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DIESEL AFTERTREATMENT DEVICES




          ENGINE DEVELOPMENT LABORATORY
                                      1
ENGINE DEVELOPMENT LABORATORY
                            2
Diesel Emissions Regulations
                 Drive the Technology
                                            China:
                                            Heavy duty vehicles
                                             NOx + PM
                                              2010 Euro IV
                      India:                  2012 Euro V
                      Heavy duty vehicles
                       NOx + PM
                         2010 Euro IV


                                            S. Korea:
Brazil:                                     Heavy duty vehicles
Heavy duty vehicles                          NOx + PM
 NOx + PM                                      2007 – Euro IV
  2009 Euro IV                                 2010 – Euro V
                            ENGINE DEVELOPMENT LABORATORY
                                                        3
VEHICLE EMISSION NORMS & SULPHUR
  REDUCTION SCHEDULE IN INDIA




           ENGINE DEVELOPMENT LABORATORY
                                       4
European Fuel Sulphur Levels (PPM)
 Fuel Quality (Sulphur Level) is critical for controlling Emissions



                       Euro 2         Euro 3            Euro 4   Euro 5

         500                                                                 India 2010
                                Widely Available
         400                     In 2005; 100%                            Sulphur: 50 PPM
                                     In 2009
         300
         200
         100
             0
                         Gasoline                          Diesel          Source: CAI-Asia

                                               ENGINE
Ref: M. Walsh, Clean Fuels in China (June, 2003)
                                                        DEVELOPMENT LABORATORY
                                                                             5
DIESEL EMISSIONS


                                     PM – particulate matter or soot
         HC & CO



HC – Hydrocarbons              PM
CO – Carbon monoxide                    Diesel
                                      challenges
                                                    NOx

                   NOx – Oxides of nitrogen

                         ENGINE DEVELOPMENT LABORATORY
                                                     6
POST COMBUSTION EMISSION
CONTROL TECHNOLOGY OPTIONS
              NOx / PM CONTROL

NOx CONTROL         PM CONTROL METHODS
 METHODS
  DeNOx             SOF       SOLID PARTICLES

 LNT/LNC           DIESEL           DIESEL
                  OXIDATION     PARTICUALTE
   SCR            CATALYST         FILTER
                               ACTIVE / PASSIVE
                                    TYPE
                COMBINATION


                 ENGINE DEVELOPMENT LABORATORY
                                             7
DIESEL EMISSION CONTROL
   DIESEL OXIDATION CATALYST ( DOC )
REQUIREMENTS OF DOC:e SOF portion of not oxidize SO2 to SO3
 For CO & HC reduction. It does not alter NOx
 Reduce SOF portion of PM
 It should not oxidize SO2 to SO3
 The catalysts such as the precious metals (Pt, Pd), which are active to
  oxidize the SOF are also active towards the oxidation of SO 2 to SO3.
 Adding base metal Oxides (Vanadia) to high Pt loaded catalyst to
  suppress the sulphate making reactions.
 At low temperature SOF is adsorbed in pores & at high temperature
  H2SO4 is released. This is avoided with washcoat additives such as silica,
  zirconia, titania.




                              ENGINE DEVELOPMENT LABORATORY
                                                          8
DIESEL EMISSION CONTROL




NOx / PM Trade-off
        critical
       diesel tuning

                         PM


 NOx

        ENGINE DEVELOPMENT LABORATORY
                                    9
NOx vs PM
   Parameter         Effect     Effect on PM
    change          on NOx
Cycle
temperature                      Better Combustion
increases                        conditions prevails

There is excess
air in bowl                      Towards complete
                                 combustion

Longer premixed
                                 Improved initial
combustion                       mixing, chances of
phase                            better combustion




                  ENGINE DEVELOPMENT LABORATORY
                                             10
NOx – PM
    emission control
strategy
 PM

                                      A   2-V config

100%                                  B   4-V config
                                  A
                                      C   Increased inj. rate
                                  B   D   Inj. Timing retard
                                  C   E   Electronics in injection

 50%                             D    F   Variable swirl

                             E        G   Oxicat, EGR

                         F            H   DPF, DeNOx Cat

                     G
                 H
           50%            100%     NO LABORATORY
                     ENGINE DEVELOPMENT       11
                                      x
Exhaust Gas Recirculation




         ENGINE DEVELOPMENT LABORATORY
                                    12
Influence of EGR

      200%
                         hot EGR

                                     (20% ↓ NOx
      150%                           70% ↑ PM)
 PM




                     cooled EGR

      100%                                          without EGR

                         (≈ NOx
                         60% PM ↓)
      50%
         50%       75%                       100%             125%
                            NOx




                   ENGINE DEVELOPMENT LABORATORY
                                              13
HIGHLIGHTS OF THE LITERATURE STUDY AND ANALYSIS WORK
EGR


           Methods -
           • High Pressure
           • Low Pressure
           • Combination




                             Low pressure is FIRST choice for Euro-V
                              High pressure can be used upto Euro-IV


                      ENGINE DEVELOPMENT LABORATORY
                           14                    14
Diesel Engine Euro III Technology Options




               ENGINE DEVELOPMENT LABORATORY
                                          15
Emission control technology               4-V technology
for Diesel Passenger Cars                 Electronic diesel control
                                              – Rotary pump
     PM                                   EGR ??
                                          Oxicat
     0.080   EURO-
             2              4-V technology
                            Common Rail DI
                            EGR – cooled ??
                            Variable swirl control - ??
                            Double oxicat
     0.050   EURO-3
                 + DPF
                 NOx Cat
     0.025       Cooled EGR
                 Variable Swirl control

     g/km EURO-4
             0.030       0.056 0.070    HC+NO
                 ENGINE DEVELOPMENT LABORATORY
                                            16
                                                                 x
HIGHLIGHTS OF THE LITERATURE STUDY AND ANALYSIS WORK




 Combustion




                    ENGINE DEVELOPMENT LABORATORY
                         17                    17
Particulate Matter
Reduction




      ENGINE DEVELOPMENT LABORATORY
                                 18
TREND IN DIESEL EMISSION CONTROL


 CRDI turbo- charged diesel engine fitted with Diesel Oxidation Catalyst (DOC)
   has low emissions, but still needs trade-off between Particulate Matter (PM)
   and Oxides of Nitrogen (NOx).
 High percentage of EGR upto 30% can be used to reduce NOx considerable,
   but this leads to increase in PM.
 Need for independent technology to reduce NOx & PM

 For PM control, we require the use of Catalysed Diesel Particulate Filter
   (CDPF)
 For NOx control, we require Lean NOx Trap (LNT) or Selective Catalytic
   Reduction (SCR).
 Use of CDPF and LNT or SCR together will produce simultaneous reduction of
   PM and NOx.


                              ENGINE DEVELOPMENT LABORATORY
                                                         19
INTRODUCTION TO DPF
 The first utilization of diesel filters on car was made in California
  by Mercedes-Benz in 1985
 Starting from 2000, the interest in diesel filter systems by
  automotive manufacturers was reestablished
 Since 2001, PSA Peugeot was the first company to utilize DPF on
  passenger cars with Fuel Additives for Passive Regeneration.
 Since 2003, Damlier Chrysler utilized Catalyzed DPF (CDPF) on
  Passenger cars for Passive Regeneration.
 Recently, other car producers started to introduce diesel filters in
  certain models.
 As regards particulate emissions, the wall-flow diesel particulate
  filter (DPF) is today the most efficient after-treatment device,
  attaining filtration efficiencies over 90% (for dry particulate)
  under normal operating conditions.


                            ENGINE DEVELOPMENT LABORATORY
                                                       20
DIESEL PARTICULATE FILTER (DPF)
OR CATALYZED SOOT FILTER (SCF) FOR
         PM REDUCTION




                      Plugged channel honeycomb
                      Particulates trapped on wall
                      Regenerated to burn particles
                      Catalyzed or uncatalyzed


            ENGINE DEVELOPMENT LABORATORY
                                       21
EMISSION CONTROL USING DOC & CDPF




           ENGINE DEVELOPMENT LABORATORY
                                      22
PERFORMANCE REQUIREMENTS FOR DPF
The four basic requirements which the filter must
  meet are:
 adequate filtration efficiency to satisfy
  particulate emissions legislation;
 low pressure drop to minimize fuel penalty and
  conserve engine power (10 g/l loading allowed)
 high thermal shock resistance to ensure filter
  integrity during soot regeneration;
 high surface area per unit volume for compact
  packaging.

                  ENGINE DEVELOPMENT LABORATORY
                                             23
1. Development History
  1988         1998       1999         2000       2001        2002           2003    2004       2005       2006

   Fine Ceramics                   Euro3 regulation                                     Euro4 regulation
(β-type SiC Powder)
                              1 st Mass-Production 1 st Mass-Production                     Mass-Production Lines
                                   Line in Japan        Line in France                           in Hungary
Unique features of SiC
1988 - Start of DPF development
         - Basic Evaluation

      Co-Development with EU customers
                       - Durability Test
                           1 st series equipment in the world

                                              SOP in June 2000
                                                  DPF for additive system
                                           FBC(Fuel Borne Catalyst) System
                                                                                    SOP in January 2004
                                                                                    DPF for catalytic coating system




    City Bus & Construction machines
                                              ENGINE DEVELOPMENT LABORATORY
                                                                         24
2. Technology Roadmap
       2005              Euro4         2010             Euro5          2015      Euro6
  maintenance Interval   100Kkm                         160Kkm                   250Kkm?
                                            From Euro5 almost all cars require DPF
Develop and supply DPF
                                                                C/C C-DPF 2brick
hat would comply with                                           System       (20-40g/L)   RD053
he requirements for all                                                        (40-60g/L) RD061
 ngines and generations.
                                                                                 Thin DOC+C-DPF
                           C/C C-DPF 2brick System
                                           (20-40g/L)
                                                         Newly designed OS thin wall type: RD053
                                                           OS+Medium porosity design: SD061
  U/F C-DPF System
                                      Thin DOC+C-DPF          Maintenance free/Downsizing

                                       High Robustness                  -High Coat ability
                                                                         -High Coat ability
                                       Low Pressure loss                -Low Pressure Loss
                                                                         -Low Pressure Loss
               DOC+C-DPF          Thin wall / Low porosity type         -Low Heat Capacity
                                                                         -Low Heat Capacity
                                              SD031                     -High Ash Capacity
       High Robustness                                                   -High Ash Capacity
       Low porosity type
        SD991/SD021                   Optimized Asymmetrical cell structure            Outlet

