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Acknowledgement:
   Information and pictorial illustrations to create this
    work have been drawn from class notes, prescribed
    text books and various internet resources. The author
    gratefully acknowledges the same. Any objections to
    the use of internet resources may please be indicated
    to suddurocks@yahoo.in so that the same can be
    removed from the illustrations used in this file.
   This presentation is created with the sole intention of
    benefitting a large number of student community.
    This may not be used for any commercial purpose.
Contents :
 Laws of Chemical Combination
 About Atoms

 About Molecules

 About Ions

 Writing Chemical Formulae

 Molecular Mass & Mole Concept

 Multiple Choice Questions

 Some Interesting Pictures
Laws of Chemical Composition
 The following two laws of chemical
  combination were established after much
  experiments by Lavoisier and Joseph L
  Proust :
(i) Law of conservation of mass :
     - Law of constant of mass states that
  mass can neither be created nor
  destroyed in a chemical reaction.
(ii) Law of Constant Proportions
       - Lavoisier, along with other scientists,
   noted that many compounds were
   composed of two or more elements and
   each such compound had the same
   elements in the same proportions,
   irrespective of where the compound came
   from or who prepared it.
In a compound such as water, the ratio
of the mass of hydrogen to the mass of
oxygen is always 1:8, whatever the source
of water. Similarly in ammonia, nitrogen
and hydrogen are always present in the
ratio 14:3 by mass, whatever the method
or the source from which it is obtained.

   This led to the law of constant
proportions which is also known as the
Law of Definite Proportions.
About Atoms
According to Dalton’s atomic theory, all
matter whether an element, a compound
or a mixture is composed of small particles
called Atoms.
The postulates of this theory may be
   started as follows :
(i)All matter is made of very tiny particles
   called Atoms.
(ii) Atoms are indivisible particles, which
   cannot be created or destroyed in a
   chemical reaction.
(iii) Atoms of a given element are identical in
   mass and chemical properties.
(iv)Atoms of different elements have
   different masses and chemical properties.
(v) Atoms combine in the ratio of small
  whole numbers to form compounds.
(vi) The relative number and kinds of atoms
  are constant in a given compound.
   The building blocks of all matter are atoms.




   Atoms are very small. They are smaller than
    anything we can imagine or compare with.
► Atomic   radius is measured in nanometers.
Relative Sizes :
Modern Day Symbols of
Atoms of Different Elements
Symbols for Some Elements
   Aluminum : Al
   Argon : Ar
   Barium : Ba
   Boron : B
   Bromine : Br
 Calcium : Ca
 Carbon : C
Chlorine : Cl
Cobalt : Co
• Copper : Cu
► Fluorine   :F
► Gold   : Au
   Hydrogen : H
   Iodine : I
   Iron : Fe
   Lead : Pb
   Magnesium : Mg
• Neon : Ne
   Nitrogen : N
   Oxygen : O
   Potassium : K
   Silicon : Si
 Silver : Ag
 Sodium : Na
• Sulphur : S
► Uranium   :U
   Zinc : Zn
   Phosphorus : P
   Platinum : Pt
   Mercury : Hg
• Nickel : Ni
   Tin : Sn
   Bismuth : Bi
   Antimony : Sb
   Arsenic : As
   Manganese : Ma
 Tungsten : W
 Titanium : Ti
• Cerium : Ce
   Strontium : Sr
   Beryllium : Be
   Zirconium :
   In 1961 a university accepted atomic mass
    unit, carbon-12 isotope was chosen as the
    standard reference for measuring atomic
    masses.
   One atomic mass unit is a mass unit equal
    to exactly one twelfth the mass of one
    atom of carbon-12.
Atomic Masses of Few Elements
    Element       Atomic Mass (u)
(i) Hydrogen              1
(ii) Carbon               12
(iii) Nitrogen            14
(iv) Oxygen               16
(v) Sodium                23
(vi) Magnesium            24
Element     Atomic Mass (u)
(vii) Sulphur       32
(viii) Chlorine     35.5
(ix) Calcium        40
   Atoms of most elements are not able
    to exist independently.
 Atoms form molecules and ions.




