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                                                                                                         Ministry of Energy, Mines and Petroleum Resouxes




                           KIMBERLITES IN BRITISH COLU1M:BIA
           THE CROSS KIMBERLITE (82J/2)                                                     et al., 1986; Ijewliw,1986,1987; Pell, 1987) and reader
                                                                                                                                               the
                                                                                            is referred to those works for additional details.
                   The Cross diatremeis exposed at an elevation of 2200                          The Cross diatreme intrudes Pennsylvanian-Pennian
           metres on the north side of Crossing Creek, 8 kilometres                         Rocky Mountain     Snpergroupstrata(Hovdebo,19.57). It out-
           northwest of Elkford (latitude 5O0O5'24'W, longitude                             crops on steep face and an of approxitmate1:y by 15
                                                                                                      a                  area                   55
           114"59'48'W). It is 60 kilometres east of the Rocky Moun-                        metres is exposed. Its western contact is wall exposed and
           tain Trench, or approximately20 kilometres east of the axis                      clearly crosscuts shallow-dippingcrinoidal dolo!:tones and
           of the zone containing the other intrusions in the Elk River                     dolomitic sandstones  (Figure 82). Aminor s:hearzone forms
           - Bull River areas (Figure 73). It represents the only true                      the eastern contact. No thermal effects 011 the wallrocks
                                                                                            were observed.
           kimberlite known in the province to date. Access is by heli-
           copter or by four-wheel-drivevehicle and a hike along an
           undriveable road. It has previously been reported on
           (Meeks, 1979;Robertsetal., 1980;Grieve. 1981,1982;Hall




                           @                         Creek      f Crossing
                                                                  kirnberllts                                     /              
                   10.00

               I



                   5.00




                   0.00
                          0.00   5.00    10.00       15.00          20.00
                                                                               -25.00 3 .
                                                                                       00



                           03                                   + Crorrtng       Creek
               25.00                                                 kirnberllte
                                                                @ Averoga klrnberlile

               20.00

                          1              ponolitlc

                                                                    barmillto
                                                                    lephrite

                                                                    Iarnprophyre
                   50
                    .0
                                                                     bora11


                   0.00                                                        "
                      20.00      30.00    40.00        50.00           60.00       70.00
                                                  SI02

            Figure 83. Major element discriminant
                                                plots, Cross kirnberlite.                       Figure 84. Major element ternaryplots, Cross kinlberlite

                                                                                            -
           Bulletin 88                                                                                                                                     103
~~   ~




                                                                              Ministry of Energy, Mines and P e t r o o Resources




                  ECONOMHC CONSIDERATIONS AND
                        EXPLORATION POTENTIAL
     Many metals and industrial minerals are either pro-         al., 1986). The other British Columbia carbonatite com-
duced from alkaline rocks or are known to occur in eco-          plexes which have been examined all have averageNbzOs
nomically significant amounts in alkaline rocks. Alkaline        values of 0.30% or less, but there is excellent potentia1 for
rocks are a major sourceniobiumand rare-eartb elements
                        of                                       the discovery of other carbonatites with potential ore-grade
among the metals and of nepheline, barite, vermiculite, co-      niobium concentrations.
rundum and diamond among nonmetals. Molybdenum,
                             the                                       Tantalum is not abundant British Columbi:l carbona-
                                                                                                 in
zirconium,copper, fluorite, wollastonite and apatite are also    tites. Most of the complexes have NLxTa ratios typical of
recovered from alkaline rocks. The important features of         carbonatites, approaching 1OO:l or more ana niobium
economicallysignificant materials in alkaline rocks in Brit-     grades are never sufficient to result in signifi.cant concentra-
ish Columbia are outlined in the following summary.              tions of tantalum. Carbonatites in the Blue 'River area have
                                                                 anomalous Nb:Ta ratios, in the order of 4:l and tantalum
NIOBIUM AND TANTALUM                                             analyses of up to 2400 ppm are reported (Aaqui:.t, 1982b).
                                                                 On average, however, theniobium grades Blue River are
                                                                                                              at
     Carbonatites contain the bulk ofthe world's reserves of     low, ranging between 0.06 to 0.1% NbzOs and, therefore,
niobium, a metal whichis used in the production of high-         even with anomalous NbTa ratios, currently suteconomic
temperature speciality steels and superalloys for nuclear,       with respect to tantalum.
aerospace, heavy equipment pipeline applications. Nio-
                               and
binm also has important potential as a superconductor of         RARE-EARTH ELEMENTS AND
electricity at cryogenic temperatures  (Cunningham, 1985a).
The principal niobium mineral carbonatites is pyrochlore,
                                 in                              YTTRIUM
although other niobium-bearing species such as columbite              Rare-earth elements are concentratedl in all alkaline
and fersmite may also be present. The majority of the            rocks. In carbonatites they are present main'lyin the form of
world's niobium, approximately 85% of total production,          the cerium subgroup, or light rare earths. A considerable
comes from Araxa, Brazil, where pyrochlore has been con-         concentration of rare-earth elements may be contained in
centrated by residual weathering and grades arc in the order     common minerals such as calcite, dolomite, pyrochlore,
of 3% NbzOs. In Canada, niobium is mined by Niobec Inc.          fluorite, apatite, sphene and zircon. Rare-earth carbonate
(Teck Corporation and Cambior Inc.) at St. 1Ionor6, near          and fluorocarbonate minerals such as bastnaesite and
Chicoutimi, Quebec, where grades 0.5 to 0.67% NbzOs.
                                     are                         parisite, or phosphate minerals such as monazit: or xeno-
     Tantalum is a relatively rare, heavy, inert metal that is   time, may   also be present in alkaline suites a.nd contain rare-
used in electronics, chemical processing equipment,   metal-     earth elements. Yttrium, although not    strictly a rare earth, is
cutting tools and high-temperaturesteel alloys. It is recov-     commonly grouped with them its chemical properties are
                                                                                                   as
ered principally as a coproduct of other metal mining,           similar to the heavy rare earths.
associated with tin lodes, tin placers and beryllium-tin-nio-         These elements are used principally in petroleum-
biumpegmatites (Cunningham,1985b). Tantalum may          also    cracking catalysts, iron, steel and other metal-alloying
be present in significant amounts in carbonatites, generally     agents, glass-polishing compounds and      glass add Itives, per-
in the mineral pyrochlore. In alkaline rocks the Nb:Taratios     manent magnetsand phosphors for television and lighting
commonly exceed     100,whereas in granitic rocks theyaver-      (Hendrick, 1985). The rare earths also have importantpo-
age 4.8 (Cume, 1976b).                                           tential in the manufacture of superconducsm ar.d applica-
     Carbonatites in British Columbia areall anomalous in        tions in advanced ceramics and lasers, piuticnlarly yttria
niobium. The Aley   carbonatite complex appears have the
                                                   to            (Wheat, 1987). The U.S.A., Australia and China are the ma-
greatest niobium potential of any of the complexes so far        jor producers of rare earths (Griffiths, 1984; Hendrick,
discovered. Work by Cominco Ltd. since 1982, which in-            1985). Most of the economic recovery the U.I .A. comes
                                                                                                           in
cludes surface exploration and diamond drilling, has de-         from the Mountain Pass carbonatite in Califonia, which
fined extensive zones in both the rauhaugite core and            grades 7 8% total rare-earth oxides, predominiatly of the
                                                                           to
sovites, containing between two-thirds and three-quarters of     cerium subgroup. Bastnaesite is the principal ole mineral.
a percent NbzOs (K.R. Pride, personal communication,             InAustraliarareearthsarerecoveredfromnlonaziteplacers;
1986) and grades which rival the St. Honor6 complex
                         easily                                  in China rare earths are recovered fromtabular magnetite
in Quebec. Local areas containing greater than 2% Nbz0s          iron ores, fluorite-quartz-carbonate and tungsten-quartz
have been outlined in the Aley complex. At Aley,the nio-         veins, pegmatites and placers (Lee, 1970). Recently, the
                                                                                         tin
bium is present mainly in the minerals fersmite and pyro-        greatest demand has been for samarium and        nedymium to
chlore; columbite is also present in minor amounts (Pride et     be used inthe magnet industry and for yttrium in:?hosphors,


                                                             -                                                 _"
Bullelin 88                                                                                                                  107
_"
           British Columbia                                                                                                        "




                The diatreme is lithologically heterogeneous and, lo-          between phases be gradational or sharp. Athin dike, 10
                                                                                                 may
           tally, very friable. The west end o the outcrop is a light
                                                 f                             to 30 centimetres wide, cuts the central breccia phase
           green, strongly foliated rock containing some red   hematized            Ultramafic xenoliths are almost entirely serpentinized
           clasts, abundant pelletal lapilli and cobble-sizedpellets, as       pseudomorphs of olivine and pyroxene. The         original pres-
           well as autobreccia fragments (western     breccia phase). Fo-      ence of olivine is indicated by the typical olivine outlin e and
           liation is at a high angle to bedding in adjacent sediments.        fracture pattern; the grains, however are completel. 1 ser-1
           This grades eastwards to a massive, inclusion-poor light            pentinized. Some relict pyroxene, with      characteristic c:leav-
           green unit (western massive phase) in turn grades into
                                                 which                         age and   birefringence, is preserved. Talc replaces pyroxene
           a rock with 40% inclusions, 5 to 10% of which are ul-
                                                                               to a limited extent and also rims and veins sapentinized
           tramafic xenoliths (central breccia phase). The inclusions
                                                                               grains. Interstitial spinels are also present in minor amounts.
           often form the cores of accretionary lapilli (Plate 55). Far-
           ther east the rock is a dark green, massive, unfoliated unit        The interstitial spinels analysed on the energy dispersive
           withfewerclasts but containing abundant,randomly distrib-           system of the scanning electron microscope are in the chro-
           uted phlogopite books and ultramafic xenoliths (eastern             mite-hercynite solid solution series and can best be ~epre-
           massive phase). Bright red hematization is progressively            sented by the formula (Fe, Mg) (Cr, A1)204 (Ijewliw, 1987).
           more evident toward top and
                                  the         centre of the outcrop where      The xenoliths may be broadly classified as spinel lher-
           entire mineral or xenolithic fragments may be hematized.            zolites. Also preserved, although not abundant, are : m e t
                                                                                                                        as               €
           Pyrite is present as discrete grains in the groundmass and  as      lherzolites and glimmeritexenoliths (Hall et al., 1986,).
           rims surrounding   clasts where it may, in turn, be enveloped            The macrocryst population (0.5 to 5.0 mm insize:)con-
           by ragged, bright red hematite spotted phase). Contacts
                                            (red                               sists of completely serpentinized olivines, partially altered
                                                                               garnets, garnets with   kelyphitic rims andphlogopites. They
                                                                               may be                or
                                                                                        round, oval lath shaped in random orientation and
                                   TABLE 18                                    make up 10 to 20% of the rock volume. Garnets sf~ow             a
                             CHEMICALANALYSIS                                  moderate to high degree alteration or dissolution in reac-
                                                                                                           of
                          CROSSING CREEK KIMBERLITE
                                                                               tion with the matrix. None are enhedral. They are rounded
     ~~~

           ~
                                                                               and irregular in shape and surrounded kelyphitic rims or
                                                                                                                          by
           _wr %
            _                  1       2         3                             reaction coronas of opaque iron oxides (Ijewliw, 198711.The
               Si02
               Ti02
               A1203
               Fe203T
                     30.04
                      1.28
                      2.23
                      6.89
                                     30.74
                                      1.45
                                      2.31
                                      8.28
                                               30.02
                                                1.29
                                                2.21
                                                5.31
                                                          1.44
                                                          2.10
                                                          7.48
                                                                   I;:
                                                                     7.70
                                                                               garnets arepyrope rich. Phlogopites are occasionally zoned,
                                                                               with rims darker and morestrongly pleochroic than cores
                                                                               and often displayingreversepleochroism (Halletal., 1986).
                                                                                    The phenocryst population comprised of completely
                                                                                                                   is
               MnO    0.12            0.16      0.09      0.11
               MgO   25.03           27.72     23.54     27.75       0.151
                                                                    23.84      serpentinized olivine, together with phlogopite and :;pinel
               CaO   13.48            9.78     14.94      9.55      14.21      (Plate 56). Phlogopite grains vary insize, are randomly ori-
               Na20   0.07            0.09      0.03      0.02                 ented, square to rectangular in shape and relatively unal-
               K20    1.37            1.01      1.47      1.26       1.22
                                                                     0.05I
                                                                               tered. Reddish brown translucent spinels are disseminated
           LO1     17.87
                    15.38
                     17.04                                15.4      17.37
           no5        0.99            1.06      1.03      0.99                 in the groundmass and show magnetite reaction rims
           - 0.14
           S                          0.23      0.09      0.12                 (Ijewliw, 1987). The groundmass composed ofca1ci:e and
                                                                                                                    is
             Total   98.68           98.22     97.88     98.35                 serpentine with minor apatite and anatase.
               ppm
               Ni            1000     1000      10W       1300           X90
               Cr        12941398
                           1369                           1747      1728
               co               60      56        54        70          55
               Rb               56      40        53        57          54
               Sr            1177    1073       1171      1452      14921
               Ba            3237    2642       3497      2648      3442
               Zr              292    322        301       313       367
               Nb              187    207        200       199       %30
               Y                18     22         21                    21
               La              134    157        126       132       197
               Ce              258    300        239       266       363
               Nd               na     na
                                       na         na                    na
               Yb            2 1        3                    0       .:-I
               sc         20.323.1              23.7        20      25.1
               Ta                7      14         9         11         11

           iu
           !"c
           j u
               Th
                    14
                    73   1
                               18
                              14
                             196
                              54
                                        19
                                       196
                                                  24
                                                  15
                                                208
                                                 50
                                                            2
                                                             18
                                                             ;
                                                              51
           All amlyss'8 b;vXRF, B.C. G.S.B.analytical laboraforv
                                                                         4
                                                                        41




           1. .CX5-6 K n
                       i                         .     .                              0.00      400.00     800.00    1200.00    1600.00
           2. - CX57BHemotire-spotred kimberlite: red-sparredphase:                                            Cr ppm             ~-
           3. - CX5-8A Kimberlife, easrem massivephase:
           4. - CX6-Dl Fine-grained crosscutting, inclusion-free dike;         Figure 85. "Average" values from Wederhal Maramatsu 1979.
                                                                                                                     and
           5. - CX5.7Micaceouskimberlite, red-sparfedphase.                    Ni vs Cr plot, Cross kimberlite.



           104                                                                                                      Geological Survey Itranch
Ministry of Energy, Mines and Petroleum Resources


GEOCHEMISTRY                                                                       GEOCHRONOLOGY
     TheCrossdiatreme is the only trne kimberlite so far          Rubidium-strontiumdating of micaseparateshas
recognized in the province. It fits both the petrologic and   yie,ded Pemo-T~assicages of 240            244 k,a for the
geochemical definitions of a kimberlite (Figures 83 and 84;
                                                              Cross kimberlite (Grieve, 1982; Smith, 1983; F:all et al.,
Table 18 ). Although it appears to bequite a heterogeneous
intrusion,        analyzed were all v e similar geochemi-
                                           ~                  1986 ). Both the Cross kimherlite and its hostrocks are sig-
cally. It is characterizedby low silica, high magnesium, high  nificantly younger than other British Cohtmbia diatreme
strontium and high nickel and chrome(Figure 85; Table 18). suites.