                                      “Unique Octo-Square Cell Structure”
                                       ENGINE DEVELOPMENT LABORATORY
                                                                 Inlet
                                                                       25
6. Advantages of SiC-DPF




                           SiC grain     Characteristics of SiC-DPF
                                          + High Thermal Resistance
                                          + High Chemical Resistance
                                          + Low Pressure Loss
         Pore                             + High Filtration Efficiency

                Uniform pore structure
                        ENGINE DEVELOPMENT LABORATORY
                                                   26
6. Advantages of SiC-DPF
High Thermal Resistance
                                                                         セLength: 150.5mm
                                                                          グメントの長さ  :10” L
                                 35
 Accumulated soot mass [ g/ L]


                                                    SiC-DPF 問題なし
                                                     SiC Non crackNo problem                  SiC: Cracked
                                 30                 SiC-DPF クラック発生
                                                     SiC Cracked Cracked
                                                    コージェライト 問題なし
                                                    Cordierite crack problem
                                                     Cord. Non No
                                 25                 Cordierite クラック/溶損
                                                    コージェライト Cracked/Melted
                                                     Cord. Cracked or Melted

                                 20

                                 15
                                                                                             Cordierite:
                                                 SiC-DPF
                                                  SiC-DPF
                                                 SiC-DPF 
                                                                  Melt
                                 10                                                          Melted
                                                  安全領域
                                                   Safety
                                                 Safety Area
                                                   area          Crack
                                 5                                         コージェライト
                                                                            Cord.-DPF
                                                                           Cordierite
                                                                            Safety Area
                                                                           安全領域
                                                                             Safety
                                 0                                            area
                                      0   0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4
                                                      Gas velocity [ m/ sec]

 -Thanks to high thermal resistance, SiC-DPF has higher SML

  compared to Cordierite.
                          ENGINE DEVELOPMENT LABORATORY   27
 -Failure mode of SiC-DPF is only “crack” in case of soot
6. Advantages of SiC-DPF
                      High Filtration Efficiency                                     SiC-DPF

                                           Pore dia. distribution
                            3.0

                            2.5
dV/ dlo gD Po re Vo lum e




                            2.0

                            1.5
                                                                                     Cordierite
                            1.0

                            0.5

                            0.0
                                  1                      10                    100
                                               Po re dia m e t e r (um )




                            Thanks to the sharp pore dia. distribution, SiC-DPF has uniform
                            pore structure, which enables to reach high filtration efficiency.
                                                                           ENGINE DEVELOPMENT LABORATORY
                                                                                                      28
6. Advantages of SiC-DPF
Low Pressure loss
                               Flow velocity = 5m/sec                  SiC-17/100
                                                                       Cordierite-17/100
                                                                       SiC-14/200 High duration type
                      45                                               SiC-12/300 low pressure type
Pressure loss [Kpa]




                      40
                      35
                      30
                      25
                      20
                      15
                      10
                       5
                       0
                           0       2     4      6       8    10   12   14    16      18
                                                    Soot [g/L]

                                                   ENGINE DEVELOPMENT LABORATORY
                               To compare cordierite ,SiC-DPF has a low pressure 29
                               loss
6. Advantages of SiC-DPF
  High Chemical Resistance

                     Additive                                              Ash
CS
i
ei r e d o C




               CuO     Fe 2 O 3   CeO 2      Ash           CeO 2    Fe 2 (SO 4 ) 3   CuSO 4    Na 2 SO 4     K 2 SO 4
 t i r




                                                                     -nH 2 O         -5H 2 O

  (Condition/Temp=1350deg.C, Time = 50hrs)                 (Condition/Temp=1350deg.C, Time = 1hr)


                                             No reaction           Discoloration           Melted          Cracked




                     SiC is stable material against chemicals.

                                          ENGINE DEVELOPMENT LABORATORY
                                                                     30
DPF Regeneration




   ENGINE DEVELOPMENT LABORATORY
                              31
Passive Regeneration




      ENGINE DEVELOPMENT LABORATORY
                                 32
Diesel Particulate Filter System




                             Source: CAI-Asia

          ENGINE DEVELOPMENT LABORATORY
                                     33
Post Injection Regeneration for an Uncoated DPF




                  ENGINE DEVELOPMENT LABORATORY
                                             34
                                            (Umicore)
CDPF ACTIVE REGENERATION




        ENGINE DEVELOPMENT LABORATORY
                                   35
THE MAIN GOALS IN THE DEVELOPMENT OF A
        CATALYTIC FILTER COATING
 Reduction of the activation energy for soot oxidation
 Improvement of the passive regeneration behavior,
  lowering of the balance point (This is defined as the
  temperature at which the same amount of soot in the
  particulate filter is oxidized as is emitted by the engine
  in the same unit of time)
 Suppression of secondary emissions during filter
  regeneration
 Good HC/CO light-off for supporting the function of
  an upstream oxidation catalyst
 High thermal stability
 Preferably no negative impact on backpressure

                       ENGINE DEVELOPMENT LABORATORY
                                                  36
CATALYTIC COATING OF SiC DIESEL PARTICULATE FILTERS

 The advantage of these new filter substrates is a higher tolerance with
  respect to the backpressure behavior compared to a catalytic activation.
 However, lower mechanical stability and reduced maximum soot loading
  represent disadvantages.
 In contrast to standard applications such as three-way or oxidation
  catalyst, in which the substrate serves exclusively as the carrier for the
  catalyst, the diesel particulate filter has its own functionality which is
  changed by a catalyst coating .
 In this way, for example the coating can increase the filtration efficiency
  of the filter and influence its maximum soot loading.
 Decisive, however, is the effect of the coating on the backpressure
  behavior of the filter.
 This interaction between filter substrate and coating must be taken into
  consideration in the development of a suitable catalyst.
 Taking these factors into account, two coating processes for particulate
  filters have been developed .
 These processes are referred to as “Microcoating” and “Macrocoating”.

                              ENGINE DEVELOPMENT LABORATORY
                                                         37
Continuous Regenerative Trap (CRT)
• Oxidises CO and HC to CO2 and H2O
• NO is oxidised to NO2
• Collects Soot in wall-flow particle filter
• NO2 reacts with trapped soot to form CO2 & NO
• Requirements: Fuel S < 50 ppm & NOx/PM > 20
• Passive system - no external heating necessary
  provided Temperature is high enough
  (>260°C for 40% of the time)
• CO, HC, PM reduction > 90%

                   ENGINE DEVELOPMENT LABORATORY
                                              38
CRT Particulate Filter
                                   Outlet
                                   Section
                         Filter
                         Section
          Catalyst
          Section
Inlet
Section




                     Honeycomb     Wall-flow
                     Catalyst      Filter
NO2 Reaction in a CRT

                                                          NO+CO2

   NO           NO2
 ½O2
                               NO2
       CO        CO2
     ½O2

                                                        NO+CO2
     HC       H2O+CO2
O2




      Flow Through Catalyst          Wall Flow Filter


                              ENGINE DEVELOPMENT LABORATORY
                                                         40
US 2007 Emission Control is Focused on PM




               ENGINE DEVELOPMENT LABORATORY
                                          41
HC De-NOx (Diesel Lean NOx Catalyst DLNC)
Zeolite absorbs HC during Cold Start and when the temp is
high enough for light-off, the HC is released for reduction of
NOx. Fuel is injected downstream of catalyst which acts as a
NOx redundant. Operating Temp. window 200 to 300 deg C.

NOx Adsorber (Lean NOx Trap LNT)
Base metal Barium Alumina absorbs and stores NOx in lean
burn operation. Regeneration reqd to avoid deposition on
catalyst material. Occasionally rich mixture is fed which
converts adsorbed Nitrate into N2 .

Urea SCR (Selective Catalytic Reduction)
Urea in solid or aqueous form is used. In the presence of
catalyst urea decomposes to produce NH3, which reacts with
NOx selectively. NH3 reacts with NO and NO2 converting to
N2 molecules and H2O.

                        ENGINE DEVELOPMENT LABORATORY
                                                   42
HC DeNOx CATALYST OR DIESEL LEAN NOx CATALYST (DLNC)
  Reducing NOx by HC under the excess of oxygen is currently the most
    advanced diesel DeNOx concept
  Zeolite absorbs HC during Cold Start and when the temp is high enough
    for light-off, the HC is released for reduction of NOx.
  HC emissions are used to reduce NOx at around 300°C

  The catalyst for the HC DeNOx is Pt on support oxide
    (Al2O3, SiO2,TiO2, ZrO2..)

  This method requires reasonable amounts of HC in the exhaust gas,
    which can be achieved, either by post injection using CRDi or by
    secondary fuel injection.
  NOx reduction up to 30% possible.

  However, there is fuel penalty (3-6%) and expensive system cost.
                                 ENGINE DEVELOPMENT LABORATORY
                                                            43
HC DeNOx MECHANISM
NO + O2= NO2
[NO activation, requires reducible site]


CxHy + NO2= CO2 + N2 + H2O (Preferred)

            [Competition for HC, on oxidizable sites]


CxHy + O2 =CO2 + H2O (Not preferred)
[HC oxidation, very fast]
                     ENGINE DEVELOPMENT LABORATORY
                                                44
EMISSION CONTROL USING HC DeNOx & CDPF




US2010/ EU VI


                De
                   NO
                      x



                          Oxidation Catalyst
                                               Catalyzed Soot
                                               Filter


                          ENGINE DEVELOPMENT LABORATORY
                                                     45
NOx Adsorber Catalysts
• Lean conditions (lambda > 1)
  – Oxidises CO and HC to CO2 and H2O
  – Oxidises NO to NO2
  – NO2 is stored as Nitrate
• Rich conditions (lambda < 1)
  – Nitrates are reduced to NO2
  – NO2 is released and reduced to N2
• NOx reduction > 70% possible.
• Requirements: S < 10 ppm
                   ENGINE DEVELOPMENT LABORATORY
                                              46
NOx Adsorber Catalyst Functions
                                LEAN:

                                NO2 generation
                                NO2 storage
                                (CO, HC, SOF oxidation)




    RICH:

    NOx release
    NOx conversion
    (Desulfation)


