Small but mighty

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SmallButMighty

Design Negócios Diversão e humor

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. A study has been made to investigate the effect of some azoheterocyclic dyes of the type 3-arylazo 1,2,4-triazole (AT) on the corrosion of copper exposed to 0.5M nitric acid solution at different temperatures and at different AT concentrations. Using potentiodynamic polarization and Tafel electrochemical methods, it can be shown that AT compounds are good inhibitors of copper corrosion in HNO 3 solution. The kinetic and thermodynamic parameters of the inhibited system were determined. The high inhibition efficiency of these compounds may be due to the adsorption of the additive itself and/or the adsorption of the formed Cu(II)-AT complexes at the polarized electrode interface. Cathodic polarization measurements showed that AT dyes are predominantly cationic inhibitor

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The inhibition of corrosion of iron in 2M nitric acid and 2M sulfuric acid solutions by substituted phenylhydantoin, thiohydantoin, and dithiohydantoin compounds was measured using thermometric, weight loss, and polarization methods. The three methods gave consistent results. The polarization curves indicated that the hydantoin compounds act as mixed-type inhibitors. The adsorption of the inhibitors were found to obey the Temkin adsorption isotherm. The higher inhibition ef®ciency of the additives in nitric with respect to sulfuric acid solution may be attributed to the reduced formation of soluble quaternary nitrogen salts in nitric acid medium, favouring adsorption of the parent additive on the metal surface. The obtained results indicate that the corrosion rate of iron in both acids increases with increasing temperature, both in absence and presence of the tested inhibitors. Kinetic-thermodynamic model functions and Temkin isotherm data are compared and discussed. The synergistic effect of halide anions on the inhibition ef®ciency of the hydantoin compounds was also investigated.

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Small but mighty

1. aka. SMALL BUT MIGHTY

3. BY YUSUF BALOGUN aka. Small But Mighty

4. DJ SMALL BUT MIGHTY

7. Una Papa, Una Go Fall For My Hand One Day BY : YUSUF BALOGUN aka. SMALL BUT MIGHTY

Small but mighty

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Small but mighty