                                                                                                         ~~-
Bulletin 88                                                                                                           105
~-
106   Geological Survey Eranch
engineering ceramics and superconductors(Roskill Infor-             he 1 to 4 metres wide and over metres long. Mafic syenite
                                                                                                   30
mation Services, 1988).                                             dikes in the area generally contain lower concentrations of
      Significant enrichment in rare-earth elements is re-          rare earths than the pegmatites; local concentrations up to
ported from five localities in British Columbia, the Aley           4.26% total rare earths have been found (Halleran and
complex and Rock Canyon Creek, both Rocky Monn-
                                           in the                   Russell, 1990). Very little work has been done the IvIount
                                                                                                                   in
tains; the Wicheeda Lake area along the Rocky Mountain              Bisson area and preliminary results indicate some potential;
Trench near Prince George; Kechika River area in the
                               the                                  this area might warrant further work in the future, particu-
 Cassiar Mountains; and the Mount Bisson area in the                larly if the demand for cerium and lanthanum incream.
Omineca Mountains. Aley narrow
                        At              dikes enrichedin rare-           The presence of these five highly anomalous occur-
earth elements, and locally fluorite, cnt the altered sedi-         rences indicates that British Columbia is highly prospwtive
ments peripheral to the main complex. Samplescontaining             for economic accumulations of carbonatite-related rare-
in excess of 2.1% total rare-earth oxides are present. The          earth elements.
rare earths are contained in carbonate minerals as bast-
                                                   such
 naesite, burbankite, cordylite and huanghoite (Miider,             ZIRCONIUM
 1987). These dikes are thin and sporadically developed and,
although worthy ofnote, not of major economic         interest.          Zirconium is strongly concentrated in some alkaline
      At Rock Canyon Creek a    metasomatically altered    (feni-   rocks and comprise up 2%. The main zirconium
                                                                               may                to                          min-
tized) zone rich in rare earths and fluorite, measuring ap-         erals present in these rocks are zircon, eudyialite (Na-Zr sili-
proximately 1000 by 100 metres, has been identified.                cate) and haddeleyite (ZrOz), with alkaline rocks beir,g the
 Samplescontaininginexcessof 2.7%total rare-earthoxides             only known source of substantial amounts of haddele yite.
 (predominantly cerium and lanthanum oxides) have been                   The major application of zirconium is in four dries
obtained from outcrops this zone.The rare-earth fluoro-
                           of                                       where it is in mineral form facing for molds for metal
                                                                                used                  as
carbonate minerals    hastuaesite and parisite, and gorceixite,     casting. It is also used in refractories, nuclear powerappli-
a phosphate   mineral, have been identified. At RockCanyon          cations and chemical processing equipment. increasing
                                                                                                                    Of
 Creek, locally high rare-earth values at surface, the size of      importance is the application of zirconium inadvanccd ce-
the zone and lack of extensive work suggest that further
               the                                                  ramics which have suchdiverse uses as heat-resistant tiles,
work is warranted.                                                  sensors and automobileexhausts. The principal sources of
                                                                    zirconium are zircon recovered as a hyproducl. from tita-
      In the Wicheeda Lake area a series of alkaline rocks
including carbonatites, syenites and leucitites are exposed.        nium placer deposits and haddeleyite      produced as a copro-
                                                                    duct from   apatite mining ofthe Palabora carhonatite, Sonth
Work by TeckCorporation has indicated that one carhona-
                                                                    Africa and of niobium mining Araxa and Pocos C aldas
                                                                                                     at                  de
tite plug locally contains in excess of 4% total rare-earth
                                                                    carhonatites in Brazil (Adam, 1985).
elements and one trench, across part the carbonatite, ex-
posed material grading 2.60% total rare earths over its 42-              Zircon is a ubiquitous phase in carbonatitc: and
metre length (Betmanis, 1988). These valnes are                     nephelinesyenite gneiss complexesin BritishCo1umb.a and
predominantly in light rare earths, in particular cerium and        crystals often exceed 1 centimetre in length. The Aley com-
lanthanum,however, the results are favourahle and area  this        plex, Paradise Lake syenite, Verity carhonatite, Tjident
might warrant further work in the future, particularly ifthe        Mountain syenite and Lonnie and      Vergil complexes all con-
demand for cerium and lanthanum increases.                          tain coarse zircon inexcess of 1%. In the Lonnie. and 'Jergil
                                                                    complexes, the syenitic rocks may contain 3 to '15% zircon
      In the Kechika River area, alkaline rocks consisting of       locally. Althoughit is unlikely that any of these rocks could
syenites, malignites, breccias and fenites are intermittently       compete with placer deposits, it is possible that zircceium
exposed along a northwest-trending zone in excess of 15             could he produced as a hyprodnctof niobium 0.r rare..earth
kilometres in strike length. During a recent exploration pro-       mining and should hetested for.
gram, samplescontainingin excess      of 3.77% total rare-earth
oxides (mainly cerium snhgronp elements) werecollected
from carhonatite dikes; other samples containing up to              PHOSPHATES
 1.13% Y203, 0.30% NdzO3, 0.11% Sm2O3 and 0.14%                          Ultrabasic alkaline igneous complexes commonly con-
Dy2O3 were taken from phosphate-richsegregations, con-              tain high concentrations of phosphate, largely in the fcrm of
taining upto 19.3% P2O5, in a mylonitized      syenitekrachyte      themineralapatiteandapproximately 18%ofallphos&hates
(Pel1 et al., 1990). Rare-earth elements and yttrium in the         mined come from igneous complexes. Apatite: from car-
Kechika River area are present mainly in monazite, xeno-            bonatites is mined at Palabora, South Africa; Dorowa, Zim-
time and other phosphate minerals. The size of this zone,           babwe; the Kola Peninsula in the U.S.S.R.; and Araxa and
lack of detailed work and presence of anomalous concen-             JacupirangainBrazil (Currie, 1976a;Russell, 1987; Feman-
trations of heavy rare-earth elements suggest additional
                                                 that               des, 1989). Grades as low as 4% P2O5 are currently recov-
work is warranted.                                                  ered. Approximately 90% all the phosphatemined i:; used
                                                                                                 of
      Light rare-earth elements, particularly cerium and lan-       in the fertilizer industry; other uses include organicm d in-
thanum, are concentratedin allanite pegmatites and allan-           organic chemicals, soapsand detergents, pesticides, :nsec-
ite-hearing mafic syenite dikes that are associated with large      ticides, alloys, animal-food supplements, ceranics,
fenite zones in the Mount Bisson    area. Some of the pegma-        beverages, catalysts, motor lubricants, photographic mate-
tites reportedly contain up to 14.5% total rare earths and can      rials and dental cements.



108                                                                                                     Geological Survey 1:ranch
~   ~




                                                                               M n s r of Energy, Mines and P e t r e Resources
                                                                                iity


      In British Columbia, all carbonatites contain some apa-      1989). The remote  location of this body, howeve!; severely
tite. The Aley complex and carbonatites in the Blue River          limits its economic potential.
area are more enriched in apatite than many of the other
carbonatites, containing, on average, 5 to 15% apatite, with       VERMICULITE
P205 contents up to 11% (Tables 1 and and averaging
                                           9)              3.5
to 5%. The Ren    carbonatite also has an average1'20s content           Vermiculite is a mineral which expan& whm heated.
of approximately    3.5%, with maximum values of 4.2% (Ta-         It is formed from alteration o biotite or phlogopite and a
                                                                                                 f                          is
ble 12). Carbonatitedikes cutting ultramafic rocks of the Ice      characteristic accessory in ultrabasic rocks associated with
River complex locally contain np to 8% PzOs (Table 3).             carbonatites. Vermiculite is present in minor amounts   asso-
Syenitic mylonites in the Kechikaarea contain small zones          ciated with carbonatites in the Blue River area, but is not
which assay as high as 19.3% P20s and haveapatite as one           reported from other areas. The potential for vermi<:ulite pro-
of the major rock-forming minerals. contin.uity of
                                        The              these     duction from carbonatites in British Columbia is :xtremely
phosphate zones is unknown and it is unlikely that they            limited.
would be exploited for phosphate alone.
                                                                   MOLYBDENUM
      It has been estimated that the Aley complex may con-
tain as much as 15 billion tonnes of 5% P2O5, while other               Molybdenum is generally associated with granitic as
carbonatites probably contain only a few million tonnes of         opposed to syenitic rocks, but,in some c a w , it may bepre-
phosphate reserves (Butrenchnk, in preparation). Produc-           sent in alkaline complexes (Currie, 1976a). In British Co-
tion of phosphates from these carbonatites as a primary            lumbia, the nepheline syenite gneisses associate1 with the
commodity is unlikely in light of competition from sedi-           Frenchman Cap domecommonly contain nlolybdenite and
mentary deposits, but byproduct recovery apatite might
                                              of                   the Mount Copeland showings the focns of r.ignificant
                                                                                                       were
prove feasible, particularly in the case of Aley, if niobium       exploration and development  work inthe late 1960s (Fyles,
were to be mined.                                                  1970). Current economics,however, do natfavour exploi-
                                                                   tation ofmolybdenum from such deposits.
NEPHELINE AND NEPHELINE SYENITE                                    WOLLASTONITE
     Nepheline and nephelinesyenite are of major impor-                 Wollastoniteis an important mineral nscd primar-
                                                                                                             filler
tance in the glass and ceramicsindustries due to their high        ily in the paint and ceramics industries. It #:an b,: found in
alumina contentin the presence of abundant sodium; these           two main geological environments:contact .metarnorpbicor
elements act as a flux which affects the rate and temperature      metasomatic (skarn) deposits and in carbonatite!:, as a pri-
of melting, the flnidity of the melt andthe physical proper-       mary, magmatic mineral. Most world production comes
ties of the finished product. Small amounts also used in
                                               are                 from contact deposits (Harben andBates, 1990).
paints and as fillers in plastics. Canada is currently the larg-        Wollastonite has not been recognized in any carbona-
est free-world producer of nepheline syenite which is all          tites in British Columbia; however, it is worth looking for
quarried in the Blue Mountainregion of Ontario.                    in fntnre discoveries.
     Nepheline syenite occurs in large volumes in a number
of areas of British Columbia; the Ice River complex, Bear-         TITANIUM
paw Ridge, Paradise Lake, Trident Mountain, the Perry                  Titanium-bearing minerals are present in a inumber of
River area and Mount Copeland.With the exception of the            the carbonatite and alkaline rock complexesin Rritish Co-
latter, most are relatively inaccessible. TheMonntCopeland         lumbia. Sphene,perovskite and ilmenite have all been rec-
syenite gneisses, which are   located 25 kilometres northwest      ognized. As well, knopite, a rare-earth emiched variety of
of Revelstoke, may be reached by old      mining roads. Onav-      perovskite, has been reported from the Ice R.iver area
erage they contain moreiron, manganese, calcium andpo-             (Ellsworth and Walker, 1926).In most cases, these titanium
tassium, and less sodium, silica and aluminum     than thoseat     minerals are present in relatively low concent:ations; at
Blue Mountain (Table 11; Currie, 1976a). In general, the           Howard Creek, however, sphene is a rock-forming mineral
Mount Copeland      syenites are medium to coarse grained and      in a melteigite of limited spatial distribution. It is unlikely
it was considered that many of the impurities (ferromagne-         that titanium could be produced from any of th,:se wcur-
sian minerals - in particular biotite) could potentially be        rences.
removed by crushing and magneticseparation techniques;
however, beneficiation tests failed to produce a product with      DIAMOND
a low enough iron content to meet industry specifications
(White, 1989). Some of the other syenites, such asthe Para-             Diamonds were traditionally considered to be prcsent
disesyeniteorthelargehodyonTridentMountain,arequite                in economic concentrations in kimberlites oniy. Recent
similar in composition to those being minecl in Ontario.           studies have shown that they may also be recosered from
Beneficiation tests run on samples from Trident Mountain           lamproites, and they havealso been reported fro:n such di-
indicate that this syenite is low in magnetic impurities, has      verse rock typesas peridotites and even carbonaites. Only
a high recovery rate of nonmagnetic materials and, there-          one true kimberlite has been discovered Briti:;h Colum-
                                                                                                               in
fore, has good potential to produce a commercial-grade             bia, the Cross diatreme, but no results of laboratoly research
                                  a
nepheline syenite product with brightness of 85% (White,                                    or
                                                                   on mineral composition diamond recovery have been          re-


                                                                                                                _"
Bulletin 88                                                                                                                   109
~




British Columbia                                                                                                        "




Stevens, R.D., Delahio, R.N. and Lachance, G.R.  (1982):Age De-         sition of Three Basaltic MagmaTypes; in Kimberlites, Dia-
     terminations and Geological Shldies, K-AI Isotopic Ages,           tremes and Diamonds: Their Geology, Petrology and Geo-
     Report 16;Geological Surveyo Canada, Paper 82-2.
                                      f                                 chemistry,American Geophysical Union,   Procwdings ofthe
Stewart, J.H. (1972): Initial Deposits in the Cordilleran Geosyn-       Second International Kimherlite Conference, Volume 1,
     cline: Evidence of Late Precambrian (R my) Continental             pages 300-312.
     Separation; GeologicalSociefyofAmerica,Bulletin,Volume         Wheat, T.A. (1987):Advanced Ceramics Canada;
                                                                                                          in          Canadian In-
     83,pages 1345-1360.                                                stitute ofMining andMefaNurgy,Bulletin, Volume 80,Num-
Stewart, J.H. and Poole, F.G. (1974):Lower Paleozoic and Upper-         ber 900,pages 43-48.
     most Precambrian Miogeocline, Great Basin, Western             Wheeler, J.O. (1962): Rogers Pass Maparea, British Col~mbia
     United States; in Tectonics and Sedimentation, Sociefy of          and Alberta;Geological Survey o Canada, Map 43-1
                                                                                                        f                        962.
     Economic Paleontologists and Mineralogists,Special Puh-        Wheeler, J.O. (1963): Rogers Pass Map-area, British Colmhia
     lication 22,pages 28-57.                                           and Alberta;Geological Surveyo Canada, P a p 62.32.
                                                                                                        f
Symons, D.T.A. and Lewchuk, M.T. (in press): Paleomagnetism         Wheeler,J.O.(1965):BigBendMapArea,BritishColumhia;Geo-
     of the MississippianHP Pipe the Western Marginof the
                                    and                                  logical Survey of Canada, Paper 64-32.
     North American Craton; American Geophysical Union,
     Monograph Series.                                              Wheeler, J.O., Campbell, R.B., Reesor, J.E. and Mountjoy. E.W.
                                                                        (1972): Structural Style of the Southern Canadian C!ordil-
Taylor, G.C. and Stott, D.F. (1979): Monkman Pass (931)Map              lera; International Geological Congress, Excursion A-01-
     Area, British Columbia;
     File Report 630.
                               GeologicalSurvey o Canada, Open
                                                  f                      xo1.
                                                                    White, G.P.E. (1 982):Notes on Carbonatites in
                                                                                                                 CentralBriti ;h Co-
Thompson,R.I.(1978):GeologicalMapsandSectionsoftheHalf-                  lumbia; in Geological Fieldwork1981,B.C. Ministry of En-
     way River Map Area, British Columbia (94B); Geological              erg3 Mines and Pefroleum Resources,    Paper 1!>82-1, pages
     Survey o Canada, Open File Report
             f                          536.                             68-69.
                                        (1987)Extension and
Thompson, R.I., Mercier, E. and Roots, C.                       White, G.P.E. (1985): Further Notes on Carhonatims in C!entral
      its Influence onCanadian Cordilleran Passive-margin Evo-       British Columbia;in Geological Fieldwork1984,B.C: Min-
      lution; in ContinentalExtensional Tectonics, Howard,
                                                         M.P.,       istry of Energ3 Mines and Petroleum Resources, Paper
      Dewey, J.F. and Hancock,P.L., Editors, GeologicalSociety,      1985-1,  pages 95-100.
      Special Publication 28,pages 409-417.
                                                                White, G.V. (1989):Feldspar and Nepheline Syenite Potertial in
Vaillancourt, P. and Payne, J.G. (1979):Diamond Drilling Report      British Columbia;in Geological Fieldwork1988,B.C Min-
      on the LonnieRitch Claims, MansonCreek Area, Omineca           istry o Energy, Mines and Petroleum Resources. Paper
                                                                            f
      Mining Division; B. C. Ministry ofEnergy, Mines and Petro-     1989-1,  pages 483-487.
      leum Resources, Assessment Report7515.
                                                                Wooley, A.R. (1982):ADiscussion of CarhonatiteEvoluticm and
von Knorring, 0. and du Bois, C.G.B. (1961): Carbonatite Lava        Nomenclature and the Generation of Sodic :md Potassic
      from Fort Portal Area in Western Uganda;Nature, Volume         Fenites; Mineralogical Magazine,Volume 46,pages 13-17.
      192,pages 1064-1065.
                                                                Woyski, MS. (1980):Geology of the Mountain Pass Carbmatite
Warhol, W.N. (1980): Molycorp's Mountain Pass Operations; in         Complex - A Review; in Geology and Mineral  Weatk ofthe
                                    of
      Geology and Mineral Wealth the California Desert,  South       California Desert, South Coast Geological Society, pages
      Coast Geological Sociefy,  pages 359-366.                      367-377.
Wedepohl, K.H. and Mnramatsn, Y (1979):The Chemical Com-
                                    .
                                            the
      position of Kimberlites Compared with Average Compo-




