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EERA SHALEGAS 
Review of innovative stimulation 
technologies 
Andrzej Rogala 
Anna Mykowska 
Department of Chemical Technology 
Faculty of Chemistry 
Gdansk University of Technology
INTRODUCTION 
• The aim of presentation is a short review of innovative 
stimulation technologies to inspire the discussion between 
industry and academia in the topic of environmental 
friendly but also economically profitable technology 
adequate to Polish shales. 
• Two stages of stimulation will be considered. First is the 
pre-completion stage of unconventional oil and gas 
recovery and seconds are different methods of fracturing.
INTRODUCTION 
Type of 
fracturing 
Description Divided into: 
HYDRAULIC 
FRACTURING 
Liquid fluid use to fracture 
the reservoir rock 
• Water-based fluids 
• Foam-based fluids 
• Oil-based fluids 
• Acid-based fluids 
• Alcohol-based fluids – 
• Emulsion-based fluids 
• Cryogenic fluids (CO2, N2, He, etc.) 
PNEUMATIC 
FRACTURING 
Gas (air or nitrogen) use 
to fracture the reservoir 
rock 
FRACTURING 
WITH 
DYNAMIC 
LOADING 
Fluids are not used • Explosive fractuing 
• Electric fracturing 
OTHER 
METHODS 
• Thermal (cryogenic) fracturing 
• Mechanical cutting of the shale formation 
• Enhanced bacterial methanogenesis 
• Heating of the rock mass 
(Based on Gandossi, 2013)
• One of the most important advantage of 
liquid CO2 fracturing is the elimination of 
conditional formation damage normally 
related with fracturing fluids, another one is 
rapidly clean-up process and evaluation of 
the well following the fracturing. CO2 
fracturing keeps clays (smectite and illite) 
stabilized and prevents metal leaching and 
chemical interactions. 
• In Canada were more than 1,200 
accomplished with success only up to late 
nineties. The technology was also used in 
the USA for Devonian shale in East Kentucky 
andWest Pennsylvania, Texas and Colorado. 
It was observed that the average gas production in some wells was as much as five 
times greater than in the case of production using as also used in the USA for 
conventional HF treatments. 
• The main problems related with carbon dioxide fracturing (also using nitrogen or 
CO2/N2 mixture) are using special fracturing equiptment, CO2 transport in the liquid 
state, and storage it in pressurized tanks. 
4 
Carbon dioxide fracturing
Advantages 
• increase the productivity of the well 
• lower viscosity, density and surface tension of the fluid, which results in lower energy 
consumption during fracturing 
• full compatibility with reservoirs because LPG and hydrocarbons are mutually soluble 
• smaller volume of chemicals added to the fracturing fluid 
• sustainable, recyclable and more environmentally friendly then HF 
• more dense than air, so there is no risk to air contamination and impact on global 
warming 
Disadvantages 
• Investment costs are higher than for HF, because LPG is pumped into well at a very high 
pressure, and after each fracturing it has to be liquefied again, 
• LPG must be stored in costly pressurize tanks (water in HF is stored in non-pressure 
tanks or in natural outdoor pools), 
• LPG is explosive, 
• LPG is more dense than air and fills up the ground cavities. 
5 
LPG fracturing
Energized fluids 
The flexibility of energized solutions allows hydraulic fracturing fluids to be mixed 
according to the technological needs of unconventional reservoirs. They provide 
more rapid and complete fluid recovery, help to clean without swabbing, and reduce 
formation damage by minimizing the amount of aqueous fluids introduced into the 
formation. In addition, many times energized solutions have superior proppant 
transport properties without creating ultrahigh molecular weight polymer structures 
and in the case of underpressured or depleted zones, provide enhanced energy for 
hydrocarbon recovery. 
Liquid leak-off increases water saturation, thereby decreasing the formation’s relative 
permeability to gas. This may play a significant role in damaging gas reservoirs. 
