated Hazardous Substances [NOHSC:10005(1999)]
                             Australian Code For The Transport Of Dangerous Goods By Road And Rail – Sixth Edition.
                             Standard for the Uniform Scheduling of Drugs and Poisons.
                             National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC:
                             2011(2003)]
                             Approved Criteria for Classifying Hazardous Substances [NOHSC:1008(1999)]
                             Material Safety Data Sheets – individual raw materials – Suppliers.
                             HSIS – Hazardous Substance Information System – National Worksafe Data Base.
Revision Information         New Issue to standard: 2nd Edition [NOHSC:2011(2003)].
Note                         Safety Data Sheets are updated frequently. Please ensure that you have a current copy.
Contact Point                Regulatory Affairs Manager.    Telephone                    07 3807 7400
Issue Date                   JAN 2010                       Supersedes Issue Date        1ST issue
This MSDS summarizes at the date of issue our best knowledge of the health and safety hazard information of this product, and
in particular how to safely handle and use this product in the workplace. Since the supplier cannot anticipate or control the
conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the
user intends to handle and use the product in the workplace. If clarification or further information is needed to ensure that an
appropriate assessment can be made, the user should contact this supplier.

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Gear hand sanitizer

  • 1. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 1 of Total 7 SECTION 1 – STATEMENT OF CHEMICAL PRODUCT AND COMPANY IDENTIFICATION SUPPLIER: MOGA HOLDINGS PTY LTD T/as KOALA AUTO KARE ADDRESS: P.O. Box 1071 Ashmore City, QLD 4214 Trade Name: “HG4948E” HAND SANITIZER TELEPHONE: 07 3807 7400 FAX: 07 3807 7491 AH EMERGENCY TELEPHONE: 13 1126 in Australia ABN: 64 692 649 921 Substance: Alcohol based Product Use: Hand sanitizer Creation Date: JAN 2010 Revision Date: JAN 2015 Product Code: SECTION 2 – HAZARDS IDENTIFICATION  This product is classified as HAZARDOUS (FLAMMABLE) according to criteria of the National Occupational Health and Safety Commission Australia.  This product is classified as Dangerous Goods according to the Australian Dangerous Goods (ADG) Code.  This product is NOT classified as a Scheduled Poison according to the SUSDP. Approved Criteria R11 Highly Flammable. Classification S16 Keep away from sources of ignition – no smoking S2 Keep out of reach of children S7 Keep container tightly closed. UN Number 1193 ADG Classification 3 Shipping Name Class FLAMMABLE LIQUIDS, N.O.S. (ETHANOL, ISOPROPANOL) Hazchem Code 3[Y]E Packing Group II SUSDP Classification None allocated ADG Subsidiary Risk none allocated EMERGENCY OVERVIEW Colour White milky Odour Fragrant Physical Description Liquid Viscosity Non-viscous liquid Major Health Hazards None known SECTION 3 – COMPOSITION AND INFORMATION ON INGREDIENTS Ingredients determined not to be hazardous are present in concentrations that do not exceed the relevant cut-off concentrations as found from NOHSC publication “List of Designated Hazardous Substances” or have been found NOT to meet the criteria of a hazardous substance as defined in the NOHSC publication “Approved Criteria for Classifying Hazardous Substances”. Ingredients: CAS Proportion: Exposure Exposure Number: Standards Standards STEL TWA 1000ppm Ethanol 64-17-5 < 10% w/w Not set 1880 mg/m3 400ppm 500ppm Isopropyl alcohol 67-63-0 > 60 % w/w (983 mg/m3) (1230 mg/m3) Ingredients determined not to be hazardous Various <10% w/w Not set Not set Water 7732-18-5 10 –30% w/w Not set Not set The TWA exposure value is the Time Weighted Average airborne concentration of a particular substance when calculated over a normal 8-hour working day for a 5-day working week. The STEL (Short Term Exposure Limit) is an exposure value that should not be exceeded for more than 15 minutes and should not be repeated for more than 4 times per day. There should be