                                                                                                                      -~
124                                                                                                      Geological         Branch
ported by industry.Microdiamonds have, however, report-         have also been reportedfrom alkaline lamprophyre dikes in
edly been recovered from of the lamprophyre diatremes
                            two                                 Montana.
in the Golden - Columbia Icefields area. One of the pipes             Nepheline syenites are known from a localities in
                                                                                                             few
reported to have yielded microdiamonds from    concentrates     B.C. (e&, Paradise Lake, Ice River, etc.). These areas have
collected and processedat two different times, from differ-     not been evaluated for their potential to contain gem corun-
ent laboratories. Asignificant amount additional research
                                       of                       dum. Alkaline lamphrophyres are present in the Rcckies
is necessary to establish if economic concentrations are pre-   (e.g., Golden cluster) and couldalso be prospected fa: gem
sent.                                                           corundum varieties.
                                                                      Blue corundum crystals (star sapphires) up to 1 to 2
GEMSTONES                                                       centimetres in size, have recently been discovered in the
     Corundum (sapphire, ruby) is a common accessory            Slocan Valley withina syenitic phase o the Valballa Gneiss
                                                                                                        f
mineral in silica-undersaturated, alumina-rich rocks as
                                                   such         Complex, part of the Passmore Dome. These gneisser also
nepheline syenites and nepheline-feldspar pegmatites. In        contain sphene and amphibole and, in outcrop, resemble
the Bancroft area of Ontario,corundum occurs nepheline-
                                              in                fenites in the Blue River and Perry River (Z.D. Hora,
                                                                                                            areas
                                    of
bearing rocks and marginal zones nepheline syenite in-          personal communication,1993). Fenites are widesprer.d, as-
trusions at Blue Mountain and elsewhere. Nepheline              sociated with carbonatites and syenite gneiss complexes
syenites at Cabonga Reservoir, Quebec contain blue corun-       within metamorphosed rocks or the Ominica Belt and
dum crystals mantled by biotite (Currie, 1976a). Sapphires                             for
                                                                should be prospected gem corundum.




                                                                                                             _"
110                                                                                              Geological Survey 3ranch
Ministry ojEnergy, Mines and Pelruleurn Resources




                                 SUMMARY AND CONCLUSIONS
CARBONATITESAND SYENITE                                            are sill-like bodies with extensive fenitic aureolss. Work
GNEISSES                                                           done to date indicates moderate enrichment in rare-earth
                                                                   elements, with or without niobium.
      Carbonatites and   syenite gneisses crop out inthreebelts         There appears to be a relationship between depth of
parallel to the Rocky Mountain Trench. The     intrusions in the   emplacement, degreeof associated metasonratism and en-
 eastern Rocky and Cassiar Mountain are middle Paleo-
                                        belt                       richment in economically interesting elements suchas nio-
 zoic, predominantly Devono-Mississippian in age, hosted           bium or rare earths. All of these factors are prohabl y related
by lower to middle Paleozoicstrata and therefore are rela-         to the original volatile content of the magma.. The most fa-
tively high-level intmsions. They can be large and elliptical      vourable areas for additional exploration for these slements
 in shape and have significant alteration halos (e&, Aley car-     would appear to bethose underlain by lower to middle Pa-
bonatite), consist simply of metasomatic alteration zones          leozoic strata of North American affinity. The western
                                         or
 (e.& Rock Canyon Creek showing), be extensive linear              Rocky Mountains and some      regions of the eastern 13mineca
belts comprising numerous and lithologically varied sills,         Belt, close to the Rocky Mountain Trench, have the best
 dikes and plugs (e.g. the Wicheeda Lake and Kechika River         potential. Byproduct recoveryof apatite and zircon should
 showings). The carbonatites in the eastern belt can be sig-       also be considered  when assessing the niobium or me-earth
 nificantly enriched in niobium, fluorine, yttrium and rare-       potential of any prospects.
 earth elements.                                                        Commercial-grade nepheline      syenite could pcttentially
      The central belt lies within the Omineca Belt, immedi-       be produced from the Trident Mountain       syenite, however,
ately west ofthe Rocky Mountain Trench. The intrusions in          current inaccessibility precludes immediate    exploitation. If
this belt are also Devono-Mississippian in age, hut are            this area were everto become moreaccessible, through the
hosted by Precambrian strata; they were not emplaced as            development of good loggingroads, the nepheline syenite
high in the stratigraphic succession as those in the eastem        potential of this body would warrant serious exar.lination.
belt. The carbonatites in the Omineca Mountainsare thin,           Other compositionally    similarsyenites are presentin British
discontinuous, sill-like intrusions generally with narrow          Columbia, but are also in remote locations and remain un-
fenite alteration halos. With one exception Mount Bis-
                                               (the                tested.
son intrusions), they are not enriched in niobium,
                               as                      fluorine
or rare-earth elements as their eastern counterparts.              KIMBERLJTES, LAMPROPHYRES AND
      The western belt, also within the Omineca Mountains,         OTHER ULTRABASIC DIATREMES
comprises intrusive and extrusive carbonatites and                      Ultrabasic diatremes have been recognized areas
                                                                                                                   in five
nepheline syenite gneisses hosted by the autochthonous             of British Columbia; the Kechika River and Ospika       River
cover sequence of the Frenchman Cap gneiss dome. The               areas of northern British Columbia, the Goldan, Bull River
enclosing metasedimentary rocks of uncertain age, how-
                                          are                      -Elk River and Elkford areas of the Kcatenays. Iri the Os-
ever, recent studies suggest that they mayhave been depos-         pika River area north of Mackenzie, and in the Columbia
ited in a period which spans Precambrianto Eocambrian
                              late                                 Icefields area north of Golden (Figure Z, the diatrwnes are
                                                                                                             )
time (HOy and Godwin, 1988). A single radiometric date,            characterized by macrocryst-rich breccias and dikes. The
obtained on one of the alkaline intrusive bodies (Mount            macrocryst population consists of clinopyroxene, phlo-
Copeland syenite) which occurs near the base of the man-
tling gneiss succession, indicates an age of emplacementof         gopite, green diopside, spinel and olivine, with either py-
                                                                   roxene or phlogopite as the most abundantphase. In some
circa 770 Ma for that intrusion (Okulitch et al., 1.981).This
                                                                   cases, microphenocrystic feldspars are present :,.nsmall
gives a minimum age for the basal part of the succession.          amounts. These rocks aretentatively classifi,ed as lampro-
Much higher in the mantling gneiss stratigraphy, overlying         phyres; the HPpipe in the Golden area and the Ospika pipe
the carbonatitehorizons, a strataboundlead-zincdeposit has         can he classified as aillikites, which are members c f the ul-
yielded an Eocamhrian to early Cambrian lead-lead date.            tramafic lamprophyreclan based on their modal mineralogy
This suggests that the highest stratigraphic levels of the         and, to a lesser extent, the chemistry. The other ultrabasic
mantling gneiss succession are Early Cambrian and the in-          intmsions in the Golden area are more difficltlt to 'classify;
tervening stratigraphy was deposited between Late Protero-         they appear to be most similar to amphibole-free alkaline
zoic and early Paleozoic time. The extrusive carhonatites          lamprophyres.In all cases the breccia pipes commonly con-
are located relatively high in the mantling gneiss stratigra-      tain multiple phases of intrusion characterized by variable
phy, approximately 100 metres below the lead4nc layer              proportions of xenoliths, macrocrysts and accretionary
and, like the lead-zinc deposit, are probably Eocambrian in        lapilli or spherical structules. The breccia matrix in some
age.                                                               cases is clearly magmatic. These pipes are characteristic of
      The carbonatites in the western belt comprise high-          the diatreme facies material, as described from kilnberlite
level intrusions and extrusives. The carbonatite intrusions        pipes and/or hypabysal-facies (Clement and Reid, 1986).



Bullelin 88                                                                                                                   111
.                            ~~




    Brirish Columbia                                                                     ~~~~
                                                                                                                            “




    They formed from extremely volatile-rich magmas, so rich,           diatreme-facies tufflsitic breccias. Some pipes bneached the
    in some cases, that as they reached the surface and vesicu-         paleosurface andthe upper parts of the crater zone contain
    lated, the magmatic phase exsolved from volatiles and
                                                 the                    beddedepiclasticorpyroclasticrocks.Anumhert~fthe])ipes
    actually formed the ‘bubbles’, as indicated by the spherical                           -
                                                                        in the Bull River Elk River      area intrude Ordovician-Silu-
    stmctures (or globular segregations) and armoured xeno-             rian Beaverfoot carbonate rocks and      contain bedded cl’ater-
    liths. At Lens Mountain, Mons Creek and Valenciennes                facies material which is unconformably overlain          b.,   the
    River sandy tuffisitic or gas-stream breccias, with an insig-       basal Devonianunit (MiddleDevonian) suggesting           anl3arly
    nificant recognizable igneous component, are present.
                                                     also               Devonian age of emplacement of approximately 4oC Ma.
         Rubidium-strontium and potassium-argon dates of                Other pipes and flows apparently underlie and predate the
    3381r3 and 323f10 Ma have      been obtained from phlogopite        Beaverfoot Formation, but cut middleSilurian rocks and,
    separates from the Ospika pipe. These dates indicate that           therefore, must be approximately 455 Ma in. age. The
    emplacement occurred inDevono-Mississippiantime, as is              Kechika pipe is also hosted by Ordovician to Silnrian litrata
    the case for the most of the carbonatites in the eastern and        and associatedwith bedded      tuffs whichmust be of the Same
    central belts. Aillikites and alnoites arenoted for their affili-   age as the host strata (possibly circa 450 Ma.).
    ation with carbonatites (Rock, 1986). Pipes and dikes from               The craters containing these breccias are envisaged to
    two areas north of Golden have also been dated. In area,
                                                          that          have a ‘champagne glass’ structure, similar to that of lam-
    most of the diatremes were emplaced slightly earlier, in            proite or basaltic craters, with no extensively developedrmt
    Early Devonian time (circa 400 Ma). Zircons from ultra-             zone. The breccias are commonly associated with cro5 scut-
    basic rocks in the Mons Creek yielded concordant
                                     area                      lead-    ting porphyritic dikes and flows, characterized by the pres-
    lead ages of 469 Ma; ifthese zircons are not xenocrystic, it        ence of phenocrystic olivine and titanaugite, with ahwdaut
    may indicate that there was athird period of emplacement            feldspar (plagioclaseorpotassiumfeldspar),titanaugite and
    in the Late Ordovicianto Early Silurian.                            opaque oxide microphenocrystsin a fine-grained ground-
         Intrusions in the Bull River and Kechika are dis-
                                                       areas            mass. These rocks are extremely       difficult to classify: they
    tinctly different than those in the Golden or Ospika areas.         are ultrabasic, and locally quite potassic, feldspar-bearing
    They are characterized by chaotic breccias containing abun-         rocks that can contain vesiculated glass lapilli and are gen-
    dant vesiculated glass lapilli, juvenile lapilli and rare altered   erally devoid of hydrous mafic minerals and       feldspathoids.
    olivine, altered pyroxene, feldspars and chromian spinel            They may have originated in volatile-enriched systems, but
    macrocrysts and by theabsence of primary micas. The ma-             not to the extent of the previous diatremes; as ihey n:ared
    trix of these breccias is not magmatic; they are crater and         the surface the volatiles exsolved fromthe maglna and not




    Figure 86. Structural position diaEemes, B - Bush River;C -Lens Mountain; D - Mons Creek;E - Valenciennes River;P HP pipe; G
                                 of
    - Shatch Mountain;H - Russell Peak;I - Blackfoot;J - Quinn Creek; K - Summer :L - Crossing Creek,
                                                                                                    Geology modified from Wheeler
    (1963),Wheeleretal., ( 1972),Leech (1979), Price(1981).


