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Disperse Dyes
Disperse Dyes
• The term “disperse dye” have been applied to the organic

colouring substances which are free from ionizing groups, are
of low water solubility and are suitable for dyeing
hydrophobic fibres.
• Disperse dyes are the only water insoluble dyes that dye
polyester and acetate fibers. Disperse dye molecules are the
smallest dye molecules among all dyes.
• Disperse dyes are used for dyeing man made cellulose ester
and synthetic fibres specially acetate and polyester fibres and
sometimes nylon and acrylic fibres.
• Carrier or dispersing agents are required for dyeing with

disperse dyes.
• Disperse dyes have fair to good light fastness with rating
about 4-5.
 MECHANISM OF DISPERSE DYE
Wander Wall’s Forces.
High affinity for Fibers.
Attraction between Fiber Surface and the Dye
Molecule.

 STRUCTURE
 SOLUBILITY
Non-Soluble in Water.

 CHARGEABILITY
Neutral Charge.
Penetrate Because of Transition State of Synthetic Fibers.

 ENVIRONMENT BEHAVIOUR
Non-Environmental Friendly.
Human effect dyeing method.
 FASTNESS PROPERTIES
Washing
: Good .
Lightening
: Good .
Crocking
: Good .
Gas Fume Fade : Average .

 APPLIANCES
They are Applied to Synthetic Fibers such as
Acetate, Triacetate, Polyester, Nylon and Acrylic.
 COLOUR RANGE
Wide Range of Colors.
Bright and Lighter Shades.
Major Colors: Pale Yellow and Blue.

 COST
Cheap method for dyeing process .
Other agents used in
Polyester dyeing


Dispersing Agent
• It increases the solubility of the dye in water .
• It helps to increase the rate of the dye exhaustion .


Leveling Agent
• Leveling agents hold the rate of the dyeing and
helps to get uniform dyeing.

Buffer
• These agents protect the dye from reduction in
high temperature bath .
 High temperature dyeing process .
 Thermosol process.
High Temperature Dyeing Process
• High temperature dyeing of polyester can be done in
Beam Dyeing machines , Jet dyeing machines
and Pressure Jiggers .
• This method dye applied under pressure at
temperature of about 130`c .
• Heating help to swell the highly compact
polyester polymer and make available
more space for the dye molecule to enter
in to the amorphous region of the fiber .
Dyeing Of Polyester Fabric With Disperse Dyes By
High Temperature Exhaust Method

Procedure :
Prepare The Dye Bath Using The Recipe Below

• M:L:R
• Ammonium Sulphate
• Dispersing Agent

1:30 to 1:40
2g/l
0.5g/l
Dye The Sample Using The Following Dyeing Cycle
Dyeing With Disperse Dye
( High Temperature Exhaust Method )
• First the dye bath is made with the dye , dispersing agent and
the temperature is raised to 60`C .
• Next , Formic acid and Ammonium-Sulphate added till the pH is 5-6 .
• The dyeing should be continued and the temperature is raised to
130`C over period of 45 min.
• Then temperature reaches 130`C dyeing is done for 1 hour .
• Rinsed the sample with cold water .
• Removal the disperse dye on the surface of the fabric by
using Caustic Soda and Sodium Hydrosulphite and rinsed , Neutralize
the sample.
Thermolsol Process
• This process is suitable for mixed fabric of
Poly-Cotton or Poly-Wool .
• The thermo-sol dyeing process is consists of the
following stages .
Padding

Drying

Thermofixing

After Treatment
 Padding
The Padding Carried Out At 30 - 40`C With The
Following Ingredients

•
•
•
•
•
•

Dispensing Agent
Water
Disperse dye
Acetic Acid ( pH 6 – 7 )
Wetting Agent
Neutral alginate thickener
Thermosol Process
• After padding the cloth with the dye and the other
dried .
•

Next stage is fixation of the disperse dye , the cloth is passed
through a hot air pin stenter for 60 second at 190 – 210 `C.

