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SANDWICH METALLIC THERMAL PROTECTION
 PANELS WITH PERIODIC CELLULAR CORE
             STRUCTURE
Hybrid Composites

•   Hybrid Composites, wherein one uses more than one type of fiber.

•   Cost- performance effectiveness can be increased by judiciously using
    different reinforcement types and selectively placing them to get the
    highest strength in highly stressed locations and directions.

•   For example, in a hybrid composite laminate, the cost can be
    minimized by reducing the carbon fiber content, while the
    performance is maximized by optimal placement and orientation of
    the fiber.
Possibilities of Hybridization
Part of the E–ρ property chart
Material-property chart of thermal conductivity and
Young’s modulus
Young’s modulus and density
Classification of Hybrid Composites

• Hybridisation is commonly used for improving the properties and for
  lowering the cost of conventional composites. There are different types
  of hybrid composites classified according to the way in which the
  component materials are incorporated. Hybrids are designated as
   i) Sandwich ii) Interply      iii) Intraply    iv) Intimately mixed
• Sandwich: one material is sandwiched between layers of another.
• Interply: alternate layers of two or more materials are stacked in
  regular manner.
• Intraply: Rows of two or more constituents are arranged in a regular
  or random manner.
• Intimately mixed: constituents are mixed as much as possible so that
  no concentration of either type is present in the composite material.
Sandwich Structure

•   Sandwich composites involve two or more layers of the same or
    different materials.

•   Fibrous form results mainly in fiber reinforcement direction.

•   Of course one can arrange fibers in two dimensional or even three
    dimensional arrays, but this still does not gainsay the fact that one is
    not getting the full reinforcement effect in directions other than the
    fiber axis.

•   If a less anisotropic behavior is the objective, then perhaps sandwich
    composites made of, say two different materials would be more
    effective.
Sandwich Structure

•   Sandwich structure, consists of high strength facings or skins, being
    adhesively bonded to the low density core.

•   Core: A centrally located layer of a sandwich construction, usually low
    density, which separates and stabilizes the facings and transmits shear
    between the facings and provides most of the shear rigidity of the
    construction.

•   Facing (skin/face/face sheet): The outermost layer, generally thin and
    of high density, which resists of most of the edgewise loads and flatwise
    bending moments.

•   Adhesives: The adhesives are used to bind the Core and Facing.
Sandwich Structure

•   Sandwich panels are used in bending and compression dominated
    components.

•   The face sheets carry the applied in-plane and bending loads.

•   The core resist the transverse shear and transverse normal loads, as
    well as keep the facings supported and working as a single unit.

        face sheet
     adhesive layer
       honeycomb
Sandwich panels (broken line) extend the range of
flexural modulus
Selection of Materials for High
Temperature Applications ( T >7000c )
Materials for selection

•   Metallic materials
•   Polymeric materials
•   Ceramic materials
•   Composite materials




                          13
Properties for selection

•   Thermal expansion coefficient
•   Electrical conductivity
•   Oxidation resistance
•   Corrosion resistance
•   Yield strength
•   Elastic modulus
•   Joinability
•   Formability
•   Cost
•   Others, including resistance to hydrogen embrittlement,
    and machinability
                                                              14
Maximum service temperature of common
       Engineering Materials




                                 Cont’d…
                                           15
Maximum service temperature of common
       Engineering Materials




                                Cont’d…
                                          16
Maximum service temperature of common
       Engineering Materials




                                        17
T < 700OC

•   Plain carbon steels (%C < 0.08 to 1.03 ) Normalizing
     – Increase in carbon % improves the creep strength
     – Aluminium used as deoxidizer produce fine grain and reduces creep strength
     – Aluminium effects reduced by presence of Manganese and molybdenum
•   Low alloy steels (Alloy %< 10)
     – Molybdenum and vanadium raise the creep resistance
     – %C<0.15 + 0.5% Mo~6000C (super heater tubes)
     – Above this temperature spheroidization and graphitization takes place and reduces
       creep strength
     – %Cr=1 increases the resistance to graphitization
     – Used for 7500c in boiler tubes




