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IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE)
e-ISSN: 2278-1684 Volume 5, Issue 5 (Mar. - Apr. 2013), PP 01-08
www.iosrjournals.org

     “Effect Of Polluted Surface Water On Groundwater: A Case
                       Study Of Budha Nullah”
             Gursimran Singh1 , Dapinder Deep Singh2, Prof. S.K.Sharma3
   1, 2
     ME Student, Department of Environmental Engineering, PEC University of Technology, Chandigarh. 3
 Associate Professor, Department of Environmental Engineering, PEC University of Technology, Chandigarh

Abstract: Groundwater is one of the most important natural resources. It is a major source of fresh drinking
water in both the rural and urban regions. The groundwater quality, however in recent time has got
deteriorated due to the percolation of polluted water in to the soils from the wastewater drains, polluted rivers
and ponds. As a result its quality has not remained potable in many parts of the country. Contaminated
groundwater of Mettupalayam Taluk in Tamil Nadu, Amravati River Basin of Karur District, Tamil Nadu,
Eastern Uttar Pradesh are some of the example. Therefore, the evaluation of water quality of the rivers,
groundwater and impact of polluted groundwater on environment and health has drawn attention of the
researchers. The present thesis is also an attempt on such study. The pollution level of Budha Nullah water and
its effect on groundwater and vicinity area have been studied in the present paper. Total eleven groundwater
samples, seven Budha Nullah samples and five soil samples were collected from different locations within 6 km
stretch of Budha Nullah and its adjoining areas. The samples of the different points were collected from
handpumps and tubewells, the water from which is used for drinking and other purposes.
          All the quality parameters of these samples were analyzed using standard methods prescribed in
“Standard methods for examination of water and wastewater” (18 TH edition). It was observed that pH of all the
collected samples was within permissible limit of 6.5-8.5. The surface water analysis of Budha Nullah reveals
high values of Total Dissolved solids up to 1642 mg/L, chlorides up to 400 mg/L, Chemical Oxygen Demand
values up to 448mg/L, Biochemical Oxygen Demand varying between 52-195 mg/L, Most Potable Number
varying from 240+ upto 2400+ per 100ml, heavy metal like Cr in the Budha Nullah has value 0.031 mg/L, Fe
0.913 mg/L, Mn 0.043 mg/L and Ni 0.222 mg/L. The quality of ground water at many places was found to be
unfit for drinking mainly due to high amount of total dissolved solids and most potable number being much
higher than the prescribed limit as per ISO 10500 standards. SAR of soil ranges from 3.78 to 6.98 mg/kg, which
is optimum value for soil, as soils with SAR value less than 10 are considered good for leaching and water
percolation. The reason behind the presence of other form of impurities and heavy metals in the ground water
could be due to presence of heavy metals in surface water of Budha Nullah and its seepage in the adjacent
groundwater aquifers.

Objectives Of Study:
         The rapid industrialization in Ludhiana, though contributed to economic development, has resulted in
heavy losses to economic welfare in terms of effects on agricultural activities, human health and ecosystem at
large through air and water pollution. Solid and liquid wastes emanating from the industrial activities are the
inevitable by-products of manufacturing process. These wastes contain toxic chemicals such as Chromium salts,
sulfides and other substances including heavy toxic trace metals. These materials enter the surface water and
subsurface aquifers resulting in water pollution. The town which earned the name of Manchester of Punjab
landed into dubious distinction of being one of the most polluted human settlements in the country (G.S Gill et
al.,1997). Similarly industries located in Mettupalayam taluk, Tamilnadu dispose their effluents on land, and the
farmers of the adjacent farmlands have complained that their shallow open wells get polluted and also the salt
content of soil has started building up slowly. Study found that continuous disposal of industrial effluents on
land, which has limited capacity to assimilate the pollution load, has led to groundwater pollution (Mukherjee at
el., 2006).
         In this dissertation an attempt has been made to study the water quality of the Budha Nullah and
groundwater. Grab sampling was done from the different locations through the 12 km stretch of Budha Nullah
in the Ludhiana city .

The Main Objectives Of The Study Are :
    1) To analyze the physico-chemical parameters, biological parameters.
    2) To examine Heavy metal in the surface and groundwater samples.
    3) To examine heavy metals in the soil samples


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“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”

Significance Of The Study:
         Water is an absolute necessity for life. Water bodies may host harmful biological and chemical agents
that impact the health of the humans. There exist a strong correlation between waterborne biological agents and
human disease. In my study, various physico-chemical, biological and heavy metal analysis studies are done to
check the groundwater and surface quality and analysis of heavy metals in soils is done. For effective protection,
setting of abatement strategy and successive revitalization of ecosystems it is necessary to know the ecological
quality of surface and groundwater. Protecting of water resources is of paramount importance thus assessing the
water quality after regular intervals is necessary for the decision makers to take remedial actions and to solve the
problem well in time.

