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Water Quality
Water is a common chemical substance that is essential for the
survival of all known forms of life. In typical usage, water refers
only to its liquid form or state, but the substance also has a solid
state (ice), and a gaseous state (water vapor or steam).


                                         Solid (ice)
            Vapor




                          Liquid
Importance of Water

    To function properly, man needs at least 8
    glasses of water daily.
Water plays an important role in the world economy,
as it functions as a solvent for a wide variety of
chemical substances and facilitates industrial cooling
and transportation.
Approximately 70% of freshwater is consumed by
agriculture.

Different bodies of water provide livelihood and
economic security to different countries.
Water Quality

       Water quality is the physical, chemical, biological, and
       aesthetic characteristics of water which determines its
     fitness for a variety of uses and for protecting the health
                and integrity of aquatic ecosystems.


 Another general perception of water quality is that of a simple
      property that tells whether water is polluted or not.


 Water quality depends on the local geology and ecosystem, as
    well as human uses such as sewage dispersion, industrial
pollution, use of water bodies as a heat sink, and overuse (which
                may lower the level of the water).
SOURCES OF WATER

             &

WATER QUALITY CLASSIFICATION
Water Resource

     Surface Water is:
            - 97% saltwater (oceans and seas)
            - 2.4% glaciers and polar ice caps
            - 0.6% other land surface water such as rivers,
                  lakes, and ponds

 Ground Water – all water that saturates the tiny spaces between
   alluvial material (sands, gravel, silt, clay) or the crevices or
   fractures in rocks. This includes the aeration zone, aquifers,
    saturation zones, capillary water, and water-bearing rocks.


  A very small amount of the Earth's water is contained within
water towers, biological bodies, manufactured products, and food
                              stores.
Philippine’s Water Resources

   The Philippines comprises more than 7,100 islands.
    Large bodies of water separated three major island
    groups: Luzon, Visayas, and Mindanao. Fishing is one
    of the major industries of the country. Aside from
    being a source of food and livelihood, water source
    plays an important role in other industries and
    domestic households.

   Water resources in the Philippines include inland fresh
    water, lake, and coastal and oceanic waters. Inland
    fresh water includes rivers, lakes, and ground water.

   There are 421 principal river basins, 19 are considered
    major river basins. Marine water encompasses coastal
    and oceanic water, the main source of fish and other
    aquatic plants and animals.
Water Quality in the Philippines
  Water quality protection and operation and maintenance of
   sanitation facilities are a collaborative undertaking of the
  Department of Environment and Natural Resources (DENR)
    through the Environmental Management Bureau (EMB),
   Department of Health (DOH), Department of Works and
                    Sewerage System (DWSS).

  The problem is that there are too many policies and laws
 about water quality that some of them are not implemented
and monitored properly, and some agencies have unclear and
                   overlapping mandates.

 To answer the growing problems of water quality several
investment projects were done to monitor and ensure safe
                         water.
For Coastal and Marine Waters (as amended by DAO 97-23)
   The Philippine government aims to maintain the quality
    of its surface waters according to their best beneficial
    use. This is embodied in the DENR Administrative Order
    (DAO) No. 34, which classifies bodies of water according
    to the degree of protection required.

   Class AA and SA have the most stringent water quality
    for fresh surface waters and marine/coastal waters; and
    D and SD waters have the least stringent water quality
    for fresh surface water and marine waters, respectively.

   Hot spots areas of surface water quality were assessed
    by province using Dissolved Oxygen (DO) and
    Biochemical Oxygen Demand (BOD) as parameters.
    Groundwater quality was assessed by using Total
    Dissolved Solids (TDS) and Coliform. Saltwater intrusion
    was mapped based on National Water Resources Board
    (NWRB) data.

   Other hot spots were identified and rated on the basis of
    the objective of recovering the water quality of surface
    waters (rivers, lakes, and bays) for beneficial use, i.e.,
    Class A (for fresh surface waters) for drinking, and Class
    SB ( for coastal and marine waters) for recreation.
Quality of Philippine Water
    Resources

   Over half of the Philippine rivers that were classified have
    lower quality and cannot be used for drinking unless
    treated.

   The coastal areas are densely populated thus causing
    water pollution.

   Philippines’s main source of water is rainfall. The surface
    and ground water quality shows the problem is getting
    severe in urban and coastal areas.

   Clean water should be the priority. Fifty-eight percent of
    ground water wells that were sampled were contaminated
    with coliform. Water contamination contributes to low
    water quality resulting in water pollution. This is the
    result of urbanization. As people flock into the metropolis
    and build homes, water quality problems arise.
Categories
 The parameters for water
 quality are determined by
 the intended use. Work in
 the area of water quality
 tends to be focused on
 water that is treated for
 human consumption or in
 the environment.
For Human Consumption or
     Drinking-Water
   World Health Organization has set the Guidelines for
    Drinking-water Quality of which the primary purpose is
    the protection of public health.

