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Session 5B - Measurement




Victoria Zavras – Anotec Pty Limited, AUSTRALIA
Combined Sensory & Analytical
           Methods to
Formulate Develop Determine




  Viable odour control technologies
       Presentation by Anotec Pty Limited 2003
Exhaust emissions usually contain
significant amounts of various odorous
components.

The perceived odour is due to the
effect of all compounds in the mixture
and depends upon the concentration
and odorous qualities of the
component compounds.

       Therefore, it is logical that an odorous gas
        sample be characterised in two ways.

Firstly, in the analytical expression, whereby the
components are identified and their concentrations are
measured
1. Analytical expression,
whereby the components
 are identified and their
   concentrations are
       measured



               2. Sensory expression,
              where the human response
                to the odorous mix is
                      measured.
GC/MS Analysis reveals the composition of
the odorous mix but will not be able to
determine the human response.
Olfactometry reveals the human response
to a particular odour mix but cannot
address its chemistry.
Challenging malodours.
1. Masking Agent formulation (generic)
2. Anotec 0307 (site specific formulations
   based on testing)
Introducing:                Officer Anotec,
      Officer Masking       Badge # 0307
      Badge ID Generic

               Mal Odour
Masking Agent
A generic masking agent (perfume) was formulated to be applied in all
instances. There was no variation in the formulation as Anotec were testing the
“Broad Spectrum” or “one size fits all” theory of masking agent applications. In
the following scene Officer Masking has apprehended Mal Odour without a
thorough investigation.




                                Officer Masking apprehends
                                Mal Odour. Frisks him, but comes up
                                empty handed. Masking lets him go.
Masking Agent
A generic masking agent (perfume) was formulated to be applied in all
instances. There was no variation in the formulation as Anotec were testing the
“Broad Spectrum” or “one size fits all” theory of masking agent applications. In
the following scene Officer Masking has apprehended Mal Odour without a
thorough investigation.


                                Mal Odour is on the run again.
                                He’s getting away with the crime.
                                Besides, he was far too big and
                                And strong compared to Masking.
Anotec 0307
All 0307 formulations evaluated were developed as a direct result of the odour
testing conducted. Therefore, a site-specific odour control formula was applied
to the relevant odour source. In the following scene, Officer Anotec is aware
that Mal Odour is on the loose, but he approaches the situation differently by
fully utilising the resources available to him.



                                         The crime scene is examined.
                                         Officer Anotec has engaged
                                         The services of a private
                                         Detective firm. (Olfactometry)
Anotec 0307
              Not only did scientific
              evidence shows that Mal
              was directly responsible for
              the crime, witnesses
              attested to his
              extraordinary strength
Anotec 0307

Investigations show that Mal Odour is wanted
in every state in every country. Positive
identification is made and Officer Anotec can
now actively pursue and apprehend the
criminal.
Anotec 0307




              The sentence is execution
Sampling
   Emissions from Stack




   Sampling
   Site




  Treatment               Samples sent to
                           Laboratories
200,000



180,000


                                                                                                                           RE (%)
160,000                                                                             Testing Parameter               ODU    Initial

                                                                                                                    152,
                                                                            Raw Odour                               450       -
140,000
                                                                                                                    2,63
                                                                            Raw Odour + Anotec 0307                    1     98

120,000                                                                                                             189,
                                                                            Raw Odour + Masking Agent               620    -24.38


100,000                                                                     ODU = Odour Dilution Units (Strength)


 ODU                                                                        RE = Removal Efficiency
 80,000



 60,000



 40,000



 20,000



     0
          Raw Odour   Raw Odour + Anotec 0307   Raw Odour + Masking Agent
                      Te st ing parame t e rs
RE       RE
              Component          RO        MA      0307    (MA)    (0307)
              Carbondisulfide         4      3.1      1    18.42    73.68
              Cabonylsulfide      142      129.6   12.3     8.73    91.34
              Methanol          41,266    39,505    497     4.27    98.80
              Ethanol           96,227    93,235    766     3.11    99.20
              Acetonitrile       2,050    1985.2   37.3     3.16    98.18
              Benzene           62,602    61,599    546     1.60    99.13
              Toluene           11,735    11,021    336     6.08    97.14
              m,p-xylenes        9,310     9,263    117     0.50    98.74




    100,000
     90,000
     80,000                                                                 Carbondisulfide
     70,000                                                                 Cabonylsulfide
     60,000
ppb 50,000                                                                  Methanol
     40,000                                                                 Ethanol
     30,000                                                                 Acetonitrile
     20,000
     10,000                                                                 Benzene
          0                                                                 Toluene
                   RO                 MA                  0307
                                                                            m,p-xylenes
                         Testing Parameter
Conclusion:
Combined odour measurement techniques show
us the “Big Picture”
Enables facility operators the freedom to
choose the best available technology when
presented with more than one option
Masking Agents may be much more suited to
temporary and transient odours and are a poor
performer in continuous odour streams.
Site specific odour control formulations based on
the combination of the odour measurement
techniques yield up to 98% removal efficiency
when compared to masking agent applications.