 These molecules or ions aggregate in
 large numbers to form the matter that we
 can see, feel or touch.
About Molecules
 A molecule is a general group of two or
 more atoms that are chemically bonded
 together, that is, tightly held together by
 attractive forces.
A molecule can be defined as the smallest
particle of an element or a compound & is
capable of an independent existence and
shows all the properties of that substance.
Atoms of the same element or of different
elements can join together to form
molecules.
Molecules of Elements
• The molecules of an element are
  constituted by the same type of atoms.
► Moleculesof an element are constituted
 by the same type of atoms.
► Moleculesof many elements, such as
 argon(Ar), helium(He),…etc. are made up
 of only one atom of that element.




► But,
     this is not the case with most of the
 non-metals.
   For example, a molecule of oxygen consists of
    two atoms of oxygen and hence it is known as
    a diatomic module O2.




   If 3 atoms of oxygen unite into a molecule,
    instead of the usual 2, we get ozone.
   The number of atoms constituting a
    molecule is known as its Atomicity.
Atomicity of Some Elements
     Type of Element : Non – Metal
         Name                  Atomicity
(i) Argon             -   Monoatomic
(ii) Helium           -   Monoatomic
   Type of Element : Non – Metal
       Name                  Atomicity
(i) Oxygen                  Diatomic
(ii) Hydrogen              Diatomic
(iii) Nitrogen             Diatomic
(iv) Chlorine              Diatomic
   Type of Element : Non – Metal
       Name                 Atomicity
(i) Phosphorus         Tetra - atomic
   Type of Element : Non – Metal
       Name                 Atomicity
(i) Sulphur                   Poly-atomic
   Atoms of different elements join together
    in definite proportions to form molecules
    of compounds.
Molecules of Some Compounds
   Compound : Water
    Combining Elements : Hydrogen, Oxygen
    Ratio by Mass : 1:8
   Compound : Ammonia
    Combining Elements : Nitrogen,   Hydrogen
    Ratio by Mass : 14:8
   Compound : Carbon Dioxide
     Combining Elements : Carbon,
    Oxygen
     Ratio by mass : 3:8
About Ions
   Compounds composed of metals and
    non metals contain charged species.
    The charged species are known as
    Ions.
An ion is a charged particle and can be
negatively or positively charged.
A negatively charged ion is called an
‘Anion’ and the positively charged ion is
called a ‘Cation’.
Some Ionic Compounds
• Ionic Compound : Calcium Oxide
   Constituting Elements : Calcium &
  Oxygen
   Ratio by Mass : 5:2
► IonicCompound : Magnesium Sulphide
  Constituting Elements : Magnesium &
 Sulphur
  Ratio by Mass : 3:4
► IonicSolution : Sodium Chloride
  Constituting Elements : Sodium &
 Chlorine
  Ratio by Mass : 23:35.5
Molecular Mass & Mole Concept
   The molecular mass of a substance is the sum
    of the atomic masses of all the atoms in a
    molecule of the substance.
   It is therefore the relative mass of a
    molecule expressed in atomic mass units
    (u).
   The formula unit mass of a substance is a
    sum of the atomic masses of all atoms in a
    formula unit of a compound.
   Formula unit mass is calculated in the same
    manner as we calculate the molecular mass.




   The only difference is that we use the word
    formula unit for those substances whose
    constituent particles are ions.
   EXAMPLE : Reaction of hydrogen and
    oxygen to form water:
       2H2 + O2  2H2O

   The above reaction indicates that :
(i) Two molecules of hydrogen combine with
   one molecule of oxygen to form two
   molecules of water.         Or,
(ii) 4 u of hydrogen molecules combine with
   32 u of oxygen molecules to form 36 u of
   water molecules.
   We can infer from the above equation that
    the quantity of a substance can be
    characterised by its mass or the number
    of molecules.