   Water is essential to sustain life, and a satisfactory
    (adequate, safe, and accessible) supply must be
    available to all. Improving access to safe drinking-water
    can result in tangible benefits to health.

   The great majority of evident water-related problems
    are the result of microbial (bacteriological, viral,
    protozoan, or other biological) contamination.
    Nevertheless, an appreciable number of serious health
    problems may occur as a result of the chemical
    contamination of drinking water.
Human Consumption or Drinking-
    Water - Parameters

   Alkalinity
   Color of water
   pH
   Taste and odor
   Dissolved metals and salts (sodium, chloride, potassium,
    calcium, manganese, magnesium)
   Microorganisms such as fecal coliform bacteria
    (Escherichia coli), Cryptosporidium, and Giardia lamblia
   Dissolved metals and metalloids (lead, mercury, arsenic,
    etc.)
   Dissolved organics: colored dissolved organic matter
    (CDOM), dissolved organic carbon (DOC)
   Radon
   Heavy metals
Environmental Water Quality
  Also called ambient water quality, pertains to water bodies
                such as lakes, rivers, and oceans.

   Ambient water quality standards vary significantly due to
   different environmental conditions, ecosystems, and
   intended human uses.
Toxic substances and high populations of certain microorganisms
 can present a health hazard for non-drinking purposes such as
  irrigation, swimming, fishing, rafting, boating, and industrial
  uses. These conditions may also affect wildlife which use the
  water for drinking or as a habitat. Modern water quality laws
    general specify protection of fishable/swimmable use and
               antidegradation of current conditions.
Environmental Water Quality
    Environmental advocates express desires to return water
         bodies to pristine, or pre-industrial conditions.

  Current environmental laws focus of the designation of
  uses and therefore allow for some water contamination as
  long as the particular type of contamination is not harmful
  to the designated uses.

   Given the landscape changes in the watersheds of many
freshwater bodies, returning to pristine conditions would be a
significant challenge. In these cases, environmental scientists
    focus on achieving goals for maintaining populations of
       endangered species and protecting human health.
Environmental Water Quality –
    Parameters

   Physical Properties
    Color, odor, temperature, solids (residues), turbidity,
    oil content, and grease content.

   Chemical Properties
    - pH
    -   Conductivity
    -   Dissolved oxygen (DO)
    -   Nitrate
    -   Orthophosphate
    -   Chemical oxygen demand (COD)
    -   Biochemical oxygen demand (BOD)
    -   Pesticides

   Biological Properties
    Bacteriological parameters: coliforms, fecal coliforms,
      specific pathogens, and viruses.
COMPONENTS OF WATER QUALITY
 (microbial, biological, chemical, and physical aspects)
                            &
               MEASUREMENTS
Components of Water Quality
      Microbial Aspect



   Drinking water should not include microorganisms that are
                    known to be pathogenic.

       It should also not contain bacteria that would indicate
     excremental pollution, the primary indicator of which are
 coliform bacteria that are present in the feces of warm-blooded
                             organisms.

 Chlorine is the usual disinfectant, as it is readily available and
inexpensive. Unfortunately, it is not fully effective, as currently
                   used, against all organisms.
Components of Water Quality
      Biological Aspect

     Parasitic protozoa and helminths are also indicators of
    water quality. Species of protozoa can be introduced into
          water supply through human or animal fecal
                         contamination.

      Most common among the pathogenic protozoans are
                 Entamoeba and Giardia.

 Coliforms are not appropriate direct indicators because of the
   greater resistance of these protozoans to inactivation by
                          disinfection.

A single mature larva or fertilized egg of parasitic roundworms
and flatworms can cause infection when transmitted to humans
                    through drinking water.
Components of Water Quality
       Chemical Aspect

     Chemical contamination of water sources may be due to
   certain industries and agricultural practices, or from natural
                             sources.


  When toxic chemicals are present in drinking water, there is the
   potential that they may cause either acute or chronic health
                             effects.



  Chronic health effects are more common than acute effects
because the level of chemicals in drinking water are seldom high
             enough to cause acute health effects.
Components of Water Quality
        Physical Aspect

        The turbidity, color, taste, and odor of water can be
                              monitored.
   Turbidity should always be low, especially where disinfection is
    practiced. High turbidity can inhibit the effects of disinfection
        against microorganisms and enable bacterial growth.
Drinking water should be colorless, since coloration may be due to
             the presence of colored organic matter.