                     ENGINE DEVELOPMENT LABORATORY
                                                47
NOX ADSORBER OR LEAN NOx TRAP
 Since NO is known to show slower reactivity with metal oxides than NO2 and
  engine-out NOx primarily consist of NO (90%), NO must first be oxidized to NO2
  over an oxidation catalyst (e.g. Pt based ).
 The adsorption of a NOx adsorber catalyst entails reaction of an acidic gas (NO2)
  with a basic adsorbent (oxides or carbonates of alkali and alkaline earth
  elements, e.g. BaO and BaCO3) to form nitrate or nitroso-species, both on the
  catalyst surface.
 The operational temperature range of the NOx adsorber catalyst is governed by
  the low and high limits.
 The low limit is controlled by the light-off temperature required for the catalyst to
  oxidize NO into NO2 and the upper limit is determined by the temperature of
  thermodynamic stability of the trapped nitrogen oxide species e.g. Ba(NO3)2
 When the effective storage capacity of the adsorber is below the desirable level,
  reductant (e.g. diesel fuel) is injected to establish a rich environment.
 Under this condition, the trapped NOx is reduced to N2 following a conventional
  three-way catalytic conversion principle.
 However , the adsorbent function (e.g. BaO around Pt sites) is extremely
  susceptible to deactivation from sulphur oxides in the exhaust by the formation
  of sulfated species that hinder adsorption sites intended for NO2 storage.
                                    ENGINE DEVELOPMENT LABORATORY
                                                               48
EMISSION CONTROL USING CDPF & LNT




US2010/ EU VI


            Ox
              i
           Ca dati
             tal on
                ys
                  t

                        Catalyzed
                                      NOx Trap
                        Soot Filter




                      ENGINE DEVELOPMENT LABORATORY
                                                 49
EMISSION CONTROL USING LNT & CDPF




US2010/ EU VI


            NO
              xT
                ra
                  p


                       Oxidation Catalyst
                                            Catalyzed Soot
                                            Filter


                      ENGINE DEVELOPMENT LABORATORY
                                                 50
SELECTIVE CATALYTIC
      REDUCTION (SCR)
 Within Europe, the principal NOx control strategy
  starting in 2005, is Selective Catalytic Reduction
  (SCR) using ammonia, derived from urea as the
  reductant.
 Here ammonia reacts with NOx selectively on a
  catalyst, such as V2O5TiO2, under oxygen rich
  exhaust gas
• Urea/water solution reacts at > 200 °C
  to form NH3 and CO2.
• NH3 reduces NO and NO2 to N2.
• NOx reduction > 80 % possible.
• Fuel with S up to 500 ppm can be used.

                    ENGINE DEVELOPMENT LABORATORY
                                               51
Urea SCR System

              Urea Injector



            FLOW



Oxidation                     2 x SCR   1 x Pt Clean-up
Catalyst                      Catalysts Catalyst




                   ENGINE DEVELOPMENT LABORATORY
                                              52
DPF+SCR




 ENGINE DEVELOPMENT LABORATORY
                            53
DPF+SCR+AMOX




   ENGINE DEVELOPMENT LABORATORY
                              54
CRDPF + SCR
 Combined        Continuously
   Regenerative           Diesel
   Particulate Filter (CRDPF)
   with urea-based Selective
   Catalytic Reduction(SCR)
   for simultaneous PM &
   NOx Control.
 Two methods are used to
   achieve accurate dosing of
   urea:
a) Detailed urea injection map
   based        on       engine
   information.
 b) Urea injection based on
   real time NOx input (NOx
   sensor       based)      and
   calculation logic.



                                   ENGINE DEVELOPMENT LABORATORY
                                                              55
ONE APPROACH TO SCR
                                                           SCR Catalyst (S)
                                                     4NH3 + 4NO + O2 → 4N2 + 6H2O
  Oxidation Catalyst (V)
                                    Urea             2NH3 + NO + NO2 → 2N2 + 3H2O
   2NO + O2 → 2NO2
                                 (NH2)2CO
                                                      8NH3 + 6NO2 → 7N2 + 12H2O
4HC + 3O2 → 2CO2 + 2H2O
   2CO + O2 → 2CO2


 Exhaust
  Gas
                            V                         H          S            O


                           Hydrolysis Catalyst (H)                             Oxidation Catalyst (O)
                    (NH2)2CO + H2O → 2NH3 + CO2                               4NH3 + 3O2 → 2N2 + 6H2O




                                         ENGINE DEVELOPMENT LABORATORY
                                                                    56
SCR TECHNOLOGY : TWO TYPES OF DESIGN
 An NH3 slip control catalyst is also used    Within the Compact design, the gas first
  at the end of the SCR catalyst system to      passes through the CR-DPF system, and
  oxidize any NH3 that is not used during       is then turned through 1800 and flows
  the reaction.                                 through the SCR catalysts, which are
                                                coated onto metallic, annular substrates,
 Many of the SCR-DPF systems are
                                                fitted around the CR-DPF system.
  configured in the linear design, where
                                               This presents a wider but much shorter
  an SCR + Slip catalyst system follows a
  CRDF system                                   packaging envelope for the combined
                                                system. It is necessary that it should meet
                                                space constraints of the vehicle
 The SCR catalyst is followed by an
  ammonia slip catalyst also coated on
  ceramic substrates.
 The size of the SCR catalyst is based on
  the engine exhaust flow rates.
 Typically the volume of catalyst is 1.5
  to 2 times the engine displacement



                                    ENGINE DEVELOPMENT LABORATORY
                                                               57
UREA DOSING AND INJECTION SYSTEM
 Urea dosing and injection system        The amount of urea to be injected
  are different but contain similar        is calculated from input signals
  functions.                               received from the following:
 A metered amount of urea is             Engine Out NOx (Conc.) Sensor
  delivered into a pressurized air        Engine Parameters via installed
  stream.
                                           sensors or CAN J-1939 data bus
 The air and urea mixture is then
                                          Exhaust gas temperatures at
  transported to a nozzle that
                                           CRDPF inlet, SCR inlet and SCR
  atomizes and distributes the urea in
                                           outlet
  the exhaust flow.
                                          Urea Temperature
 The mechanical functions of the
                                          Urea and Air system pressures
  system consist of air pressure
  regulation, pumping urea from the
  tank to the dosing system and
  metering the urea into the airflow.



                                ENGINE DEVELOPMENT LABORATORY
                                                           58
THE COMPONENTS IN THE UREA DOSING SYSTEM

 This information is used along with          •   The components of the urea injection
  application specific data entered into the       system consist of a urea pump, an air
  ECU to calculate the amount of urea              regulator and a dosing manifold. Urea
  needed to get the maximum possible               is pumped from the tank to the urea
  NOx reduction, under that operating              dosing manifold via a 24 volt
  condition.                                       accumulator      pump       capable     of
 A NOx sensor is installed in the exhaust         delivering up to 157ml/min of urea.
  pipe at the outlet of the turbocharger.      •   An air regulator is used to deliver
 The retrofit system ECU uses an                  dosing manifold.
  algorithm that calculates the amount of      •   Either the test cell or the vehicle air is
  urea needed based on the engine outlet           used to supply this air to the regulator.
  NOx reading and the exhaust flow of the      •   The air regulator is specific to the
  engine.                                          system.
 The ECU then sends a signal to the Urea
  dosing manifold to deliver the required
  amount of urea to the SCR catalyst.



                                      ENGINE DEVELOPMENT LABORATORY
                                                                 59
FEV’s SCR+DPF FOR SUV




    ENGINE DEVELOPMENT LABORATORY
                               60
EMISSION CONTROL USING CDPF+SCR




           ENGINE DEVELOPMENT LABORATORY
                                      61
DESIGN VALIDATION TECHNIQUES USING CFD
 The Diesel particulate filter (DPF) is         The porous silicon carbide honeycomb, used
  composed of a ceramic square channel            for the experiments from which data will be
  honeycomb with alternate channels               used, has the following geometric features:
  plugged. The material considered for the
  test case is porous silicon carbide with
                                                   Cell density 200 channels/in.2
  the following properties:
                                                  Wall thickness 4 mil inch
    Intrinsic porosity 45%
                                                  Plug length 0.07 inch
    Intrinsic density 3100 kg/m3
                                                  Monolith diameter 5.66 inch
    Permeability 5.4 × 10-13 m2
                                                  Monolith length (L) 5.66 inch
    Effective heat capacity 690 J/kg/K (25°C)
   Effective thermal conductivity 70 W/kg/K
    (25°C)




                                        ENGINE DEVELOPMENT LABORATORY
                                                                   62
DESCRIPTION OF RELEVANT PARAMETERS TO BE OBSERVED
•   The Diesel oxidation catalyst DOC also consists of       •   The aim is for the above parameters to be
    a monolithic square channel honeycomb made of                used as realistic boundary conditions for the
    silicon carbide, which has the coating with a                application-specific models of the after-
    platinum catalyst.
                                                                 treatment devices. Specifically, within the
•    The DOC ( 2 Nos) has the following geometric                DPF, coupling with the 3-D flow solver is
    characteristics: channel density 400 channels/in.2
    wall thicknesses 6.5 mil inches, monolith length (L)         expected to improve the predictive capability
    2.5 inch, monolith diameter 5.66 inch.                       of the DPF regeneration model, which will in
•   The above properties and characteristics can be              turn be assessed by observation of:
    translated into bulk properties (e.g. flow resistance)   •   a) Time response of the DPF pressure drop
    by analytic expressions, or are otherwise used in            (flow resistance)
    modeling the bulk behavior of the honeycomb
    material regions.                                        •   b) Time response of the DPF (internal)
                                                                 temperatures and outflow temperature,
•   Hence, the focus in the current context is in
    the additional information, which a 3-D flow             •   c) Distribution of soot mass loading within
    solver can provide:                                          the filter during and after the regeneration
                                                                 sequence.
•   a) Exhaust gas velocity and temperature
    profiles entering the DPF and DOC devices,
•   b) Temperature distribution within the
    devices due to 3-D internal heat transfer and
    non-axisymmetric heat losses to the exterior.




                                               ENGINE DEVELOPMENT LABORATORY
                                                                          63
SOFTWARE & BOUNDARY CONDITIONS
 MODEL SETUP WITH THIRD-                    OUTFLOW:
  PARTY SOFTWARE :                           Pressure outlet: 0 gauge pressure. Exhaust
 The third-party software used for the       flow after the devices is vented to the
  automotive test case was Gambit2.0 and      environment.
  Fluent 6.0.1                               WALLS:
 TURBULENCE MODEL                           No-slip condition for momentum.
                                             Heat loss at the walls of an exhaust system is
 The standard k-ε model is used. The         normally treated as a function of temperature
  regions occupied by the DPF and DOC         with a heat transfer coefficient for natural
  monoliths are considered laminar zones      and/or forced convection.
  (no production or dissipation of           However, the surfaces of the experimental
  turbulence; momentum transfer based         exhaust system are wrapped with a layer of
  on laminar viscosity).                      fibrous insulation and a covering of
 INFLOW: (SPECIFIED INLET                    aluminium foil.
  VELOCITY)                                  Therefore, a very small heat loss rate
                                              proportional to the exhaust-to-environment
 25 - 35 m/s during normal (loading) and     temperature contrast can be assumed.
  regeneration mode operation                GAS PROPERTIES:
 Turbulence intensity: 10%                  (Assume properties of air, variable with
 Turbulence length scale: 0.005 m            temperature)
 Temperature: 250 – 350 °C                  Exhaust gas density: equation of state for
                                              ideal gas with molecular weight 29 gr/mol.




