White Paper Biopolymer In Interior Protection Products
1. White Paper
Biopolymer in Interior Protection Products:
The quest for durability and economy
In everything you build, there’s
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3. Biopolymer in Interior Protection Products:
White Paper
The quest for durability and economy
Executive Summary
With the rise in concern over sustainability, members of the design community have increasingly
demanded alternative plastics. Ideally, all manufacturers should be moving toward what are
known as biopolymers or bioplastics – those polymers derived from renewable and often plant-
based sources. As with any pioneering venture, R&D and the actual production of bioplastics in
architectural products are fraught with their own challenges to producing durable products at
price levels acceptable to the market. In addition, some have raised concerns that production of
biopolymers may divert potential arable land from food production to industrial goods agriculture,
with supposed impacts on world hunger.
Definition of Interior Protection Products
It’s important for us to define what we mean by interior protection products:
They are items installed to help keep the interior of a building looking newer longer by reducing the
amount of damage to doors and walls from carts, equipment, etc. and include:
• Rigid sheet wall cladding
• Impact-resistant handrails
• Wall guards/Crash rails
• Corner Guards
• Door Frame Guards/Door Edge Protectors
• Kickplates and fully clad doors
These are items found primarily in CSI MasterFormat section 10 26 00 – Wall and door protection.
The move to sustainable plastics
Figure 1 represents what we’re calling “the continuum of plastic,” which illustrates the desire by many in
the sustainable community to move further “away” from fossil fuel-based plastics, in other words using
less and less coal, crude oil or natural gas and their derivatives.
Fig. 1
The Continuum of Plastic
Polyvinyl Chloride Polycarbonate/Acrylontirile Polyethylene Terephthalate High Density Polyethylene PETG + Polylactic acid
More than half of all Polycarbonates are a Next are the polyesters HDPE is probably best Biopolymer blends hold
construction products in the U.S. family of extremely with the abbreviations known as the material the current position as
are manufactured from vinyl durable plastics that are PET and PETG. Bottled used to make milk jugs, the best plastic due to
because of its durability, easy easily worked, molded water and other beverages and is recycled into lower fossil-fuel use.
installation, cost-e ectiveness and thermoformed. are packaged in PET. plastic lumber.
and ame resistance.
4. Polyvinyl chlorideof Plastic
The Continuum (PVC)/Vinyl
Polyvinyl Chloride
More than half of all
construction products in the U.S.
White Paper are manufactured from vinyl
because of its durability, easy
installation, cost-e ectiveness
and ame resistance.
Common construction uses for vinyl are: residential siding and windows, wall covering, flooring, piping,
and membrane roofing. For interior protection, rigid PVC is an excellent choice both for its impact
resistance, color consistency, moldability and lower price point.
According to the U.S. Energy Information Administration, in 2006, about 331 million barrels of liquid
petroleum gases (LPG) and natural gas liquids (NGL) were used to make plastic products in the
plastic materials and resins industry in the United States. This represents 4.6% of total U.S. petroleum
consumption.
Almost 60 percent of the chemical makeup of Polyvinyl chloride (PVC) comes from salt. The manufacture
of PVC is more energy intensive – high amounts of heat must be used to break apart the sodium chloride
(NaCl) molecule to render the pure chloride needed to make vinyl monomer, the base PVC.
When it comes to architectural products, no other material delivers higher levels of durability, more ability
to be molded into an infinite number of shapes and colors, or the economics of vinyl. It is by far the most
durable, cost effective building material when a pound-for-pound comparison is made.
Nonetheless, the AEC community asked manufacturers to seek new alternatives to PVC. They wanted
choices. And, for manufacturers, seeking less fossil fuel-based materials reduces exposure to serious price
fluctuations in crude oil markets – producers want less commodity price volatility.
What is “Infrastructure Plastic”?
Vinyl is often referred to as the “infrastructure plastic,” and with good reason. More than half of all vinyl produced annually in the United
States is used to manufacture construction or furnishing products, and more vinyl is used in construction than any other plastic. Vinyl is used
so widely in the construction industry because of its durability, easy installation and cost-effectiveness. What’s more, the chlorine content in
vinyl makes it inherently flame resistant.
PC/ABS
The Continuum of Plastic
Polyvinyl Chloride Polycarbonate/Acrylontirile
More than half of all Polycarbonates are a
construction products in the U.S. family of extremely
are manufactured from vinyl durable plastics that are
because of its durability, easy easily worked, molded
installation, cost-e ectiveness and thermoformed.
and ame resistance.
As we move to the right on the continuum, we come to the next types of plastic: polycarbonate/
acrylonitrile butadiene styrene, or simply PC/ABS.
Polycarbonates are a family of extremely durable plastics that are easily worked, molded and
thermoformed. These plastics are probably best known to consumers as the base material for CDs, DVDs
and Blu-ray Discs™, and are also used in police riot shields and automotive applications. The cockpit
canopy of the USAF F-22 Raptor jet fighter is made from a piece of high optical-quality polycarbonate.