  • 2. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 2 of Total 7 at least 60 minutes between successive exposures at the STEL. The term “peak” is used when the TWA limit, because of the rapid action of the substance, should never be exceeded, even briefly. ____________________________________________________________________________________________ SECTION 4 – FIRST AID MEASURES Scheduled Poisons Poisons Information Centre in each Australian State capital city or in Christchurch, New Zealand can provide additional assistance for scheduled poisons. (Phone Australia 131126 or New Zealand 03 474 7000). First Aid Facilities Normal washroom facilities. Skin contact Wash skin with plenty of water. Remove contaminated clothing and wash before re-use. Seek medical advice (e.g. doctor) if irritation, burning or redness develops. Eye contact Immediately irrigate with copious quantities of water for at least 20 minutes. Eyelids to be held open. Seek medical advice (e.g. ophthalmologist). Ingestion Do NOT induce vomiting. Do NOT attempt to give anything by mouth to an unconscious person. Rinse mouth thoroughly with water immediately. Give water to drink. If vomiting occurs, give further water to achieve effective dilution. Seek medical advice (e.g. doctor). Inhalation Remove victim to fresh air away from exposure. Obtain medical attention if symptoms occur. Advice to Doctor Treat symptomatically. All treatments should be based on observed signs and symptoms of distress of the patient. Poisons Information Centre in each Australian State capital city or in Christchurch, New Zealand can provide additional assistance for scheduled poisons. Aggravated Medical Conditions None known. SECTION 5 – FIRE FIGHTING MEASURES Fire and Explosion Combustion products include oxides of carbon and unidentified organic and inorganic Hazards compounds. Extinguishing Media Keep containers exposed to extreme heat cool with water spray. Use an extinguishing media such as Carbon dioxide, foam or dry chemical, water fog/spray. Fire Fighting Combustion products include oxides of carbon and unidentified organic and inorganic compounds. Fire fighters to wear self-contained breathing apparatus if risk of exposure to products of combustion or decomposition. Flash Point < 20 °C (literature value) SECTION 6 – ACCIDENTAL RELEASE MEASURES Emergency HAZCHEM code: 3[Y]E Procedures 3 = use FOAM to fight fires. [Y] = Yes – risk of violent reaction, recommend-breathing apparatus for fire only, contain.  Shut off engine and electrical equipment off.  No smoking or naked lights within 50 metres.  Move people from immediate area; keep upwind.  Send messenger to notify fire brigade and police.  Tell them location, material quantity, UN number and emergency contact.  Indicate condition of vehicle and damage or injuries observed.  Warn other traffic. E = Consider evacuation. Occupational Release Minor spills do not normally need any special clean-up measures. In the event of a major spill, prevent spillage from entering drains or watercourses. For large spills, or tank
  • 3. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 3 of Total 7 rupture, consider initial evacuation distance of 200 metres in all directions. Stop leak if safe to do so. If available, use water spray to disperse vapour. Wear appropriate protective equipment as in section 8 below to prevent skin and eye contamination. Spilt material may result in a slip hazard and should be absorbed into dry, inert material (e.g. sand, earth or vermiculite), which then can be put into appropriately labeled drums for disposal by an approved agent according to local conditions. Residual deposits will remain slippery. Wash area down with excess water. If contamination of sewers or waterways has occurred advise the local emergency services. In the event of a large spillage notify the local environment protection authority or emergency services. SECTION 7 – HANDLING AND STORAGE Handling Avoid contact with incompatible materials. When handling, DO NOT eat, drink or smoke. Keep containers closed at all times. Avoid physical damage to containers. Always wash hands with water after handling. Do not breathe vapour, spray, and mists. Use local exhaust extraction. Extinguish any naked flames. Remove ignition sources. Avoid sparks. Do not smoke. Take precautionary measures against static discharges. Earth all equipment. Do not empty into drains. Storage Store in a cool, dry, place with good ventilation. Store away from incompatible materials (Section 10). Keep containers closed at all times – check regularly for leaks. Keep container tightly closed and in a well-ventilated