                                  ENGINE DEVELOPMENT LABORATORY
                                                             64
CONCLUSIONS
 For meeting BS IV Norms, optimised shallow combustion chamber
  with optimized CRDi, Cooled 30% EGR and DOC may be the good
  beginning.
 The next step may be addition of CDPF for PM control and engine
  optimization for NOx reduction.
 For Euro V Norms, addition of HC DeNOx, LNT or SCR may be tried
  for NOx reduction.

 In the case of new developments for Euro 4 compliance, the new design
  is recommended to be protected for high peak firing pressure
  capability.
 Transient behaviour of engines will become decisive and most
  challenging with very low engine-out emissions as mandatory
  for Euro V/VI.




                          ENGINE DEVELOPMENT LABORATORY
                                                     65
                                                                      65
REFERENCES
   1 J. Abthoff, H. D. Schuster, C. Noller: “Concept of catalytic exhaust emission control for Europe”,
    SAE Paper 94047, 1994.
   2 K. Pattas, Z. Samaras, N. Patsatzis, C. Michalopoulou, O. Zogou, A.Μ. Stamatelos and M. Barkis.
    “On-Road Experience with Trap Oxidizer Systems Installed on 5 Urban Buses”, SAE paper 900109,
    1990.
   3 K. Pattas., A. Stamatelos, “The Effect of Exhaust Throttling on the Diesel Engine Operation
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   4 J.C. Clerc, “Catalytic Diesel exhausts after-treatment”. Applied Catalysis B: Environmental 10
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   5. R.J. Farrauto, K.E. Voss, and R.M. Heck, “A Base Metal Oxide Catalyst for Reduction of Diesel
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   6 Gulati, S., “Design Consideration for Diesel Flow through Converters”, SAE 920145 (1992).
   7 R.Beckmann, W. Engeler, E. Mueller, B.H. Engler, J. Leyrer, E.S. Lox and K. Ostgathe, ” A new
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   8 M.Wayatt, W.A. Manning, S.A. Roth, M.J. D’Aniello, Jr, E.S. Andresson and S.C.G. Fredholm, “
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   9 Makoto Horiuchi, Koichi Saito and Shoichi Ichihara, “The Effects of Flow- Through Type
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   SAE Paper No2001-01-0011, 2001
   13 J.Paul Day, “Substrate Effects on Light- Off_ Part II Cell Shape Contributions”, SAE 971024.




                                       ENGINE DEVELOPMENT LABORATORY
                                                                  66
REFERENCES
   14. J. Paul Day and Louis S. Socha, Jr., “The Design of Automotive Catalyst Supports for Improved
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   15 K.P.Reddy, S.T.Gulati., Effect of contour, size and cell structure on compressive strength of
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   16. Stobbe, P., Petersen, H.G., Hoj, J.W. and Sorensen, S.C., “Sic as a Substrate for Diesel
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   17. Taoka, N., Ohno, K., Hong, S., Sato, H., Yoshida, Y.and Komori, T., “Effect of Sic-DPF with
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   19. Wade, W.R; White, J.E. and Florek, J.J.; SAE Paper No.810118 (1981)
   20. Suresh T Gulati,“Ceramic Solution for Diesel Exhaust Aftertreatment”, SAE paper No 962469.
   21. Amann, C.A.; Stivender, D.L.; Plee, S.L.andMacDonald, J.S.; SAEPaper No.800251 (1980).
   22. Weaver, C.S; SAE Paper No.840174 (1984)
   23. Gulati, S.T. and Helfinstine, J.D; SAE Paper No.850010 (1985)
   24 Gulati, S.T and Sherwood, D.L.; SAE Paper No.910135 (1991)
   25 Murtagh, M.J.; Sherwood, D.L and Socha, L.S, Jr.; SAE Paper No.940235 (1994)
   26 P. Zelenka, K. Ostgathe, E. Lox: “Reduction of Diesel Exhaust Emissions by Using Oxidation
    Catalysts”, SAEpaper 902111, 1990.
   27 J. Howitt, M. Montierth, “Cellular Ceramic Diesel Particulate Filter”, SAE paper 810114, 1981.
   28. R.J. Farrauto, K.E. Voss, “Monolithic Diesel Oxidation Catalysts”, Applied Catalysis B:
    Environmental 10 (1996) 29-51.162
   29 J.A.A. van den Tillaart, J. Leyrer, S. Eckhoff, E.S. Lox, “Effect of Support Oxide and Noble
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                                      ENGINE DEVELOPMENT LABORATORY
                                                                 67
REFERENCES
•   30 J.P.A. Neeft, M. Makkee, J.A. Moulijn, “Catalysts for the Oxidation of Soot from Diesel Exhaust
    gases, an exploratory study”, Applied Catalysis B: Environmental 8 (1996) 57-78
•   31 J.P.A. Neeft, W. Schiper, M. Makkee and J.A. Moulijn, “Feasibility Study towards a Cu/K/Mo/
    (Cl) soot Oxidation Catalyst for Application in Diesel Exhaust Gases”, Applied Catalysis B:
    Environmental 11 (1997) 365- 382
•   32 T. V. Johnson, “Diesel Emission Control in Review” SAE paper 2000-01-0184
•   33.K. Pattas, Z. Samaras, A. Roumbos, J. Lemaire, W. Mustel, P. Ruveirolles: “Regeneration of DPF
    at Low Temperatures with the use of a Cerium Based Fuel Additive”, SAE paper 960135, 1996.
•   34. T. Seguelong, G. Blanchard, J. Michelin, F. Terres, H. Weltens, “Ceria-Based Fuel-Borne
    Catalysts for Series Diesel Particulate Filter Regeneration”, SAE paper, 2003-01-0378.
•   35. B. Stanmore, J. F. Brihlac, P. Gilot, “The Ignition and Combustion of Cerium Doped diesel
    Soot”, SAE paper 1999- 01-0115.
•   36. A. Gantawar, C. Opris, J. Johnson, “A Study of the Regeneration Characteristics of Silicon
    Carbide and Cordierite Diesel Particulate Filters Using a Copper Fuel Additive”, SAE paper 970187.
•   37.D. Daly, D. McKinnon, J. Martin, D. Pavlich, “Diesel Particulate Regeneration System using a
    Copper Fuel Additive”, SAE paper, 930131, 1993.
•   38. O. Salvat, P. Marez, G. Belot, “Passenger Car Serial Application of a Particulate Filter System on
    a Common Rail Direct Injection Diesel Engine”, SAE paper 2000-01-0473
•   39. K. Ohno, K. Shimato, N. Taoka, S. Hong, T. Ninomiya, T. Komori, O. Salvat, “Characterization
    of SiC-DPF for Passenger Car”. SAE paper 2000-01-0185.
•   40. K. Nakatani, S. Hirota, S. Takeshima, K. Itoh, T. Tanaka, K. Dohmae, “Simultaneous PM and
    NOx Reduction System for Diesel Engines”, SAE paper 2002-01-0957.
•   41. J. Gieshoff, M. Preifer, A. Schafer-Sindlinger, U. Hackbarth, O. Teysset, C. Colignon, C.
    Rigaudau, O. Salvat, H. Krieg, B.W. Wenclawiak, “Regeneration of Catalytic Diesel Particulate
    Filters”, SAE paper 2000-01-0907.




                                        ENGINE DEVELOPMENT LABORATORY
                                                                   68
   42. Gulati, S.T., “Design Consideration for Diesel Flow –Through Converters”, SAE Paper
    No.920145, 1992
   43. W. Held, A. Koenig, A., T. Richter, L. Puppe “Catalytic NOx Reduction in Net Oxidizing
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   44. N. Miyoshi, S. Matsumoto, K. Katoh, N. Takahashi, K. Yokota, M. Sugiura, K. Kasahara,
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   45. Gulati, S.T “New Developments in Diesel Oxidation Catalysts and Diesel Particulate Filters”,
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   50. Ray Conway, Sougato Chatterjee “NOx and PM Reduction Using Combined SCR and DPF
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   56. http://www.un.org/esa/gite/iandm/senguptapresentation.pdf
   57. http://static.teriin.org/urban/urban.htm

                                      ENGINE DEVELOPMENT LABORATORY
                                                                 69
ENGINE DEVELOPMENT LABORATORY
                           70

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Dr. vora ppt chapter 5 diesel aftertreatment