Organic substances also cause water odor, though odors may result
   from many factors, including biological activity and industrial
                            pollution.
  Taste problems relating to water could be indicators of changes
   in water sources or treatment process. Inorganic compounds
   such as Mg, Ca, Na, Cu, Fe, and Zn are generally detected by
                         the taste of water.
Water Quality Measurement

The complexity of water quality as a subject is reflected
in the many types of measurements of water quality
indicators. Some measurements that can be made on-
site are temperature, pH, dissolved oxygen, and
conductivity.

More complex measurements that must be made in
a laboratory setting require a water sample to be
collected, preserved, and analyzed at another
location (e.g., microbiological tests).
Measurement #1
       pH
   pH, or the "potential of hydrogen", is a measure of the
    concentration of hydrogen ions in the water.

   This measurement indicates the acidity or alkalinity of the
    water. On the pH scale of 0 - 14, a reading of 7 is
    considered to be "neutral." Readings below 7 indicate
    acidic conditions, while readings above 7 indicate the water
    is alkaline or basic.

   Naturally occurring fresh waters have a pH range between
    6.5 and 8.5. The pH of the water is important because it
    affects the solubility and availability of nutrients, and how
    they can be utilized by aquatic organisms.

   The main significance of pH in domestic water supplies
    relates to its effects on water treatment.
Measurement #1
     pH
The pH of a water does not have direct health consequences
except at extremes:
   - pH <4.0, severe danger of health effects due to dissolved
         toxic metal ions are expected. Water tastes sour.
  - At pH 4.0 – 6.0, toxic effects associated with dissolved
metals, including lead, are likely to occur. Water tastes slightly
                               sour.
   - At target water quality range of 6.0 to 9.0, no significant
                  effects on health are expected.
  - At pH 9.0 – 11.0, the probability of toxic effects associated
    with deprotonated species increases sharply. Water tastes
                                bitter.
   - At pH>11.0 – severe danger of health effects due to
          deprotonated species. Water tastes soapy.

Treatment option would be the addition of an acid or an
                       alkali.
Measurement # 2
Dissolved Oxygen (DO)
   Dissolved oxygen is the amount of oxygen dissolved
    in water, measured in milligrams per liter (mg/L).

   This component in water is critical to the survival of
    various aquatic life in streams, such as fish.

   The ability of water to hold oxygen in solution is
    inversely proportional to the temperature of the
    water. For example, the cooler the water
    temperature, the more dissolved oxygen it can hold.

   Common standard for water is that DO is at 8.0 mg/L

   The Philippines standard is 5 mg/L
Measurement #3
    Biological Oxygen Demand (BOD)

   Biological Oxygen Demand is a measure of how
    much oxygen is used by microorganisms in the
    aerobic oxidation, or breakdown of organic matter
    in the streams.

   Usually, the higher the amount of organic material
    found in the stream, the more oxygen is used for
    aerobic oxidation.

   This depletes the amount of dissolved oxygen
    available to other aquatic life. This measurement is
    obtained over a period of five days, and is
    expressed in mg/L.

   Philippines standard for BOD in water is not more
    than 5 mg/L
Surface Water Class A and Coastal
 and Marine Water Class SB


               DO mg/L                   BOD mg/L
Satisfactory (S)     >5   Satisfactory (S)     <5
Marginal (M)         5    Marginal (M)         5
Unsatisfactory (U)   <5   Unsatisfactory (U)   >5
Minimum              5    Minimum              5
Requirement               Requirement
Measurement #4
Temperature

   Temperature is a measure of how cool or how
    warm the water is, expressed in degrees Celsius
    (C).

   Temperature is a critical water quality parameter,
    since it directly influences the amount of
    dissolved oxygen that is available to aquatic
    organisms.

   Water temperature that exceeds 18°C (for Class A
    Waters) has a deleterious effect on several fish
    species in streams.

    Salmonids, for example, prefer waters of
    approximately 12 to 14 degrees Celsius.
Measurement #5
Conductivity

   Conductivity is the ability of the water to
    conduct an electrical current, and is an
    indirect measure of the ion concentration.

   The more ions present, such as that of
    carbonate, bicarbonate, chloride, suphate,
    nitrate, Na, K, Ca, and Mg, the more
    electricity can be conducted by the water.

   This measurement is expressed in
    microsiemens per centimeter (uS/cm) at
    25°C. The target water quality range is 0
    – 70.
Measurement #6
Total Dissolved Solids (TDS)

   Total dissolved solids is a measure of the amount
    of particulate solids that are in solution.

   This is an indicator of nonpoint source pollution
    problems associated with various land use
    practices.

   The TDS concentration is directly proportional to
    the electrical conductivity of water.