                                               I.    Introduction
           Groundwater is one of the prime sources of fresh water. It is an important source of drinking water for
the world’s population. In 21st century our natural water resources have been used unconsciously which leads to
it’s over exploitation. Water pollution is increasing steadily due to rapid population growth, industrial
proliferations, urbanizations, increasing living standards and wide spheres of human activities.
           Ground water contamination is generally irreversible i.e. once it is contaminated; it is difficult to
restore the original water quality of the aquifer. Excessive mineralization of groundwater degrades its quality
and produces an objectionable taste, odour and excessive hardness. Although the soil mantle through which
water passes acts as an adsorbent retaining a large part of colloidal and soluble ions with its cation exchange
capacity, but ground water is not completely free from the menace of chronic pollution. Therefore, it is always
better to protect ground water in the first place rather than relying on technology to clean up contaminated water
at a later stage.
India is developing country which means infrastructure sector is growing on at a much higher rate, leads to the
development of core industries like metals, chemicals, fertilizers, drugs and petroleum etc and other industries
such as plastics, pesticides, detergents, solvents, paints, dyes, and food disposed their effluents and emissions on
land and water bodies and polluting our environment. The disposal of solid and liquid wastes containing heavy
metals like lead, nickel, chromium, molybdenum, and mercury in to the ecosystem, leads to heavy metal
contamination of our natural habitat (i.e. soil, water and air ecosystems).

Budha Nullah:
         It runs parallel to Sutlej, on its south for fairly large section of its course in the district and ultimately
joins Sutlej at Gorsian Kadar Baksh in the north western corner of the district. Ludhiana and Machhiwara are
situated to the south of the Budha Nullah. The water of the stream becomes polluted after it enters Ludhiana
City. With the industrialization/ urbanization of the area, Budha Nullah has become the sullage/ sewage as well
as industrial effluent carrier for the Ludhiana city leading to River Sutlej.

                                        II.    Materials And Method
Location of sampling source:
Water samples were collected from Budha Nullah and its vicinity in Ludhiana. For the purpose of water
collection site has been divided into two parts.
     1) Budha Nullah
     2) Vicinity area of Budha Nullah (within 500m perpendicular distance)
     3) Area away from Budha Nullah ( > 500m perpendicular distance from) Budha Nullah

   TABLE: Site details of water quality sampling stations of 6 km stretch from starting point of Budha
                                                Nullah
           Sample no.    Source           Location                                         Distance from
                                                                                           Budha nullah
                                                                                           (m) approx.
           1             Tubewell         Opp treatment plant, Jamalpur                    10-20
           2             Budha Nullah     Tajpur road (Near Gurjit Public School)          -
           3             Handpump         Tajpur Bhonian link road                         50-60
           4             Budha Nullah     Mohar Singh Nagar                                -
           5             Tubewell         Residential area, 3 no gali, Mohar Singh Nagar   30-40
           6             Budha Nullah     48 MLD STP, Jamalpur                             -
           7             Tubewell         STP, Jamalpur                                    10-20
           8             Budha Nullah     Near Chand Cinema, Tajpur road.                  -
           9             Budha Nullah     Near Old Sabji Mandi, Tajpur Road                -
           10            Tubewell         Near Old Sabji Mandi, Tajpur Road                15-25

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“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”

          11            Budha Nullah   gaushala road                           -
          12            Budha Nullah   near mehak telecom, gaushala road       -
          13            Tubewell       near mehak telecom, gaushala road       40-50
          14            Handpump       Near cremation ground, gaushala road    400-450
          15            Tubewell       Near rahon road                         400-450
          16            Tubewell       jain nagar                              200-250
          17            Handpump       jain nagar                              250-300
          18            Tubewell       near chand cinema, clock tower road     900-1000
          19            Tubewell       Residential Area, Upkaar Nagar.        20-30
          20            Budha Nullah   Near Sanatan Vidya Mandir.             -
          21            Tubewell       Near Sanatan Vidya Mandir.             40-50
          22            Tubewell       Residential Area,Joshi Nagar.          30-40
          23            Tubewell       Residential Area,Joshi Nagar.          20-30
          24            Hand pump      Near Haibowal Khurd Road.              30-40
          25            Budha Nullah   Near joshi Nagar                       -
          26            Tubewell       Near Lord Mahavir Hospital,Haibowal.   40-50
          27            Tubewell       Haibowal.                              20-30
          28            Budha Nullah   Near Haibowal.                         -
          29            Tubewell       Haibowal .                             20-30
          30            Hand pump      Village Churpur.                       40-50
          31            Tubewell       Kulbir Singh Dairy,                    50-60
                                       Village Churpur.
          32            Budha Nullah   Near 152 MLD STP, Balloke.             -
          33            Tubewell       152 MLD STP, Balloke.                  450-500
          34            Tubewell       Green Avenue,Churpur.                  600-700
          35            Budha Nullah   Near Village, Churpur.                 -

Site Locations on Map




                                                 Figure 3.1




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“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”




Pollution Parameters Analyzed
Various impurities present in water are expressed through pollution parameters. These are broadly classified into
three categories namely:
1) Physico-chemical parameters:
The parameters analyzed in this study were pH, color, Total hardness as CaCO 3, chlorides, Total Dissolved
Solids, Alkalinity and Chemical Oxygen Demand (COD).
2) Biological parameters:
 The biological parameters analyzed in present study included Biochemical Oxygen Demand (BOD) and Most
Probable Number (MPN).
3) Heavy metal testing:
The heavy metals analyzed were Arsenic, Boron, Calcium, Cadmium, Chromium, Copper, Iron, Lead,
Potassium, Magnesium, Manganese, Phosphorous, Sulphur Sodium, Nickel and Zinc.