   But, a chemical reaction equation indicates
    directly the number of atoms or molecules
    taking part in the reaction.
   Therefore, it is more convenient to refer to the
    quantity of a substance in terms of the number
    of its molecules or atoms, rather than their
    masses.
   So, a new unit “Mole” was introduced.
Multiple Choice Questions


 Q 1 : A molecule does not signify
(a) Atomic mass unit
(b) 22.4 litres of a gas at STP
(c) Gram molecular mass
(d) None of the above
Answer :
Option :
    (a) Atomic mass unit
 Q 2 : Which of the following does
  not change when a chemical
  reaction takes place ?
(a) Volume
(b) Mass
(c) Physical properties
(d) Chemical properties
Answer :
Option :
    (b) Mass
Q 3 : Molecules of the following
  element are made up of only one
  atom of that element:
(a) Iron
(b) Sodium
(c) Helium
(d) Chlorine
Answer :

Option :
    (c) Helium
 Q 4 : Law of definite proportion was
  given by
(a) John Dalton
(b) Lavoisier
(c) Joseph Proust
(d) Ritcher
Answer :
Option :
    (b) Lavoisier
Q  5 : Argon is
(a) Monoatomic
(b) Diatomic
(c) Triatomic
(d) Polyatomic
Answer :
Option :
    (a) Monoatomic
Q  6 : Which of the following supports
  Dalton's atomic theory of matter?
(a) Formation of isotopes
(b) Formation of isobars
(c) Law of multiple proportion
(d) Graphite and diamond though
  made from carbon, show different
  properties.
Answer :
Option :
    (c) Law of Multiple Proportion
 Q 7 : Choose the odd molecule
(a) Argon molecule
(b) Chlorine molecule
(c) Oxygen Molecule
(d) Fluorine Molecule
Answer :
Option :
    (a) Argon Molecule
• Q 8 : choose the element which will
  not have a charged valency
(a) Calcium
(b) Argon
(c) Silicon
(d) Aluminium
Answer :
Option :
   (b) Argon
Q 9 : Take out the odd concept
(a) Atomic mass unit
(b) Mole
(c) Avogadro
(d) Gram atomic mass
Answer :
Option :
    (a) Atomic mass unit
 Q 10 : Which one of the following
  elements give polyatomic molecules?
(a) Ne
(b) P
(c) Ni
(d) Si
Answer :
Option :
    (b) P
Some Interesting Pictures
Thank You !!!

Compiled By :
Sudarshan.S.K.