   Since conductivity is much easier to measure than
    TDS, it is routinely used as an estimate of the TDS
    concentration.

   TDS is expressed in (mg/L) with target water
    quality range of 0 – 450 mg/L.
Measurement #7
    Turbidity

   Turbidity is a measure of the clarity of the water.

   It is the amount of solids suspended in the water.

   It can be in the form of minerals or organic matter.

   It is a measure of the light scattering properties of
    water, thus an increase in the amount of suspended
    solid particles in the water may be visually described
    as cloudiness or muddiness.

   Turbidity is measured in Nephelometric Turbidity Units
    (NTU).

   Standard is 5 NTU’s
Measurement #8
Fecal Coliform Bacteria

   Fecal coliform bacteria are microscopic organisms
    that live in the intestines of all warm blooded
    animals, and in animal wastes or feces eliminated
    from the intestinal tract.

   Fecal coliform bacteria may indicate the presence
    of disease-carrying organisms which live in the
    same environment as the fecal coliform bacteria.

   The measurement is expressed as the number of
    organisms per 100 mL sample of water
    (#/100mL).

   Standard Fecal Coliform Bacteria is 100 organisms
    per 100 mL
Environmental Water Quality –
Biological Assessment

  Biological monitoring metrics have been developed in many
     places, and one widely used measure is the presence and
     abundance of members of the insect orders
     Ephemerontera (Mayfly), Plecoptera (Stonefly) and
     Trichoptera (Caddisfly)

  Generally, within a region, the greater the number of taxa
    from these orders, the better the water quality.

  Without the laboratory scale analysis, an individual can use
     this biological indicator to get a general reading of water
     quality (such as the benthic macro-invertebrate indicator
     key).
SOURCES OF CONTAMINATION
Sources of Contamination
   Construction and mining sites, disturbed land areas,
  streambank erosion and alterations, cultivated farmland
                           ***
   Fertilizer on agricultural, residential, commercial and
     recreational lawns, animal wastes, effluent from
   aquaculture facilities, leaky sewers and septic tanks,
      atmospheric deposition, municipal wastewater
                              ***
Pesticide applications, disinfectants (chlorine), automobile
fluids, accidental spills, illegal dumping, urban stormwater
                  runoff, industrial effluent
                              ***
Wastewater effluent, organic matter, leaking sewers and
              septic tanks, animal waste
Sources of Contamination
Failing septic tanks, animal waste, runoff from livestock
  operations, wildlife, improperly disinfected wastewater
                            effluent
                              ***
             Salt applications to snow and ice
                           ***
 Leaky automobiles, industrial areas, illegal dumping
                      ***
Hydrological modifications that influence the amount of
       fresh or saline waters entering a system
                          ***

 Heated landscape areas, runoff from impervious areas,
   tree removal along streams, wet detention ponds
MEANS OF TREATMENT
Means of Treatment

      Coagulation – the separation or precipitation of particles
        in a dispersed state from a suspension resulting from
         their growth. This may result from the addition of an
        electrolyte (coagulant), prolonged heating, or from a
         condensation reaction between a solvent and solute.
    Flocculation – the addition of chemical reagents
    (flocculants) to bring small particles together in flocs
    through the process of coagulation, aggregation, or
    biochemical reaction of fine suspended particles.


Ion exchange – the interchange of ions of like charge, usually on
  a solid medium and is used in water treatment, such as water
                           softening.
Means of Treatment

               Ozonation – disinfection using ozone.

    Reverse Osmosis – a technique in the desalination of
    water in which pressure is applied to the surface of the
    saline solution, forcing pure water to pass through a semi-
    permeable membrane which prevents passage of other
    ions.

Distillation – the process of producing gas or vapor from a liquid
     by heating the liquid in a vessel and then collecting and
                condensing the vapors into liquids.

   Electodialysis – the process of selective diffusion through a
   membrane conducted with the aid of an electromotive force
      applied to electrodes on both sides of the membrane.
Means of Treatment
   Disinfections – to kill living organisms (ex. chlorination,
    ozonation, use of potassium permanganate, UV light, or
                           silver ions.
  Filtrations/ultra-filtrations – ex. A bed of sand or
  pulverized coal, or through a matrix of fibrous material
  supported on a perforated core.
Adsorption – ex. using activated alumina, activated carbon or
                  activated carbon (GAC).
Aeration – a process of exposing water to air by dividing the
water into small drops, by forcing air through the water, or by
combination of both. It is used to add oxygen to water and to
remove CO2, hydrogen sulfide, and taste-producing gases or
                            vapors .