                            Analytical methods and equipments used in the study
   S. No      Parameter                            Method                              Instrument/Equip-ment
   1         pH                                    Electrometric                        pH meter
   2         color                                 Electrometric (Pt-Co scale)         DR 2800 HACH
   3         Total hardness as CaCO3               EDTA titrimetry method              Titrimetry
   4         Chlorides                             Argentometric method                Titrimetry
   5         Total Dissolved Solids                Gravimetry method                   Oven
   6         Alkalinity                            Potentiometric titration            Titrimetry
   7         Chemical Oxygen Demand                Digestion followed by titration     COD digestor
   8         Biochemical Oxygen Demand             5 days incubation followed by       BOD incubator
                                                   titration
   9         Most Probable Number                  Coliform MPN                        Bacteriological
                                                                                       Incubator, autoclave,
                                                                                       laminar flow
   10        Arsenic, Boron, Calcium, Cadmium,     Inductively Coupled Plasma method   ICAP-AES
             Chromium, Copper, Iron, Potassium,
             Magnesium, Manganese, Sodium,
             Nickel, Zinc
   Where
   ICAP-AES = Inductively Coupled Argon Plasma – Atomic Emission Spectrometry




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“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”

                                    Table showing results of water samples
  S.No.   PARAMETERS                IS10500:1991 COMPARISION RESULT
                                    DESIRABLE
                                    LIMIT
  1       pH                        6.5 – 8.5       All samples are within range
  2       Chlorides                 250 mg/L        Sample 2, 4, 6 ,8, 9, 11, 12, 17, 18, 20, 25, 28,32 and 35
                                                    have chloride content greater than desirable limit
  3       Alkalinity                200 mg/L        All the samples have value lower than desirable limit
  4       Biochemical Oxygen        0 mg/L          BOD is present in all the samples
          Demand (BOD)
  5       Chemical Oxygen           0 mg/L             COD is present in all the samples
          Demand (COD
  6       Total dissolved solids    500 mg/L           Sample 3, 4, 6, 7, 8, 11, 12, 17, 20,25,28,32 and 35
                                                       have TDS greater than desirable limit
  7       MPN                       10 per 100ml       All the samples haveMPN values greater than desirable
                                                       limit
  8       Arsenic                   0.05 mg/L          All samples have value lower than desirable limit
  9       Boron                     1 mg/L             All samples have value lower than desirable limit
  10      Calcium                   75 mg/L            All samples have value lower than desirable limit
  11      Cadmium                   0.01 mg/L          All samples have value lower than desirable limit
  12      Cobalt
  13      Chromium                  0.05 mg/L          Sample 25, 26, 30, 33 and 34 have value greater than
                                                       desirable limit
  14      Copper                    0.05 mg/L          Sample 4, 21, 24, 29 and 30 have value greater than
                                                       desirable limit
  15      Iron                      0.30 mg/L          Sample 4, 7, 8 ,9, 11, 12, 17, 20, 25, 28, 32 and 35 have
                                                       value greater than desirable limit
  16      Potassium
  17      Magnesium                 30 mg/L            All samples have value lower than desirable limit
  18      Manganese                 0.1mg/L            Sample 3 and 26 have value greater than desirable limit
  19      Sodium
  20      Nickel                    0.02 mg/L          Sample 11, 17, 23, 25, 32 and 35 have value greater
                                                       than desirable limit
  21      Phosphorous
  22      Lead                      0.05 mg/L          All samples have value lower than desirable limit
  23      Sulphur
  24      Zinc                      5mg/L              All samples have value lower than desirable limit

SOIL QUALITY ANALYSIS: Materials and methodology
Location of sampling source:
Soil samples were collected from vicinity of Budha Nullah in Ludhiana. For the purpose of water collection site
has been divided into two parts.
     1) Vicinity area of Budha Nullah (within 500m perpendicular distance)
     2) Area away from Budha Nullah ( > 500m perpendicular distance from) Budha Nullah

                                 TABLE: Site details of soil sampling stations
                    Sample no.     Location                               Distance from
                                                                          Budha Nullah (m)
                                                                          approx.
                    1              Opp treatment plant, Jamalpur          500-550
                    2              Near Old SabjiMandi                    5-10
                    3              Gaushala Road                          40-50
                    4              Rahon Road                             100-150
                    5              Jain Nagar                             600-650
                    6              Upkaar nagar                           30-40
                    7              Joshi nagar                            40-50
                    8              Haibowal                               40-50
                    9              Green Avenue, Churpur                  600-700
                    10             Near 152 MLD STP, Balloke              50-60