Energized solutions, however, use less water than conventional fracturing treatments 
and provide energy for recovering induced fluids while decreasing the fluid leak-off 
potential to minimize reservoir damage. Less water means less potential for clay 
swelling, fines migration, liberating hydrogen sulfide, forming emulsion, and fluid 
retention. Less damage enhances flow for effective flow back, reducing the time it 
takes to move to production, while increasing overall production. Energized solutions 
are ideal for reservoirs with low permeability, water sensitivity, underpressured or 
depleted zones, or poor flow back caused by low pressure or strong capillary forces. 
They also are used for refracturing wells where production has declined 
6
Energized fluids 
7 
Averaged 10-Year Decline Analysis for Energized versus Nonenergized Frac Fluids
HiWAY – Flow Channel Fracturing Technique 
Traditionally, efforts to enhance conductivity 
have been directed toward improving flow 
through a porous proppant pack. Strategies for 
improving fracture production 
• enhancing proppant roundness and strength 
• lowering proppant crush and gel loadings 
• improving gel breakers 
The HiWAY technique changes the way 
proppant fractures generate conductivity.
HiWAY – Flow Channel Fracturing Technique 
Proppant is delivered in short high 
frequency pulses to create stable 
flow channels.
10 
Perforating technologies for 
shale gas recovery 
Basic 
FracGun 
PulseFrac 
StressFrac 
Improved 
StimGun 
GasGun 
MP
FracGun 
System of perforation engineered for wells requiring fracture stimulation, sand 
control operations, and coalbed methane wells. 
The main benefits of this system is increased safety from real-time 
communication, optimized frac jobs and maximized production from the 
flexibility of using custom-designed charges in different guns or intervals. 
The guns are conveyed with wireline or slickline. A plug and shoot adapter makes 
it possible to set a plug and shoot multiple guns on the same descent, saving 
operating time. 
11
The StimGun perforator is composed of explosive charges encased in layer of solid 
propellant and connected to detonator (Snider et al., 1998). There is a two stage 
perforation. First, high explosive is ignited, making perforation. Next, propellant is 
ignited, instantly producing a burst of high pressure gases. The resulting pressure 
causes the formation of fractures. During this process, dislocations of the fractures 
made by very fast increase of pressure in reservoir occurs but also blocking of 
fractures results by fragments of rocks formed during fracturing. This allows free gas 
flow in spite of no proppant application. The StimGun has been used also with great 
success in a variety of applications ranging from both soft and hard rock perforating 
and perforation breakdown, near well bore stimulation, acid stimulation and many 
others. The technology is still being developed, by applying changes in charges 
geometry, perforation tools, explosive ingredients and ignition systems, to reach 
greater length of perforation (Snider and Zierolf, 2007). Unfortunately, at this stage 
of development of these techniques, perforation hardly exceeds 0.7 m, reaching 1.6 
m under some conditions whereas for comparison hydraulic fracturing achieves 100 - 
200 m or longer. 
12 
Stimgun
Stimgun 
13
14 
Gasgun
GasGun is the most advanced technology of pre-stimulation of reservoirs using solid 
propellants. It is based on the ballistic U.S. military technology, designed to perforate 
hydrocarbon bearing rocks. It is much more effective compared to other known 
perforation technologies due to creation of multiple radial fractures, removing skin 
and cleaning up the well-bore damaged by perforators, drilling fines, cement, 
paraffin, mud cake, etc. The principle of operation of GasGun is based on three step 
rocket fuel combustion and has no shape charges. Both, the perforation as well as 
the fracturing are done by high pressure gases. In the first stage of StimGun, the 
pressure increase is slower than in the case of high explosives use in the classical 
methods, but 
lasts longer and gives much better results. According to literature length of the 
perforation can reach from 0.3 up to 3 m. Therefore, it is a potential method, which 
is worth developing as an alternative to the hydraulic fracturing. Unfortunately, for 
this moment, there is not enough data to determine how often a maximum range of 
perforation can be achieved. In addition, the effectiveness of GasGun and StimGun 
oscillates around 5 - 10 %, due to the ineffective flow control of gases, generated 
during the perforation. 
