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Car-Plastics meets its Re-Maker

Developing a Supply Cycle for Car Plastic



                                    Chris Slijkhuis
Creating a Global Footprint to produce Green Plastics




                                  UK
                    California          Austria

        Guangzhou
Announcement of new MBA Polymers Plant in the UK

                                                                                                       MBA Polymers strengths
            European Metal Recycling strengths



                                                    Non-                       Remove                                          Global
                                      Shredding                    Remove                   Plastics
   Item collection and   Decon-                     ferrous                    remaining                  Grade     Com-       sales,
                                      and ferrous                  remaining                type
   aggregation           tamination                 concen-                    non-target                 sorting   pounding   marketing
                                      recovery                     metals                   sorting
                                                    tration                    materials                                       & support




                                                              one Key element                          MBA Polymers
                                                              is Pre-processing




EMR and MBA Polymers decided to create teamwork to Close the Loop for Plastics
Teaming up to get from Supply Chain to Supply Cycle……..


                         Design For the Environment


                       Manufacturing     Delivery
                        Operations
      Procurement

                                          Integrated     Customer
                                                         C
                                            Supply
                                             Chain
                                                       Use / Service
           Recycling
                                         Take-back
                                         Take back

                       De-pollution



                             Waste Minimisation
Pre-processing ASR is key to liberate the plastics

  De-Pollution

  Shredder                Ferrous-Metals


                 Non-FE                                       Size reduction,
                                      Non-Ferrous-Metals      liberation and
                 Separations
                                                                 separation



 Pre-Processing ASR to further Separate Plastic/non-Plastic




Mixed Plastic Rich Materials
View on the ASR Raw Material




Feed stock
Feed-stock for plastic material pre-processing
                                pre processing
The key challenges with ASR plastics
       Low quantity and composition of t g t plastics
       L       tit    d       iti    f target l ti
       • Most ASR contains less than 30% plastics
       • Much of which small amounts of many specialty plastics
       • Upgrading is required to eliminate most non-plastics
       Removal of non-thermoplastic contaminants
                  non thermoplastic
       •   Rubber
       •   Wood
       •   Fabric, foam & other “fluff”
       •   Dirt, glass & stones
       Large variety of many different plastics
       Painted/coated plastics
       And other surface contamination like dirt, fluids, etc.
IARC
Composition of a typical ASR fraction




     Plastics and
       Rubber
       R bb                Fines

           Fibers, foam,
              stones,
            rubber etc.
What is necessary to produce 1 ton of plastics?

                 approx. 900 liter crude oil


                               Approx. 9 tons ASR


                 approx. 14.000 kWh


                                 approx. 950 kWh
                                  pp



                            OR
                  <10% of the water consumption
                  <10% of the energy consumption
                                  gy       p
    2-3 kg reduction of CO2 emissions per kg of recycled plastic
So there is a good incentive to recycle plastics




      Plastics and
        Rubber
                                  Fines
                                  Fi

                Fibers, foam,
                      ,      ,
                   stones,
                 rubber etc.
Pre-processing principles
    Sourcing & Goods In
               Goods-In
•     Material Handling / Logistics

•     Assaying / Material Analysis

    Pre-Processing
•     Cleaning material of minerals

      •   Glass, stones, dust

•     Eliminating organic fractions

      •   such as wood, rubber, foam, textiles
                      ,       ,     ,

    Size reduction to a standard particle size

    Concentrating target plastics to some 80% by weight
                          l                   b      h
View on Pre-processed Plastic Rich Material




  From feed stock to pre processed plastics
       feed-stock    pre-processed
View on Pre-Processing non-plastic byproducts
        Foam                    Rubber and wood
                                  concentrate




    Dirt and other fluff     Example of
                           metals recovered
                               from SR




Potential feed-stock for Recycling & Thermal Recovery
Some 80 % Target Plastics after pre-processing
                                        Other non-plastics,Fines & Dust, 0.2%
                                                            5.7%
                           Wires/Electronics, 0 %
                            i     l Wood, 0.7%
                                         i    0.7%
                            Foam/Fluff, 1.3%                                    PP, 16.2%