Mail Your Feedback And Suggestions
For Improvement To :
suddurocks@yahoo.in

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Atoms and molecules

  • 1.
  • 2. Acknowledgement:  Information and pictorial illustrations to create this work have been drawn from class notes, prescribed text books and various internet resources. The author gratefully acknowledges the same. Any objections to the use of internet resources may please be indicated to suddurocks@yahoo.in so that the same can be removed from the illustrations used in this file.  This presentation is created with the sole intention of benefitting a large number of student community. This may not be used for any commercial purpose.
  • 3. Contents :  Laws of Chemical Combination  About Atoms  About Molecules  About Ions  Writing Chemical Formulae  Molecular Mass & Mole Concept  Multiple Choice Questions  Some Interesting Pictures
  • 4. Laws of Chemical Composition  The following two laws of chemical combination were established after much experiments by Lavoisier and Joseph L Proust : (i) Law of conservation of mass : - Law of constant of mass states that mass can neither be created nor destroyed in a chemical reaction.
  • 5. (ii) Law of Constant Proportions - Lavoisier, along with other scientists, noted that many compounds were composed of two or more elements and each such compound had the same elements in the same proportions, irrespective of where the compound came from or who prepared it.
  • 6. In a compound such as water, the ratio of the mass of hydrogen to the mass of oxygen is always 1:8, whatever the source of water. Similarly in ammonia, nitrogen and hydrogen are always present in the ratio 14:3 by mass, whatever the method or the source from which it is obtained. This led to the law of constant proportions which is also known as the Law of Definite Proportions.
  • 7. About Atoms According to Dalton’s atomic theory, all matter whether an element, a compound or a mixture is composed of small particles called Atoms.
  • 8. The postulates of this theory may be started as follows : (i)All matter is made of very tiny particles called Atoms. (ii) Atoms are indivisible particles, which cannot be created or destroyed in a chemical reaction. (iii) Atoms of a given element are identical in mass and chemical properties. (iv)Atoms of different elements have different masses and chemical properties.
  • 9. (v) Atoms combine in the ratio of small whole numbers to form compounds. (vi) The relative number and kinds of atoms are constant in a given compound.
  • 10. The building blocks of all matter are atoms.  Atoms are very small. They are smaller than anything we can imagine or compare with.
  • 11. ► Atomic radius is measured in nanometers.
  • 13.
  • 14. Modern Day Symbols of Atoms of Different Elements
  • 15.
  • 16. Symbols for Some Elements  Aluminum : Al
  • 17. Argon : Ar
  • 18. Barium : Ba
  • 19. Boron : B
  • 20. Bromine : Br
  • 27. ► Gold : Au
  • 28. Hydrogen : H
  • 29. Iodine : I
  • 30. Iron : Fe
  • 31. Lead : Pb
  • 32. Magnesium : Mg
  • 34. Nitrogen : N
  • 35. Oxygen : O
  • 36. Potassium : K
  • 37. Silicon : Si
  • 42. Zinc : Zn
  • 43. Phosphorus : P
  • 44. Platinum : Pt
  • 45. Mercury : Hg
  • 47. Tin : Sn
  • 48. Bismuth : Bi
  • 49. Antimony : Sb
  • 50. Arsenic : As
  • 51. Manganese : Ma
  • 55. Strontium : Sr
  • 56. Beryllium : Be
  • 57. Zirconium :
  • 58. In 1961 a university accepted atomic mass unit, carbon-12 isotope was chosen as the standard reference for measuring atomic masses.
  • 59. One atomic mass unit is a mass unit equal to exactly one twelfth the mass of one atom of carbon-12.
  • 60. Atomic Masses of Few Elements Element Atomic Mass (u) (i) Hydrogen 1 (ii) Carbon 12 (iii) Nitrogen 14 (iv) Oxygen 16 (v) Sodium 23 (vi) Magnesium 24
  • 61. Element Atomic Mass (u) (vii) Sulphur 32 (viii) Chlorine 35.5 (ix) Calcium 40
  • 62. Atoms of most elements are not able to exist independently.
  • 63.  Atoms form molecules and ions.  These molecules or ions aggregate in large numbers to form the matter that we can see, feel or touch.
  • 64. About Molecules  A molecule is a general group of two or more atoms that are chemically bonded together, that is, tightly held together by attractive forces.
  • 65. A molecule can be defined as the smallest particle of an element or a compound & is capable of an independent existence and shows all the properties of that substance.
  • 66. Atoms of the same element or of different elements can join together to form molecules.
  • 67. Molecules of Elements • The molecules of an element are constituted by the same type of atoms.
  • 68. ► Moleculesof an element are constituted by the same type of atoms.
  • 69. ► Moleculesof many elements, such as argon(Ar), helium(He),…etc. are made up of only one atom of that element. ► But, this is not the case with most of the non-metals.