place. Keep away from direct sunlight and other sources of heat or ignition. Do not smoke in storage areas. SECTION 8 – EXPOSURE CONTROLS AND PERSONAL PROTECTION Exposure Limits National Occupational Exposure Limits, as published by National Occupational Health & Safety Commission: Time-weighted Average (TWA): None established for specific product. See SECTION 3 for Exposure Limits of individual ingredients. Short Term Exposure Limit (STEL): None established for specific product. See SECTION 3 for Exposure Limits of individual ingredients. Biological Limit Value None established for product. Engineering Controls Ensure ventilation is adequate to maintain air concentrations below exposure standards. Avoid generating mists of the product. Use only in a well-ventilated area. Ensure airflow, where this product is used, is directed away from the operators. Personal Protective Use good occupational work practice. The use of protective clothing and equipment Equipment depends upon the degree and nature of exposure. Final choice of appropriate protection will vary according to individual circumstances i.e. methods of handling or engineering controls and according to risk assessments undertaken. The following protective equipment should be available; Eye Protection Generally not required to handle the product as per label directions. The use of safety glasses with side shield protection, goggles or face shield is recommended to handle in quantity, cleaning up spills, decanting, etc. Contact lenses pose a special hazard; soft lenses may absorb irritants and all lenses concentrate them. Skin Protection Generally not required to handle the product as per label directions – hand cleaner/sanitizer. Overalls, work boots and gloves are recommended for handling the concentrated product
  • 4. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 4 of Total 7 (as per AS/NZS 2161, or as recommended by supplier) to handle in quantity, cleaning up spills, decanting, etc. Protective Material Material suitable for detergent contact – Butyl rubber, Natural Latex, Neoprene, PVC, and Types Nitrile. Respirator Generally not required to handle the product as per label directions. If engineering controls are not effective in controlling airborne exposure then respiratory protective equipment should be used suitable for protecting against airborne contaminants. Final choice of appropriate breathing protection is dependant upon actual airborne concentrations and the type of breathing protection required will vary according to individual circumstances. Expert advice may be required to make this decision. Reference should be made to Australian Standards AS/NZS 1715, Selection, Use and maintenance of Respiratory Protective Devices; and AS/NZS 1716, Respiratory Protective Devices. SECTION 9 – PHYSICAL AND CHEMICAL PROPERTIES Physical State Liquid gel Colour Clear to slightly hazy liquid Odour Citrus odour Specific Gravity < 1.0 @ 25 °C Boiling Point Approximately 70 °C Freezing Point Not available Vapour Pressure Not available Vapour Density Not available Flash Point < 20 °C Flammable Limits LEL: 2.2%v, UEL: 12.7%v Water Solubility Miscible in all proportions pH 6.0 – 8.0 neat Volatile Organic Coefficient of Water/Oil Not available Compounds (VOC) Distribution Not available Viscosity Not available Odour Threshold Not available Evaporation Rate Not available Per Cent Volatile Ca 96 % v/v SECTION 10 – STABILITY AND REACTIVITY Chemical Stability Stable at normal temperatures and pressure. Conditions to Avoid Excessive heat, sources of ignition. Incompatible Materials Strong oxidizing agents. Hazardous Product can decompose on combustion to form Carbon Monoxide, Carbon Dioxide, and Decomposition other possibly toxic gases and vapours. Hazardous Reactions None known. SECTION 11 – TOXICOLOGICAL INFORMATION PRODUCT MIXTURE INFORMATION Local Effects Mild irritant: eye, skin, inhalation and ingestion. Target Organs Eyes, mucous membranes, skin, lungs. POTENTIAL HEALTH EFFECTS Ingestion Short term exposure Swallowing large amounts of this product can cause stomach irritation, nausea and diarrhea. Aspiration of liquid into the lungs can produce chemical pneumonia. Long term exposure No information available. Skin contact Short term exposure Properly used wash solutions not expected to be irritating. Prolonged contact with concentrated solutions may have a degreasing effect on skin.