                       Rubber, 7.0%



     un-ID'd plastics, 0.8%

    trace plastics, 2.8%

           POM, 1.4%
    PPO-filled, 1.6%
    PPO-filled 1 6%

      PC-PBT, 1.9%
                                                                                                         ABS, 15.8%
    PA-filled, 1.9%

      PC ABS,
      PC-ABS, 2.0%

          PPO, 2.1%

             PVC, 2.6%


              ABS-FR, 3.3%



                      PA-filled, 5.0%                                                 PP-filled, 14.0%


                                         HIPS, 6.5%
                                                                   PE, 6.5%
High Tech Separations of the Plastics

    Cleaning plastics
•     Closed circuit water treatment

•     A wide variety of separations

•     Stringent Quality & Process Control

    High-Tech Seperations
•     Obtaining PP,
      Obt i i PP ABS & (HI)PS flakes
                              fl k

•     In several grades

    Resulting in pure flakes of PP, HIPS and ABS
•     The flakes are the raw material for quality plastics
View on purified filled PP Flakes
View on purified ABS flakes
View on purified HIPS Flakes
Blending, Extrusion and Compounding
    Blending the flakes
•     Creating homogenous products
             g     g      p

    Extruding into pellets
•     High tech compounding lines

•     To create purified resins (virgin like properties)

    Final products Quality Control
•     Stringent quality control as practiced in other MBA Polymers plants
      •   MFI (Melt Flow Index) – viscosity at given temperature and shear
          rate
      •   Izod (Impact Strength Measurement)
      •   Tensile Strength
PP products made from ASR in comparison
                                       MBA            MBA                      OEM B        OEM B
           Property                                               OEM A
                                       PP-A           PP-B                     PP-A *       PP-B *
   Melt flow rate (g/10 min)
                                        2.2            3.7          ------      >7.0          >7.0
          @ 230/2 16
            230/2.16
Tensile strength at yield (MPa)        19.3           20.5          >21         >14.0        >14.0
   Tensile modulus (MPa)                741           1040          ------      ------        ------
Tensile l
T il elongation at b k (%)
           ti    t break               43.4
                                       43 4           35.0
                                                      35 0          ------       >50
                                                                                  50          >35
                                                                                               35
   Flexural strength (MPa)             ------         ------        ------      >8.8         >16.7
   Flexural modulus (MPa)              ------         ------        >870      400-600      500-700
  Notched izod impact (J/m)             465            190          >100        >400         >300
                                                                   0.89-
       Specific gravity                0.935          0.954                     <0.95        <0.95
                                                                   0.92


    * Properties were measured using comparable ISO standards. Results have been converted to
    ASTM units where appropriate (e.g. notched izod impact), and should be nearly identical with
                                         ASTM test results.
Why a High-Tech Global Footprint.......

Electronics & Automotive OEM’s are Global and
   they demand:
   • Global Supply of Plastics
   • Virgin-like quality of the tech plastics they use
   • Large dependable and consistent volumes
     Large,
   • Consistent technical specifications
   • A global answer to their Waste Plastics
   • Reliable service levels


for new products
to become designed in
                   in........
Products – ABS, PS, PP as pellets & compounds
Consistent Properties with MBA Polymers’ Resins

                                10,0
    MF (200°C/5k in [g/10min]




                                 9,0
                                 90             MFR Analysis Type MBA PS 3 30
                                                      a ys s ype       S 3130


                                 8,0
               kg)




                                 7,0

                                 6,0
     FR




                                 5,0

                                 4,0
                                 40
                                       0   20     40     60     80      100     120   140   160
                                                              Samples
MBA Polymers’ Resin Advantages