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“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”

Site location on map




                                                  Figure




                                       Table: Results of soil samples
                 S.No.   PARAMETERS                 RANGE OF METALS PRESENT IN ALL
                                                    SAMPLES (mg/L)
                 1       Arsenic                    Lies between 0.007-0.014
                 2       Boron                      Lies between 0.088-0.179
                 3       Calcium                    Lies between 298.2-508.4
                 4       Cadmium                    Lies between 0.004-0.144
                 5       Chromium                   Lies between 0.005-0.021
                 6       Copper                     Lies between 0.358-11.484
                 7       Iron                       Lies between 2.447-6.584
                 8       Potassium                  Lies between 10.46-28.32
                 9       Magnesium                  Lies between 47.2-108.9
                 10      Manganese                  Lies between 2.72-5.24
                 11      Nickel                     Lies between 0.014-8.746
                 12      Phosphorous                Lies between 0.043-1.541
                 13      Lead                       Lies between 0.354-3.864
                 14      Sulphur                    Lies between 8.43-89.14
                 15      Zinc                       Lies between 0.583-36.02
                 16      Sodium                     Lies between 49.4-156.4



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“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”

                                     SAR VALUES OF SOIL SAMPLES
                                     SOIL SAMPLE           SAR VALUE

                                     1.                    6.98
                                     2.                    3.78
                                     3.                    6.03
                                     4.                    5.26
                                     5.                    5.12
                                     6                     7.12
                                     7.                    3.35
                                     8.                    9.57
                                     9.                    9.22
                                     10.                   4.54

                             III.    Conclusions And Recommendations
Conclusion:
1) The quality of the surface water at different stretches of Budha Nullah has been impaired as the stream
   progresses through the city. Untreated waste from the industries and human settlements are found to be the
   major cause for deterioration in the water quality in Ludhiana. The surface water analysis of Budha Nullah
   reveals high values of Total Dissolved solids up to 1642 mg/L, chlorides up to 400 mg/L, Chemical Oxygen
   Demand values up to 448mg/L, Biochemical Oxygen Demand varying between 52-195 mg/L, Most Potable
   Number varying from 240+ upto 2400+ per 100ml, heavy metal like Cr in the Budha Nullah has value
   0.084 mg/L, Fe 0.913 mg/L, Mn 0.095 mg/L and Ni 0.222 mg/L. As per the water quality criteria given by
   Central Pollution Control Board (CPCB), the water quality of Budha Nullah comes under E class of water
   which is not suitable for drinking, outdoor bathing, propagation of wildlife and fisheries, irrigation and
   industrial cooling.
2) Most of the Heavy metals were within permissible limit except iron which was found to be more than
   permissible limit in samples of the Budha Nullah as well as groundwater
3) The quality of ground water at many places was found to be unfit for drinking mainly due to high amount of
   total dissolved solids and most potable number being much higher than the prescribed limit under CPCB.
4) Heavy metals were found in samples of groundwater in the vicinity of Budha Nullah and their concentration
   decreases as we move away from the Budha Nullah. So it can be concluded that presence of heavy metals in
   groundwater is due to seepage of surface water of Budha Nullah into the aquifer.
5) BOD values of groundwater was also high ranging from 2 to 12 due to which it falls under category E i.e. it
   is unfit for human consumption but can be used for irrigational purposes.
6) pH parameter analyzed in ground water samples as well as Budha Nullah were within the range of IS:10500
   Drinking Water Standards between 6.5-8.5.
7) Amount of calcium in soil ranges from 298.2 to 508.4 mg/kg, sulphur from 8.43 to 89.14 mg/kg, nickel
   ranges from 0.076 to as high as 8.746 mg/kg.
8) SAR of soil ranges from 3.35 to 9.57 mg/kg, which is optimum value for soil, as soils with SAR value less
   than 10 are considered good for leaching and water percolation.

Overall Comment On Water Quality Assessment
         Surface water of Ludhiana is highly contaminated by the effluents released by the industries and
sewage which is added by the human settlements. This is the main reason for the heavy metals contamination
and presence of microbes in the surface water.
         Surface water of Budha Nullah is highly colored, the main reason for this is the colored effluents that
are released particularly by the textile industries.
         Dumping of the garbage into the water also obstructs the flow of this Nullah due to which at many
places the water is Stagnant which hinders the self –purification mechanism of water and is one of the major
factors for the occurrence of diseases like malaria, jaundice, cholera, diarrhea and gastroenteritis. Callousness
approach of the people in the city has rendered the surface water of Budha Nullah to come under E class of
water, which cannot be used for drinking, outdoor bathing, propagation of wildlife and fisheries, irrigation and
industrial cooling.
Heavy metal analysis of all the ground water samples is within the desirable limit.
MPN values are high in the ground water, which indicates microbial contamination of water.

Recommendations For Water Quality Assessment
Regular monitoring of the water should be done.
                                             www.iosrjournals.org                                        7 | Page
“Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah”

The results of the analysis of water should be published for the purpose of record and benefit of public.
Strict laws should be imposed on the industries which release their effluents directly into the water.
Regular monitoring of small scale industries which are also a major contributor for polluting the surface water
and ultimately contaminates the ground water.
Educating the people about the various problems specially the labour class that works in industries will also help
to clean the environment as the best way to manage the environment, is to manage ourselves.