          ~~




    112                                                                                                       Geological Survey haranch
Ministry of Energy, Mines and Petrnleum Resourres


the reverse. In some cases they maybe tentatively classified        North America, it is   unlikely that significant concentrations
 as limburgites, in others they appear to be most similar to        of diamonds can found in nonkimberlitic rock!: originat-
                                                                                        be
 members of the alkaline basalt family, but gmerally are            ing so far from the stable craton; however, the we.;tern con-
more basic than typicalalkaline basalts which suggests that          tinental margin at the time of diatreme emplacement was
they are verging towardsnephelinites.                               probably significantly more complex       than theone proposed
      The last distinct rock typeis represented by one exam-        in Haggerty’s model for South Africa. The locat ion of the
ple, the Cross kimberlite, located at Crossing Creek, nortb                        of
                                                                    westem edge the continental mass at that time is unknown
 of Elkford. As the nameimplies, it is a true kimberlite, the        and the depth to the lithosphere-asthenosphere bcandary is
only one so far recognized in the province. It is apparently        also uncertain, therefore, the proposed constraints on dia-
a deeply eroded pipe      remnant and contains two generations      mond genesis may be not directly applicable.
of olivine, phlogopite, pyroxene, garnet and spinel
megacrysts as well as garnet and spinel lhemlite nodules            TECTONIC IMPLICATIONS
 (Hall etal., 1986). Rubidium-strontiumisotopic ratios indi-
cate that the pipe was emplaced in Permo-Tiiassic time,                   The emplacement of carbonatites, kimberlites and
circa 245 Ma (Grieve, 1982; Hall etal., 1986).                      other alkaline rocks in the Canadian Cordillera appears to
                                                                    be related, in part, to extension and  rifting along t t e western
      At this point it is difficult to completely assCss the depth  continental margin that produced and deepened the basin
 of origin and diamond     potential of theserocks. The Crossing    into which the miogeoclinal succession ‘was t.eposited.
Creek kimberlite apparently originated deep in the mantle, Sedimentological and stratigraphic evidence inc.icate that
it contains abundant pyrope      garnets and has sampled mantle the western continental margin was tectonically active
lithologies including garnet lherzolites. This suggests that it     throughout much of the Proterozoic and Paleozc,ic eras. It
may have originated at depths generally considered suffi-
                                                                    does not appear have behaved entirely in a passive man-
                                                                                       to
cient to be in the diamond field; however, diamond genesis          ner and therefore may not be strictly analogous lo the pre-
apparently depends on oxygen          fugacity as well as pressure  sent day Atlantic margin, as earlier workers proposed
and depth origin alone is not sufficient to predict thedia-
            of                                                      (Stewart, 1972; Stewart andPoole, 1974); rather it appears
mond potential of a pipe (Haggerty, 1986). The pipes inthe          that several superimposed ‘passive margin-type’ :;equences
 other arms of British Columbia do not appear to have origi-
                                                                    are present as a result of periodic extensional activity (Pell
nated as deep in the mantle as the Crossing Creek       kimberlite.
                                                                    and Simony, 1987; Thompson e t al., 1987). During these
They contain no good evidence of deep mantle xenoliths;             periods of extension, deep faults and fractures in the crust
the xenolith and xenocryst populationsare generally con-            may have released pressure and triggered partial melting,
fined to crustal material: rare eclogites, spinel. lberzolites,
                                                                    whichultimatelyresultedinalkalinemagmatism(Tab1e19).
chrome spinels and very rare pyrope garnets (Northcote,
 1983a, 1983b). This suggests an origin in the spinel lher-               The earliest event recorded alkaline activi:y in west-
                                                                                                        by
zolite field of the uppermantle, which is generally consid-         ern Canada is represented by the Mount Copelandsyenite
ered to be at pressures below those required for diamond            of Late Proterozoic in age (circa 770 to 750 Ma);it may
formation. Microdiamonds reportedly found in two of the             record extension or rifting of the North Ame:rican (craton    and
pipes in the Golden swarm suggest that these pipes may              the initiation of the Late Proterozoic Windermere basin. Di-
have sampled the uppermost levels of the diamond field.             abase dikes and sills of similar age (770 Ma) in northern
                                                                    Canada also record extension preceding Windemlere           depo-
      When comparedto current models, it appears that the
probability of British Columbia diatremescontaining eco-            sition (Armstrong et al., 1982). Slightly younger datas of
nomic concentrations of diamonds is low. From craton to             728 and 741 Ma (U-Pb, zircons) have been obtained from
margin, a sequence of kimberlite with diamond, kimberlite           granitic gneisses which appear to be basemen1 for Win-
                                                                    dermere Supergroup      strata in north-central and central Brit-
without diamond(e&, Cross) and diamond-free ultrabasic
                                                                    ish Columbia ( Parrish and Armstrong, 1983;        Evznchick ef
diatremes (nonkimberlitic) is commonly proposed (Hag-
gerty, 1986). In an   attempt to establish the original positions   al., 1984). This implies that rifting began as early as 770 Ma
                                                                    in some areas, but that the event spanneda pericd of time
of the diatremes relative to the North Americancontinent,
                                                                    and, locally,Windermere sedimentation not beginuntil
                                                                                                                 did
theirpositions have beenprojectedonto          cross-sections (Fig-
                                                                    after 730 Ma.
ure 86). If these sections were restored to predeformational
configurations, the pipes contained in the most westerly                  Sedimentary loading and synsedimentary       faulting (Lis
thrust sheet would have been the farthest outboard. The             and Price, 1976; Eisbacher, 1981; Root, 1.983; Bond and
Cross kimberlite is in the Bourgean thrust sheet and is the         Kominz, 1984; Devlin and Bond, 1984) accoun:ed for the
easternmost of the diatremes. The ultrabasic diatremes in           deepening of the basin and the continuation of deposition
the Bull Riverarea are carried by the Bull River Gypsum -           into the early Paleozoic. Minor extensional activity is also
fault (Figure 86), which is west of the Bourgeau thrust. As         indicated by the presence of acid to basic volcanic andin-
the faults are traced to tbe north, the Bull River- Gypsum          trusive rocks throughoutthe Hadrynian to early Paleozoic
thrust apparently dies out and the displacement is accom-           sedimentary wedge (Simony and Wind, 1970; Raeside and
modatcdby the Simpsons Pass          thrust. The alnoitic rocks and Simony, 1983; Pell and Simony, 1987; Sevigny, 1987).
alkaline lamprophyres north of Golden are carried on a                   Extrusion of   theMount Grace carbonatiteandintrusion
thrust (the Mons fault) which lies west of the Simpsons Pass of shallow-level carbonatites, accompanied by :he forma-
thrust and apparently originated the farthest outboard of the       tion of extensive zones of fenitization, probably occurred in
continent. If Haggerty’s model is applicable to western             Eocambrian to Early Cambrian time (Htiy and Godwin,



Bulletin 88                                                                                                                     113
Minisfry of Eneqy, Mines and Pet,%l    Resources


 1988). These rocks occur a relatively thin cover-succes-
                             in                                     ported from the mid-Devonian to early M:ississippian se-
sion above core gneisses of the Frenchman Cap dome,                 quence in the northern and central Canadian 'Cordillera
which suggests that the dome may reflect a tectonic high in         (Gordey, 1981; Mortensen, 1982; Gordey et al.. 1987) as
late Precambrian to Early Cambrian time. Emplacement of             well as in the southern Canadian Cordil.lera :Wheeler,
the alkalic rocks may have coincided      with foundering of an     1965).
extensive Lower Cambrian       platform to the east. This period         The Devono-Mississippian extension was synchronous
is also interpreted by many workers as the time of the rift-        with, or slightly postdated, compression to the south that
to-drift transition along the western continental margin            was associated with Antler
                                                                                         the        orogeny. Devono- Mississip-
(Bond and Kominz, 1984; Devlin and Bond, 1984;                      pian granites and granitic gneisses have also been docu-
Thompson et al., 1987). In the southwestern United States,          mented inthe Canadian Cordillera and Alaska (Okulitch     et
carbonatites of Eocambriau to Early Cambrian age are re-            ab, 1975; Dillonefal., 1980;   Montgomery, 1985: Okulitch,
ported from a number localities (Figure 87); for example,
                         of                                         1985;Mortensen 1986;Mortensenetal.,       19117).Theserocks
the McClure Mountain carbonatite-alkalic complex, the               crop out west of the alkaline intrusions and are believed to
Gem Park and the Iron Hill carbonatite complexes in C o b           have intruded near the western edge of the Paleozoic Cor-
rado and the Lobo Hills syenite and carbonatite in New              dilleran miogeocline (Okulitch er al., 1975). Aso during
Mexico (Fenton and Faure, 1970; Olson et al., 1.977; Loring         Devono-Mississippian time,a mixed volcanic and sedirnen-
and Armstrong, 1980; Annbrustmacher, 1984;           McLemore,      tary sequence, termed Eagle Bay assemEdage, was
                                                                                           the                            form-
              ).
 1984; 1987; Although these intrusions are structurally in-         ing o f fthe western contintental margin; these rocks record
board of the Mount Grace carbonatite, their emplacement             a change from an   island arc environment at the base of the
may be related to the same large-scale extensional tectonic         sequence, where   calcalkaline volcanics wen: forning above
event.                                                              a subductingplate, to a rift environment wbicb alkaline
                                                                                                               in
      Anumberofperiods ofPaleozoic        extension areinferred     volcanism and sedimentation took place 6:Schi;lrizza and
along the western continental margin; however, additional           Preto, 1987).
dating is necessary to clearly define these periods and elimi-
nate possibilities of overlap. The earliest event is Late Or-            Thesedatasuggestthatacomplextectonicre,:imemust
dovician to Ordovician-Silurianin age (circa 450 Ma) and            have pertained at the end of the Devonian and it was not
                                                                                                                  that
is recorded by the emplacementof some ultra'basic diatre-           simply a timeof extension. A more complex     mollel is nec-
                                                                    essary to explain westerly sources for Devono-:Mississip-
mes and alkaline lamprophyres in the southern Rocky
Mountains and the Golden area of British Columbia. The              pian miogeoclinal sediments, obduction a1 the latitude of
Bearpaw Ridge sodalite syenite (eastern belt, Figure 1)     may     present-day northern California and southern OIegon, and
also prove to be Ordovician to Early Silurian in age as was         emplacement of granites in southern British Colnmbia, the
originally proposed by Taylor and Stott (1980). who be-             Cariboo and Alaska approximately the same timeas ex-
                                                                                          at
lieved it to be a subvolcanic pluton   related to alkaline basalt   tension and alkaline intrusion were taking placl: near the
flows in the Silurian Nonda Formation. Syenites, trachytes,         eastern margin ofthe Canadian Cordilleran miog:ocline. A
carbonatites and ultrabasic diatremes and tuffs in the              sequence of events may have occurred which culminated     in
                                                                    the development of an incipient continental back:arc rift at
Kechika area may also be of a similar age. Carbonatites of
                                                                    a complex, attenuated margin (see Struik, 1987). as local-
approximatelythe same age are found Lemitar Moun-
                                          in the
                                                                    ized obduction (and possibly subduction) occurred to the
tains of New Mexico (McLemore,1987).
                                                                    south and outboard. Subduction probably   resulted inpartial
     A secondperiod of alkaline igneous activi.ty along the         melting and genesis of granite and calcalkaline volcanic
western margin of North America occurred in Early De-               rocks; this compressional regime was ap;parently super-
vonian time (circa 400 to 410 Ma). Most of the ultrabasic           ceded by an extensional regime. Alternatively, e:ctensional
and alkaline lamprophyres in the Golden area and somenl-            basins may have resulted from strike-slip faulting: outboard
trabasic diatremes in southern British Colnmbia were em-            of the preserved marginof the miogeocline, as pr,>posed by
placed at this time. Diatremebreccias in the Yukon Territory        Eisbacher (1983) and Gordeyet al. (1987:1; however, this
(e.g., Mountain diatreme, R.L. Armstrong, personal com-             scenario does notexplain the intrusion of g:raniter.
munication, 1988) of the same age. In a more continental
                     are
setting (Figure 87). Early  Devonian kimherlites are reported            The last Paleozoic extensional event is inferred liom
from thecolorado-Wyoming        State-Linedistrict (McCallum        the presence of Permo-Triassic kimberlite in the Rocky
et al., 1975; McCallum and Marbarak,        1976; Hauselet al.,     Mountains. Although only one example known, it is
                                                                                                              is            pos-
1979).                                                              sible that other alkaline intrusions of simihu age exist and
     A third Paleozoic extensional event at the end of the          that other evidence for extension may be discovered. As
Devonian (circa 350 to 370 Ma)resulted in the intrusion of          with theprevious event, Permo-Triassic extmsion occurred
carbonatites into the miogeoclinal successionin the Fore-           approximately synchronously with compression in the
land and Omineca belts. Aillikite diatremes(ultramafic lam-         southern Cordillera (Sonomau orogeny).
prophyres) and dikes in the Ospika River area were also                 In Late Jurassic to Early Tertiary time, orogmesis oc-
emplaced at this time. The tectonic instability resulting from      curred when a compressional regime established on the
                                                                                                           was
this major Devono-Mississippian       extensional event is also     Pacific margin whilerifting and the opening: ofthe Atlantic
evident in the stratigraphic record (Thompsonet al., 1987);         took place on the opposite side of the continent. During OIO-
volcanic rocks (someperalkaline in composition),synsedi-            genesis the continental margin prism was telascoped the
                                                                                                                          and
mentary block faults and chert-pebble conglomerates are       re-   alkaline igneous rocks were deformed,    metamorphosed and



Bulletin 88                                                                                                                  115
;     Tom
                                                                 LEGEND

                                                     WILLIAM HENRYBAY
                                                                                            .
                                                                                            I:        LEGEND
                                                                                              MOUNTAIN DIATREME
                                                i    SALMON BAY                               KECHIKA PIPE
                                                !    KECHIKA
                                                ,    ALEY
                                                i    LONNIE
                                                F    MOUNT BISSON
                                                1    WICHEEOA LAKE
                                                i    BEARPAW RIDGE
                                                IO   BLUE RIVER AREA
                                                II   TRiOENT MOUNTAIN
                                                I2   PERRY RIVER-MOUNT GRACE
                                                I3   MOUNT COPELAND
                                                14   THREE VALLEY GAP
                                                I5   ICE RIVER
                                                16   ROCK CANYON CREEK
                                                17   RAINEY CREEK
                                                I8   BEARPAW MOUNTAINS
                                                I9   RAVALLliLEMHl COUNTIES
                                                !O   IRON HILL. GUNNISON COUNTl
                                                !l   WET MOUNTAINS CUSTER
                                                     AND FREMONT COUNTIES
                                                !Z   GEM PARK/MsLURE MOUNTAiN
                                                !3   MONTE LARGO
                                                24   LEMITAR MOUNTAINS
                                                !5   MOUNTAIN PASS


                                                            SYMBOLS                                      SYMBOLS
                              19+               0 Age unknown                                   Age unknown
                                                                                             v Tertiary (-50 & -30Ma)
                                                01Tsriiary (Eocans) -50Mo
                                                + UpperCretocsour -90-95Ma
                                                                                            X Oevono-Mirrirrlplon -350Ha
                                                                                            # Permo-Trioaric -245Mo
                                       UNITED   X Dewno-Uisriraippian
                                                                                            0 Ordorician-Silurian -450Ma
                                                       350-375Ma                             A EarlyDevonian -4OOMo
     OCEAN                                      0 Ordoviclon-Silurlon            -45OMa
                                       STATES                                                t Placediamond
                                                                                                     r          Ioc~lity
                                                I Lower
                                                      Cambrion-EoCombrlon                   :D) MlsrodlomondIoEOlity
                                                       520-58OMo
                                                t L o bp r o t e r o r o l s   -770Mo
                                                A Mid-Pmlerozolc               1400-15OOM

                                  23
                                                     M C o r d l l l e r o n front
                                                     ,---Western          limit of the
                     ..                                      miageoc1ino1     rtrato
                              .