  • 5. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 5 of Total 7 Long term exposure Prolonged and repeated skin contact with solutions may induce eczematoid dermatitis in certain individuals. Eye contact Short term exposure This product may cause eye irritation, watering, and redness. Long term exposure No information available. Inhalation short term exposure Irritating to respiratory system, drowsiness. Vapor may cause dizziness and headache. Mist may cause breathing problems. long term exposure No information available. Carcinogen Status NOHSC No significant ingredient is classified as carcinogenic by NOHSC. NTP No significant ingredient is classified as carcinogenic by NTP. IARC No significant ingredient is classified as carcinogenic by IARC. Medical conditions aggravated by exposure No information available. CLASSIFICATION OF INDIVIDUAL INGREDIENTS NOTE : This information relates to each individual ingredient, when evaluated as pure undiluted chemical. See SECTION 3 for actual proportions of ingredients present in this product. Ingredients R-Phrases. Isopropanol R11 Highly flammable. R36 Irritating to eyes. Ethanol R11 INDIVIDUAL INGREDIENT INFORMATION ETHANOL 100% Irritation Data Moderately irritating to skin – may cause redness. Moderately irritating to eyes – may injure tissue. Moderately irritating to respiratory system and mucous membranes. Toxicity Data Excessive chronic absorption may result in liver damage. LD50 oral (rat) : 2080 mg/kg. LD50 oral (rat) : 13.9 g/kg Local Effects Absorbed into the body by inhalation and ingestion. Irritant of sensitive tissues, eg eyes and mucous membranes. Central nervous system depression. Target Organs Eyes, mucous membranes, liver, central nervous system. Acute Toxicity Level Mild toxicity. Narcotic properties: ingestion. Mutagenic Data No available information. Reproductive Effects No available information. ISOPROPYL ALCOHOL 100% Irritation Data Vapour concentrations above recommended exposure levels may be irritating to the eyes and the respiratory tract, may cause headaches and dizziness could be anesthetic and may have other central nervous system effects. Negligible hazard at ambient temperature (-18 to 38°C). Skin irritation test (rabbit): Slight irritations. Toxicity Data Acute oral toxicity: LD50 = 5045 mg/kg (rat). Acute dermal toxicity: LD50= 12500 mg/kg (rabbit). Acute toxicity of the vapour: LC50= 16970 ppm 4hrs (rat). Chronic effects on humans: developmental toxicity – Proven – the substance is toxic to kidneys, lungs, the nervous system, the reproductive system, liver, immune system, eyes, skin. Local Effects Irritant: inhalation, skin, eye. Mutagenic Data Mutagenicity (test of mammal cells): negative. Bacterian Mutagenicity: Salmonella typhimurium: negative. Bacterian Mutagenicity: Ames-Test: negative Reproductive Data There were no indications of developmental toxicity in the rabbits at any exposure level. Findings from a multigeneration oral reproduction study indicate that infant and immature rats are more sensitive than their parents to the acute oral toxicity induced by high (1000 mg/kg/day) doses of Isopropanol. The effect levels for rats and rabbits were at several times the maximum exposure that would occur at the TLV.