ABS’s light weight and ability to be injection molded and extruded make it useful in numerous
manufacturing products, such as drain-waste-vent pipe systems, musical instruments, golf club heads,
automotive bumper bars, protective headgear, whitewater canoes, small kitchen appliances, and toys,
including LEGO® bricks.
As you can guess, PC/ABS is a blend of these two plastics that yields a stronger plastic. In architectural
applications, PC/ABS is an extremely durable material for wall and door protection products.
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http://www.azom.com/article.aspx?ArticleID=988
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http://205.254.135.24/tools/faqs/faq.cfm?id=34&t=6
5. PETG
The Continuum of Plastic
Polyvinyl Chloride Polycarbonate/Acrylontirile Polyethylene Terephthalate
More than half of all Polycarbonates are a Next are the polyesters
construction products in the U.S. family of extremely with the abbreviations
White Paper are manufactured from vinyl durable plastics that are PET and PETG. Bottled
because of its durability, easy easily worked, molded water and other beverages
installation, cost-e ectiveness and thermoformed. are packaged in PET.
and ame resistance.
Next on the continuum are the polyesters. The official names are polyethylene terephthalate (PET), and
glycol-modified polyethylene terephthalate (PETG). They are thermoplastic polymer resins of the polyester
family and are used extensively in the manufacture of beverage, food and other liquid containers. Look at
the bottom of your water bottle, and you’ll likely see the PET abbreviation.
PETG is used extensively in clear shelving in retail product and point-of-purchase display applications.
In addition, through a process called encapsulation, decorative panels can be produced by sandwiching
design elements in between two translucent PETG sheets . In addition, PETG has proven to be a
tremendous base material for interior signage. However, unless UV stabilizers are added, PETG does not
hold up well in exterior applications.
PETG, a derivative or co-polymer of PET, is a clear amorphous thermoplastic that can be injection
molded or sheet extruded. It can be colored during processing. When considering application in interior
protection products, like crash rails for instance, PETG showed great promise in the quest for alternatives
to other plastics.
However, when used in building materials, PETG has a significant flaw – while more durable than many
acrylics, it can be extremely brittle. This leads to two problems in the field:
• Installers have trouble cutting and trimming PETG products – the material can splinter and shatter,
which leaves a risk of sharp edges that can injure the craftsman. The brittleness can also lead to
greater waste since broken parts must be discarded.
• Poorer impact resistance – the whole purpose of interior protection products is to often absorb impact
from carts and equipment. PETG in its pure form can’t take hard abuse … it cracks and breaks.
So, while moving architecture away from oil-based polymers by using a more-sustainable plastic, there
are serous drawbacks to using pure PETG in building materials due to its inherent brittleness.
HDPE
The Continuum of Plastic
Polyvinyl Chloride Polycarbonate/Acrylontirile Polyethylene Terephthalate High Density Polyethylene
More than half of all Polycarbonates are a Next are the polyesters HDPE is probably best
construction products in the U.S. family of extremely with the abbreviations known as the material
are manufactured from vinyl durable plastics that are PET and PETG. Bottled used to make milk jugs,
because of its durability, easy easily worked, molded water and other beverages and is recycled into
installation, cost-e ectiveness and thermoformed. are packaged in PET. plastic lumber.
and ame resistance.
Moving along the continuum, we come to High Density Polyethylene (HDPE), another of the petroplastics,
that is probably best known as the material used to produce milk jugs. Additional applications include
plastic lumber, folding chairs and tables, and use in plastic surgery for skeletal and facial reconstruction.
Because of its high recyclability, HDPE consumer packaging can be reborn in other goods and materials.
For interior protection products, the biggest gains come in the use of heavy HDPE plastic lumber for back-
of-house applications at hotels, casinos and hospitals. For instance, to date, one company has placed more
than 13 miles of HDPE wall guard at various Las Vegas resorts and casinos, primarily in service corridors,
kitchens and loading docks (see Fig. 2).
You can judge from its position on the continuum that HDPE is in a much better position than other
plastics. However, while excellent in certain applications, it not ideal when considering the aesthetic
qualities necessary for interior protection products.
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http://www.eastman.com/Company/Encapsulation_Technology/Pages/Encapsulation_Overview.aspx
6. Enter the Biopolymers
The Continuum of Plastic
Polyvinyl Chloride Polycarbonate/Acrylontirile Polyethylene Terephthalate High Density Polyethylene PETG + Polylactic acid
More than half of all Polycarbonates are a Next are the polyesters HDPE is probably best Biopolymer blends hold
construction products in the U.S. family of extremely with the abbreviations known as the material the current position as
PET and PETG. Bottled
White Paper
are manufactured from vinyl durable plastics that are used to make milk jugs, the best plastic due to
because of its durability, easy easily worked, molded water and other beverages and is recycled into lower fossil-fuel use.
installation, cost-e ectiveness and thermoformed. are packaged in PET. plastic lumber.
and ame resistance.