               Boiling – to kill some bacteria.
WATER QUALITY
 MANAGEMENT
Water Quality Management

Water quality management is the planning for the
protection of a water’s quality

    - for various beneficial use,

    - for the provision of adequate wastewater
      collection, treatment, and disposal of
      municipalities and industries, and

    - for activities that might create water quality
      problems, and regulating and enforcing
      programs to accomplish the planning goals, and
      law and regulations dealing with the water
      pollution control.
Water Quality Management

  The United Nations, in its recent examination of global
 water scarcity (1997) identified water quality as one of
     the key concerns in Asia in the next century. This
       concern is based on the fact that water quality
degradation is so severe in many Asian countries that it is
    placing serious constraints on economic growth. It
continues to be a serious problem for human health and it
  is causing widespread negative environmental effects.
MADAMO GUID NGA SALAMAT
         SA TANAN
SA INYO PAGPAMATI SA AKON
          REPORT

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Lecture 12. water quality

  • 2. Water is a common chemical substance that is essential for the survival of all known forms of life. In typical usage, water refers only to its liquid form or state, but the substance also has a solid state (ice), and a gaseous state (water vapor or steam). Solid (ice) Vapor Liquid
  • 3. Importance of Water To function properly, man needs at least 8 glasses of water daily. Water plays an important role in the world economy, as it functions as a solvent for a wide variety of chemical substances and facilitates industrial cooling and transportation. Approximately 70% of freshwater is consumed by agriculture. Different bodies of water provide livelihood and economic security to different countries.
  • 4. Water Quality Water quality is the physical, chemical, biological, and aesthetic characteristics of water which determines its fitness for a variety of uses and for protecting the health and integrity of aquatic ecosystems. Another general perception of water quality is that of a simple property that tells whether water is polluted or not. Water quality depends on the local geology and ecosystem, as well as human uses such as sewage dispersion, industrial pollution, use of water bodies as a heat sink, and overuse (which may lower the level of the water).
  • 5. SOURCES OF WATER & WATER QUALITY CLASSIFICATION
  • 6. Water Resource Surface Water is: - 97% saltwater (oceans and seas) - 2.4% glaciers and polar ice caps - 0.6% other land surface water such as rivers, lakes, and ponds Ground Water – all water that saturates the tiny spaces between alluvial material (sands, gravel, silt, clay) or the crevices or fractures in rocks. This includes the aeration zone, aquifers, saturation zones, capillary water, and water-bearing rocks. A very small amount of the Earth's water is contained within water towers, biological bodies, manufactured products, and food stores.
  • 7. Philippine’s Water Resources  The Philippines comprises more than 7,100 islands. Large bodies of water separated three major island groups: Luzon, Visayas, and Mindanao. Fishing is one of the major industries of the country. Aside from being a source of food and livelihood, water source plays an important role in other industries and domestic households.  Water resources in the Philippines include inland fresh water, lake, and coastal and oceanic waters. Inland fresh water includes rivers, lakes, and ground water.  There are 421 principal river basins, 19 are considered major river basins. Marine water encompasses coastal and oceanic water, the main source of fish and other aquatic plants and animals.
  • 8. Water Quality in the Philippines Water quality protection and operation and maintenance of sanitation facilities are a collaborative undertaking of the Department of Environment and Natural Resources (DENR) through the Environmental Management Bureau (EMB), Department of Health (DOH), Department of Works and Sewerage System (DWSS). The problem is that there are too many policies and laws about water quality that some of them are not implemented and monitored properly, and some agencies have unclear and overlapping mandates. To answer the growing problems of water quality several investment projects were done to monitor and ensure safe water.
  • 9.
  • 10.
  • 11. For Coastal and Marine Waters (as amended by DAO 97-23)
  • 12. The Philippine government aims to maintain the quality of its surface waters according to their best beneficial use. This is embodied in the DENR Administrative Order (DAO) No. 34, which classifies bodies of water according to the degree of protection required.  Class AA and SA have the most stringent water quality for fresh surface waters and marine/coastal waters; and D and SD waters have the least stringent water quality for fresh surface water and marine waters, respectively.  Hot spots areas of surface water quality were assessed by province using Dissolved Oxygen (DO) and Biochemical Oxygen Demand (BOD) as parameters. Groundwater quality was assessed by using Total Dissolved Solids (TDS) and Coliform. Saltwater intrusion was mapped based on National Water Resources Board (NWRB) data.  Other hot spots were identified and rated on the basis of the objective of recovering the water quality of surface waters (rivers, lakes, and bays) for beneficial use, i.e., Class A (for fresh surface waters) for drinking, and Class SB ( for coastal and marine waters) for recreation.