• After heat treatment the cloth washed .
Thank You
Ashan Ranasinghe

Gayan Weerasinghe

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Disperse Dyes for Synthetic Fibers

  • 2. Disperse Dyes • The term “disperse dye” have been applied to the organic colouring substances which are free from ionizing groups, are of low water solubility and are suitable for dyeing hydrophobic fibres. • Disperse dyes are the only water insoluble dyes that dye polyester and acetate fibers. Disperse dye molecules are the smallest dye molecules among all dyes.
  • 3. • Disperse dyes are used for dyeing man made cellulose ester and synthetic fibres specially acetate and polyester fibres and sometimes nylon and acrylic fibres. • Carrier or dispersing agents are required for dyeing with disperse dyes. • Disperse dyes have fair to good light fastness with rating about 4-5.
  • 4.  MECHANISM OF DISPERSE DYE Wander Wall’s Forces. High affinity for Fibers. Attraction between Fiber Surface and the Dye Molecule.  STRUCTURE
  • 5.  SOLUBILITY Non-Soluble in Water.  CHARGEABILITY Neutral Charge. Penetrate Because of Transition State of Synthetic Fibers.  ENVIRONMENT BEHAVIOUR Non-Environmental Friendly. Human effect dyeing method.
  • 6.  FASTNESS PROPERTIES Washing : Good . Lightening : Good . Crocking : Good . Gas Fume Fade : Average .  APPLIANCES They are Applied to Synthetic Fibers such as Acetate, Triacetate, Polyester, Nylon and Acrylic.
  • 7.  COLOUR RANGE Wide Range of Colors. Bright and Lighter Shades. Major Colors: Pale Yellow and Blue.  COST Cheap method for dyeing process .
  • 8. Other agents used in Polyester dyeing  Dispersing Agent • It increases the solubility of the dye in water . • It helps to increase the rate of the dye exhaustion .
  • 9.  Leveling Agent • Leveling agents hold the rate of the dyeing and helps to get uniform dyeing. Buffer • These agents protect the dye from reduction in high temperature bath .
  • 10.  High temperature dyeing process .  Thermosol process.
  • 11. High Temperature Dyeing Process • High temperature dyeing of polyester can be done in Beam Dyeing machines , Jet dyeing machines and Pressure Jiggers . • This method dye applied under pressure at temperature of about 130`c . • Heating help to swell the highly compact polyester polymer and make available more space for the dye molecule to enter in to the amorphous region of the fiber .
  • 12. Dyeing Of Polyester Fabric With Disperse Dyes By High Temperature Exhaust Method Procedure : Prepare The Dye Bath Using The Recipe Below • M:L:R • Ammonium Sulphate • Dispersing Agent 1:30 to 1:40 2g/l 0.5g/l
  • 13. Dye The Sample Using The Following Dyeing Cycle
  • 14. Dyeing With Disperse Dye ( High Temperature Exhaust Method ) • First the dye bath is made with the dye , dispersing agent and the temperature is raised to 60`C . • Next , Formic acid and Ammonium-Sulphate added till the pH is 5-6 . • The dyeing should be continued and the temperature is raised to 130`C over period of 45 min. • Then temperature reaches 130`C dyeing is done for 1 hour . • Rinsed the sample with cold water . • Removal the disperse dye on the surface of the fabric by using Caustic Soda and Sodium Hydrosulphite and rinsed , Neutralize the sample.
  • 15. Thermolsol Process • This process is suitable for mixed fabric of Poly-Cotton or Poly-Wool . • The thermo-sol dyeing process is consists of the following stages . Padding Drying Thermofixing After Treatment
  • 16.  Padding The Padding Carried Out At 30 - 40`C With The Following Ingredients • • • • • • Dispensing Agent Water Disperse dye Acetic Acid ( pH 6 – 7 ) Wetting Agent Neutral alginate thickener
  • 17. Thermosol Process • After padding the cloth with the dye and the other dried . • Next stage is fixation of the disperse dye , the cloth is passed through a hot air pin stenter for 60 second at 190 – 210 `C. • After heat treatment the cloth washed .