    High quality resin with stable properties
•     ISO 9001:2000

•     RoHS certification

    Custom properties for custom applications
           p p                    pp

    100% Post-Consumer Recycled Content

    Green “Cl
    G     “Cleantech” image and responsibility
                   h” i       d        ibili

    Saving large amounts of energy

    Low CO2 Emissions

       Resins with Environmental Awareness
The World Economic Forum recognized MBA Polymers

                         Technology Pioneer 2006


                         The criteria for becoming this
                         WEF recognition as Tech Pioneer are:

                           Innovation
                           Potential Impact
                           Proof of Concept
                           Growth and Sustainability
                           Leadership
                           L d hi
                           Status
Our president and founder puts his teeth into ASR plastics....
and is determined not to loose them...




Thank you very much for your attention

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IARC Münich 2008 Plastics Recycling

  • 1. Car-Plastics meets its Re-Maker Developing a Supply Cycle for Car Plastic Chris Slijkhuis
  • 2. Creating a Global Footprint to produce Green Plastics UK California Austria Guangzhou
  • 3. Announcement of new MBA Polymers Plant in the UK MBA Polymers strengths European Metal Recycling strengths Non- Remove Global Shredding Remove Plastics Item collection and Decon- ferrous remaining Grade Com- sales, and ferrous remaining type aggregation tamination concen- non-target sorting pounding marketing recovery metals sorting tration materials & support one Key element MBA Polymers is Pre-processing EMR and MBA Polymers decided to create teamwork to Close the Loop for Plastics
  • 4. Teaming up to get from Supply Chain to Supply Cycle…….. Design For the Environment Manufacturing Delivery Operations Procurement Integrated Customer C Supply Chain Use / Service Recycling Take-back Take back De-pollution Waste Minimisation
  • 5. Pre-processing ASR is key to liberate the plastics De-Pollution Shredder Ferrous-Metals Non-FE Size reduction, Non-Ferrous-Metals liberation and Separations separation Pre-Processing ASR to further Separate Plastic/non-Plastic Mixed Plastic Rich Materials
  • 6. View on the ASR Raw Material Feed stock Feed-stock for plastic material pre-processing pre processing
  • 7. The key challenges with ASR plastics Low quantity and composition of t g t plastics L tit d iti f target l ti • Most ASR contains less than 30% plastics • Much of which small amounts of many specialty plastics • Upgrading is required to eliminate most non-plastics Removal of non-thermoplastic contaminants non thermoplastic • Rubber • Wood • Fabric, foam & other “fluff” • Dirt, glass & stones Large variety of many different plastics Painted/coated plastics And other surface contamination like dirt, fluids, etc. IARC
  • 8. Composition of a typical ASR fraction Plastics and Rubber R bb Fines Fibers, foam, stones, rubber etc.
  • 9. What is necessary to produce 1 ton of plastics? approx. 900 liter crude oil Approx. 9 tons ASR approx. 14.000 kWh approx. 950 kWh pp OR <10% of the water consumption <10% of the energy consumption gy p 2-3 kg reduction of CO2 emissions per kg of recycled plastic
  • 10. So there is a good incentive to recycle plastics Plastics and Rubber Fines Fi Fibers, foam, , , stones, rubber etc.
  • 11. Pre-processing principles Sourcing & Goods In Goods-In • Material Handling / Logistics • Assaying / Material Analysis Pre-Processing • Cleaning material of minerals • Glass, stones, dust • Eliminating organic fractions • such as wood, rubber, foam, textiles , , , Size reduction to a standard particle size Concentrating target plastics to some 80% by weight l b h