I



                              MEXICO
       0 . "

:i      KILOMFTRLI
                                       1                                                   I
:!
Minisfry o Energy, Mines and P e t r e Resoumes
                                                                                    f


transported eastwards in thrust sheets. Their present distr-    Cordillera, however, young calcalkaline lamprophyres,
bution near the Rocky Mountain    Trench is due to original     strongly alkaline basalts and miaskitic syenite complexes
location along a rifted continental margin, not to later tec-   such as KrugerMountain, Copper Mountainand theCoryel1
tonics. No syn or postorogenic carbonatites or alkaline nl-     intrusions are present.
tramafic diatremes have been discovered in the Canadian




Bulletin 88                                                                                                          I17
British   Columbia               "




118                  Geological S~rrvey
                                      3ranch
Ministry of Enevy, Mines andP e t l w Resources




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     the Interior, Bureau ofMines, Bulletin 675, pages 941-956.         Geological Society ofAmerica,Bulletin 95, pag:s 155-173.
Ahroon, T.A. (1979): Airborne Helicopter Magnetometer-Spec-        Bonney, T.G.(1902): On a Sodalite Syenite (Ditroit:) from Ice
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                                                                         Mines, Bulletin 675, pages 811-822.
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    (1969): Geology, McLeod Lake, British Columbia (933);            Currie, K.L. (1975): The Geology and Petrologyof the Ice River
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     Stratigraphic-Tectonic Significance of Proterozoic Diabase      Cunie, K.L. (1976a): The Alkaline Rocks Cmada: Geological
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                                                                                                              Columbia;Geologi-
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                                                                 -
Bulletin 88                                                                                                                      119
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)
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BCGS: Carbonatites, Nepheline Syenites & Related Rocks in British Columbia (Chapters 7&8) (Pell, 1994)