15 
Gasgun
Comparison of energetic and hydraulic fracturing 
pressure 
16
Multistage Perforator 
The overall concept of the project 
Multistage Perforator is a combination of high explosive, shaped charges 
and a progressively burning, solid propellant (solid rocket fuel which is rapidly burning, 
accompanied by production of large amounts of heat and the considerable amount of gas 
under high pressure) and a proppant (fine material added to the fracturing fluids used for 
hydraulic fracturing, which, to prevent fracture closure, which in turn allows the gas 
outflow from reservoir). It consists of two phases: detonation of high cumulative charges 
and immediately after multistage propellant combustion. The additional low explosive 
propellant is used in order to generate high pressure gas at very high rate to create multiple 
fractures slippage radiating over 10 m in Sweet Spot from the well-bore, regardless shale 
Least Principle Stress orientation and fracture - slippage type with secondary detonation 
in the reservoir. 
17
Multistage Perforator 
Multistage Perforator allow to: 
 Increasing the efficiency of hydraulic fracturing through the creation of a network of 
cracks already in the stage of of perforation of considerable range. Hydraulic 
fracturing preceded this kind of perforation cover a larger volume of deposit, giving a 
much higher gas production. The literature suggests that to achieve the larger fracture 
net during of perforation translates to increased efficiency of the hydraulic fracturing 
 The possibility of extracting gas from shale layers separated by layers of other rocks. 
Polish gas-bearing shales are often separated by several meter thick layers of other 
rocks which prevents hydraulic fracturing after the standard perforation. By applying 
the proposed method, perforation tunnel is long enough to reach for shale which 
allows you to perform hydraulic fracturing in this type of deposits 
 Additional gas flow associated with a very effective fracturing of near borehole zone. 
 Protection of perforations and preliminary fractures 
- physical - by the presence of proppant in a stream of cumulative charges, entering 
18 
into the reservoir and keep fractures open 
- chemical - additives for solid rocket fuel and combustion products ensure the 
stability of the reservoir until fracturing
19 
Classic perforators vs Mulstistage perforator
20 
Classic perforators vs Mulstistage perforator
Thank you for your attention 
21

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Innovative stimulation am ar_10.10

  • 1. EERA SHALEGAS Review of innovative stimulation technologies Andrzej Rogala Anna Mykowska Department of Chemical Technology Faculty of Chemistry Gdansk University of Technology
  • 2. INTRODUCTION • The aim of presentation is a short review of innovative stimulation technologies to inspire the discussion between industry and academia in the topic of environmental friendly but also economically profitable technology adequate to Polish shales. • Two stages of stimulation will be considered. First is the pre-completion stage of unconventional oil and gas recovery and seconds are different methods of fracturing.