  • 12. View on Pre-processed Plastic Rich Material From feed stock to pre processed plastics feed-stock pre-processed
  • 13. View on Pre-Processing non-plastic byproducts Foam Rubber and wood concentrate Dirt and other fluff Example of metals recovered from SR Potential feed-stock for Recycling & Thermal Recovery
  • 14. Some 80 % Target Plastics after pre-processing Other non-plastics,Fines & Dust, 0.2% 5.7% Wires/Electronics, 0 % i l Wood, 0.7% i 0.7% Foam/Fluff, 1.3% PP, 16.2% Rubber, 7.0% un-ID'd plastics, 0.8% trace plastics, 2.8% POM, 1.4% PPO-filled, 1.6% PPO-filled 1 6% PC-PBT, 1.9% ABS, 15.8% PA-filled, 1.9% PC ABS, PC-ABS, 2.0% PPO, 2.1% PVC, 2.6% ABS-FR, 3.3% PA-filled, 5.0% PP-filled, 14.0% HIPS, 6.5% PE, 6.5%
  • 15. High Tech Separations of the Plastics Cleaning plastics • Closed circuit water treatment • A wide variety of separations • Stringent Quality & Process Control High-Tech Seperations • Obtaining PP, Obt i i PP ABS & (HI)PS flakes fl k • In several grades Resulting in pure flakes of PP, HIPS and ABS • The flakes are the raw material for quality plastics
  • 16. View on purified filled PP Flakes
  • 17. View on purified ABS flakes
  • 18. View on purified HIPS Flakes
  • 19. Blending, Extrusion and Compounding Blending the flakes • Creating homogenous products g g p Extruding into pellets • High tech compounding lines • To create purified resins (virgin like properties) Final products Quality Control • Stringent quality control as practiced in other MBA Polymers plants • MFI (Melt Flow Index) – viscosity at given temperature and shear rate • Izod (Impact Strength Measurement) • Tensile Strength
  • 20. PP products made from ASR in comparison MBA MBA OEM B OEM B Property OEM A PP-A PP-B PP-A * PP-B * Melt flow rate (g/10 min) 2.2 3.7 ------ >7.0 >7.0 @ 230/2 16 230/2.16 Tensile strength at yield (MPa) 19.3 20.5 >21 >14.0 >14.0 Tensile modulus (MPa) 741 1040 ------ ------ ------ Tensile l T il elongation at b k (%) ti t break 43.4 43 4 35.0 35 0 ------ >50 50 >35 35 Flexural strength (MPa) ------ ------ ------ >8.8 >16.7 Flexural modulus (MPa) ------ ------ >870 400-600 500-700 Notched izod impact (J/m) 465 190 >100 >400 >300 0.89- Specific gravity 0.935 0.954 <0.95 <0.95 0.92 * Properties were measured using comparable ISO standards. Results have been converted to ASTM units where appropriate (e.g. notched izod impact), and should be nearly identical with ASTM test results.
  • 21. Why a High-Tech Global Footprint....... Electronics & Automotive OEM’s are Global and they demand: • Global Supply of Plastics • Virgin-like quality of the tech plastics they use • Large dependable and consistent volumes Large, • Consistent technical specifications • A global answer to their Waste Plastics • Reliable service levels for new products to become designed in in........
  • 22. Products – ABS, PS, PP as pellets & compounds
  • 23. Consistent Properties with MBA Polymers’ Resins 10,0 MF (200°C/5k in [g/10min] 9,0 90 MFR Analysis Type MBA PS 3 30 a ys s ype S 3130 8,0 kg) 7,0 6,0 FR 5,0 4,0 40 0 20 40 60 80 100 120 140 160 Samples
  • 24. MBA Polymers’ Resin Advantages High quality resin with stable properties • ISO 9001:2000 • RoHS certification Custom properties for custom applications p p pp 100% Post-Consumer Recycled Content Green “Cl G “Cleantech” image and responsibility h” i d ibili Saving large amounts of energy Low CO2 Emissions Resins with Environmental Awareness
  • 25. The World Economic Forum recognized MBA Polymers Technology Pioneer 2006 The criteria for becoming this WEF recognition as Tech Pioneer are: Innovation Potential Impact Proof of Concept Growth and Sustainability Leadership L d hi Status
  • 26. Our president and founder puts his teeth into ASR plastics....
  • 27. and is determined not to loose them... Thank you very much for your attention