  • 1. DIESEL AFTERTREATMENT DEVICES ENGINE DEVELOPMENT LABORATORY 1
  • 3. Diesel Emissions Regulations Drive the Technology China: Heavy duty vehicles NOx + PM 2010 Euro IV India: 2012 Euro V Heavy duty vehicles NOx + PM 2010 Euro IV S. Korea: Brazil: Heavy duty vehicles Heavy duty vehicles NOx + PM NOx + PM 2007 – Euro IV 2009 Euro IV 2010 – Euro V ENGINE DEVELOPMENT LABORATORY 3
  • 4. VEHICLE EMISSION NORMS & SULPHUR REDUCTION SCHEDULE IN INDIA ENGINE DEVELOPMENT LABORATORY 4
  • 5. European Fuel Sulphur Levels (PPM) Fuel Quality (Sulphur Level) is critical for controlling Emissions Euro 2 Euro 3 Euro 4 Euro 5 500 India 2010 Widely Available 400 In 2005; 100% Sulphur: 50 PPM In 2009 300 200 100 0 Gasoline Diesel Source: CAI-Asia ENGINE Ref: M. Walsh, Clean Fuels in China (June, 2003) DEVELOPMENT LABORATORY 5
  • 6. DIESEL EMISSIONS PM – particulate matter or soot HC & CO HC – Hydrocarbons PM CO – Carbon monoxide Diesel challenges NOx NOx – Oxides of nitrogen ENGINE DEVELOPMENT LABORATORY 6
  • 7. POST COMBUSTION EMISSION CONTROL TECHNOLOGY OPTIONS NOx / PM CONTROL NOx CONTROL PM CONTROL METHODS METHODS DeNOx SOF SOLID PARTICLES LNT/LNC DIESEL DIESEL OXIDATION PARTICUALTE SCR CATALYST FILTER ACTIVE / PASSIVE TYPE COMBINATION ENGINE DEVELOPMENT LABORATORY 7
  • 8. DIESEL EMISSION CONTROL DIESEL OXIDATION CATALYST ( DOC ) REQUIREMENTS OF DOC:e SOF portion of not oxidize SO2 to SO3  For CO & HC reduction. It does not alter NOx  Reduce SOF portion of PM  It should not oxidize SO2 to SO3  The catalysts such as the precious metals (Pt, Pd), which are active to oxidize the SOF are also active towards the oxidation of SO 2 to SO3.  Adding base metal Oxides (Vanadia) to high Pt loaded catalyst to suppress the sulphate making reactions.  At low temperature SOF is adsorbed in pores & at high temperature H2SO4 is released. This is avoided with washcoat additives such as silica, zirconia, titania. ENGINE DEVELOPMENT LABORATORY 8
  • 9. DIESEL EMISSION CONTROL NOx / PM Trade-off critical diesel tuning PM NOx ENGINE DEVELOPMENT LABORATORY 9
  • 10. NOx vs PM Parameter Effect Effect on PM change on NOx Cycle temperature Better Combustion increases conditions prevails There is excess air in bowl Towards complete combustion Longer premixed Improved initial combustion mixing, chances of phase better combustion ENGINE DEVELOPMENT LABORATORY 10
  • 11. NOx – PM emission control strategy PM A 2-V config 100% B 4-V config A C Increased inj. rate B D Inj. Timing retard C E Electronics in injection 50% D F Variable swirl E G Oxicat, EGR F H DPF, DeNOx Cat G H 50% 100% NO LABORATORY ENGINE DEVELOPMENT 11 x
  • 12. Exhaust Gas Recirculation ENGINE DEVELOPMENT LABORATORY 12
  • 13. Influence of EGR 200% hot EGR (20% ↓ NOx 150% 70% ↑ PM) PM cooled EGR 100% without EGR (≈ NOx 60% PM ↓) 50% 50% 75% 100% 125% NOx ENGINE DEVELOPMENT LABORATORY 13
  • 14. HIGHLIGHTS OF THE LITERATURE STUDY AND ANALYSIS WORK EGR Methods - • High Pressure • Low Pressure • Combination Low pressure is FIRST choice for Euro-V High pressure can be used upto Euro-IV ENGINE DEVELOPMENT LABORATORY 14 14
  • 15. Diesel Engine Euro III Technology Options ENGINE DEVELOPMENT LABORATORY 15
  • 16. Emission control technology 4-V technology for Diesel Passenger Cars Electronic diesel control – Rotary pump PM EGR ?? Oxicat 0.080 EURO- 2 4-V technology Common Rail DI EGR – cooled ?? Variable swirl control - ?? Double oxicat 0.050 EURO-3 + DPF NOx Cat 0.025 Cooled EGR Variable Swirl control g/km EURO-4 0.030 0.056 0.070 HC+NO ENGINE DEVELOPMENT LABORATORY 16 x
  • 17. HIGHLIGHTS OF THE LITERATURE STUDY AND ANALYSIS WORK Combustion ENGINE DEVELOPMENT LABORATORY 17 17
  • 18. Particulate Matter Reduction ENGINE DEVELOPMENT LABORATORY 18
  • 19. TREND IN DIESEL EMISSION CONTROL  CRDI turbo- charged diesel engine fitted with Diesel Oxidation Catalyst (DOC) has low emissions, but still needs trade-off between Particulate Matter (PM) and Oxides of Nitrogen (NOx).  High percentage of EGR upto 30% can be used to reduce NOx considerable, but this leads to increase in PM.  Need for independent technology to reduce NOx & PM  For PM control, we require the use of Catalysed Diesel Particulate Filter (CDPF)  For NOx control, we require Lean NOx Trap (LNT) or Selective Catalytic Reduction (SCR).  Use of CDPF and LNT or SCR together will produce simultaneous reduction of PM and NOx. ENGINE DEVELOPMENT LABORATORY 19
  • 20. INTRODUCTION TO DPF  The first utilization of diesel filters on car was made in California by Mercedes-Benz in 1985  Starting from 2000, the interest in diesel filter systems by automotive manufacturers was reestablished  Since 2001, PSA Peugeot was the first company to utilize DPF on passenger cars with Fuel Additives for Passive Regeneration.  Since 2003, Damlier Chrysler utilized Catalyzed DPF (CDPF) on Passenger cars for Passive Regeneration.  Recently, other car producers started to introduce diesel filters in certain models.  As regards particulate emissions, the wall-flow diesel particulate filter (DPF) is today the most efficient after-treatment device, attaining filtration efficiencies over 90% (for dry particulate) under normal operating conditions. ENGINE DEVELOPMENT LABORATORY 20
  • 21. DIESEL PARTICULATE FILTER (DPF) OR CATALYZED SOOT FILTER (SCF) FOR PM REDUCTION  Plugged channel honeycomb  Particulates trapped on wall  Regenerated to burn particles  Catalyzed or uncatalyzed ENGINE DEVELOPMENT LABORATORY 21
  • 22. EMISSION CONTROL USING DOC & CDPF ENGINE DEVELOPMENT LABORATORY 22
  • 23. PERFORMANCE REQUIREMENTS FOR DPF The four basic requirements which the filter must meet are:  adequate filtration efficiency to satisfy particulate emissions legislation;  low pressure drop to minimize fuel penalty and conserve engine power (10 g/l loading allowed)  high thermal shock resistance to ensure filter integrity during soot regeneration;  high surface area per unit volume for compact packaging. ENGINE DEVELOPMENT LABORATORY 23
  • 24. 1. Development History 1988 1998 1999 2000 2001 2002 2003 2004 2005 2006 Fine Ceramics Euro3 regulation Euro4 regulation (β-type SiC Powder) 1 st Mass-Production 1 st Mass-Production Mass-Production Lines Line in Japan Line in France in Hungary Unique features of SiC 1988 - Start of DPF development - Basic Evaluation Co-Development with EU customers - Durability Test 1 st series equipment in the world SOP in June 2000 DPF for additive system FBC(Fuel Borne Catalyst) System SOP in January 2004 DPF for catalytic coating system City Bus & Construction machines ENGINE DEVELOPMENT LABORATORY 24
  • 25. 2. Technology Roadmap 2005 Euro4 2010 Euro5 2015 Euro6 maintenance Interval 100Kkm 160Kkm 250Kkm? From Euro5 almost all cars require DPF Develop and supply DPF C/C C-DPF 2brick hat would comply with System (20-40g/L) RD053 he requirements for all (40-60g/L) RD061 ngines and generations. Thin DOC+C-DPF C/C C-DPF 2brick System (20-40g/L) Newly designed OS thin wall type: RD053 OS+Medium porosity design: SD061 U/F C-DPF System Thin DOC+C-DPF Maintenance free/Downsizing High Robustness -High Coat ability -High Coat ability Low Pressure loss -Low Pressure Loss -Low Pressure Loss DOC+C-DPF Thin wall / Low porosity type -Low Heat Capacity -Low Heat Capacity SD031 -High Ash Capacity High Robustness -High Ash Capacity Low porosity type SD991/SD021 Optimized Asymmetrical cell structure Outlet “Unique Octo-Square Cell Structure” ENGINE DEVELOPMENT LABORATORY Inlet 25
  • 26. 6. Advantages of SiC-DPF SiC grain Characteristics of SiC-DPF + High Thermal Resistance + High Chemical Resistance + Low Pressure Loss Pore + High Filtration Efficiency Uniform pore structure ENGINE DEVELOPMENT LABORATORY 26
  • 27. 6. Advantages of SiC-DPF High Thermal Resistance セLength: 150.5mm グメントの長さ :10” L 35 Accumulated soot mass [ g/ L] SiC-DPF 問題なし SiC Non crackNo problem SiC: Cracked 30 SiC-DPF クラック発生 SiC Cracked Cracked コージェライト 問題なし Cordierite crack problem Cord. Non No 25 Cordierite クラック/溶損 コージェライト Cracked/Melted Cord. Cracked or Melted 20 15 Cordierite: SiC-DPF SiC-DPF SiC-DPF  Melt 10 Melted 安全領域 Safety Safety Area area Crack 5 コージェライト Cord.-DPF Cordierite Safety Area 安全領域 Safety 0 area 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 1.8 2.0 2.2 2.4 Gas velocity [ m/ sec] -Thanks to high thermal resistance, SiC-DPF has higher SML compared to Cordierite. ENGINE DEVELOPMENT LABORATORY 27 -Failure mode of SiC-DPF is only “crack” in case of soot
  • 28. 6. Advantages of SiC-DPF High Filtration Efficiency SiC-DPF Pore dia. distribution 3.0 2.5 dV/ dlo gD Po re Vo lum e 2.0 1.5 Cordierite 1.0 0.5 0.0 1 10 100 Po re dia m e t e r (um ) Thanks to the sharp pore dia. distribution, SiC-DPF has uniform pore structure, which enables to reach high filtration efficiency. ENGINE DEVELOPMENT LABORATORY 28
  • 29. 6. Advantages of SiC-DPF Low Pressure loss Flow velocity = 5m/sec SiC-17/100 Cordierite-17/100 SiC-14/200 High duration type 45 SiC-12/300 low pressure type Pressure loss [Kpa] 40 35 30 25 20 15 10 5 0 0 2 4 6 8 10 12 14 16 18 Soot [g/L] ENGINE DEVELOPMENT LABORATORY To compare cordierite ,SiC-DPF has a low pressure 29 loss
  • 30. 6. Advantages of SiC-DPF High Chemical Resistance Additive Ash CS i ei r e d o C CuO Fe 2 O 3 CeO 2 Ash CeO 2 Fe 2 (SO 4 ) 3 CuSO 4 Na 2 SO 4 K 2 SO 4 t i r -nH 2 O -5H 2 O (Condition/Temp=1350deg.C, Time = 50hrs) (Condition/Temp=1350deg.C, Time = 1hr) No reaction Discoloration Melted Cracked SiC is stable material against chemicals. ENGINE DEVELOPMENT LABORATORY 30
  • 31. DPF Regeneration ENGINE DEVELOPMENT LABORATORY 31
  • 32. Passive Regeneration ENGINE DEVELOPMENT LABORATORY 32
  • 33. Diesel Particulate Filter System Source: CAI-Asia ENGINE DEVELOPMENT LABORATORY 33
  • 34. Post Injection Regeneration for an Uncoated DPF ENGINE DEVELOPMENT LABORATORY 34 (Umicore)
  • 35. CDPF ACTIVE REGENERATION ENGINE DEVELOPMENT LABORATORY 35
  • 36. THE MAIN GOALS IN THE DEVELOPMENT OF A CATALYTIC FILTER COATING  Reduction of the activation energy for soot oxidation  Improvement of the passive regeneration behavior, lowering of the balance point (This is defined as the temperature at which the same amount of soot in the particulate filter is oxidized as is emitted by the engine in the same unit of time)  Suppression of secondary emissions during filter regeneration  Good HC/CO light-off for supporting the function of an upstream oxidation catalyst  High thermal stability  Preferably no negative impact on backpressure ENGINE DEVELOPMENT LABORATORY 36
  • 37. CATALYTIC COATING OF SiC DIESEL PARTICULATE FILTERS  The advantage of these new filter substrates is a higher tolerance with respect to the backpressure behavior compared to a catalytic activation.  However, lower mechanical stability and reduced maximum soot loading represent disadvantages.  In contrast to standard applications such as three-way or oxidation catalyst, in which the substrate serves exclusively as the carrier for the catalyst, the diesel particulate filter has its own functionality which is changed by a catalyst coating .  In this way, for example the coating can increase the filtration efficiency of the filter and influence its maximum soot loading.  Decisive, however, is the effect of the coating on the backpressure behavior of the filter.  This interaction between filter substrate and coating must be taken into consideration in the development of a suitable catalyst.  Taking these factors into account, two coating processes for particulate filters have been developed .  These processes are referred to as “Microcoating” and “Macrocoating”. ENGINE DEVELOPMENT LABORATORY 37