  • 3. INTRODUCTION Type of fracturing Description Divided into: HYDRAULIC FRACTURING Liquid fluid use to fracture the reservoir rock • Water-based fluids • Foam-based fluids • Oil-based fluids • Acid-based fluids • Alcohol-based fluids – • Emulsion-based fluids • Cryogenic fluids (CO2, N2, He, etc.) PNEUMATIC FRACTURING Gas (air or nitrogen) use to fracture the reservoir rock FRACTURING WITH DYNAMIC LOADING Fluids are not used • Explosive fractuing • Electric fracturing OTHER METHODS • Thermal (cryogenic) fracturing • Mechanical cutting of the shale formation • Enhanced bacterial methanogenesis • Heating of the rock mass (Based on Gandossi, 2013)
  • 4. • One of the most important advantage of liquid CO2 fracturing is the elimination of conditional formation damage normally related with fracturing fluids, another one is rapidly clean-up process and evaluation of the well following the fracturing. CO2 fracturing keeps clays (smectite and illite) stabilized and prevents metal leaching and chemical interactions. • In Canada were more than 1,200 accomplished with success only up to late nineties. The technology was also used in the USA for Devonian shale in East Kentucky andWest Pennsylvania, Texas and Colorado. It was observed that the average gas production in some wells was as much as five times greater than in the case of production using as also used in the USA for conventional HF treatments. • The main problems related with carbon dioxide fracturing (also using nitrogen or CO2/N2 mixture) are using special fracturing equiptment, CO2 transport in the liquid state, and storage it in pressurized tanks. 4 Carbon dioxide fracturing
  • 5. Advantages • increase the productivity of the well • lower viscosity, density and surface tension of the fluid, which results in lower energy consumption during fracturing • full compatibility with reservoirs because LPG and hydrocarbons are mutually soluble • smaller volume of chemicals added to the fracturing fluid • sustainable, recyclable and more environmentally friendly then HF • more dense than air, so there is no risk to air contamination and impact on global warming Disadvantages • Investment costs are higher than for HF, because LPG is pumped into well at a very high pressure, and after each fracturing it has to be liquefied again, • LPG must be stored in costly pressurize tanks (water in HF is stored in non-pressure tanks or in natural outdoor pools), • LPG is explosive, • LPG is more dense than air and fills up the ground cavities. 5 LPG fracturing
  • 6. Energized fluids The flexibility of energized solutions allows hydraulic fracturing fluids to be mixed according to the technological needs of unconventional reservoirs. They provide more rapid and complete fluid recovery, help to clean without swabbing, and reduce formation damage by minimizing the amount of aqueous fluids introduced into the formation. In addition, many times energized solutions have superior proppant transport properties without creating ultrahigh molecular weight polymer structures and in the case of underpressured or depleted zones, provide enhanced energy for hydrocarbon recovery. Liquid leak-off increases water saturation, thereby decreasing the formation’s relative permeability to gas. This may play a significant role in damaging gas reservoirs. Energized solutions, however, use less water than conventional fracturing treatments and provide energy for recovering induced fluids while decreasing the fluid leak-off potential to minimize reservoir damage. Less water means less potential for clay swelling, fines migration, liberating hydrogen sulfide, forming emulsion, and fluid retention. Less damage enhances flow for effective flow back, reducing the time it takes to move to production, while increasing overall production. Energized solutions are ideal for reservoirs with low permeability, water sensitivity, underpressured or depleted zones, or poor flow back caused by low pressure or strong capillary forces. They also are used for refracturing wells where production has declined 6
  • 7. Energized fluids 7 Averaged 10-Year Decline Analysis for Energized versus Nonenergized Frac Fluids
  • 8. HiWAY – Flow Channel Fracturing Technique Traditionally, efforts to enhance conductivity have been directed toward improving flow through a porous proppant pack. Strategies for improving fracture production • enhancing proppant roundness and strength • lowering proppant crush and gel loadings • improving gel breakers The HiWAY technique changes the way proppant fractures generate conductivity.
  • 9. HiWAY – Flow Channel Fracturing Technique Proppant is delivered in short high frequency pulses to create stable flow channels.