                                                                                       18
T > 700OC

•   Chromium + molybdenum + vanadium + C% upto 0.5
    – High yield strength and creep strength
    – Bolts, steam turbine rotors operating at 7500c
    – Chromium content will increase the resistance to corrosion and oxidation


     Cr.     Comp.       Operat.
                                                       Applications
    Steels    (%)        Temp.
     410                  7500C     Steam valve, bolts, pump shaft
     422                  9000C     Steam valve, bolts, pump shaft

                                    Heat-exchange equipment, condensers, piping
     430     16% Cr.      12500C
                                    and furnace parts
                                    Heat-exchange equipment, condensers, piping
     446     25% Cr.      17000C
                                    and furnace parts

                                                                                  19
Austenitic stainless steels

•   Chromium+nickel+carbon
    – Better creep properties than chromium steels



     Austen     Comp.      Operat.
                                                      Applications
     . Steels    (%)       Temp.
                                      Furnace linings, boiler baffles, thermocouple
                25% Cr
       310                  12000C    wells, aircraft-cabin heaters and jet-engine
                +20% Ni
                                      burner liners
                 18% Cr               steam liners, super heater tubes, gas turbines
       347      +11% Ni     1350 C
                                0
                                      and exhaust systems in reciprocating engines
                +Cb& Ta




                                                                                       20
Chromium-nickel-molybdenum-iron alloys

•   Small amount of titanium and aluminium added




      Trade     Comp.   Operat.
                                                  Applications
      Name       (%)    Temp.
      A-286                        Forgings for Turbine Wheels, Gas turbines,
                        9500C to
     Discaloy                      sheet-metal casings, housings and exhaust
                         11500C
     Incoloy                       equipments




                                                                                21
Nickel alloys

    – 50 to 70% nickel

    – 20% chromium

    – 10% molybedenum or tungsten

    – upto 20% cobalt

    – titanium and aluminium

•   Applications
    – Manifold, collector rings, exhaust valves of reciprocating engines, sheet form for
      combustion liners, tail pipes, casings of gas turbines and jet engines

    Cobalt+chromium+nickel alloys have lower strength
    used for wheels and buckets of gas turbines


                                                                                           22
Conclusion

•   Commercial Alloys lose their strength rapidly when heated above
    17000C
•   Allowable operating temperature can be raised by suitable base
    elements

•   MOLYBDENUM-47300F
•   TUNGSTEN-61700F




                                                                      23
FABRICATION
Metallic Foams

• Metallic foam can be defined as a metallic
  material with a cellular structure.

• Metal foams have plenty of pores inside
  and their density is much lower than the
  solid one.

•    Cellular materials are multifunctional
    materials with porous structure.
Preparation of Metal Foam

•   Liquid Metallurgy Route
•   Aluminium is melt in stir casting furnace
•   The foaming agent is added to Aluminium melt
•   Aluminium and foaming agent decompose and release the gases
•   When trapped gases in the solidifying metal convert it into a closed-
    cell foam

•   Foaming Agent
–   Titanium hydride      -        Effective Foaming Agent
–   Zirconium hydride     -        High Cost
–   Calcium carbonate     -        Low Cost ,Easily Available
–   Sodium Carbonate      -        Low Cost , Easily available
Preparation of Metal Foam

•   First stage
•   1.1 kg of Aluminium alloy is melt in stir casting furnace
•   The melt reaches 650 ºc, the furnace is turned off
•   Start the stirrer until the temperature reaches 635 ºC
•   Add the 3.3 wt % of foaming agent to the molten metal
•   Continue stirring up to 60sec
•   When the temperature reaches 580ºC,the rotating stirrer is stopped
•   After that crucible with foam can be taken out from the furnace
•   The metallic Foam is cooled by air

•   Second Stage
•   Insert the precursor into sintering furnace
•   Bake the precursor for 15min at 650ºc
•   Precursor (Foam) can be left cool in air
Preparation of Core Metallic structure
Pyramidal truss core fabrication process
Panel assembly unit cell
Fabricated Structure
Manufacturing Route of the Triangular Honeycomb