  • 38. Continuous Regenerative Trap (CRT) • Oxidises CO and HC to CO2 and H2O • NO is oxidised to NO2 • Collects Soot in wall-flow particle filter • NO2 reacts with trapped soot to form CO2 & NO • Requirements: Fuel S < 50 ppm & NOx/PM > 20 • Passive system - no external heating necessary provided Temperature is high enough (>260°C for 40% of the time) • CO, HC, PM reduction > 90% ENGINE DEVELOPMENT LABORATORY 38
  • 39. CRT Particulate Filter Outlet Section Filter Section Catalyst Section Inlet Section Honeycomb Wall-flow Catalyst Filter
  • 40. NO2 Reaction in a CRT NO+CO2 NO NO2 ½O2 NO2 CO CO2 ½O2 NO+CO2 HC H2O+CO2 O2 Flow Through Catalyst Wall Flow Filter ENGINE DEVELOPMENT LABORATORY 40
  • 41. US 2007 Emission Control is Focused on PM ENGINE DEVELOPMENT LABORATORY 41
  • 42. HC De-NOx (Diesel Lean NOx Catalyst DLNC) Zeolite absorbs HC during Cold Start and when the temp is high enough for light-off, the HC is released for reduction of NOx. Fuel is injected downstream of catalyst which acts as a NOx redundant. Operating Temp. window 200 to 300 deg C. NOx Adsorber (Lean NOx Trap LNT) Base metal Barium Alumina absorbs and stores NOx in lean burn operation. Regeneration reqd to avoid deposition on catalyst material. Occasionally rich mixture is fed which converts adsorbed Nitrate into N2 . Urea SCR (Selective Catalytic Reduction) Urea in solid or aqueous form is used. In the presence of catalyst urea decomposes to produce NH3, which reacts with NOx selectively. NH3 reacts with NO and NO2 converting to N2 molecules and H2O. ENGINE DEVELOPMENT LABORATORY 42
  • 43. HC DeNOx CATALYST OR DIESEL LEAN NOx CATALYST (DLNC)  Reducing NOx by HC under the excess of oxygen is currently the most advanced diesel DeNOx concept  Zeolite absorbs HC during Cold Start and when the temp is high enough for light-off, the HC is released for reduction of NOx.  HC emissions are used to reduce NOx at around 300°C  The catalyst for the HC DeNOx is Pt on support oxide (Al2O3, SiO2,TiO2, ZrO2..)  This method requires reasonable amounts of HC in the exhaust gas, which can be achieved, either by post injection using CRDi or by secondary fuel injection.  NOx reduction up to 30% possible.  However, there is fuel penalty (3-6%) and expensive system cost. ENGINE DEVELOPMENT LABORATORY 43
  • 44. HC DeNOx MECHANISM NO + O2= NO2 [NO activation, requires reducible site] CxHy + NO2= CO2 + N2 + H2O (Preferred) [Competition for HC, on oxidizable sites] CxHy + O2 =CO2 + H2O (Not preferred) [HC oxidation, very fast] ENGINE DEVELOPMENT LABORATORY 44
  • 45. EMISSION CONTROL USING HC DeNOx & CDPF US2010/ EU VI De NO x Oxidation Catalyst Catalyzed Soot Filter ENGINE DEVELOPMENT LABORATORY 45
  • 46. NOx Adsorber Catalysts • Lean conditions (lambda > 1) – Oxidises CO and HC to CO2 and H2O – Oxidises NO to NO2 – NO2 is stored as Nitrate • Rich conditions (lambda < 1) – Nitrates are reduced to NO2 – NO2 is released and reduced to N2 • NOx reduction > 70% possible. • Requirements: S < 10 ppm ENGINE DEVELOPMENT LABORATORY 46
  • 47. NOx Adsorber Catalyst Functions LEAN: NO2 generation NO2 storage (CO, HC, SOF oxidation) RICH: NOx release NOx conversion (Desulfation) ENGINE DEVELOPMENT LABORATORY 47
  • 48. NOX ADSORBER OR LEAN NOx TRAP  Since NO is known to show slower reactivity with metal oxides than NO2 and engine-out NOx primarily consist of NO (90%), NO must first be oxidized to NO2 over an oxidation catalyst (e.g. Pt based ).  The adsorption of a NOx adsorber catalyst entails reaction of an acidic gas (NO2) with a basic adsorbent (oxides or carbonates of alkali and alkaline earth elements, e.g. BaO and BaCO3) to form nitrate or nitroso-species, both on the catalyst surface.  The operational temperature range of the NOx adsorber catalyst is governed by the low and high limits.  The low limit is controlled by the light-off temperature required for the catalyst to oxidize NO into NO2 and the upper limit is determined by the temperature of thermodynamic stability of the trapped nitrogen oxide species e.g. Ba(NO3)2  When the effective storage capacity of the adsorber is below the desirable level, reductant (e.g. diesel fuel) is injected to establish a rich environment.  Under this condition, the trapped NOx is reduced to N2 following a conventional three-way catalytic conversion principle.  However , the adsorbent function (e.g. BaO around Pt sites) is extremely susceptible to deactivation from sulphur oxides in the exhaust by the formation of sulfated species that hinder adsorption sites intended for NO2 storage. ENGINE DEVELOPMENT LABORATORY 48
  • 49. EMISSION CONTROL USING CDPF & LNT US2010/ EU VI Ox i Ca dati tal on ys t Catalyzed NOx Trap Soot Filter ENGINE DEVELOPMENT LABORATORY 49
  • 50. EMISSION CONTROL USING LNT & CDPF US2010/ EU VI NO xT ra p Oxidation Catalyst Catalyzed Soot Filter ENGINE DEVELOPMENT LABORATORY 50
  • 51. SELECTIVE CATALYTIC REDUCTION (SCR)  Within Europe, the principal NOx control strategy starting in 2005, is Selective Catalytic Reduction (SCR) using ammonia, derived from urea as the reductant.  Here ammonia reacts with NOx selectively on a catalyst, such as V2O5TiO2, under oxygen rich exhaust gas • Urea/water solution reacts at > 200 °C to form NH3 and CO2. • NH3 reduces NO and NO2 to N2. • NOx reduction > 80 % possible. • Fuel with S up to 500 ppm can be used. ENGINE DEVELOPMENT LABORATORY 51
  • 52. Urea SCR System Urea Injector FLOW Oxidation 2 x SCR 1 x Pt Clean-up Catalyst Catalysts Catalyst ENGINE DEVELOPMENT LABORATORY 52
  • 53. DPF+SCR ENGINE DEVELOPMENT LABORATORY 53
  • 54. DPF+SCR+AMOX ENGINE DEVELOPMENT LABORATORY 54
  • 55. CRDPF + SCR  Combined Continuously Regenerative Diesel Particulate Filter (CRDPF) with urea-based Selective Catalytic Reduction(SCR) for simultaneous PM & NOx Control.  Two methods are used to achieve accurate dosing of urea: a) Detailed urea injection map based on engine information. b) Urea injection based on real time NOx input (NOx sensor based) and calculation logic. ENGINE DEVELOPMENT LABORATORY 55
  • 56. ONE APPROACH TO SCR SCR Catalyst (S) 4NH3 + 4NO + O2 → 4N2 + 6H2O Oxidation Catalyst (V) Urea 2NH3 + NO + NO2 → 2N2 + 3H2O 2NO + O2 → 2NO2 (NH2)2CO 8NH3 + 6NO2 → 7N2 + 12H2O 4HC + 3O2 → 2CO2 + 2H2O 2CO + O2 → 2CO2 Exhaust Gas V H S O Hydrolysis Catalyst (H) Oxidation Catalyst (O) (NH2)2CO + H2O → 2NH3 + CO2 4NH3 + 3O2 → 2N2 + 6H2O ENGINE DEVELOPMENT LABORATORY 56
  • 57. SCR TECHNOLOGY : TWO TYPES OF DESIGN  An NH3 slip control catalyst is also used  Within the Compact design, the gas first at the end of the SCR catalyst system to passes through the CR-DPF system, and oxidize any NH3 that is not used during is then turned through 1800 and flows the reaction. through the SCR catalysts, which are coated onto metallic, annular substrates,  Many of the SCR-DPF systems are fitted around the CR-DPF system. configured in the linear design, where  This presents a wider but much shorter an SCR + Slip catalyst system follows a CRDF system packaging envelope for the combined system. It is necessary that it should meet space constraints of the vehicle  The SCR catalyst is followed by an ammonia slip catalyst also coated on ceramic substrates.  The size of the SCR catalyst is based on the engine exhaust flow rates.  Typically the volume of catalyst is 1.5 to 2 times the engine displacement ENGINE DEVELOPMENT LABORATORY 57
  • 58. UREA DOSING AND INJECTION SYSTEM  Urea dosing and injection system  The amount of urea to be injected are different but contain similar is calculated from input signals functions. received from the following:  A metered amount of urea is  Engine Out NOx (Conc.) Sensor delivered into a pressurized air  Engine Parameters via installed stream. sensors or CAN J-1939 data bus  The air and urea mixture is then  Exhaust gas temperatures at transported to a nozzle that CRDPF inlet, SCR inlet and SCR atomizes and distributes the urea in outlet the exhaust flow.  Urea Temperature  The mechanical functions of the  Urea and Air system pressures system consist of air pressure regulation, pumping urea from the tank to the dosing system and metering the urea into the airflow. ENGINE DEVELOPMENT LABORATORY 58
  • 59. THE COMPONENTS IN THE UREA DOSING SYSTEM  This information is used along with • The components of the urea injection application specific data entered into the system consist of a urea pump, an air ECU to calculate the amount of urea regulator and a dosing manifold. Urea needed to get the maximum possible is pumped from the tank to the urea NOx reduction, under that operating dosing manifold via a 24 volt condition. accumulator pump capable of  A NOx sensor is installed in the exhaust delivering up to 157ml/min of urea. pipe at the outlet of the turbocharger. • An air regulator is used to deliver  The retrofit system ECU uses an dosing manifold. algorithm that calculates the amount of • Either the test cell or the vehicle air is urea needed based on the engine outlet used to supply this air to the regulator. NOx reading and the exhaust flow of the • The air regulator is specific to the engine. system.  The ECU then sends a signal to the Urea dosing manifold to deliver the required amount of urea to the SCR catalyst. ENGINE DEVELOPMENT LABORATORY 59
  • 60. FEV’s SCR+DPF FOR SUV ENGINE DEVELOPMENT LABORATORY 60
  • 61. EMISSION CONTROL USING CDPF+SCR ENGINE DEVELOPMENT LABORATORY 61
  • 62. DESIGN VALIDATION TECHNIQUES USING CFD  The Diesel particulate filter (DPF) is  The porous silicon carbide honeycomb, used composed of a ceramic square channel for the experiments from which data will be honeycomb with alternate channels used, has the following geometric features: plugged. The material considered for the test case is porous silicon carbide with  Cell density 200 channels/in.2 the following properties:   Wall thickness 4 mil inch Intrinsic porosity 45%   Plug length 0.07 inch Intrinsic density 3100 kg/m3   Monolith diameter 5.66 inch Permeability 5.4 × 10-13 m2   Monolith length (L) 5.66 inch Effective heat capacity 690 J/kg/K (25°C)  Effective thermal conductivity 70 W/kg/K (25°C) ENGINE DEVELOPMENT LABORATORY 62