  • 10. 10 Perforating technologies for shale gas recovery Basic FracGun PulseFrac StressFrac Improved StimGun GasGun MP
  • 11. FracGun System of perforation engineered for wells requiring fracture stimulation, sand control operations, and coalbed methane wells. The main benefits of this system is increased safety from real-time communication, optimized frac jobs and maximized production from the flexibility of using custom-designed charges in different guns or intervals. The guns are conveyed with wireline or slickline. A plug and shoot adapter makes it possible to set a plug and shoot multiple guns on the same descent, saving operating time. 11
  • 12. The StimGun perforator is composed of explosive charges encased in layer of solid propellant and connected to detonator (Snider et al., 1998). There is a two stage perforation. First, high explosive is ignited, making perforation. Next, propellant is ignited, instantly producing a burst of high pressure gases. The resulting pressure causes the formation of fractures. During this process, dislocations of the fractures made by very fast increase of pressure in reservoir occurs but also blocking of fractures results by fragments of rocks formed during fracturing. This allows free gas flow in spite of no proppant application. The StimGun has been used also with great success in a variety of applications ranging from both soft and hard rock perforating and perforation breakdown, near well bore stimulation, acid stimulation and many others. The technology is still being developed, by applying changes in charges geometry, perforation tools, explosive ingredients and ignition systems, to reach greater length of perforation (Snider and Zierolf, 2007). Unfortunately, at this stage of development of these techniques, perforation hardly exceeds 0.7 m, reaching 1.6 m under some conditions whereas for comparison hydraulic fracturing achieves 100 - 200 m or longer. 12 Stimgun
  • 15. GasGun is the most advanced technology of pre-stimulation of reservoirs using solid propellants. It is based on the ballistic U.S. military technology, designed to perforate hydrocarbon bearing rocks. It is much more effective compared to other known perforation technologies due to creation of multiple radial fractures, removing skin and cleaning up the well-bore damaged by perforators, drilling fines, cement, paraffin, mud cake, etc. The principle of operation of GasGun is based on three step rocket fuel combustion and has no shape charges. Both, the perforation as well as the fracturing are done by high pressure gases. In the first stage of StimGun, the pressure increase is slower than in the case of high explosives use in the classical methods, but lasts longer and gives much better results. According to literature length of the perforation can reach from 0.3 up to 3 m. Therefore, it is a potential method, which is worth developing as an alternative to the hydraulic fracturing. Unfortunately, for this moment, there is not enough data to determine how often a maximum range of perforation can be achieved. In addition, the effectiveness of GasGun and StimGun oscillates around 5 - 10 %, due to the ineffective flow control of gases, generated during the perforation. 15 Gasgun
  • 16. Comparison of energetic and hydraulic fracturing pressure 16
  • 17. Multistage Perforator The overall concept of the project Multistage Perforator is a combination of high explosive, shaped charges and a progressively burning, solid propellant (solid rocket fuel which is rapidly burning, accompanied by production of large amounts of heat and the considerable amount of gas under high pressure) and a proppant (fine material added to the fracturing fluids used for hydraulic fracturing, which, to prevent fracture closure, which in turn allows the gas outflow from reservoir). It consists of two phases: detonation of high cumulative charges and immediately after multistage propellant combustion. The additional low explosive propellant is used in order to generate high pressure gas at very high rate to create multiple fractures slippage radiating over 10 m in Sweet Spot from the well-bore, regardless shale Least Principle Stress orientation and fracture - slippage type with secondary detonation in the reservoir. 17
  • 18. Multistage Perforator Multistage Perforator allow to:  Increasing the efficiency of hydraulic fracturing through the creation of a network of cracks already in the stage of of perforation of considerable range. Hydraulic fracturing preceded this kind of perforation cover a larger volume of deposit, giving a much higher gas production. The literature suggests that to achieve the larger fracture net during of perforation translates to increased efficiency of the hydraulic fracturing  The possibility of extracting gas from shale layers separated by layers of other rocks. Polish gas-bearing shales are often separated by several meter thick layers of other rocks which prevents hydraulic fracturing after the standard perforation. By applying the proposed method, perforation tunnel is long enough to reach for shale which allows you to perform hydraulic fracturing in this type of deposits  Additional gas flow associated with a very effective fracturing of near borehole zone.  Protection of perforations and preliminary fractures - physical - by the presence of proppant in a stream of cumulative charges, entering 18 into the reservoir and keep fractures open - chemical - additives for solid rocket fuel and combustion products ensure the stability of the reservoir until fracturing
  • 19. 19 Classic perforators vs Mulstistage perforator
  • 20. 20 Classic perforators vs Mulstistage perforator
  • 21. Thank you for your attention 21