  • 1. ,.., ~ ~~~~ ~ Ministry of Energy, Mines and Petroleum Resouxes KIMBERLITES IN BRITISH COLU1M:BIA THE CROSS KIMBERLITE (82J/2) et al., 1986; Ijewliw,1986,1987; Pell, 1987) and reader the is referred to those works for additional details. The Cross diatremeis exposed at an elevation of 2200 The Cross diatreme intrudes Pennsylvanian-Pennian metres on the north side of Crossing Creek, 8 kilometres Rocky Mountain Snpergroupstrata(Hovdebo,19.57). It out- northwest of Elkford (latitude 5O0O5'24'W, longitude crops on steep face and an of approxitmate1:y by 15 a area 55 114"59'48'W). It is 60 kilometres east of the Rocky Moun- metres is exposed. Its western contact is wall exposed and tain Trench, or approximately20 kilometres east of the axis clearly crosscuts shallow-dippingcrinoidal dolo!:tones and of the zone containing the other intrusions in the Elk River dolomitic sandstones (Figure 82). Aminor s:hearzone forms - Bull River areas (Figure 73). It represents the only true the eastern contact. No thermal effects 011 the wallrocks were observed. kimberlite known in the province to date. Access is by heli- copter or by four-wheel-drivevehicle and a hike along an undriveable road. It has previously been reported on (Meeks, 1979;Robertsetal., 1980;Grieve. 1981,1982;Hall @ Creek f Crossing kirnberllts / 10.00 I 5.00 0.00 0.00 5.00 10.00 15.00 20.00 -25.00 3 . 00 03 + Crorrtng Creek 25.00 kirnberllte @ Averoga klrnberlile 20.00 1 ponolitlc barmillto lephrite Iarnprophyre 50 .0 bora11 0.00 " 20.00 30.00 40.00 50.00 60.00 70.00 SI02 Figure 83. Major element discriminant plots, Cross kirnberlite. Figure 84. Major element ternaryplots, Cross kinlberlite - Bulletin 88 103
  • 2. ~~ ~ Ministry of Energy, Mines and P e t r o o Resources ECONOMHC CONSIDERATIONS AND EXPLORATION POTENTIAL Many metals and industrial minerals are either pro- al., 1986). The other British Columbia carbonatite com- duced from alkaline rocks or are known to occur in eco- plexes which have been examined all have averageNbzOs nomically significant amounts in alkaline rocks. Alkaline values of 0.30% or less, but there is excellent potentia1 for rocks are a major sourceniobiumand rare-eartb elements of the discovery of other carbonatites with potential ore-grade among the metals and of nepheline, barite, vermiculite, co- niobium concentrations. rundum and diamond among nonmetals. Molybdenum, the Tantalum is not abundant British Columbi:l carbona- in zirconium,copper, fluorite, wollastonite and apatite are also tites. Most of the complexes have NLxTa ratios typical of recovered from alkaline rocks. The important features of carbonatites, approaching 1OO:l or more ana niobium economicallysignificant materials in alkaline rocks in Brit- grades are never sufficient to result in signifi.cant concentra- ish Columbia are outlined in the following summary. tions of tantalum. Carbonatites in the Blue 'River area have anomalous Nb:Ta ratios, in the order of 4:l and tantalum NIOBIUM AND TANTALUM analyses of up to 2400 ppm are reported (Aaqui:.t, 1982b). On average, however, theniobium grades Blue River are at Carbonatites contain the bulk ofthe world's reserves of low, ranging between 0.06 to 0.1% NbzOs and, therefore, niobium, a metal whichis used in the production of high- even with anomalous NbTa ratios, currently suteconomic temperature speciality steels and superalloys for nuclear, with respect to tantalum. aerospace, heavy equipment pipeline applications. Nio- and binm also has important potential as a superconductor of RARE-EARTH ELEMENTS AND electricity at cryogenic temperatures (Cunningham, 1985a). The principal niobium mineral carbonatites is pyrochlore, in YTTRIUM although other niobium-bearing species such as columbite Rare-earth elements are concentratedl in all alkaline and fersmite may also be present. The majority of the rocks. In carbonatites they are present main'lyin the form of world's niobium, approximately 85% of total production, the cerium subgroup, or light rare earths. A considerable comes from Araxa, Brazil, where pyrochlore has been con- concentration of rare-earth elements may be contained in centrated by residual weathering and grades arc in the order common minerals such as calcite, dolomite, pyrochlore, of 3% NbzOs. In Canada, niobium is mined by Niobec Inc. fluorite, apatite, sphene and zircon. Rare-earth carbonate (Teck Corporation and Cambior Inc.) at St. 1Ionor6, near and fluorocarbonate minerals such as bastnaesite and Chicoutimi, Quebec, where grades 0.5 to 0.67% NbzOs. are parisite, or phosphate minerals such as monazit: or xeno- Tantalum is a relatively rare, heavy, inert metal that is time, may also be present in alkaline suites a.nd contain rare- used in electronics, chemical processing equipment, metal- earth elements. Yttrium, although not strictly a rare earth, is cutting tools and high-temperaturesteel alloys. It is recov- commonly grouped with them its chemical properties are as ered principally as a coproduct of other metal mining, similar to the heavy rare earths. associated with tin lodes, tin placers and beryllium-tin-nio- These elements are used principally in petroleum- biumpegmatites (Cunningham,1985b). Tantalum may also cracking catalysts, iron, steel and other metal-alloying be present in significant amounts in carbonatites, generally agents, glass-polishing compounds and glass add Itives, per- in the mineral pyrochlore. In alkaline rocks the Nb:Taratios manent magnetsand phosphors for television and lighting commonly exceed 100,whereas in granitic rocks theyaver- (Hendrick, 1985). The rare earths also have importantpo- age 4.8 (Cume, 1976b). tential in the manufacture of superconducsm ar.d applica- Carbonatites in British Columbia areall anomalous in tions in advanced ceramics and lasers, piuticnlarly yttria niobium. The Aley carbonatite complex appears have the to (Wheat, 1987). The U.S.A., Australia and China are the ma- greatest niobium potential of any of the complexes so far jor producers of rare earths (Griffiths, 1984; Hendrick, discovered. Work by Cominco Ltd. since 1982, which in- 1985). Most of the economic recovery the U.I .A. comes in cludes surface exploration and diamond drilling, has de- from the Mountain Pass carbonatite in Califonia, which fined extensive zones in both the rauhaugite core and grades 7 8% total rare-earth oxides, predominiatly of the to sovites, containing between two-thirds and three-quarters of cerium subgroup. Bastnaesite is the principal ole mineral. a percent NbzOs (K.R. Pride, personal communication, InAustraliarareearthsarerecoveredfromnlonaziteplacers; 1986) and grades which rival the St. Honor6 complex easily in China rare earths are recovered fromtabular magnetite in Quebec. Local areas containing greater than 2% Nbz0s iron ores, fluorite-quartz-carbonate and tungsten-quartz have been outlined in the Aley complex. At Aley,the nio- veins, pegmatites and placers (Lee, 1970). Recently, the tin bium is present mainly in the minerals fersmite and pyro- greatest demand has been for samarium and nedymium to chlore; columbite is also present in minor amounts (Pride et be used inthe magnet industry and for yttrium in:?hosphors, - _" Bullelin 88 107
  • 3. _" British Columbia " The diatreme is lithologically heterogeneous and, lo- between phases be gradational or sharp. Athin dike, 10 may tally, very friable. The west end o the outcrop is a light f to 30 centimetres wide, cuts the central breccia phase green, strongly foliated rock containing some red hematized Ultramafic xenoliths are almost entirely serpentinized clasts, abundant pelletal lapilli and cobble-sizedpellets, as pseudomorphs of olivine and pyroxene. The original pres- well as autobreccia fragments (western breccia phase). Fo- ence of olivine is indicated by the typical olivine outlin e and liation is at a high angle to bedding in adjacent sediments. fracture pattern; the grains, however are completel. 1 ser-1 This grades eastwards to a massive, inclusion-poor light pentinized. Some relict pyroxene, with characteristic c:leav- green unit (western massive phase) in turn grades into which age and birefringence, is preserved. Talc replaces pyroxene a rock with 40% inclusions, 5 to 10% of which are ul- to a limited extent and also rims and veins sapentinized tramafic xenoliths (central breccia phase). The inclusions grains. Interstitial spinels are also present in minor amounts. often form the cores of accretionary lapilli (Plate 55). Far- ther east the rock is a dark green, massive, unfoliated unit The interstitial spinels analysed on the energy dispersive withfewerclasts but containing abundant,randomly distrib- system of the scanning electron microscope are in the chro- uted phlogopite books and ultramafic xenoliths (eastern mite-hercynite solid solution series and can best be ~epre- massive phase). Bright red hematization is progressively sented by the formula (Fe, Mg) (Cr, A1)204 (Ijewliw, 1987). more evident toward top and the centre of the outcrop where The xenoliths may be broadly classified as spinel lher- entire mineral or xenolithic fragments may be hematized. zolites. Also preserved, although not abundant, are : m e t as € Pyrite is present as discrete grains in the groundmass and as lherzolites and glimmeritexenoliths (Hall et al., 1986,). rims surrounding clasts where it may, in turn, be enveloped The macrocryst population (0.5 to 5.0 mm insize:)con- by ragged, bright red hematite spotted phase). Contacts (red sists of completely serpentinized olivines, partially altered garnets, garnets with kelyphitic rims andphlogopites. They may be or round, oval lath shaped in random orientation and TABLE 18 make up 10 to 20% of the rock volume. Garnets sf~ow a CHEMICALANALYSIS moderate to high degree alteration or dissolution in reac- of CROSSING CREEK KIMBERLITE tion with the matrix. None are enhedral. They are rounded ~~~ ~ and irregular in shape and surrounded kelyphitic rims or by _wr % _ 1 2 3 reaction coronas of opaque iron oxides (Ijewliw, 198711.The Si02 Ti02 A1203 Fe203T 30.04 1.28 2.23 6.89 30.74 1.45 2.31 8.28 30.02 1.29 2.21 5.31 1.44 2.10 7.48 I;: 7.70 garnets arepyrope rich. Phlogopites are occasionally zoned, with rims darker and morestrongly pleochroic than cores and often displayingreversepleochroism (Halletal., 1986). The phenocryst population comprised of completely is MnO 0.12 0.16 0.09 0.11 MgO 25.03 27.72 23.54 27.75 0.151 23.84 serpentinized olivine, together with phlogopite and :;pinel CaO 13.48 9.78 14.94 9.55 14.21 (Plate 56). Phlogopite grains vary insize, are randomly ori- Na20 0.07 0.09 0.03 0.02 ented, square to rectangular in shape and relatively unal- K20 1.37 1.01 1.47 1.26 1.22 0.05I tered. Reddish brown translucent spinels are disseminated LO1 17.87 15.38 17.04 15.4 17.37 no5 0.99 1.06 1.03 0.99 in the groundmass and show magnetite reaction rims - 0.14 S 0.23 0.09 0.12 (Ijewliw, 1987). The groundmass composed ofca1ci:e and is Total 98.68 98.22 97.88 98.35 serpentine with minor apatite and anatase. ppm Ni 1000 1000 10W 1300 X90 Cr 12941398 1369 1747 1728 co 60 56 54 70 55 Rb 56 40 53 57 54 Sr 1177 1073 1171 1452 14921 Ba 3237 2642 3497 2648 3442 Zr 292 322 301 313 367 Nb 187 207 200 199 %30 Y 18 22 21 21 La 134 157 126 132 197 Ce 258 300 239 266 363 Nd na na na na na Yb 2 1 3 0 .:-I sc 20.323.1 23.7 20 25.1 Ta 7 14 9 11 11 iu !"c j u Th 14 73 1 18 14 196 54 19 196 24 15 208 50 2 18 ; 51 All amlyss'8 b;vXRF, B.C. G.S.B.analytical laboraforv 4 41 1. .CX5-6 K n i . . 0.00 400.00 800.00 1200.00 1600.00 2. - CX57BHemotire-spotred kimberlite: red-sparredphase: Cr ppm ~- 3. - CX5-8A Kimberlife, easrem massivephase: 4. - CX6-Dl Fine-grained crosscutting, inclusion-free dike; Figure 85. "Average" values from Wederhal Maramatsu 1979. and 5. - CX5.7Micaceouskimberlite, red-sparfedphase. Ni vs Cr plot, Cross kimberlite. 104 Geological Survey Itranch
  • 4. Ministry of Energy, Mines and Petroleum Resources GEOCHEMISTRY GEOCHRONOLOGY TheCrossdiatreme is the only trne kimberlite so far Rubidium-strontiumdating of micaseparateshas recognized in the province. It fits both the petrologic and yie,ded Pemo-T~assicages of 240 244 k,a for the geochemical definitions of a kimberlite (Figures 83 and 84; Cross kimberlite (Grieve, 1982; Smith, 1983; F:all et al., Table 18 ). Although it appears to bequite a heterogeneous intrusion, analyzed were all v e similar geochemi- ~ 1986 ). Both the Cross kimherlite and its hostrocks are sig- cally. It is characterizedby low silica, high magnesium, high nificantly younger than other British Cohtmbia diatreme strontium and high nickel and chrome(Figure 85; Table 18). suites. ~~- Bulletin 88 105
  • 5. ~- 106 Geological Survey Eranch
  • 6. engineering ceramics and superconductors(Roskill Infor- he 1 to 4 metres wide and over metres long. Mafic syenite 30 mation Services, 1988). dikes in the area generally contain lower concentrations of Significant enrichment in rare-earth elements is re- rare earths than the pegmatites; local concentrations up to ported from five localities in British Columbia, the Aley 4.26% total rare earths have been found (Halleran and complex and Rock Canyon Creek, both Rocky Monn- in the Russell, 1990). Very little work has been done the IvIount in tains; the Wicheeda Lake area along the Rocky Mountain Bisson area and preliminary results indicate some potential; Trench near Prince George; Kechika River area in the the this area might warrant further work in the future, particu- Cassiar Mountains; and the Mount Bisson area in the larly if the demand for cerium and lanthanum incream. Omineca Mountains. Aley narrow At dikes enrichedin rare- The presence of these five highly anomalous occur- earth elements, and locally fluorite, cnt the altered sedi- rences indicates that British Columbia is highly prospwtive ments peripheral to the main complex. Samplescontaining for economic accumulations of carbonatite-related rare- in excess of 2.1% total rare-earth oxides are present. The earth elements. rare earths are contained in carbonate minerals as bast- such naesite, burbankite, cordylite and huanghoite (Miider, ZIRCONIUM 1987). These dikes are thin and sporadically developed and, although worthy ofnote, not of major economic interest. Zirconium is strongly concentrated in some alkaline At Rock Canyon Creek a metasomatically altered (feni- rocks and comprise up 2%. The main zirconium may to min- tized) zone rich in rare earths and fluorite, measuring ap- erals present in these rocks are zircon, eudyialite (Na-Zr sili- proximately 1000 by 100 metres, has been identified. cate) and haddeleyite (ZrOz), with alkaline rocks beir,g the Samplescontaininginexcessof 2.7%total rare-earthoxides only known source of substantial amounts of haddele yite. (predominantly cerium and lanthanum oxides) have been The major application of zirconium is in four dries obtained from outcrops this zone.The rare-earth fluoro- of where it is in mineral form facing for molds for metal used as carbonate minerals hastuaesite and parisite, and gorceixite, casting. It is also used in refractories, nuclear powerappli- a phosphate mineral, have been identified. At RockCanyon cations and chemical processing equipment. increasing Of Creek, locally high rare-earth values at surface, the size of importance is the application of zirconium inadvanccd ce- the zone and lack of extensive work suggest that further the ramics which have suchdiverse uses as heat-resistant tiles, work is warranted. sensors and automobileexhausts. The principal sources of zirconium are zircon recovered as a hyproducl. from tita- In the Wicheeda Lake area a series of alkaline rocks including carbonatites, syenites and leucitites are exposed. nium placer deposits and haddeleyite produced as a copro- duct from apatite mining ofthe Palabora carhonatite, Sonth Work by TeckCorporation has indicated that one carhona- Africa and of niobium mining Araxa and Pocos C aldas at de tite plug locally contains in excess of 4% total rare-earth carhonatites in Brazil (Adam, 1985). elements and one trench, across part the carbonatite, ex- posed material grading 2.60% total rare earths over its 42- Zircon is a ubiquitous phase in carbonatitc: and metre length (Betmanis, 1988). These valnes are nephelinesyenite gneiss complexesin BritishCo1umb.a and predominantly in light rare earths, in particular cerium and crystals often exceed 1 centimetre in length. The Aley com- lanthanum,however, the results are favourahle and area this plex, Paradise Lake syenite, Verity carhonatite, Tjident might warrant further work in the future, particularly ifthe Mountain syenite and Lonnie and Vergil complexes all con- demand for cerium and lanthanum increases. tain coarse zircon inexcess of 1%. In the Lonnie. and 'Jergil complexes, the syenitic rocks may contain 3 to '15% zircon In the Kechika River area, alkaline rocks consisting of locally. Althoughit is unlikely that any of these rocks could syenites, malignites, breccias and fenites are intermittently compete with placer deposits, it is possible that zircceium exposed along a northwest-trending zone in excess of 15 could he produced as a hyprodnctof niobium 0.r rare..earth kilometres in strike length. During a recent exploration pro- mining and should hetested for. gram, samplescontainingin excess of 3.77% total rare-earth oxides (mainly cerium snhgronp elements) werecollected from carhonatite dikes; other samples containing up to PHOSPHATES 1.13% Y203, 0.30% NdzO3, 0.11% Sm2O3 and 0.14% Ultrabasic alkaline igneous complexes commonly con- Dy2O3 were taken from phosphate-richsegregations, con- tain high concentrations of phosphate, largely in the fcrm of taining upto 19.3% P2O5, in a mylonitized syenitekrachyte themineralapatiteandapproximately 18%ofallphos&hates (Pel1 et al., 1990). Rare-earth elements and yttrium in the mined come from igneous complexes. Apatite: from car- Kechika River area are present mainly in monazite, xeno- bonatites is mined at Palabora, South Africa; Dorowa, Zim- time and other phosphate minerals. The size of this zone, babwe; the Kola Peninsula in the U.S.S.R.; and Araxa and lack of detailed work and presence of anomalous concen- JacupirangainBrazil (Currie, 1976a;Russell, 1987; Feman- trations of heavy rare-earth elements suggest additional that des, 1989). Grades as low as 4% P2O5 are currently recov- work is warranted. ered. Approximately 90% all the phosphatemined i:; used of Light rare-earth elements, particularly cerium and lan- in the fertilizer industry; other uses include organicm d in- thanum, are concentratedin allanite pegmatites and allan- organic chemicals, soapsand detergents, pesticides, :nsec- ite-hearing mafic syenite dikes that are associated with large ticides, alloys, animal-food supplements, ceranics, fenite zones in the Mount Bisson area. Some of the pegma- beverages, catalysts, motor lubricants, photographic mate- tites reportedly contain up to 14.5% total rare earths and can rials and dental cements. 108 Geological Survey 1:ranch