  • 63. DESCRIPTION OF RELEVANT PARAMETERS TO BE OBSERVED • The Diesel oxidation catalyst DOC also consists of • The aim is for the above parameters to be a monolithic square channel honeycomb made of used as realistic boundary conditions for the silicon carbide, which has the coating with a application-specific models of the after- platinum catalyst. treatment devices. Specifically, within the • The DOC ( 2 Nos) has the following geometric DPF, coupling with the 3-D flow solver is characteristics: channel density 400 channels/in.2 wall thicknesses 6.5 mil inches, monolith length (L) expected to improve the predictive capability 2.5 inch, monolith diameter 5.66 inch. of the DPF regeneration model, which will in • The above properties and characteristics can be turn be assessed by observation of: translated into bulk properties (e.g. flow resistance) • a) Time response of the DPF pressure drop by analytic expressions, or are otherwise used in (flow resistance) modeling the bulk behavior of the honeycomb material regions. • b) Time response of the DPF (internal) temperatures and outflow temperature, • Hence, the focus in the current context is in the additional information, which a 3-D flow • c) Distribution of soot mass loading within solver can provide: the filter during and after the regeneration sequence. • a) Exhaust gas velocity and temperature profiles entering the DPF and DOC devices, • b) Temperature distribution within the devices due to 3-D internal heat transfer and non-axisymmetric heat losses to the exterior. ENGINE DEVELOPMENT LABORATORY 63
  • 64. SOFTWARE & BOUNDARY CONDITIONS  MODEL SETUP WITH THIRD-  OUTFLOW: PARTY SOFTWARE :  Pressure outlet: 0 gauge pressure. Exhaust  The third-party software used for the flow after the devices is vented to the automotive test case was Gambit2.0 and environment. Fluent 6.0.1  WALLS:  TURBULENCE MODEL  No-slip condition for momentum.  Heat loss at the walls of an exhaust system is  The standard k-ε model is used. The normally treated as a function of temperature regions occupied by the DPF and DOC with a heat transfer coefficient for natural monoliths are considered laminar zones and/or forced convection. (no production or dissipation of  However, the surfaces of the experimental turbulence; momentum transfer based exhaust system are wrapped with a layer of on laminar viscosity). fibrous insulation and a covering of  INFLOW: (SPECIFIED INLET aluminium foil. VELOCITY)  Therefore, a very small heat loss rate proportional to the exhaust-to-environment  25 - 35 m/s during normal (loading) and temperature contrast can be assumed. regeneration mode operation  GAS PROPERTIES:  Turbulence intensity: 10%  (Assume properties of air, variable with  Turbulence length scale: 0.005 m temperature)  Temperature: 250 – 350 °C  Exhaust gas density: equation of state for ideal gas with molecular weight 29 gr/mol. ENGINE DEVELOPMENT LABORATORY 64
  • 65. CONCLUSIONS  For meeting BS IV Norms, optimised shallow combustion chamber with optimized CRDi, Cooled 30% EGR and DOC may be the good beginning.  The next step may be addition of CDPF for PM control and engine optimization for NOx reduction.  For Euro V Norms, addition of HC DeNOx, LNT or SCR may be tried for NOx reduction.  In the case of new developments for Euro 4 compliance, the new design is recommended to be protected for high peak firing pressure capability.  Transient behaviour of engines will become decisive and most challenging with very low engine-out emissions as mandatory for Euro V/VI. ENGINE DEVELOPMENT LABORATORY 65 65
  • 66. REFERENCES  1 J. Abthoff, H. D. Schuster, C. Noller: “Concept of catalytic exhaust emission control for Europe”, SAE Paper 94047, 1994.  2 K. Pattas, Z. Samaras, N. Patsatzis, C. Michalopoulou, O. Zogou, A.Μ. Stamatelos and M. Barkis. “On-Road Experience with Trap Oxidizer Systems Installed on 5 Urban Buses”, SAE paper 900109, 1990.  3 K. Pattas., A. Stamatelos, “The Effect of Exhaust Throttling on the Diesel Engine Operation Characteristics and Thermal Loading”, SAE paper 890399, 1989.  4 J.C. Clerc, “Catalytic Diesel exhausts after-treatment”. Applied Catalysis B: Environmental 10 (1996) 99-115.  5. R.J. Farrauto, K.E. Voss, and R.M. Heck, “A Base Metal Oxide Catalyst for Reduction of Diesel Particulates”  6 Gulati, S., “Design Consideration for Diesel Flow through Converters”, SAE 920145 (1992).  7 R.Beckmann, W. Engeler, E. Mueller, B.H. Engler, J. Leyrer, E.S. Lox and K. Ostgathe, ” A new Generation of Diesel Oxidation Catalyst”, SAE 922330.  8 M.Wayatt, W.A. Manning, S.A. Roth, M.J. D’Aniello, Jr, E.S. Andresson and S.C.G. Fredholm, “ The design of Flow- Through Diesel Oxidation Catalysts”, SAE930130.  9 Makoto Horiuchi, Koichi Saito and Shoichi Ichihara, “The Effects of Flow- Through Type Oxidation Catalyst on the Particulate Reduction of 1990’s Diesel Engines”, SAE 900600.  10 Douglas J. Ball, And Robert G. Stack, “Catalyst Consideration for Diesel Converters”, SAE902110  11 Stroom, “Systems Approach to packaging Design for Automotive Catalytic Converters” SAE 900500(1990).  12 Gulati, S.T., “Design and Durability of standard and Advanced Ceramic Substrates”,  SAE Paper No2001-01-0011, 2001  13 J.Paul Day, “Substrate Effects on Light- Off_ Part II Cell Shape Contributions”, SAE 971024. ENGINE DEVELOPMENT LABORATORY 66
  • 67. REFERENCES  14. J. Paul Day and Louis S. Socha, Jr., “The Design of Automotive Catalyst Supports for Improved Pressure Drop and Conversion Efficiency”, SAE Paper 910371, 1991  15 K.P.Reddy, S.T.Gulati., Effect of contour, size and cell structure on compressive strength of porous cordierite ceramic substrates. SAE paper 932663, 1993  16. Stobbe, P., Petersen, H.G., Hoj, J.W. and Sorensen, S.C., “Sic as a Substrate for Diesel Particulate Filters”, SAE Paper No.932495.  17. Taoka, N., Ohno, K., Hong, S., Sato, H., Yoshida, Y.and Komori, T., “Effect of Sic-DPF with high Cell Density for Pressure Loss and Regeneration,”SAE Paper No.2001-01-00191.  18. Vincent, M.W and Richards, P.J., “The Long Distance Road Trial of a Combined Diesel Particulate Filter and Fuel Additive”, SAE Paper No.2000-01-2849  19. Wade, W.R; White, J.E. and Florek, J.J.; SAE Paper No.810118 (1981)  20. Suresh T Gulati,“Ceramic Solution for Diesel Exhaust Aftertreatment”, SAE paper No 962469.  21. Amann, C.A.; Stivender, D.L.; Plee, S.L.andMacDonald, J.S.; SAEPaper No.800251 (1980).  22. Weaver, C.S; SAE Paper No.840174 (1984)  23. Gulati, S.T. and Helfinstine, J.D; SAE Paper No.850010 (1985)  24 Gulati, S.T and Sherwood, D.L.; SAE Paper No.910135 (1991)  25 Murtagh, M.J.; Sherwood, D.L and Socha, L.S, Jr.; SAE Paper No.940235 (1994)  26 P. Zelenka, K. Ostgathe, E. Lox: “Reduction of Diesel Exhaust Emissions by Using Oxidation Catalysts”, SAEpaper 902111, 1990.  27 J. Howitt, M. Montierth, “Cellular Ceramic Diesel Particulate Filter”, SAE paper 810114, 1981.  28. R.J. Farrauto, K.E. Voss, “Monolithic Diesel Oxidation Catalysts”, Applied Catalysis B: Environmental 10 (1996) 29-51.162  29 J.A.A. van den Tillaart, J. Leyrer, S. Eckhoff, E.S. Lox, “Effect of Support Oxide and Noble Metal Precursor on the Activity of Automotive Diesel Catalysts”. Applied Catalysis B: Environmental 10 (1996) 53-68. ENGINE DEVELOPMENT LABORATORY 67
  • 68. REFERENCES • 30 J.P.A. Neeft, M. Makkee, J.A. Moulijn, “Catalysts for the Oxidation of Soot from Diesel Exhaust gases, an exploratory study”, Applied Catalysis B: Environmental 8 (1996) 57-78 • 31 J.P.A. Neeft, W. Schiper, M. Makkee and J.A. Moulijn, “Feasibility Study towards a Cu/K/Mo/ (Cl) soot Oxidation Catalyst for Application in Diesel Exhaust Gases”, Applied Catalysis B: Environmental 11 (1997) 365- 382 • 32 T. V. Johnson, “Diesel Emission Control in Review” SAE paper 2000-01-0184 • 33.K. Pattas, Z. Samaras, A. Roumbos, J. Lemaire, W. Mustel, P. Ruveirolles: “Regeneration of DPF at Low Temperatures with the use of a Cerium Based Fuel Additive”, SAE paper 960135, 1996. • 34. T. Seguelong, G. Blanchard, J. Michelin, F. Terres, H. Weltens, “Ceria-Based Fuel-Borne Catalysts for Series Diesel Particulate Filter Regeneration”, SAE paper, 2003-01-0378. • 35. B. Stanmore, J. F. Brihlac, P. Gilot, “The Ignition and Combustion of Cerium Doped diesel Soot”, SAE paper 1999- 01-0115. • 36. A. Gantawar, C. Opris, J. Johnson, “A Study of the Regeneration Characteristics of Silicon Carbide and Cordierite Diesel Particulate Filters Using a Copper Fuel Additive”, SAE paper 970187. • 37.D. Daly, D. McKinnon, J. Martin, D. Pavlich, “Diesel Particulate Regeneration System using a Copper Fuel Additive”, SAE paper, 930131, 1993. • 38. O. Salvat, P. Marez, G. Belot, “Passenger Car Serial Application of a Particulate Filter System on a Common Rail Direct Injection Diesel Engine”, SAE paper 2000-01-0473 • 39. K. Ohno, K. Shimato, N. Taoka, S. Hong, T. Ninomiya, T. Komori, O. Salvat, “Characterization of SiC-DPF for Passenger Car”. SAE paper 2000-01-0185. • 40. K. Nakatani, S. Hirota, S. Takeshima, K. Itoh, T. Tanaka, K. Dohmae, “Simultaneous PM and NOx Reduction System for Diesel Engines”, SAE paper 2002-01-0957. • 41. J. Gieshoff, M. Preifer, A. Schafer-Sindlinger, U. Hackbarth, O. Teysset, C. Colignon, C. Rigaudau, O. Salvat, H. Krieg, B.W. Wenclawiak, “Regeneration of Catalytic Diesel Particulate Filters”, SAE paper 2000-01-0907. ENGINE DEVELOPMENT LABORATORY 68
  • 69. 42. Gulati, S.T., “Design Consideration for Diesel Flow –Through Converters”, SAE Paper No.920145, 1992  43. W. Held, A. Koenig, A., T. Richter, L. Puppe “Catalytic NOx Reduction in Net Oxidizing Atmosphere”, SAE paper 920496, 1994.  44. N. Miyoshi, S. Matsumoto, K. Katoh, N. Takahashi, K. Yokota, M. Sugiura, K. Kasahara, “Development of New Concept Three Way Catalyst for Automotive Lean Burn Engines”, SAE paper 950809, 1995.  45. Gulati, S.T “New Developments in Diesel Oxidation Catalysts and Diesel Particulate Filters”, SAE Paper No2003-26-0017  46. B.J. Cooper, H.J. Jung, J.E. Thoss, “Treatment of Diesel Exhaust Gas”, US Patent 4,902,487, 1990  47. Y. Levendis, C. Larsen, “Use of Ozone-Enriched Air for Diesel Particulate Trap Regeneration”, SAE paper 1999-01-0114.  48 M. V. Twigg “System and Method for Purifying Exhaust Gases”. US patent 6,557,340 May 6, 2003  49 S. Thomas, et al, “Non Thermal Plasma Aftertreatment of Particulates - Theoretical Limits and Impact on Reactor Design”, SAE paper 2000-01-1926.  50. Ray Conway, Sougato Chatterjee “NOx and PM Reduction Using Combined SCR and DPF Technology in Heavy Duty Diesel Applications” SAE paper No-2005-01-3548  51 Michael K. Neylon, “Bifunctional Catalysts for the Selective Catalytic Reduction of NO by Hydrocarbons”, Proceedings of 9th Diesel Emissions Reduction Conference Newport, RI, August 24-28, 2003  52. Parks, J.E, G.J. Wangner, “ NOx Sorbate Catalyst System with Sulfur Catalyst Protection for Aftertreatment of No.2 Diesel Exhaust”, SAE Paper 1999-01-3557,1999”  53. Luders, H., P. Stommel and S. Geckler, “ Diesel Exhaust Aftertreatment –New Approaches to Ultra Low Emission Diesel Vehicles”, SAE Paper 1999-01-0108,1999  54 B.H.Engler, D.Lindner,”Reduction of Exhaust Gas Emissions by Using Hydrocarbon Adsorber Systems”, SAE Paper 930738(1993)  55.M.Guyon, P.Blanche “ NOx- Trap Development and Characterization for Diesel Engines Emission Control”, SAE paper No: 2000-01-2910.  56. http://www.un.org/esa/gite/iandm/senguptapresentation.pdf  57. http://static.teriin.org/urban/urban.htm ENGINE DEVELOPMENT LABORATORY 69