  • 13. Quality of Philippine Water Resources  Over half of the Philippine rivers that were classified have lower quality and cannot be used for drinking unless treated.  The coastal areas are densely populated thus causing water pollution.  Philippines’s main source of water is rainfall. The surface and ground water quality shows the problem is getting severe in urban and coastal areas.  Clean water should be the priority. Fifty-eight percent of ground water wells that were sampled were contaminated with coliform. Water contamination contributes to low water quality resulting in water pollution. This is the result of urbanization. As people flock into the metropolis and build homes, water quality problems arise.
  • 14.
  • 15. Categories The parameters for water quality are determined by the intended use. Work in the area of water quality tends to be focused on water that is treated for human consumption or in the environment.
  • 16. For Human Consumption or Drinking-Water  World Health Organization has set the Guidelines for Drinking-water Quality of which the primary purpose is the protection of public health.  Water is essential to sustain life, and a satisfactory (adequate, safe, and accessible) supply must be available to all. Improving access to safe drinking-water can result in tangible benefits to health.  The great majority of evident water-related problems are the result of microbial (bacteriological, viral, protozoan, or other biological) contamination. Nevertheless, an appreciable number of serious health problems may occur as a result of the chemical contamination of drinking water.
  • 17. Human Consumption or Drinking- Water - Parameters  Alkalinity  Color of water  pH  Taste and odor  Dissolved metals and salts (sodium, chloride, potassium, calcium, manganese, magnesium)  Microorganisms such as fecal coliform bacteria (Escherichia coli), Cryptosporidium, and Giardia lamblia  Dissolved metals and metalloids (lead, mercury, arsenic, etc.)  Dissolved organics: colored dissolved organic matter (CDOM), dissolved organic carbon (DOC)  Radon  Heavy metals
  • 18. Environmental Water Quality Also called ambient water quality, pertains to water bodies such as lakes, rivers, and oceans. Ambient water quality standards vary significantly due to different environmental conditions, ecosystems, and intended human uses. Toxic substances and high populations of certain microorganisms can present a health hazard for non-drinking purposes such as irrigation, swimming, fishing, rafting, boating, and industrial uses. These conditions may also affect wildlife which use the water for drinking or as a habitat. Modern water quality laws general specify protection of fishable/swimmable use and antidegradation of current conditions.
  • 19. Environmental Water Quality Environmental advocates express desires to return water bodies to pristine, or pre-industrial conditions. Current environmental laws focus of the designation of uses and therefore allow for some water contamination as long as the particular type of contamination is not harmful to the designated uses. Given the landscape changes in the watersheds of many freshwater bodies, returning to pristine conditions would be a significant challenge. In these cases, environmental scientists focus on achieving goals for maintaining populations of endangered species and protecting human health.
  • 20. Environmental Water Quality – Parameters  Physical Properties Color, odor, temperature, solids (residues), turbidity, oil content, and grease content.  Chemical Properties - pH - Conductivity - Dissolved oxygen (DO) - Nitrate - Orthophosphate - Chemical oxygen demand (COD) - Biochemical oxygen demand (BOD) - Pesticides  Biological Properties Bacteriological parameters: coliforms, fecal coliforms, specific pathogens, and viruses.
  • 21. COMPONENTS OF WATER QUALITY (microbial, biological, chemical, and physical aspects) & MEASUREMENTS
  • 22. Components of Water Quality Microbial Aspect Drinking water should not include microorganisms that are known to be pathogenic. It should also not contain bacteria that would indicate excremental pollution, the primary indicator of which are coliform bacteria that are present in the feces of warm-blooded organisms. Chlorine is the usual disinfectant, as it is readily available and inexpensive. Unfortunately, it is not fully effective, as currently used, against all organisms.
  • 23. Components of Water Quality Biological Aspect Parasitic protozoa and helminths are also indicators of water quality. Species of protozoa can be introduced into water supply through human or animal fecal contamination. Most common among the pathogenic protozoans are Entamoeba and Giardia. Coliforms are not appropriate direct indicators because of the greater resistance of these protozoans to inactivation by disinfection. A single mature larva or fertilized egg of parasitic roundworms and flatworms can cause infection when transmitted to humans through drinking water.
  • 24. Components of Water Quality Chemical Aspect Chemical contamination of water sources may be due to certain industries and agricultural practices, or from natural sources. When toxic chemicals are present in drinking water, there is the potential that they may cause either acute or chronic health effects. Chronic health effects are more common than acute effects because the level of chemicals in drinking water are seldom high enough to cause acute health effects.