                  Slotting Together of the Constituent Elements




2 Shapes of Slotted Sheets Employed   Assembled Triangular Honeycomb Core
Periodic cellular Core structure
Foams and micro-truss structures are hybrids of
material and space
APPLICATIONS
Sandwich Assembly
Sandwich Thermal Insulation Panels

•   Exposed surface temperature found under such conditions was 5240C

•   Temperature of the air outside the colder (inner) surface of the
    sandwich panel was sustained at 210C (room temperature)
Comparison by varying the thickness
(Thermal Barrier Coating)
Questions
Thank you

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Presentation

  • 1. SANDWICH METALLIC THERMAL PROTECTION PANELS WITH PERIODIC CELLULAR CORE STRUCTURE
  • 2. Hybrid Composites • Hybrid Composites, wherein one uses more than one type of fiber. • Cost- performance effectiveness can be increased by judiciously using different reinforcement types and selectively placing them to get the highest strength in highly stressed locations and directions. • For example, in a hybrid composite laminate, the cost can be minimized by reducing the carbon fiber content, while the performance is maximized by optimal placement and orientation of the fiber.
  • 4. Part of the E–ρ property chart
  • 5. Material-property chart of thermal conductivity and Young’s modulus
  • 7. Classification of Hybrid Composites • Hybridisation is commonly used for improving the properties and for lowering the cost of conventional composites. There are different types of hybrid composites classified according to the way in which the component materials are incorporated. Hybrids are designated as i) Sandwich ii) Interply iii) Intraply iv) Intimately mixed • Sandwich: one material is sandwiched between layers of another. • Interply: alternate layers of two or more materials are stacked in regular manner. • Intraply: Rows of two or more constituents are arranged in a regular or random manner. • Intimately mixed: constituents are mixed as much as possible so that no concentration of either type is present in the composite material.
  • 8. Sandwich Structure • Sandwich composites involve two or more layers of the same or different materials. • Fibrous form results mainly in fiber reinforcement direction. • Of course one can arrange fibers in two dimensional or even three dimensional arrays, but this still does not gainsay the fact that one is not getting the full reinforcement effect in directions other than the fiber axis. • If a less anisotropic behavior is the objective, then perhaps sandwich composites made of, say two different materials would be more effective.
  • 9. Sandwich Structure • Sandwich structure, consists of high strength facings or skins, being adhesively bonded to the low density core. • Core: A centrally located layer of a sandwich construction, usually low density, which separates and stabilizes the facings and transmits shear between the facings and provides most of the shear rigidity of the construction. • Facing (skin/face/face sheet): The outermost layer, generally thin and of high density, which resists of most of the edgewise loads and flatwise bending moments. • Adhesives: The adhesives are used to bind the Core and Facing.
  • 10. Sandwich Structure • Sandwich panels are used in bending and compression dominated components. • The face sheets carry the applied in-plane and bending loads. • The core resist the transverse shear and transverse normal loads, as well as keep the facings supported and working as a single unit. face sheet adhesive layer honeycomb
  • 11. Sandwich panels (broken line) extend the range of flexural modulus
  • 12. Selection of Materials for High Temperature Applications ( T >7000c )
  • 13. Materials for selection • Metallic materials • Polymeric materials • Ceramic materials • Composite materials 13
  • 14. Properties for selection • Thermal expansion coefficient • Electrical conductivity • Oxidation resistance • Corrosion resistance • Yield strength • Elastic modulus • Joinability • Formability • Cost • Others, including resistance to hydrogen embrittlement, and machinability 14
  • 15. Maximum service temperature of common Engineering Materials Cont’d… 15
  • 16. Maximum service temperature of common Engineering Materials Cont’d… 16
  • 17. Maximum service temperature of common Engineering Materials 17