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A0550108

  • 1. IOSR Journal of Mechanical and Civil Engineering (IOSR-JMCE) e-ISSN: 2278-1684 Volume 5, Issue 5 (Mar. - Apr. 2013), PP 01-08 www.iosrjournals.org “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” Gursimran Singh1 , Dapinder Deep Singh2, Prof. S.K.Sharma3 1, 2 ME Student, Department of Environmental Engineering, PEC University of Technology, Chandigarh. 3 Associate Professor, Department of Environmental Engineering, PEC University of Technology, Chandigarh Abstract: Groundwater is one of the most important natural resources. It is a major source of fresh drinking water in both the rural and urban regions. The groundwater quality, however in recent time has got deteriorated due to the percolation of polluted water in to the soils from the wastewater drains, polluted rivers and ponds. As a result its quality has not remained potable in many parts of the country. Contaminated groundwater of Mettupalayam Taluk in Tamil Nadu, Amravati River Basin of Karur District, Tamil Nadu, Eastern Uttar Pradesh are some of the example. Therefore, the evaluation of water quality of the rivers, groundwater and impact of polluted groundwater on environment and health has drawn attention of the researchers. The present thesis is also an attempt on such study. The pollution level of Budha Nullah water and its effect on groundwater and vicinity area have been studied in the present paper. Total eleven groundwater samples, seven Budha Nullah samples and five soil samples were collected from different locations within 6 km stretch of Budha Nullah and its adjoining areas. The samples of the different points were collected from handpumps and tubewells, the water from which is used for drinking and other purposes. All the quality parameters of these samples were analyzed using standard methods prescribed in “Standard methods for examination of water and wastewater” (18 TH edition). It was observed that pH of all the collected samples was within permissible limit of 6.5-8.5. The surface water analysis of Budha Nullah reveals high values of Total Dissolved solids up to 1642 mg/L, chlorides up to 400 mg/L, Chemical Oxygen Demand values up to 448mg/L, Biochemical Oxygen Demand varying between 52-195 mg/L, Most Potable Number varying from 240+ upto 2400+ per 100ml, heavy metal like Cr in the Budha Nullah has value 0.031 mg/L, Fe 0.913 mg/L, Mn 0.043 mg/L and Ni 0.222 mg/L. The quality of ground water at many places was found to be unfit for drinking mainly due to high amount of total dissolved solids and most potable number being much higher than the prescribed limit as per ISO 10500 standards. SAR of soil ranges from 3.78 to 6.98 mg/kg, which is optimum value for soil, as soils with SAR value less than 10 are considered good for leaching and water percolation. The reason behind the presence of other form of impurities and heavy metals in the ground water could be due to presence of heavy metals in surface water of Budha Nullah and its seepage in the adjacent groundwater aquifers. Objectives Of Study: The rapid industrialization in Ludhiana, though contributed to economic development, has resulted in heavy losses to economic welfare in terms of effects on agricultural activities, human health and ecosystem at large through air and water pollution. Solid and liquid wastes emanating from the industrial activities are the inevitable by-products of manufacturing process. These wastes contain toxic chemicals such as Chromium salts, sulfides and other substances including heavy toxic trace metals. These materials enter the surface water and subsurface aquifers resulting in water pollution. The town which earned the name of Manchester of Punjab landed into dubious distinction of being one of the most polluted human settlements in the country (G.S Gill et al.,1997). Similarly industries located in Mettupalayam taluk, Tamilnadu dispose their effluents on land, and the farmers of the adjacent farmlands have complained that their shallow open wells get polluted and also the salt content of soil has started building up slowly. Study found that continuous disposal of industrial effluents on land, which has limited capacity to assimilate the pollution load, has led to groundwater pollution (Mukherjee at el., 2006). In this dissertation an attempt has been made to study the water quality of the Budha Nullah and groundwater. Grab sampling was done from the different locations through the 12 km stretch of Budha Nullah in the Ludhiana city . The Main Objectives Of The Study Are : 1) To analyze the physico-chemical parameters, biological parameters. 2) To examine Heavy metal in the surface and groundwater samples. 3) To examine heavy metals in the soil samples www.iosrjournals.org 1 | Page