  • 25. Components of Water Quality Physical Aspect The turbidity, color, taste, and odor of water can be monitored. Turbidity should always be low, especially where disinfection is practiced. High turbidity can inhibit the effects of disinfection against microorganisms and enable bacterial growth. Drinking water should be colorless, since coloration may be due to the presence of colored organic matter. Organic substances also cause water odor, though odors may result from many factors, including biological activity and industrial pollution. Taste problems relating to water could be indicators of changes in water sources or treatment process. Inorganic compounds such as Mg, Ca, Na, Cu, Fe, and Zn are generally detected by the taste of water.
  • 26. Water Quality Measurement The complexity of water quality as a subject is reflected in the many types of measurements of water quality indicators. Some measurements that can be made on- site are temperature, pH, dissolved oxygen, and conductivity. More complex measurements that must be made in a laboratory setting require a water sample to be collected, preserved, and analyzed at another location (e.g., microbiological tests).
  • 27. Measurement #1 pH  pH, or the "potential of hydrogen", is a measure of the concentration of hydrogen ions in the water.  This measurement indicates the acidity or alkalinity of the water. On the pH scale of 0 - 14, a reading of 7 is considered to be "neutral." Readings below 7 indicate acidic conditions, while readings above 7 indicate the water is alkaline or basic.  Naturally occurring fresh waters have a pH range between 6.5 and 8.5. The pH of the water is important because it affects the solubility and availability of nutrients, and how they can be utilized by aquatic organisms.  The main significance of pH in domestic water supplies relates to its effects on water treatment.
  • 28. Measurement #1 pH The pH of a water does not have direct health consequences except at extremes: - pH <4.0, severe danger of health effects due to dissolved toxic metal ions are expected. Water tastes sour. - At pH 4.0 – 6.0, toxic effects associated with dissolved metals, including lead, are likely to occur. Water tastes slightly sour. - At target water quality range of 6.0 to 9.0, no significant effects on health are expected. - At pH 9.0 – 11.0, the probability of toxic effects associated with deprotonated species increases sharply. Water tastes bitter. - At pH>11.0 – severe danger of health effects due to deprotonated species. Water tastes soapy. Treatment option would be the addition of an acid or an alkali.
  • 29. Measurement # 2 Dissolved Oxygen (DO)  Dissolved oxygen is the amount of oxygen dissolved in water, measured in milligrams per liter (mg/L).  This component in water is critical to the survival of various aquatic life in streams, such as fish.  The ability of water to hold oxygen in solution is inversely proportional to the temperature of the water. For example, the cooler the water temperature, the more dissolved oxygen it can hold.  Common standard for water is that DO is at 8.0 mg/L  The Philippines standard is 5 mg/L
  • 30. Measurement #3 Biological Oxygen Demand (BOD)  Biological Oxygen Demand is a measure of how much oxygen is used by microorganisms in the aerobic oxidation, or breakdown of organic matter in the streams.  Usually, the higher the amount of organic material found in the stream, the more oxygen is used for aerobic oxidation.  This depletes the amount of dissolved oxygen available to other aquatic life. This measurement is obtained over a period of five days, and is expressed in mg/L.  Philippines standard for BOD in water is not more than 5 mg/L
  • 31. Surface Water Class A and Coastal and Marine Water Class SB DO mg/L BOD mg/L Satisfactory (S) >5 Satisfactory (S) <5 Marginal (M) 5 Marginal (M) 5 Unsatisfactory (U) <5 Unsatisfactory (U) >5 Minimum 5 Minimum 5 Requirement Requirement
  • 32. Measurement #4 Temperature  Temperature is a measure of how cool or how warm the water is, expressed in degrees Celsius (C).  Temperature is a critical water quality parameter, since it directly influences the amount of dissolved oxygen that is available to aquatic organisms.  Water temperature that exceeds 18°C (for Class A Waters) has a deleterious effect on several fish species in streams.  Salmonids, for example, prefer waters of approximately 12 to 14 degrees Celsius.
  • 33. Measurement #5 Conductivity  Conductivity is the ability of the water to conduct an electrical current, and is an indirect measure of the ion concentration.  The more ions present, such as that of carbonate, bicarbonate, chloride, suphate, nitrate, Na, K, Ca, and Mg, the more electricity can be conducted by the water.  This measurement is expressed in microsiemens per centimeter (uS/cm) at 25°C. The target water quality range is 0 – 70.
  • 34. Measurement #6 Total Dissolved Solids (TDS)  Total dissolved solids is a measure of the amount of particulate solids that are in solution.  This is an indicator of nonpoint source pollution problems associated with various land use practices.  The TDS concentration is directly proportional to the electrical conductivity of water.  Since conductivity is much easier to measure than TDS, it is routinely used as an estimate of the TDS concentration.  TDS is expressed in (mg/L) with target water quality range of 0 – 450 mg/L.