Notas do Editor

  1. Increasingly, governments beyond the US, Europe and Japan, are recognizing the importance of cleaner air. For example, Brazil, India, China and South Korea all have plans to further tighten emissions regulations through 2012. Many other countries are evaluating making these moves as well.
  2. As I mentioned, diesel emissions offer new challenges, particulate matter, or PM, and oxides of nitrogen, or NOx. (CLICK) Both can be dealt with independently but the unique chemistry of diesel exhaust make it a particularly difficult challenge to provide clean diesels. So let ’ s talk about what technology is available to allow us to address this global issue and meet the regulations. The most effective and feasible technology for reducing PM emissions is the diesel particulate filter.
  3. Diesel particulate filters clean by having the gas pass through the ceramic wall. Every other channel is plugged at the entrance to the filter. At the exit end, the open channels are unplugged. This product design yields the characteristic “ checkerboard ” pattern shown on the slide ’ s left side. How does the filter actually work? As particulate matter, more commonly called soot, enters the filter, it gets trapped in the channel. Soot accumulates and burns off with normal driving conditions or when conditions require assistance. The diesel systems will automatically burn off the balance. Optimization of product design becomes more critical with a catalyst that does not impact the overall performance of the filter. The challenge for filters is significant, made even more so by the expectation of delivering this performance for the expected life of light-duty vehicles and up to 435,000 miles for heavy-duty vehicles. (You may need to click twice to advance. The first click will stop the video. The second will advance.)
  4. 当社は、ベータ型炭化珪素結晶体の生成に成功して以来、炭化珪素に関する固有技術の蓄積と、緻密体、多孔体のアプリケーション開発に注力してまいりました。 1988 年以降、炭化珪素素材での DPF 開発に着手し、レトロフィット市場、建機市場でのご評価をいただきながら、 DPF 固有技術の蓄積、耐久性の向上など 開発を進めて参りました。クリーンディーゼルエンジンの開発を行っていた欧州自動車会社の目に留まり、ディーゼル乗用車へ当社の DPF が世界で初めて搭載されました。 遠くでは、メキシコのコカコーラの配達のトラックに使用されている。らしい。 お客さまのご要望に沿う、 DPF の開発を行い、世界のすべての自動車グループさまにご採用頂いております。お客さまの需要にお答えすべく、 日本始め、フランス、ハンガリーに生産ラインを立上げ、現在、17ラインの生産ラインを保有いたしております。 2004 年からは 2 ヶ月に一本のペースでラインを立ち上げて参りました。 始めに量産化したお客が燃料添加材システム方式であったために、まずはその方向で進み、現在は触媒化システムの方向でも生産が可能
  5. 当社は、 SiC - DPF の最大の特徴である、堅牢性を生かしたセル、気孔構造の SD991 を添加剤システムへ、 SD021 を触媒化システム向けの DPF として設計いたしました。 更に高性能エンジンの出力維持を実現できる、低圧損フィルター SD031 を設計致しました。 現在では、 Euro5 世代以降の小型化、高性能化を図った、薄壁、 OS セル構造を持つ製品の開発を行っております。
  6. SiC-DPF の特徴を簡単にご紹介申し上げます。当社の SiC-DPF は、ユニットと呼ばれる、 34mm 角の柱体を複数本組上げてフィルターを作成いたしております。 SiC-DPF は、その素材の高い性能から、 DPF として必要な、耐熱性や、耐化学薬品性、均一気孔による低圧損、高捕集効率を備えております。一方他の素材と比較して熱膨張係数は大きいですが、分割構造をとる事で、解決いたしております。 自身の発する熱で自分が壊れるのを防ぐために、低ヤング率の接着剤を使用して、それを防いでいる。
  7. こちらの図は、ススの捕集量と気体流速に対するフィルターの破損状況を示しております。従来の触媒担体保持材のコージェライトに対して、 3 倍のスス量をためることができます。又過捕集状態で燃焼した場合でも、 SiCDPF はクラックが発生するだけで、溶損することはありません。この事から、再生回数の低減など、 C02 低減に寄与できる物と考えております。 溶損は発生せず、
  8. SiC は耐化学薬品性に優れております。排ガスに含まれるそれぞれの材料に対して高い安定性を有していることが判ります。
  9. In stoichiometric gasoline applications NOx is treated to 98+% efficiency in modern automobiles. This is possible because one pollutant can be reacted against another in an oxygen-deprived atmosphere, as in: CO + NOx = N2 + CO2 In lean applications like diesel, the NOx reduction is much more difficult, because the reducing pollutant, CO or HC, prefers to react with oxygen, leaving none left for NOx reduction. The industry has been searching for decades for a selective catalyst that will selectively reduce NOx with carbon-based reductants in an oxygen-rich gas. Success has been limited. The leading selective catalyst works well using ammonia as the reductant. NH3 + NOx = N2 + H2O However, ammonia has to be provided from an external source, the most common of which is urea. As such, Europe, Japan, the US, and now India are establishing urea infrastructures to facilitate the SCR systems on trucks, allowing removal of NOx from lean exhaust up to 90%.