As we reach the right side of the continuum, biopolymers hold the current position as the ideal plastic,
and what all producers and users should strive for. They are considered the best by the fact they would
use the least amount of fossil fuel in their manufacture, and are derived from rapidly renewable sources.
As the name implies, biopolymers (or organic polymers) are a form of plastic derived from renewable
biomass sources, such as vegetable oil, corn starch, wheat gluten, or pea starch. Said another way, all
bioplastics begin with a living organism.
While there are numerous experimental forms of bioplastics being derived from such diverse sources
as algae and shrimp shells, we are going to confine our discussion here to industrial-grade, plant-based
biopolymers, and specifically polylactic acid (PLA). This focus on PLA will become apparent when we move
to the discussion of economics and price shortly.
Through the natural process of photosynthesis, plants produce and store carbon in starches. Much of
the biopolymer used for industrial production comes from “harvesting” the carbon in the starches and
breaking them down into natural sugars. Through natural fermentation (similar to making wine or beer)
and then distillation and purification, the plant starch becomes a ready-to-use plastic called polylactic
acid (PLA).
By far, the largest current users of bioplastics are producers of disposable items like packaging and food
serving utensils. The development of new and more-durable formulas should see bioplastics move into
the textiles, automotive and electronics industries.
One of the largest producers of plant-based biopolymer in the world is NatureWorks LLC, a joint venture
between U.S. agricultural giant Cargill and Teijin, a Japanese-based materials company. According to the
company’s website, the NatureWorks plant located in Blair, Nebraska, USA, has capacity to produce 300
million pounds (140,000 metric tons) of its Ingeo biopolymer.
For forward-thinking building products manufacturers, a huge leap will occur in 2012 with the adoption
of the U.S. Green Building Council LEED® 2012 standard. The current draft of the proposed standard
contains a Materials and Resources credit for bio-based building materials.
Next generation formula: Blending PETG and PLA
As we have already stated, introducing PETG certainly moves the interior protection industry in the right
direction by reducing the amount of fossil fuels needed to produce petroplastic-based building materials.
But, PETG was too brittle for products such as corner guards, impact-resistant handrails and wall guards.
The answer was found in the blending of PETG with other polymers in order to increase impact-resistance.
The economics of supply and demand
Like any commodity, the price of various plastics is driven by supply and demand. Given that PVC is
so prevalent in the construction of buildings – from piping to wall guards to residential siding and
membrane roofing – there is an abundant supply of base vinyl available. Like all petroplastics, there has
been greater price volatility with shifts in the world oil market, often driven by instability in the oil-
producing Middle East.
When it comes to bioplastics, the challenge for manufacturers is on the supply side – low-scale
experimentation with substances like algae and shrimp shells cannot produce adequate supply to offset
petroplastics. As a result, companies have to turn to the one source that is of sufficient supply and,
therefore, at a price that allows them to still profitably produce their products.
Until other biopolymer sources are discovered and perfected to the level of industrial production, plant-
based biopolymers – and specifically those derived from corn – are the only adequate source of bioplastic
available. Plant-based PLA is the only plastic that can be considered a commodity level bioplastic (i.e.,
large-scale production, homogenous quality and availability at a reasonable price).
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http://www.natureworksllc.com/
7. World food supply
We close this white paper with a brief discussion of bioplastic production and the question of supplying
food to the world. The argument goes something like this: If more crops are grown to make bioplastic,
won’t that take away land to grow food?
White Paper We have found that there has been little or no research on the “food vs. plastic” question. Perhaps it’s
too early in the bioplastics saga. However, one illuminating report was published in the Aril 2009 issue
of Bioplastics magazine. Entitled Land Use for Bioplastics , using solid statistical analysis, researchers
Michael Carus and Stephan Piotrowski of nova-Institute GmbH in Hürth, Germany, made several cogent
observations, which are paraphrased here:
• There is adequate land under cultivation as well as sufficient production to feed the world
• Hunger occurs due to failed distribution and logistics or inadequate financial resources
• Even with projected population growth, the amount of arable land available for cultivation should
support food needs and industrial demand well into the future
• Industrial use of crops to produce biofuels and bioplastics has had little or no impact on the prices
of consumable food crops
• Bioplastics have had an impact 250 times lower than the impact of biofuels, meaning bioplastics
have virtually no impact.
Let us close by saying that we are well aware of and sympathetic to instances of human suffering due to
starvation and malnutrition. We also are not advocating rampant industrial production over the needs
of the world’s population. However, we find that Msrs. Carus and Piotrowski observations offer the first
rational treatment of issue.
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http://bioplastics-cms.de/bioplastics/download/land_use_bioplasticsMAGAZINE_200904.pdf