  • 70. For example, a molecule of oxygen consists of two atoms of oxygen and hence it is known as a diatomic module O2.  If 3 atoms of oxygen unite into a molecule, instead of the usual 2, we get ozone.
  • 71. The number of atoms constituting a molecule is known as its Atomicity.
  • 72. Atomicity of Some Elements  Type of Element : Non – Metal Name Atomicity (i) Argon - Monoatomic (ii) Helium - Monoatomic
  • 73. Type of Element : Non – Metal Name Atomicity (i) Oxygen Diatomic (ii) Hydrogen Diatomic (iii) Nitrogen Diatomic (iv) Chlorine Diatomic
  • 74. Type of Element : Non – Metal Name Atomicity (i) Phosphorus Tetra - atomic
  • 75. Type of Element : Non – Metal Name Atomicity (i) Sulphur Poly-atomic
  • 76. Atoms of different elements join together in definite proportions to form molecules of compounds.
  • 77. Molecules of Some Compounds  Compound : Water Combining Elements : Hydrogen, Oxygen Ratio by Mass : 1:8
  • 78. Compound : Ammonia Combining Elements : Nitrogen, Hydrogen Ratio by Mass : 14:8
  • 79. Compound : Carbon Dioxide Combining Elements : Carbon, Oxygen Ratio by mass : 3:8
  • 80. About Ions  Compounds composed of metals and non metals contain charged species. The charged species are known as Ions.
  • 81. An ion is a charged particle and can be negatively or positively charged.
  • 82. A negatively charged ion is called an ‘Anion’ and the positively charged ion is called a ‘Cation’.
  • 83. Some Ionic Compounds • Ionic Compound : Calcium Oxide Constituting Elements : Calcium & Oxygen Ratio by Mass : 5:2
  • 84. ► IonicCompound : Magnesium Sulphide Constituting Elements : Magnesium & Sulphur Ratio by Mass : 3:4
  • 85. ► IonicSolution : Sodium Chloride Constituting Elements : Sodium & Chlorine Ratio by Mass : 23:35.5
  • 86. Molecular Mass & Mole Concept  The molecular mass of a substance is the sum of the atomic masses of all the atoms in a molecule of the substance.
  • 87. It is therefore the relative mass of a molecule expressed in atomic mass units (u).
  • 88. The formula unit mass of a substance is a sum of the atomic masses of all atoms in a formula unit of a compound.
  • 89. Formula unit mass is calculated in the same manner as we calculate the molecular mass.  The only difference is that we use the word formula unit for those substances whose constituent particles are ions.
  • 90. EXAMPLE : Reaction of hydrogen and oxygen to form water: 2H2 + O2  2H2O The above reaction indicates that : (i) Two molecules of hydrogen combine with one molecule of oxygen to form two molecules of water. Or, (ii) 4 u of hydrogen molecules combine with 32 u of oxygen molecules to form 36 u of water molecules.
  • 91. We can infer from the above equation that the quantity of a substance can be characterised by its mass or the number of molecules.  But, a chemical reaction equation indicates directly the number of atoms or molecules taking part in the reaction.
  • 92. Therefore, it is more convenient to refer to the quantity of a substance in terms of the number of its molecules or atoms, rather than their masses.
  • 93. So, a new unit “Mole” was introduced.
  • 94. Multiple Choice Questions  Q 1 : A molecule does not signify (a) Atomic mass unit (b) 22.4 litres of a gas at STP (c) Gram molecular mass (d) None of the above
  • 95. Answer : Option : (a) Atomic mass unit
  • 96.  Q 2 : Which of the following does not change when a chemical reaction takes place ? (a) Volume (b) Mass (c) Physical properties (d) Chemical properties
  • 97. Answer : Option : (b) Mass
  • 98. Q 3 : Molecules of the following element are made up of only one atom of that element: (a) Iron (b) Sodium (c) Helium (d) Chlorine
  • 99. Answer : Option : (c) Helium
  • 100.  Q 4 : Law of definite proportion was given by (a) John Dalton (b) Lavoisier (c) Joseph Proust (d) Ritcher
  • 101. Answer : Option : (b) Lavoisier
  • 102. Q 5 : Argon is (a) Monoatomic (b) Diatomic (c) Triatomic (d) Polyatomic
  • 103. Answer : Option : (a) Monoatomic
  • 104. Q 6 : Which of the following supports Dalton's atomic theory of matter? (a) Formation of isotopes (b) Formation of isobars (c) Law of multiple proportion (d) Graphite and diamond though made from carbon, show different properties.
  • 105. Answer : Option : (c) Law of Multiple Proportion
  • 106.  Q 7 : Choose the odd molecule (a) Argon molecule (b) Chlorine molecule (c) Oxygen Molecule (d) Fluorine Molecule
  • 107. Answer : Option : (a) Argon Molecule
  • 108. • Q 8 : choose the element which will not have a charged valency (a) Calcium (b) Argon (c) Silicon (d) Aluminium
  • 109. Answer : Option : (b) Argon
  • 110. Q 9 : Take out the odd concept (a) Atomic mass unit (b) Mole (c) Avogadro (d) Gram atomic mass
  • 111. Answer : Option : (a) Atomic mass unit
  • 112.  Q 10 : Which one of the following elements give polyatomic molecules? (a) Ne (b) P (c) Ni (d) Si
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  • 150. Thank You !!! Compiled By : Sudarshan.S.K. Mail Your Feedback And Suggestions For Improvement To : suddurocks@yahoo.in