  • 2. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” Significance Of The Study: Water is an absolute necessity for life. Water bodies may host harmful biological and chemical agents that impact the health of the humans. There exist a strong correlation between waterborne biological agents and human disease. In my study, various physico-chemical, biological and heavy metal analysis studies are done to check the groundwater and surface quality and analysis of heavy metals in soils is done. For effective protection, setting of abatement strategy and successive revitalization of ecosystems it is necessary to know the ecological quality of surface and groundwater. Protecting of water resources is of paramount importance thus assessing the water quality after regular intervals is necessary for the decision makers to take remedial actions and to solve the problem well in time. I. Introduction Groundwater is one of the prime sources of fresh water. It is an important source of drinking water for the world’s population. In 21st century our natural water resources have been used unconsciously which leads to it’s over exploitation. Water pollution is increasing steadily due to rapid population growth, industrial proliferations, urbanizations, increasing living standards and wide spheres of human activities. Ground water contamination is generally irreversible i.e. once it is contaminated; it is difficult to restore the original water quality of the aquifer. Excessive mineralization of groundwater degrades its quality and produces an objectionable taste, odour and excessive hardness. Although the soil mantle through which water passes acts as an adsorbent retaining a large part of colloidal and soluble ions with its cation exchange capacity, but ground water is not completely free from the menace of chronic pollution. Therefore, it is always better to protect ground water in the first place rather than relying on technology to clean up contaminated water at a later stage. India is developing country which means infrastructure sector is growing on at a much higher rate, leads to the development of core industries like metals, chemicals, fertilizers, drugs and petroleum etc and other industries such as plastics, pesticides, detergents, solvents, paints, dyes, and food disposed their effluents and emissions on land and water bodies and polluting our environment. The disposal of solid and liquid wastes containing heavy metals like lead, nickel, chromium, molybdenum, and mercury in to the ecosystem, leads to heavy metal contamination of our natural habitat (i.e. soil, water and air ecosystems). Budha Nullah: It runs parallel to Sutlej, on its south for fairly large section of its course in the district and ultimately joins Sutlej at Gorsian Kadar Baksh in the north western corner of the district. Ludhiana and Machhiwara are situated to the south of the Budha Nullah. The water of the stream becomes polluted after it enters Ludhiana City. With the industrialization/ urbanization of the area, Budha Nullah has become the sullage/ sewage as well as industrial effluent carrier for the Ludhiana city leading to River Sutlej. II. Materials And Method Location of sampling source: Water samples were collected from Budha Nullah and its vicinity in Ludhiana. For the purpose of water collection site has been divided into two parts. 1) Budha Nullah 2) Vicinity area of Budha Nullah (within 500m perpendicular distance) 3) Area away from Budha Nullah ( > 500m perpendicular distance from) Budha Nullah TABLE: Site details of water quality sampling stations of 6 km stretch from starting point of Budha Nullah Sample no. Source Location Distance from Budha nullah (m) approx. 1 Tubewell Opp treatment plant, Jamalpur 10-20 2 Budha Nullah Tajpur road (Near Gurjit Public School) - 3 Handpump Tajpur Bhonian link road 50-60 4 Budha Nullah Mohar Singh Nagar - 5 Tubewell Residential area, 3 no gali, Mohar Singh Nagar 30-40 6 Budha Nullah 48 MLD STP, Jamalpur - 7 Tubewell STP, Jamalpur 10-20 8 Budha Nullah Near Chand Cinema, Tajpur road. - 9 Budha Nullah Near Old Sabji Mandi, Tajpur Road - 10 Tubewell Near Old Sabji Mandi, Tajpur Road 15-25 www.iosrjournals.org 2 | Page
  • 3. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” 11 Budha Nullah gaushala road - 12 Budha Nullah near mehak telecom, gaushala road - 13 Tubewell near mehak telecom, gaushala road 40-50 14 Handpump Near cremation ground, gaushala road 400-450 15 Tubewell Near rahon road 400-450 16 Tubewell jain nagar 200-250 17 Handpump jain nagar 250-300 18 Tubewell near chand cinema, clock tower road 900-1000 19 Tubewell Residential Area, Upkaar Nagar. 20-30 20 Budha Nullah Near Sanatan Vidya Mandir. - 21 Tubewell Near Sanatan Vidya Mandir. 40-50 22 Tubewell Residential Area,Joshi Nagar. 30-40 23 Tubewell Residential Area,Joshi Nagar. 20-30 24 Hand pump Near Haibowal Khurd Road. 30-40 25 Budha Nullah Near joshi Nagar - 26 Tubewell Near Lord Mahavir Hospital,Haibowal. 40-50 27 Tubewell Haibowal. 20-30 28 Budha Nullah Near Haibowal. - 29 Tubewell Haibowal . 20-30 30 Hand pump Village Churpur. 40-50 31 Tubewell Kulbir Singh Dairy, 50-60 Village Churpur. 32 Budha Nullah Near 152 MLD STP, Balloke. - 33 Tubewell 152 MLD STP, Balloke. 450-500 34 Tubewell Green Avenue,Churpur. 600-700 35 Budha Nullah Near Village, Churpur. - Site Locations on Map Figure 3.1 www.iosrjournals.org 3 | Page