  • 7. ~ ~ M n s r of Energy, Mines and P e t r e Resources iity In British Columbia, all carbonatites contain some apa- 1989). The remote location of this body, howeve!; severely tite. The Aley complex and carbonatites in the Blue River limits its economic potential. area are more enriched in apatite than many of the other carbonatites, containing, on average, 5 to 15% apatite, with VERMICULITE P205 contents up to 11% (Tables 1 and and averaging 9) 3.5 to 5%. The Ren carbonatite also has an average1'20s content Vermiculite is a mineral which expan& whm heated. of approximately 3.5%, with maximum values of 4.2% (Ta- It is formed from alteration o biotite or phlogopite and a f is ble 12). Carbonatitedikes cutting ultramafic rocks of the Ice characteristic accessory in ultrabasic rocks associated with River complex locally contain np to 8% PzOs (Table 3). carbonatites. Vermiculite is present in minor amounts asso- Syenitic mylonites in the Kechikaarea contain small zones ciated with carbonatites in the Blue River area, but is not which assay as high as 19.3% P20s and haveapatite as one reported from other areas. The potential for vermi<:ulite pro- of the major rock-forming minerals. contin.uity of The these duction from carbonatites in British Columbia is :xtremely phosphate zones is unknown and it is unlikely that they limited. would be exploited for phosphate alone. MOLYBDENUM It has been estimated that the Aley complex may con- tain as much as 15 billion tonnes of 5% P2O5, while other Molybdenum is generally associated with granitic as carbonatites probably contain only a few million tonnes of opposed to syenitic rocks, but,in some c a w , it may bepre- phosphate reserves (Butrenchnk, in preparation). Produc- sent in alkaline complexes (Currie, 1976a). In British Co- tion of phosphates from these carbonatites as a primary lumbia, the nepheline syenite gneisses associate1 with the commodity is unlikely in light of competition from sedi- Frenchman Cap domecommonly contain nlolybdenite and mentary deposits, but byproduct recovery apatite might of the Mount Copeland showings the focns of r.ignificant were prove feasible, particularly in the case of Aley, if niobium exploration and development work inthe late 1960s (Fyles, were to be mined. 1970). Current economics,however, do natfavour exploi- tation ofmolybdenum from such deposits. NEPHELINE AND NEPHELINE SYENITE WOLLASTONITE Nepheline and nephelinesyenite are of major impor- Wollastoniteis an important mineral nscd primar- filler tance in the glass and ceramicsindustries due to their high ily in the paint and ceramics industries. It #:an b,: found in alumina contentin the presence of abundant sodium; these two main geological environments:contact .metarnorpbicor elements act as a flux which affects the rate and temperature metasomatic (skarn) deposits and in carbonatite!:, as a pri- of melting, the flnidity of the melt andthe physical proper- mary, magmatic mineral. Most world production comes ties of the finished product. Small amounts also used in are from contact deposits (Harben andBates, 1990). paints and as fillers in plastics. Canada is currently the larg- Wollastonite has not been recognized in any carbona- est free-world producer of nepheline syenite which is all tites in British Columbia; however, it is worth looking for quarried in the Blue Mountainregion of Ontario. in fntnre discoveries. Nepheline syenite occurs in large volumes in a number of areas of British Columbia; the Ice River complex, Bear- TITANIUM paw Ridge, Paradise Lake, Trident Mountain, the Perry Titanium-bearing minerals are present in a inumber of River area and Mount Copeland.With the exception of the the carbonatite and alkaline rock complexesin Rritish Co- latter, most are relatively inaccessible. TheMonntCopeland lumbia. Sphene,perovskite and ilmenite have all been rec- syenite gneisses, which are located 25 kilometres northwest ognized. As well, knopite, a rare-earth emiched variety of of Revelstoke, may be reached by old mining roads. Onav- perovskite, has been reported from the Ice R.iver area erage they contain moreiron, manganese, calcium andpo- (Ellsworth and Walker, 1926).In most cases, these titanium tassium, and less sodium, silica and aluminum than thoseat minerals are present in relatively low concent:ations; at Blue Mountain (Table 11; Currie, 1976a). In general, the Howard Creek, however, sphene is a rock-forming mineral Mount Copeland syenites are medium to coarse grained and in a melteigite of limited spatial distribution. It is unlikely it was considered that many of the impurities (ferromagne- that titanium could be produced from any of th,:se wcur- sian minerals - in particular biotite) could potentially be rences. removed by crushing and magneticseparation techniques; however, beneficiation tests failed to produce a product with DIAMOND a low enough iron content to meet industry specifications (White, 1989). Some of the other syenites, such asthe Para- Diamonds were traditionally considered to be prcsent disesyeniteorthelargehodyonTridentMountain,arequite in economic concentrations in kimberlites oniy. Recent similar in composition to those being minecl in Ontario. studies have shown that they may also be recosered from Beneficiation tests run on samples from Trident Mountain lamproites, and they havealso been reported fro:n such di- indicate that this syenite is low in magnetic impurities, has verse rock typesas peridotites and even carbonaites. Only a high recovery rate of nonmagnetic materials and, there- one true kimberlite has been discovered Briti:;h Colum- in fore, has good potential to produce a commercial-grade bia, the Cross diatreme, but no results of laboratoly research a nepheline syenite product with brightness of 85% (White, or on mineral composition diamond recovery have been re- _" Bulletin 88 109
  • 8. ~ British Columbia " Stevens, R.D., Delahio, R.N. and Lachance, G.R. (1982):Age De- sition of Three Basaltic MagmaTypes; in Kimberlites, Dia- terminations and Geological Shldies, K-AI Isotopic Ages, tremes and Diamonds: Their Geology, Petrology and Geo- Report 16;Geological Surveyo Canada, Paper 82-2. f chemistry,American Geophysical Union, Procwdings ofthe Stewart, J.H. (1972): Initial Deposits in the Cordilleran Geosyn- Second International Kimherlite Conference, Volume 1, cline: Evidence of Late Precambrian (R my) Continental pages 300-312. Separation; GeologicalSociefyofAmerica,Bulletin,Volume Wheat, T.A. (1987):Advanced Ceramics Canada; in Canadian In- 83,pages 1345-1360. stitute ofMining andMefaNurgy,Bulletin, Volume 80,Num- Stewart, J.H. and Poole, F.G. (1974):Lower Paleozoic and Upper- ber 900,pages 43-48. most Precambrian Miogeocline, Great Basin, Western Wheeler, J.O. (1962): Rogers Pass Maparea, British Col~mbia United States; in Tectonics and Sedimentation, Sociefy of and Alberta;Geological Survey o Canada, Map 43-1 f 962. Economic Paleontologists and Mineralogists,Special Puh- Wheeler, J.O. (1963): Rogers Pass Map-area, British Colmhia lication 22,pages 28-57. and Alberta;Geological Surveyo Canada, P a p 62.32. f Symons, D.T.A. and Lewchuk, M.T. (in press): Paleomagnetism Wheeler,J.O.(1965):BigBendMapArea,BritishColumhia;Geo- of the MississippianHP Pipe the Western Marginof the and logical Survey of Canada, Paper 64-32. North American Craton; American Geophysical Union, Monograph Series. Wheeler, J.O., Campbell, R.B., Reesor, J.E. and Mountjoy. E.W. (1972): Structural Style of the Southern Canadian C!ordil- Taylor, G.C. and Stott, D.F. (1979): Monkman Pass (931)Map lera; International Geological Congress, Excursion A-01- Area, British Columbia; File Report 630. GeologicalSurvey o Canada, Open f xo1. White, G.P.E. (1 982):Notes on Carbonatites in CentralBriti ;h Co- Thompson,R.I.(1978):GeologicalMapsandSectionsoftheHalf- lumbia; in Geological Fieldwork1981,B.C. Ministry of En- way River Map Area, British Columbia (94B); Geological erg3 Mines and Pefroleum Resources, Paper 1!>82-1, pages Survey o Canada, Open File Report f 536. 68-69. (1987)Extension and Thompson, R.I., Mercier, E. and Roots, C. White, G.P.E. (1985): Further Notes on Carhonatims in C!entral its Influence onCanadian Cordilleran Passive-margin Evo- British Columbia;in Geological Fieldwork1984,B.C: Min- lution; in ContinentalExtensional Tectonics, Howard, M.P., istry of Energ3 Mines and Petroleum Resources, Paper Dewey, J.F. and Hancock,P.L., Editors, GeologicalSociety, 1985-1, pages 95-100. Special Publication 28,pages 409-417. White, G.V. (1989):Feldspar and Nepheline Syenite Potertial in Vaillancourt, P. and Payne, J.G. (1979):Diamond Drilling Report British Columbia;in Geological Fieldwork1988,B.C Min- on the LonnieRitch Claims, MansonCreek Area, Omineca istry o Energy, Mines and Petroleum Resources. Paper f Mining Division; B. C. Ministry ofEnergy, Mines and Petro- 1989-1, pages 483-487. leum Resources, Assessment Report7515. Wooley, A.R. (1982):ADiscussion of CarhonatiteEvoluticm and von Knorring, 0. and du Bois, C.G.B. (1961): Carbonatite Lava Nomenclature and the Generation of Sodic :md Potassic from Fort Portal Area in Western Uganda;Nature, Volume Fenites; Mineralogical Magazine,Volume 46,pages 13-17. 192,pages 1064-1065. Woyski, MS. (1980):Geology of the Mountain Pass Carbmatite Warhol, W.N. (1980): Molycorp's Mountain Pass Operations; in Complex - A Review; in Geology and Mineral Weatk ofthe of Geology and Mineral Wealth the California Desert, South California Desert, South Coast Geological Society, pages Coast Geological Sociefy, pages 359-366. 367-377. Wedepohl, K.H. and Mnramatsn, Y (1979):The Chemical Com- . the position of Kimberlites Compared with Average Compo- -~ 124 Geological Branch
  • 9. ported by industry.Microdiamonds have, however, report- have also been reportedfrom alkaline lamprophyre dikes in edly been recovered from of the lamprophyre diatremes two Montana. in the Golden - Columbia Icefields area. One of the pipes Nepheline syenites are known from a localities in few reported to have yielded microdiamonds from concentrates B.C. (e&, Paradise Lake, Ice River, etc.). These areas have collected and processedat two different times, from differ- not been evaluated for their potential to contain gem corun- ent laboratories. Asignificant amount additional research of dum. Alkaline lamphrophyres are present in the Rcckies is necessary to establish if economic concentrations are pre- (e.g., Golden cluster) and couldalso be prospected fa: gem sent. corundum varieties. Blue corundum crystals (star sapphires) up to 1 to 2 GEMSTONES centimetres in size, have recently been discovered in the Corundum (sapphire, ruby) is a common accessory Slocan Valley withina syenitic phase o the Valballa Gneiss f mineral in silica-undersaturated, alumina-rich rocks as such Complex, part of the Passmore Dome. These gneisser also nepheline syenites and nepheline-feldspar pegmatites. In contain sphene and amphibole and, in outcrop, resemble the Bancroft area of Ontario,corundum occurs nepheline- in fenites in the Blue River and Perry River (Z.D. Hora, areas of bearing rocks and marginal zones nepheline syenite in- personal communication,1993). Fenites are widesprer.d, as- trusions at Blue Mountain and elsewhere. Nepheline sociated with carbonatites and syenite gneiss complexes syenites at Cabonga Reservoir, Quebec contain blue corun- within metamorphosed rocks or the Ominica Belt and dum crystals mantled by biotite (Currie, 1976a). Sapphires for should be prospected gem corundum. _" 110 Geological Survey 3ranch
  • 10. Ministry ojEnergy, Mines and Pelruleurn Resources SUMMARY AND CONCLUSIONS CARBONATITESAND SYENITE are sill-like bodies with extensive fenitic aureolss. Work GNEISSES done to date indicates moderate enrichment in rare-earth elements, with or without niobium. Carbonatites and syenite gneisses crop out inthreebelts There appears to be a relationship between depth of parallel to the Rocky Mountain Trench. The intrusions in the emplacement, degreeof associated metasonratism and en- eastern Rocky and Cassiar Mountain are middle Paleo- belt richment in economically interesting elements suchas nio- zoic, predominantly Devono-Mississippian in age, hosted bium or rare earths. All of these factors are prohabl y related by lower to middle Paleozoicstrata and therefore are rela- to the original volatile content of the magma.. The most fa- tively high-level intmsions. They can be large and elliptical vourable areas for additional exploration for these slements in shape and have significant alteration halos (e&, Aley car- would appear to bethose underlain by lower to middle Pa- bonatite), consist simply of metasomatic alteration zones leozoic strata of North American affinity. The western or (e.& Rock Canyon Creek showing), be extensive linear Rocky Mountains and some regions of the eastern 13mineca belts comprising numerous and lithologically varied sills, Belt, close to the Rocky Mountain Trench, have the best dikes and plugs (e.g. the Wicheeda Lake and Kechika River potential. Byproduct recoveryof apatite and zircon should showings). The carbonatites in the eastern belt can be sig- also be considered when assessing the niobium or me-earth nificantly enriched in niobium, fluorine, yttrium and rare- potential of any prospects. earth elements. Commercial-grade nepheline syenite could pcttentially The central belt lies within the Omineca Belt, immedi- be produced from the Trident Mountain syenite, however, ately west ofthe Rocky Mountain Trench. The intrusions in current inaccessibility precludes immediate exploitation. If this belt are also Devono-Mississippian in age, hut are this area were everto become moreaccessible, through the hosted by Precambrian strata; they were not emplaced as development of good loggingroads, the nepheline syenite high in the stratigraphic succession as those in the eastem potential of this body would warrant serious exar.lination. belt. The carbonatites in the Omineca Mountainsare thin, Other compositionally similarsyenites are presentin British discontinuous, sill-like intrusions generally with narrow Columbia, but are also in remote locations and remain un- fenite alteration halos. With one exception Mount Bis- (the tested. son intrusions), they are not enriched in niobium, as fluorine or rare-earth elements as their eastern counterparts. KIMBERLJTES, LAMPROPHYRES AND The western belt, also within the Omineca Mountains, OTHER ULTRABASIC DIATREMES comprises intrusive and extrusive carbonatites and Ultrabasic diatremes have been recognized areas in five nepheline syenite gneisses hosted by the autochthonous of British Columbia; the Kechika River and Ospika River cover sequence of the Frenchman Cap gneiss dome. The areas of northern British Columbia, the Goldan, Bull River enclosing metasedimentary rocks of uncertain age, how- are -Elk River and Elkford areas of the Kcatenays. Iri the Os- ever, recent studies suggest that they mayhave been depos- pika River area north of Mackenzie, and in the Columbia ited in a period which spans Precambrianto Eocambrian late Icefields area north of Golden (Figure Z, the diatrwnes are ) time (HOy and Godwin, 1988). A single radiometric date, characterized by macrocryst-rich breccias and dikes. The obtained on one of the alkaline intrusive bodies (Mount macrocryst population consists of clinopyroxene, phlo- Copeland syenite) which occurs near the base of the man- tling gneiss succession, indicates an age of emplacementof gopite, green diopside, spinel and olivine, with either py- roxene or phlogopite as the most abundantphase. In some circa 770 Ma for that intrusion (Okulitch et al., 1.981).This cases, microphenocrystic feldspars are present :,.nsmall gives a minimum age for the basal part of the succession. amounts. These rocks aretentatively classifi,ed as lampro- Much higher in the mantling gneiss stratigraphy, overlying phyres; the HPpipe in the Golden area and the Ospika pipe the carbonatitehorizons, a strataboundlead-zincdeposit has can he classified as aillikites, which are members c f the ul- yielded an Eocamhrian to early Cambrian lead-lead date. tramafic lamprophyreclan based on their modal mineralogy This suggests that the highest stratigraphic levels of the and, to a lesser extent, the chemistry. The other ultrabasic mantling gneiss succession are Early Cambrian and the in- intmsions in the Golden area are more difficltlt to 'classify; tervening stratigraphy was deposited between Late Protero- they appear to be most similar to amphibole-free alkaline zoic and early Paleozoic time. The extrusive carhonatites lamprophyres.In all cases the breccia pipes commonly con- are located relatively high in the mantling gneiss stratigra- tain multiple phases of intrusion characterized by variable phy, approximately 100 metres below the lead4nc layer proportions of xenoliths, macrocrysts and accretionary and, like the lead-zinc deposit, are probably Eocambrian in lapilli or spherical structules. The breccia matrix in some age. cases is clearly magmatic. These pipes are characteristic of The carbonatites in the western belt comprise high- the diatreme facies material, as described from kilnberlite level intrusions and extrusives. The carbonatite intrusions pipes and/or hypabysal-facies (Clement and Reid, 1986). Bullelin 88 111
  • 11. . ~~ Brirish Columbia ~~~~ “ They formed from extremely volatile-rich magmas, so rich, diatreme-facies tufflsitic breccias. Some pipes bneached the in some cases, that as they reached the surface and vesicu- paleosurface andthe upper parts of the crater zone contain lated, the magmatic phase exsolved from volatiles and the beddedepiclasticorpyroclasticrocks.Anumhert~fthe])ipes actually formed the ‘bubbles’, as indicated by the spherical - in the Bull River Elk River area intrude Ordovician-Silu- stmctures (or globular segregations) and armoured xeno- rian Beaverfoot carbonate rocks and contain bedded cl’ater- liths. At Lens Mountain, Mons Creek and Valenciennes facies material which is unconformably overlain b., the River sandy tuffisitic or gas-stream breccias, with an insig- basal Devonianunit (MiddleDevonian) suggesting anl3arly nificant recognizable igneous component, are present. also Devonian age of emplacement of approximately 4oC Ma. Rubidium-strontium and potassium-argon dates of Other pipes and flows apparently underlie and predate the 3381r3 and 323f10 Ma have been obtained from phlogopite Beaverfoot Formation, but cut middleSilurian rocks and, separates from the Ospika pipe. These dates indicate that therefore, must be approximately 455 Ma in. age. The emplacement occurred inDevono-Mississippiantime, as is Kechika pipe is also hosted by Ordovician to Silnrian litrata the case for the most of the carbonatites in the eastern and and associatedwith bedded tuffs whichmust be of the Same central belts. Aillikites and alnoites arenoted for their affili- age as the host strata (possibly circa 450 Ma.). ation with carbonatites (Rock, 1986). Pipes and dikes from The craters containing these breccias are envisaged to two areas north of Golden have also been dated. In area, that have a ‘champagne glass’ structure, similar to that of lam- most of the diatremes were emplaced slightly earlier, in proite or basaltic craters, with no extensively developedrmt Early Devonian time (circa 400 Ma). Zircons from ultra- zone. The breccias are commonly associated with cro5 scut- basic rocks in the Mons Creek yielded concordant area lead- ting porphyritic dikes and flows, characterized by the pres- lead ages of 469 Ma; ifthese zircons are not xenocrystic, it ence of phenocrystic olivine and titanaugite, with ahwdaut may indicate that there was athird period of emplacement feldspar (plagioclaseorpotassiumfeldspar),titanaugite and in the Late Ordovicianto Early Silurian. opaque oxide microphenocrystsin a fine-grained ground- Intrusions in the Bull River and Kechika are dis- areas mass. These rocks are extremely difficult to classify: they tinctly different than those in the Golden or Ospika areas. are ultrabasic, and locally quite potassic, feldspar-bearing They are characterized by chaotic breccias containing abun- rocks that can contain vesiculated glass lapilli and are gen- dant vesiculated glass lapilli, juvenile lapilli and rare altered erally devoid of hydrous mafic minerals and feldspathoids. olivine, altered pyroxene, feldspars and chromian spinel They may have originated in volatile-enriched systems, but macrocrysts and by theabsence of primary micas. The ma- not to the extent of the previous diatremes; as ihey n:ared trix of these breccias is not magmatic; they are crater and the surface the volatiles exsolved fromthe maglna and not Figure 86. Structural position diaEemes, B - Bush River;C -Lens Mountain; D - Mons Creek;E - Valenciennes River;P HP pipe; G of - Shatch Mountain;H - Russell Peak;I - Blackfoot;J - Quinn Creek; K - Summer :L - Crossing Creek, Geology modified from Wheeler (1963),Wheeleretal., ( 1972),Leech (1979), Price(1981). ~~ 112 Geological Survey haranch