  • 18. T < 700OC • Plain carbon steels (%C < 0.08 to 1.03 ) Normalizing – Increase in carbon % improves the creep strength – Aluminium used as deoxidizer produce fine grain and reduces creep strength – Aluminium effects reduced by presence of Manganese and molybdenum • Low alloy steels (Alloy %< 10) – Molybdenum and vanadium raise the creep resistance – %C<0.15 + 0.5% Mo~6000C (super heater tubes) – Above this temperature spheroidization and graphitization takes place and reduces creep strength – %Cr=1 increases the resistance to graphitization – Used for 7500c in boiler tubes 18
  • 19. T > 700OC • Chromium + molybdenum + vanadium + C% upto 0.5 – High yield strength and creep strength – Bolts, steam turbine rotors operating at 7500c – Chromium content will increase the resistance to corrosion and oxidation Cr. Comp. Operat. Applications Steels (%) Temp. 410 7500C Steam valve, bolts, pump shaft 422 9000C Steam valve, bolts, pump shaft Heat-exchange equipment, condensers, piping 430 16% Cr. 12500C and furnace parts Heat-exchange equipment, condensers, piping 446 25% Cr. 17000C and furnace parts 19
  • 20. Austenitic stainless steels • Chromium+nickel+carbon – Better creep properties than chromium steels Austen Comp. Operat. Applications . Steels (%) Temp. Furnace linings, boiler baffles, thermocouple 25% Cr 310 12000C wells, aircraft-cabin heaters and jet-engine +20% Ni burner liners 18% Cr steam liners, super heater tubes, gas turbines 347 +11% Ni 1350 C 0 and exhaust systems in reciprocating engines +Cb& Ta 20
  • 21. Chromium-nickel-molybdenum-iron alloys • Small amount of titanium and aluminium added Trade Comp. Operat. Applications Name (%) Temp. A-286 Forgings for Turbine Wheels, Gas turbines, 9500C to Discaloy sheet-metal casings, housings and exhaust 11500C Incoloy equipments 21
  • 22. Nickel alloys – 50 to 70% nickel – 20% chromium – 10% molybedenum or tungsten – upto 20% cobalt – titanium and aluminium • Applications – Manifold, collector rings, exhaust valves of reciprocating engines, sheet form for combustion liners, tail pipes, casings of gas turbines and jet engines Cobalt+chromium+nickel alloys have lower strength used for wheels and buckets of gas turbines 22
  • 23. Conclusion • Commercial Alloys lose their strength rapidly when heated above 17000C • Allowable operating temperature can be raised by suitable base elements • MOLYBDENUM-47300F • TUNGSTEN-61700F 23
  • 25. Metallic Foams • Metallic foam can be defined as a metallic material with a cellular structure. • Metal foams have plenty of pores inside and their density is much lower than the solid one. • Cellular materials are multifunctional materials with porous structure.
  • 26. Preparation of Metal Foam • Liquid Metallurgy Route • Aluminium is melt in stir casting furnace • The foaming agent is added to Aluminium melt • Aluminium and foaming agent decompose and release the gases • When trapped gases in the solidifying metal convert it into a closed- cell foam • Foaming Agent – Titanium hydride - Effective Foaming Agent – Zirconium hydride - High Cost – Calcium carbonate - Low Cost ,Easily Available – Sodium Carbonate - Low Cost , Easily available
  • 27. Preparation of Metal Foam • First stage • 1.1 kg of Aluminium alloy is melt in stir casting furnace • The melt reaches 650 ºc, the furnace is turned off • Start the stirrer until the temperature reaches 635 ºC • Add the 3.3 wt % of foaming agent to the molten metal • Continue stirring up to 60sec • When the temperature reaches 580ºC,the rotating stirrer is stopped • After that crucible with foam can be taken out from the furnace • The metallic Foam is cooled by air • Second Stage • Insert the precursor into sintering furnace • Bake the precursor for 15min at 650ºc • Precursor (Foam) can be left cool in air
  • 28. Preparation of Core Metallic structure
  • 29. Pyramidal truss core fabrication process
  • 32. Manufacturing Route of the Triangular Honeycomb Slotting Together of the Constituent Elements 2 Shapes of Slotted Sheets Employed Assembled Triangular Honeycomb Core
  • 34. Foams and micro-truss structures are hybrids of material and space
  • 37. Sandwich Thermal Insulation Panels • Exposed surface temperature found under such conditions was 5240C • Temperature of the air outside the colder (inner) surface of the sandwich panel was sustained at 210C (room temperature)
  • 38. Comparison by varying the thickness (Thermal Barrier Coating)