  • 4. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” Pollution Parameters Analyzed Various impurities present in water are expressed through pollution parameters. These are broadly classified into three categories namely: 1) Physico-chemical parameters: The parameters analyzed in this study were pH, color, Total hardness as CaCO 3, chlorides, Total Dissolved Solids, Alkalinity and Chemical Oxygen Demand (COD). 2) Biological parameters: The biological parameters analyzed in present study included Biochemical Oxygen Demand (BOD) and Most Probable Number (MPN). 3) Heavy metal testing: The heavy metals analyzed were Arsenic, Boron, Calcium, Cadmium, Chromium, Copper, Iron, Lead, Potassium, Magnesium, Manganese, Phosphorous, Sulphur Sodium, Nickel and Zinc. Analytical methods and equipments used in the study S. No Parameter Method Instrument/Equip-ment 1 pH Electrometric pH meter 2 color Electrometric (Pt-Co scale) DR 2800 HACH 3 Total hardness as CaCO3 EDTA titrimetry method Titrimetry 4 Chlorides Argentometric method Titrimetry 5 Total Dissolved Solids Gravimetry method Oven 6 Alkalinity Potentiometric titration Titrimetry 7 Chemical Oxygen Demand Digestion followed by titration COD digestor 8 Biochemical Oxygen Demand 5 days incubation followed by BOD incubator titration 9 Most Probable Number Coliform MPN Bacteriological Incubator, autoclave, laminar flow 10 Arsenic, Boron, Calcium, Cadmium, Inductively Coupled Plasma method ICAP-AES Chromium, Copper, Iron, Potassium, Magnesium, Manganese, Sodium, Nickel, Zinc Where ICAP-AES = Inductively Coupled Argon Plasma – Atomic Emission Spectrometry www.iosrjournals.org 4 | Page
  • 5. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” Table showing results of water samples S.No. PARAMETERS IS10500:1991 COMPARISION RESULT DESIRABLE LIMIT 1 pH 6.5 – 8.5 All samples are within range 2 Chlorides 250 mg/L Sample 2, 4, 6 ,8, 9, 11, 12, 17, 18, 20, 25, 28,32 and 35 have chloride content greater than desirable limit 3 Alkalinity 200 mg/L All the samples have value lower than desirable limit 4 Biochemical Oxygen 0 mg/L BOD is present in all the samples Demand (BOD) 5 Chemical Oxygen 0 mg/L COD is present in all the samples Demand (COD 6 Total dissolved solids 500 mg/L Sample 3, 4, 6, 7, 8, 11, 12, 17, 20,25,28,32 and 35 have TDS greater than desirable limit 7 MPN 10 per 100ml All the samples haveMPN values greater than desirable limit 8 Arsenic 0.05 mg/L All samples have value lower than desirable limit 9 Boron 1 mg/L All samples have value lower than desirable limit 10 Calcium 75 mg/L All samples have value lower than desirable limit 11 Cadmium 0.01 mg/L All samples have value lower than desirable limit 12 Cobalt 13 Chromium 0.05 mg/L Sample 25, 26, 30, 33 and 34 have value greater than desirable limit 14 Copper 0.05 mg/L Sample 4, 21, 24, 29 and 30 have value greater than desirable limit 15 Iron 0.30 mg/L Sample 4, 7, 8 ,9, 11, 12, 17, 20, 25, 28, 32 and 35 have value greater than desirable limit 16 Potassium 17 Magnesium 30 mg/L All samples have value lower than desirable limit 18 Manganese 0.1mg/L Sample 3 and 26 have value greater than desirable limit 19 Sodium 20 Nickel 0.02 mg/L Sample 11, 17, 23, 25, 32 and 35 have value greater than desirable limit 21 Phosphorous 22 Lead 0.05 mg/L All samples have value lower than desirable limit 23 Sulphur 24 Zinc 5mg/L All samples have value lower than desirable limit SOIL QUALITY ANALYSIS: Materials and methodology Location of sampling source: Soil samples were collected from vicinity of Budha Nullah in Ludhiana. For the purpose of water collection site has been divided into two parts. 1) Vicinity area of Budha Nullah (within 500m perpendicular distance) 2) Area away from Budha Nullah ( > 500m perpendicular distance from) Budha Nullah TABLE: Site details of soil sampling stations Sample no. Location Distance from Budha Nullah (m) approx. 1 Opp treatment plant, Jamalpur 500-550 2 Near Old SabjiMandi 5-10 3 Gaushala Road 40-50 4 Rahon Road 100-150 5 Jain Nagar 600-650 6 Upkaar nagar 30-40 7 Joshi nagar 40-50 8 Haibowal 40-50 9 Green Avenue, Churpur 600-700 10 Near 152 MLD STP, Balloke 50-60 www.iosrjournals.org 5 | Page
  • 6. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” Site location on map Figure Table: Results of soil samples S.No. PARAMETERS RANGE OF METALS PRESENT IN ALL SAMPLES (mg/L) 1 Arsenic Lies between 0.007-0.014 2 Boron Lies between 0.088-0.179 3 Calcium Lies between 298.2-508.4 4 Cadmium Lies between 0.004-0.144 5 Chromium Lies between 0.005-0.021 6 Copper Lies between 0.358-11.484 7 Iron Lies between 2.447-6.584 8 Potassium Lies between 10.46-28.32 9 Magnesium Lies between 47.2-108.9 10 Manganese Lies between 2.72-5.24 11 Nickel Lies between 0.014-8.746 12 Phosphorous Lies between 0.043-1.541 13 Lead Lies between 0.354-3.864 14 Sulphur Lies between 8.43-89.14 15 Zinc Lies between 0.583-36.02 16 Sodium Lies between 49.4-156.4 www.iosrjournals.org 6 | Page