  • 12. Ministry of Energy, Mines and Petrnleum Resourres the reverse. In some cases they maybe tentatively classified North America, it is unlikely that significant concentrations as limburgites, in others they appear to be most similar to of diamonds can found in nonkimberlitic rock!: originat- be members of the alkaline basalt family, but gmerally are ing so far from the stable craton; however, the we.;tern con- more basic than typicalalkaline basalts which suggests that tinental margin at the time of diatreme emplacement was they are verging towardsnephelinites. probably significantly more complex than theone proposed The last distinct rock typeis represented by one exam- in Haggerty’s model for South Africa. The locat ion of the ple, the Cross kimberlite, located at Crossing Creek, nortb of westem edge the continental mass at that time is unknown of Elkford. As the nameimplies, it is a true kimberlite, the and the depth to the lithosphere-asthenosphere bcandary is only one so far recognized in the province. It is apparently also uncertain, therefore, the proposed constraints on dia- a deeply eroded pipe remnant and contains two generations mond genesis may be not directly applicable. of olivine, phlogopite, pyroxene, garnet and spinel megacrysts as well as garnet and spinel lhemlite nodules TECTONIC IMPLICATIONS (Hall etal., 1986). Rubidium-strontiumisotopic ratios indi- cate that the pipe was emplaced in Permo-Tiiassic time, The emplacement of carbonatites, kimberlites and circa 245 Ma (Grieve, 1982; Hall etal., 1986). other alkaline rocks in the Canadian Cordillera appears to be related, in part, to extension and rifting along t t e western At this point it is difficult to completely assCss the depth continental margin that produced and deepened the basin of origin and diamond potential of theserocks. The Crossing into which the miogeoclinal succession ‘was t.eposited. Creek kimberlite apparently originated deep in the mantle, Sedimentological and stratigraphic evidence inc.icate that it contains abundant pyrope garnets and has sampled mantle the western continental margin was tectonically active lithologies including garnet lherzolites. This suggests that it throughout much of the Proterozoic and Paleozc,ic eras. It may have originated at depths generally considered suffi- does not appear have behaved entirely in a passive man- to cient to be in the diamond field; however, diamond genesis ner and therefore may not be strictly analogous lo the pre- apparently depends on oxygen fugacity as well as pressure sent day Atlantic margin, as earlier workers proposed and depth origin alone is not sufficient to predict thedia- of (Stewart, 1972; Stewart andPoole, 1974); rather it appears mond potential of a pipe (Haggerty, 1986). The pipes inthe that several superimposed ‘passive margin-type’ :;equences other arms of British Columbia do not appear to have origi- are present as a result of periodic extensional activity (Pell nated as deep in the mantle as the Crossing Creek kimberlite. and Simony, 1987; Thompson e t al., 1987). During these They contain no good evidence of deep mantle xenoliths; periods of extension, deep faults and fractures in the crust the xenolith and xenocryst populationsare generally con- may have released pressure and triggered partial melting, fined to crustal material: rare eclogites, spinel. lberzolites, whichultimatelyresultedinalkalinemagmatism(Tab1e19). chrome spinels and very rare pyrope garnets (Northcote, 1983a, 1983b). This suggests an origin in the spinel lher- The earliest event recorded alkaline activi:y in west- by zolite field of the uppermantle, which is generally consid- ern Canada is represented by the Mount Copelandsyenite ered to be at pressures below those required for diamond of Late Proterozoic in age (circa 770 to 750 Ma);it may formation. Microdiamonds reportedly found in two of the record extension or rifting of the North Ame:rican (craton and pipes in the Golden swarm suggest that these pipes may the initiation of the Late Proterozoic Windermere basin. Di- have sampled the uppermost levels of the diamond field. abase dikes and sills of similar age (770 Ma) in northern Canada also record extension preceding Windemlere depo- When comparedto current models, it appears that the probability of British Columbia diatremescontaining eco- sition (Armstrong et al., 1982). Slightly younger datas of nomic concentrations of diamonds is low. From craton to 728 and 741 Ma (U-Pb, zircons) have been obtained from margin, a sequence of kimberlite with diamond, kimberlite granitic gneisses which appear to be basemen1 for Win- dermere Supergroup strata in north-central and central Brit- without diamond(e&, Cross) and diamond-free ultrabasic ish Columbia ( Parrish and Armstrong, 1983; Evznchick ef diatremes (nonkimberlitic) is commonly proposed (Hag- gerty, 1986). In an attempt to establish the original positions al., 1984). This implies that rifting began as early as 770 Ma in some areas, but that the event spanneda pericd of time of the diatremes relative to the North Americancontinent, and, locally,Windermere sedimentation not beginuntil did theirpositions have beenprojectedonto cross-sections (Fig- after 730 Ma. ure 86). If these sections were restored to predeformational configurations, the pipes contained in the most westerly Sedimentary loading and synsedimentary faulting (Lis thrust sheet would have been the farthest outboard. The and Price, 1976; Eisbacher, 1981; Root, 1.983; Bond and Cross kimberlite is in the Bourgean thrust sheet and is the Kominz, 1984; Devlin and Bond, 1984) accoun:ed for the easternmost of the diatremes. The ultrabasic diatremes in deepening of the basin and the continuation of deposition the Bull Riverarea are carried by the Bull River Gypsum - into the early Paleozoic. Minor extensional activity is also fault (Figure 86), which is west of the Bourgeau thrust. As indicated by the presence of acid to basic volcanic andin- the faults are traced to tbe north, the Bull River- Gypsum trusive rocks throughoutthe Hadrynian to early Paleozoic thrust apparently dies out and the displacement is accom- sedimentary wedge (Simony and Wind, 1970; Raeside and modatcdby the Simpsons Pass thrust. The alnoitic rocks and Simony, 1983; Pell and Simony, 1987; Sevigny, 1987). alkaline lamprophyres north of Golden are carried on a Extrusion of theMount Grace carbonatiteandintrusion thrust (the Mons fault) which lies west of the Simpsons Pass of shallow-level carbonatites, accompanied by :he forma- thrust and apparently originated the farthest outboard of the tion of extensive zones of fenitization, probably occurred in continent. If Haggerty’s model is applicable to western Eocambrian to Early Cambrian time (Htiy and Godwin, Bulletin 88 113
  • 13.
  • 14. Minisfry of Eneqy, Mines and Pet,%l Resources 1988). These rocks occur a relatively thin cover-succes- in ported from the mid-Devonian to early M:ississippian se- sion above core gneisses of the Frenchman Cap dome, quence in the northern and central Canadian 'Cordillera which suggests that the dome may reflect a tectonic high in (Gordey, 1981; Mortensen, 1982; Gordey et al.. 1987) as late Precambrian to Early Cambrian time. Emplacement of well as in the southern Canadian Cordil.lera :Wheeler, the alkalic rocks may have coincided with foundering of an 1965). extensive Lower Cambrian platform to the east. This period The Devono-Mississippian extension was synchronous is also interpreted by many workers as the time of the rift- with, or slightly postdated, compression to the south that to-drift transition along the western continental margin was associated with Antler the orogeny. Devono- Mississip- (Bond and Kominz, 1984; Devlin and Bond, 1984; pian granites and granitic gneisses have also been docu- Thompson et al., 1987). In the southwestern United States, mented inthe Canadian Cordillera and Alaska (Okulitch et carbonatites of Eocambriau to Early Cambrian age are re- ab, 1975; Dillonefal., 1980; Montgomery, 1985: Okulitch, ported from a number localities (Figure 87); for example, of 1985;Mortensen 1986;Mortensenetal., 19117).Theserocks the McClure Mountain carbonatite-alkalic complex, the crop out west of the alkaline intrusions and are believed to Gem Park and the Iron Hill carbonatite complexes in C o b have intruded near the western edge of the Paleozoic Cor- rado and the Lobo Hills syenite and carbonatite in New dilleran miogeocline (Okulitch er al., 1975). Aso during Mexico (Fenton and Faure, 1970; Olson et al., 1.977; Loring Devono-Mississippian time,a mixed volcanic and sedirnen- and Armstrong, 1980; Annbrustmacher, 1984; McLemore, tary sequence, termed Eagle Bay assemEdage, was the form- ). 1984; 1987; Although these intrusions are structurally in- ing o f fthe western contintental margin; these rocks record board of the Mount Grace carbonatite, their emplacement a change from an island arc environment at the base of the may be related to the same large-scale extensional tectonic sequence, where calcalkaline volcanics wen: forning above event. a subductingplate, to a rift environment wbicb alkaline in Anumberofperiods ofPaleozoic extension areinferred volcanism and sedimentation took place 6:Schi;lrizza and along the western continental margin; however, additional Preto, 1987). dating is necessary to clearly define these periods and elimi- nate possibilities of overlap. The earliest event is Late Or- Thesedatasuggestthatacomplextectonicre,:imemust dovician to Ordovician-Silurianin age (circa 450 Ma) and have pertained at the end of the Devonian and it was not that is recorded by the emplacementof some ultra'basic diatre- simply a timeof extension. A more complex mollel is nec- essary to explain westerly sources for Devono-:Mississip- mes and alkaline lamprophyres in the southern Rocky Mountains and the Golden area of British Columbia. The pian miogeoclinal sediments, obduction a1 the latitude of Bearpaw Ridge sodalite syenite (eastern belt, Figure 1) may present-day northern California and southern OIegon, and also prove to be Ordovician to Early Silurian in age as was emplacement of granites in southern British Colnmbia, the originally proposed by Taylor and Stott (1980). who be- Cariboo and Alaska approximately the same timeas ex- at lieved it to be a subvolcanic pluton related to alkaline basalt tension and alkaline intrusion were taking placl: near the flows in the Silurian Nonda Formation. Syenites, trachytes, eastern margin ofthe Canadian Cordilleran miog:ocline. A carbonatites and ultrabasic diatremes and tuffs in the sequence of events may have occurred which culminated in the development of an incipient continental back:arc rift at Kechika area may also be of a similar age. Carbonatites of a complex, attenuated margin (see Struik, 1987). as local- approximatelythe same age are found Lemitar Moun- in the ized obduction (and possibly subduction) occurred to the tains of New Mexico (McLemore,1987). south and outboard. Subduction probably resulted inpartial A secondperiod of alkaline igneous activi.ty along the melting and genesis of granite and calcalkaline volcanic western margin of North America occurred in Early De- rocks; this compressional regime was ap;parently super- vonian time (circa 400 to 410 Ma). Most of the ultrabasic ceded by an extensional regime. Alternatively, e:ctensional and alkaline lamprophyres in the Golden area and somenl- basins may have resulted from strike-slip faulting: outboard trabasic diatremes in southern British Colnmbia were em- of the preserved marginof the miogeocline, as pr,>posed by placed at this time. Diatremebreccias in the Yukon Territory Eisbacher (1983) and Gordeyet al. (1987:1; however, this (e.g., Mountain diatreme, R.L. Armstrong, personal com- scenario does notexplain the intrusion of g:raniter. munication, 1988) of the same age. In a more continental are setting (Figure 87). Early Devonian kimherlites are reported The last Paleozoic extensional event is inferred liom from thecolorado-Wyoming State-Linedistrict (McCallum the presence of Permo-Triassic kimberlite in the Rocky et al., 1975; McCallum and Marbarak, 1976; Hauselet al., Mountains. Although only one example known, it is is pos- 1979). sible that other alkaline intrusions of simihu age exist and A third Paleozoic extensional event at the end of the that other evidence for extension may be discovered. As Devonian (circa 350 to 370 Ma)resulted in the intrusion of with theprevious event, Permo-Triassic extmsion occurred carbonatites into the miogeoclinal successionin the Fore- approximately synchronously with compression in the land and Omineca belts. Aillikite diatremes(ultramafic lam- southern Cordillera (Sonomau orogeny). prophyres) and dikes in the Ospika River area were also In Late Jurassic to Early Tertiary time, orogmesis oc- emplaced at this time. The tectonic instability resulting from curred when a compressional regime established on the was this major Devono-Mississippian extensional event is also Pacific margin whilerifting and the opening: ofthe Atlantic evident in the stratigraphic record (Thompsonet al., 1987); took place on the opposite side of the continent. During OIO- volcanic rocks (someperalkaline in composition),synsedi- genesis the continental margin prism was telascoped the and mentary block faults and chert-pebble conglomerates are re- alkaline igneous rocks were deformed, metamorphosed and Bulletin 88 115
  • 15. ; Tom LEGEND WILLIAM HENRYBAY . I: LEGEND MOUNTAIN DIATREME i SALMON BAY KECHIKA PIPE ! KECHIKA , ALEY i LONNIE F MOUNT BISSON 1 WICHEEOA LAKE i BEARPAW RIDGE IO BLUE RIVER AREA II TRiOENT MOUNTAIN I2 PERRY RIVER-MOUNT GRACE I3 MOUNT COPELAND 14 THREE VALLEY GAP I5 ICE RIVER 16 ROCK CANYON CREEK 17 RAINEY CREEK I8 BEARPAW MOUNTAINS I9 RAVALLliLEMHl COUNTIES !O IRON HILL. GUNNISON COUNTl !l WET MOUNTAINS CUSTER AND FREMONT COUNTIES !Z GEM PARK/MsLURE MOUNTAiN !3 MONTE LARGO 24 LEMITAR MOUNTAINS !5 MOUNTAIN PASS SYMBOLS SYMBOLS 19+ 0 Age unknown Age unknown v Tertiary (-50 & -30Ma) 01Tsriiary (Eocans) -50Mo + UpperCretocsour -90-95Ma X Oevono-Mirrirrlplon -350Ha # Permo-Trioaric -245Mo UNITED X Dewno-Uisriraippian 0 Ordorician-Silurian -450Ma 350-375Ma A EarlyDevonian -4OOMo OCEAN 0 Ordoviclon-Silurlon -45OMa STATES t Placediamond r Ioc~lity I Lower Cambrion-EoCombrlon :D) MlsrodlomondIoEOlity 520-58OMo t L o bp r o t e r o r o l s -770Mo A Mid-Pmlerozolc 1400-15OOM 23 M C o r d l l l e r o n front ,---Western limit of the .. miageoc1ino1 rtrato . I MEXICO 0 . " :i KILOMFTRLI 1 I :!
  • 16. Minisfry o Energy, Mines and P e t r e Resoumes f transported eastwards in thrust sheets. Their present distr- Cordillera, however, young calcalkaline lamprophyres, bution near the Rocky Mountain Trench is due to original strongly alkaline basalts and miaskitic syenite complexes location along a rifted continental margin, not to later tec- such as KrugerMountain, Copper Mountainand theCoryel1 tonics. No syn or postorogenic carbonatites or alkaline nl- intrusions are present. tramafic diatremes have been discovered in the Canadian Bulletin 88 I17
  • 17. British Columbia " 118 Geological S~rrvey 3ranch
  • 18. Ministry of Enevy, Mines andP e t l w Resources REFERENCES Aaquist, B.E. (1981): Report on Diamond Drilling on the AZ-1 Barlow, A.E. (1902): Nepheline Rocks of Ice River, British Co- Claim Group,Kamloops Mining Division; B.C. Ministry of lumbia; Ottawa Naturalist, June 1902, page 70. Energy,MinesandPetroleumResources,Asse!;smentReport Bending, D. (1978): Fluorite Claims, Golden :Minin,: Division; 9923. B.C. Ministry of Energy, Mines and Petndeum Resources, Aaquist, B.E. (1982a): Assessment Report on Verity First I, 2, 3 Assessment Report 6978. B.C. Claims, Blue River, British Columbia: Ministry of En- Betmanis, A.I. (1987): Report on Geological, Geochemical and eqy, Mines and Petroleum Resources, Assessment Report Magnetometer Surveys on the Prince and George Groups, 10955. Carib00 Mining Division; B.C. Ministry of Encrgy, Mines Aaquist, B.E. (1982b): BlueRiver Carbonatites, BritishColumbia, and Petroleum Resources, Assessment Report1.7 944. Final Report 1981; B.C. Ministry of Energy, Mines andPe- Betmanis,A.I.(1988):SamplingEvaluation,l?G.NiobiumProject troleum Resources, Assessment Report 10 274. (Prince and George Groups); unpublished repixi for Teck Aaquist, B.E. (1982~): Assessment Report, Blue River Carbona- Explorations Limited. tites, 1982; B.C. Ministry of Energy, Mines and Petroleum Bond, G.C. and Kominz, M.A. (1984): Constnlction of Tectonic Resources, Assessment Report 11 130. Subsidence Curves for the Early Paleozoic Miogeocline, Adams, W.T. (1985): Zirconium and Hafnium; in Mineral Facts Southern Canadian Rocky Mountains: Implications for Suh- and Problems, 1985 Edition, United States Department of sidence Mechanisms, Age Breakup and C N S ~ Thinning; of ;.~ the Interior, Bureau ofMines, Bulletin 675, pages 941-956. Geological Society ofAmerica,Bulletin 95, pag:s 155-173. Ahroon, T.A. (1979): Airborne Helicopter Magnetometer-Spec- Bonney, T.G.(1902): On a Sodalite Syenite (Ditroit:) from Ice trometer Survey on the Blue River Carbonatite Project, Brit- River, British Columbia; Geological Ma(:azine Volume 9, ishCo1umbia;B.C. MinistryofEnergy, MinesandPetroleum pages 199-213. Resources, Assessment Report 8216. Brown, R.L. (1980): Frenchman Cap Dome, Slmswap Complex, Ahroon,T.A. (1980): Geological Reporton theBlueRiverProject, British Columbia; in Current Research, PaR A, Geological British Columbia: B.C. Ministry of Energy, Mines and Pe- Survey o Canada, Paper XO-IA, pages 45-51. f troleum Resources, Assessment Report 9566. Butrenchnk, S.B. (in preparation): Phosphate Deposits in British Allan, J.A. (1911): Geology of the Ice River District, British Co- Columbia: B.C. Ministry of Energy, Mims and Petroleum lumbia; Geological Survey of Canada, Summary Report, Resouzes. 1910, pages 135-144. Campbell, EA. (1961): Differentiation Trends: in th: Ice River Allan, J.A. (1914): Geology theFieldMap-area, 13ritishColum- of Complex, British Columbia;American Journal of Science, bia and Alberta:Geological Survey of Canada, Memoir 55. Volume 259, pages 173-180. Alonis, E. (1979): B.C. Fluorite Claims, Golden Mining Division: Clement, C.R. and Reid, A.M. (1986): The Origin of Kimberlite . MinistpojEnergy, MinesandPetroleum Resources,Assess- Based on a Synthesis of Geological Pipes: An Interpretation ment Report7830. Features Displayed by South African Occurrences; Geologi- Armbrustmacher, T.J. (1979): Replacement and Primary Mag- cal Society of Australia,4th International Kimlmlite Con- matic Carhonatites from Wet Mountains Area, Fremont the ference, pages 167-169. and Custer Counties,Colorado;Economic Geology, Volume Clement, C.R., Skinner, E.W.M. and Scon-Snuth, B.H. (1984): 74, pages 888-901. Kimberlite Redefined; Journal of Geology, Volume 92, Armbrustmacher,T.J. (1984): AIkalineRockCompIexesinthe Wet pages 223-228. Mountains Area, Custer and Fremont Counlies, Colorado; Cunningham, L.D. (1985a): Columbium; in Mineral Facts and UnitedStates Geological Survey, Professional Paper 1269. Problems, United States Department Interioi; Bureau of of Armbrnstmacher, T.J., Brownfield, I.K. and Osmonson, L.E. Mines, Bulletin 675, pages 185-196. (1979): Multiple Carbonatite Dike at McClure Gulch, Wet Cunningham, L.D. (1985b): Tantalum:in Mineral Fac's and Prob- Mountains Alkaline Province, Fremont County, Colorado; lems, United Stares Department ojrnnlerior, Bureau of Mountain Geologist, Volume 16, Number 2, pages 37-45. Mines, Bulletin 675, pages 811-822. Armstrong, J.E., Hoadley, J.W., Muller, J.E. and Tipper, H.W. (1969): Geology, McLeod Lake, British Columbia (933); Currie, K.L. (1975): The Geology and Petrologyof the Ice River Geological Survey of Canada, 1204A. Map Alkaline Complex; Geological Survey 01Canada, Memoir 245.65 pages. Armstrong,R.L.,Eisbacher,G.H.andEvans,P.D.(1982):Ageand Stratigraphic-Tectonic Significance of Proterozoic Diabase Cunie, K.L. (1976a): The Alkaline Rocks Cmada: Geological of Sheets, Mackenzie Mountains, Northwestern Canada; Ca- Survey of Canada, Memoir 239. nadian Journal of Earth Sciences, Volume '19, pages 316- Cnrrie, K.L. (1976b): Notes on the Petrology of Nepheline 323. Gneisses near Mount Copeland, British Columbia;Geologi- Baadsgaard, H., Folinsbee, R.E. and Lipson, (1961): Potassium- J. cal Survey of Canada, Memoir 265. ArgonDatesofBiotitesfromCordilleranGranites;Geologi- Dawson, G.M. (1885): Preliminary Report on the Fhysical and cal Society ofAmerica, Bulletin, Volume 72, pages 689-702. Geological Featuresof that Portion of the Rockit Mountains - Bulletin 88 119