Anotec odour control technologies’ success in
commercialising formulations worldwide is
directly attributable to the combined sensory &
analytical measurement techniques presented
to you today.

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Anotec Combined Sensory & Analytical Methods

  • 1. Session 5B - Measurement Victoria Zavras – Anotec Pty Limited, AUSTRALIA
  • 2. Combined Sensory & Analytical Methods to Formulate Develop Determine Viable odour control technologies Presentation by Anotec Pty Limited 2003
  • 3. Exhaust emissions usually contain significant amounts of various odorous components. The perceived odour is due to the effect of all compounds in the mixture and depends upon the concentration and odorous qualities of the component compounds. Therefore, it is logical that an odorous gas sample be characterised in two ways. Firstly, in the analytical expression, whereby the components are identified and their concentrations are measured
  • 4. 1. Analytical expression, whereby the components are identified and their concentrations are measured 2. Sensory expression, where the human response to the odorous mix is measured.
  • 5. GC/MS Analysis reveals the composition of the odorous mix but will not be able to determine the human response.
  • 6. Olfactometry reveals the human response to a particular odour mix but cannot address its chemistry.
  • 7. Challenging malodours. 1. Masking Agent formulation (generic) 2. Anotec 0307 (site specific formulations based on testing) Introducing: Officer Anotec, Officer Masking Badge # 0307 Badge ID Generic Mal Odour
  • 8. Masking Agent A generic masking agent (perfume) was formulated to be applied in all instances. There was no variation in the formulation as Anotec were testing the “Broad Spectrum” or “one size fits all” theory of masking agent applications. In the following scene Officer Masking has apprehended Mal Odour without a thorough investigation. Officer Masking apprehends Mal Odour. Frisks him, but comes up empty handed. Masking lets him go.
  • 9. Masking Agent A generic masking agent (perfume) was formulated to be applied in all instances. There was no variation in the formulation as Anotec were testing the “Broad Spectrum” or “one size fits all” theory of masking agent applications. In the following scene Officer Masking has apprehended Mal Odour without a thorough investigation. Mal Odour is on the run again. He’s getting away with the crime. Besides, he was far too big and And strong compared to Masking.
  • 10. Anotec 0307 All 0307 formulations evaluated were developed as a direct result of the odour testing conducted. Therefore, a site-specific odour control formula was applied to the relevant odour source. In the following scene, Officer Anotec is aware that Mal Odour is on the loose, but he approaches the situation differently by fully utilising the resources available to him. The crime scene is examined. Officer Anotec has engaged The services of a private Detective firm. (Olfactometry)
  • 11. Anotec 0307 Not only did scientific evidence shows that Mal was directly responsible for the crime, witnesses attested to his extraordinary strength
  • 12. Anotec 0307 Investigations show that Mal Odour is wanted in every state in every country. Positive identification is made and Officer Anotec can now actively pursue and apprehend the criminal.
  • 13. Anotec 0307 The sentence is execution
  • 14. Sampling Emissions from Stack Sampling Site Treatment Samples sent to Laboratories
  • 15. 200,000 180,000 RE (%) 160,000 Testing Parameter ODU Initial 152, Raw Odour 450 - 140,000 2,63 Raw Odour + Anotec 0307 1 98 120,000 189, Raw Odour + Masking Agent 620 -24.38 100,000 ODU = Odour Dilution Units (Strength) ODU RE = Removal Efficiency 80,000 60,000 40,000 20,000 0 Raw Odour Raw Odour + Anotec 0307 Raw Odour + Masking Agent Te st ing parame t e rs
  • 16. RE RE Component RO MA 0307 (MA) (0307) Carbondisulfide 4 3.1 1 18.42 73.68 Cabonylsulfide 142 129.6 12.3 8.73 91.34 Methanol 41,266 39,505 497 4.27 98.80 Ethanol 96,227 93,235 766 3.11 99.20 Acetonitrile 2,050 1985.2 37.3 3.16 98.18 Benzene 62,602 61,599 546 1.60 99.13 Toluene 11,735 11,021 336 6.08 97.14 m,p-xylenes 9,310 9,263 117 0.50 98.74 100,000 90,000 80,000 Carbondisulfide 70,000 Cabonylsulfide 60,000 ppb 50,000 Methanol 40,000 Ethanol 30,000 Acetonitrile 20,000 10,000 Benzene 0 Toluene RO MA 0307 m,p-xylenes Testing Parameter
  • 17. Conclusion: Combined odour measurement techniques show us the “Big Picture” Enables facility operators the freedom to choose the best available technology when presented with more than one option Masking Agents may be much more suited to temporary and transient odours and are a poor performer in continuous odour streams.
  • 18. Site specific odour control formulations based on the combination of the odour measurement techniques yield up to 98% removal efficiency when compared to masking agent applications. Anotec odour control technologies’ success in commercialising formulations worldwide is directly attributable to the combined sensory & analytical measurement techniques presented to you today.