  • 6. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 6 of Total 7 SECTION 12 – ECOLOGICAL INFORMATION Fish toxicity None available for specific product. For major ingredient ISOPROPANOL: P. Promelas CL50 : 9640 mg/l /96h. Algae toxicity None available for specific product. For major ingredient ISOPROPANOL: Desmodesmus subspicatus IC50 : > 1000 mg/l /72h. Invertebrates toxicity None available for specific product. For major ingredient ISOPROPANOL: Daphnia magna EC50: 13299 mg/l /48h. Toxicity to Bacteria None available for specific product. For major ingredient ISOPROPANOL: Photobacterium phosphoreum CE50 : 22000 mg/l /15min. Microtox test. Bacterial toxic concentration limit: Ps. putida CE5 : 1050 mg/l /16h. M. Aeruginosa CE5: 1000mg/l /8d. OECD Biological Biological degradability: 95% /21d. degradation Biological degradability: good Individual components stated to be biodegradable. General Product miscible in all proportions with water. AS WITH ANY CHEMICAL PRODUCT, DO NOT DISCHARGE BULK QUANTITIES INTO DRAINS, WATERWAYS, SEWER OR ENVIRONMENT. Inform local authorities if this occurs. When introduced properly, no impairments in the function of adapted biological waste-water-treatment plants are to be expected. No ecological problems are to be expected when the product is handled and used with due care and attention. SECTION 13 – DISPOSAL CONSIDERATIONS Disposal To dispose of quantities of undiluted product, refer to State Land Waste Management Authority. Transfer product residues to a labelled, sealed container for disposal or recovery. Waste disposal must be by an accredited contractor. As with any chemical, do not put down the drain in quantity. The small quantities contained in wash solutions (when used as directed) can generally be handled by conventional sewage systems, septics, and grey water systems. For larger scale use, eg. Commercial laundry operations, a recycled water system is often recommended, or Trade Waste License obtained for disposal to sewer. SECTION 14 – TRANSPORT INFORMATION UN Number 1193 ADG Classification 3 Shipping Name Class FLAMMABLE LIQUIDS, N.O.S. (ETHANOL, ISOPROPANOL) Hazchem Code 3[Y]E Packing Group II SUSDP Classification None allocated ADG Subsidiary Risk None allocated Packaging Method 3.8.3 RT1 Special Provisions SP109, SP129, SP274 Segregation Class 3 – Flammable liquid shall not be loaded in the same vehicle or packed in the same freight container with:  Class 1, Explosives  Class 2.1, Flammable Gases, if both the Class 3 and Class 2.1 dangerous goods are in bulk  Class 2.3, Toxic Gases  Class 4.2 Spontaneously Combustible Substances  Class 5.1 Oxidizing Agents and Class 5.2, Organic Peroxides  Class 6 Toxic Substances (where the flammable liquid is nitro methane)  Class 7 Radioactive Substances.
  • 7. MATERIAL SAFETY DATA SHEET KOALA AUTO KARE Product: HAND SANITIZER Date of Issue: JAN 2010 Page 7 of Total 7  Foodstuff and foodstuff empties SECTION 15 – REGULATORY INFORMATION AICS All ingredients present on AICS. Labeling Details HAZARD FLAMMABLE RISK PHRASES R11 – Highly flammable. SAFETY PHRASES S2 - Keep out of reach of children. S16 - Keep away from sources of ignition. S 45 - In case of accident, or if you feel unwell, seek medical advice immediately (show the label wherever possible). SUSDP Not scheduled ADG Code Class 3 Flammable SECTION 16 – OTHER INFORMATION Acronyms SUSDP Standard for the Uniform Scheduling of Drugs and Poisons. ADG Code Australian Code for the Transport of Dangerous Goods by Road and Rail. CAS Number Chemical Abstracts Service Registry Number. UN Number United Nations Number. R-Phrases Risk Phrases. HAZCHEM An emergency action code of numbers and letters, which gives information to emergency services. NOHSC National Occupational Health and Safety Commission. NTP National Toxicology Program (USA). IARC International Agency for Research on Cancer. AICS Australian Inventory of Chemical Substances. TWA Time Weighted Average STEL Short Term Exposure Limit Literature References List of Designated Hazardous Substances [NOHSC:10005(1999)] Australian Code For The Transport Of Dangerous Goods By Road And Rail – Sixth Edition. Standard for the Uniform Scheduling of Drugs and Poisons. National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011(2003)] Approved Criteria for Classifying Hazardous Substances [NOHSC:1008(1999)] Material Safety Data Sheets – individual raw materials – Suppliers. HSIS – Hazardous Substance Information System – National Worksafe Data Base. Revision Information New Issue to standard: 2nd Edition [NOHSC:2011(2003)]. Note Safety Data Sheets are updated frequently. Please ensure that you have a current copy. Contact Point Regulatory Affairs Manager. Telephone 07 3807 7400 Issue Date JAN 2010 Supersedes Issue Date 1ST issue This MSDS summarizes at the date of issue our best knowledge of the health and safety hazard information of this product, and in particular how to safely handle and use this product in the workplace. Since the supplier cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, review this MSDS in the context of how the user intends to handle and use the product in the workplace. If clarification or further information is needed to ensure that an appropriate assessment can be made, the user should contact this supplier.