  • 35. Measurement #7 Turbidity  Turbidity is a measure of the clarity of the water.  It is the amount of solids suspended in the water.  It can be in the form of minerals or organic matter.  It is a measure of the light scattering properties of water, thus an increase in the amount of suspended solid particles in the water may be visually described as cloudiness or muddiness.  Turbidity is measured in Nephelometric Turbidity Units (NTU).  Standard is 5 NTU’s
  • 36. Measurement #8 Fecal Coliform Bacteria  Fecal coliform bacteria are microscopic organisms that live in the intestines of all warm blooded animals, and in animal wastes or feces eliminated from the intestinal tract.  Fecal coliform bacteria may indicate the presence of disease-carrying organisms which live in the same environment as the fecal coliform bacteria.  The measurement is expressed as the number of organisms per 100 mL sample of water (#/100mL).  Standard Fecal Coliform Bacteria is 100 organisms per 100 mL
  • 37. Environmental Water Quality – Biological Assessment Biological monitoring metrics have been developed in many places, and one widely used measure is the presence and abundance of members of the insect orders Ephemerontera (Mayfly), Plecoptera (Stonefly) and Trichoptera (Caddisfly) Generally, within a region, the greater the number of taxa from these orders, the better the water quality. Without the laboratory scale analysis, an individual can use this biological indicator to get a general reading of water quality (such as the benthic macro-invertebrate indicator key).
  • 39. Sources of Contamination Construction and mining sites, disturbed land areas, streambank erosion and alterations, cultivated farmland *** Fertilizer on agricultural, residential, commercial and recreational lawns, animal wastes, effluent from aquaculture facilities, leaky sewers and septic tanks, atmospheric deposition, municipal wastewater *** Pesticide applications, disinfectants (chlorine), automobile fluids, accidental spills, illegal dumping, urban stormwater runoff, industrial effluent *** Wastewater effluent, organic matter, leaking sewers and septic tanks, animal waste
  • 40. Sources of Contamination Failing septic tanks, animal waste, runoff from livestock operations, wildlife, improperly disinfected wastewater effluent *** Salt applications to snow and ice *** Leaky automobiles, industrial areas, illegal dumping *** Hydrological modifications that influence the amount of fresh or saline waters entering a system *** Heated landscape areas, runoff from impervious areas, tree removal along streams, wet detention ponds
  • 41.
  • 43. Means of Treatment Coagulation – the separation or precipitation of particles in a dispersed state from a suspension resulting from their growth. This may result from the addition of an electrolyte (coagulant), prolonged heating, or from a condensation reaction between a solvent and solute. Flocculation – the addition of chemical reagents (flocculants) to bring small particles together in flocs through the process of coagulation, aggregation, or biochemical reaction of fine suspended particles. Ion exchange – the interchange of ions of like charge, usually on a solid medium and is used in water treatment, such as water softening.
  • 44. Means of Treatment Ozonation – disinfection using ozone. Reverse Osmosis – a technique in the desalination of water in which pressure is applied to the surface of the saline solution, forcing pure water to pass through a semi- permeable membrane which prevents passage of other ions. Distillation – the process of producing gas or vapor from a liquid by heating the liquid in a vessel and then collecting and condensing the vapors into liquids. Electodialysis – the process of selective diffusion through a membrane conducted with the aid of an electromotive force applied to electrodes on both sides of the membrane.
  • 45. Means of Treatment Disinfections – to kill living organisms (ex. chlorination, ozonation, use of potassium permanganate, UV light, or silver ions. Filtrations/ultra-filtrations – ex. A bed of sand or pulverized coal, or through a matrix of fibrous material supported on a perforated core. Adsorption – ex. using activated alumina, activated carbon or activated carbon (GAC). Aeration – a process of exposing water to air by dividing the water into small drops, by forcing air through the water, or by combination of both. It is used to add oxygen to water and to remove CO2, hydrogen sulfide, and taste-producing gases or vapors . Boiling – to kill some bacteria.
  • 47. Water Quality Management Water quality management is the planning for the protection of a water’s quality - for various beneficial use, - for the provision of adequate wastewater collection, treatment, and disposal of municipalities and industries, and - for activities that might create water quality problems, and regulating and enforcing programs to accomplish the planning goals, and law and regulations dealing with the water pollution control.
  • 48. Water Quality Management The United Nations, in its recent examination of global water scarcity (1997) identified water quality as one of the key concerns in Asia in the next century. This concern is based on the fact that water quality degradation is so severe in many Asian countries that it is placing serious constraints on economic growth. It continues to be a serious problem for human health and it is causing widespread negative environmental effects.
  • 49. MADAMO GUID NGA SALAMAT SA TANAN SA INYO PAGPAMATI SA AKON REPORT