  • 7. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” SAR VALUES OF SOIL SAMPLES SOIL SAMPLE SAR VALUE 1. 6.98 2. 3.78 3. 6.03 4. 5.26 5. 5.12 6 7.12 7. 3.35 8. 9.57 9. 9.22 10. 4.54 III. Conclusions And Recommendations Conclusion: 1) The quality of the surface water at different stretches of Budha Nullah has been impaired as the stream progresses through the city. Untreated waste from the industries and human settlements are found to be the major cause for deterioration in the water quality in Ludhiana. The surface water analysis of Budha Nullah reveals high values of Total Dissolved solids up to 1642 mg/L, chlorides up to 400 mg/L, Chemical Oxygen Demand values up to 448mg/L, Biochemical Oxygen Demand varying between 52-195 mg/L, Most Potable Number varying from 240+ upto 2400+ per 100ml, heavy metal like Cr in the Budha Nullah has value 0.084 mg/L, Fe 0.913 mg/L, Mn 0.095 mg/L and Ni 0.222 mg/L. As per the water quality criteria given by Central Pollution Control Board (CPCB), the water quality of Budha Nullah comes under E class of water which is not suitable for drinking, outdoor bathing, propagation of wildlife and fisheries, irrigation and industrial cooling. 2) Most of the Heavy metals were within permissible limit except iron which was found to be more than permissible limit in samples of the Budha Nullah as well as groundwater 3) The quality of ground water at many places was found to be unfit for drinking mainly due to high amount of total dissolved solids and most potable number being much higher than the prescribed limit under CPCB. 4) Heavy metals were found in samples of groundwater in the vicinity of Budha Nullah and their concentration decreases as we move away from the Budha Nullah. So it can be concluded that presence of heavy metals in groundwater is due to seepage of surface water of Budha Nullah into the aquifer. 5) BOD values of groundwater was also high ranging from 2 to 12 due to which it falls under category E i.e. it is unfit for human consumption but can be used for irrigational purposes. 6) pH parameter analyzed in ground water samples as well as Budha Nullah were within the range of IS:10500 Drinking Water Standards between 6.5-8.5. 7) Amount of calcium in soil ranges from 298.2 to 508.4 mg/kg, sulphur from 8.43 to 89.14 mg/kg, nickel ranges from 0.076 to as high as 8.746 mg/kg. 8) SAR of soil ranges from 3.35 to 9.57 mg/kg, which is optimum value for soil, as soils with SAR value less than 10 are considered good for leaching and water percolation. Overall Comment On Water Quality Assessment Surface water of Ludhiana is highly contaminated by the effluents released by the industries and sewage which is added by the human settlements. This is the main reason for the heavy metals contamination and presence of microbes in the surface water. Surface water of Budha Nullah is highly colored, the main reason for this is the colored effluents that are released particularly by the textile industries. Dumping of the garbage into the water also obstructs the flow of this Nullah due to which at many places the water is Stagnant which hinders the self –purification mechanism of water and is one of the major factors for the occurrence of diseases like malaria, jaundice, cholera, diarrhea and gastroenteritis. Callousness approach of the people in the city has rendered the surface water of Budha Nullah to come under E class of water, which cannot be used for drinking, outdoor bathing, propagation of wildlife and fisheries, irrigation and industrial cooling. Heavy metal analysis of all the ground water samples is within the desirable limit. MPN values are high in the ground water, which indicates microbial contamination of water. Recommendations For Water Quality Assessment Regular monitoring of the water should be done. www.iosrjournals.org 7 | Page
  • 8. “Effect Of Polluted Surface Water On Groundwater: A Case Study Of Budha Nullah” The results of the analysis of water should be published for the purpose of record and benefit of public. Strict laws should be imposed on the industries which release their effluents directly into the water. Regular monitoring of small scale industries which are also a major contributor for polluting the surface water and ultimately contaminates the ground water. Educating the people about the various problems specially the labour class that works in industries will also help to clean the environment as the best way to manage the environment, is to manage ourselves. References [1] Aradhi K.Krishna, et al. 2009. Assessment of heavy metal pollution in water using multivariate statistical technique in an industrial area of Patancheru , Medak District, Andhra Pradesh, India. Journal of hazardous materials 167 (2009) 366-373. [2] G.S Gill and Harish Arora 2010. 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Haith and z Member, (1993), probabilistic screening of ground-water contaminations, Journal of Environmental Engineering, Vol. 119, No. 2, Paper No. 2586. [24] Peter K. Ndiba and Lisa Axe, (2010), Risk Assessment of Metal Leaching into Groundwater from Phosphate and Thermal Treated Sediments, Journal of Environmental Engineering, Vol. 136, No. 4, April 1, page no. 427–434. [25] Douglas A. Haith, Member, and Ethan M. Laden, (1986), screening of groundwater contamination by travel-time distributions, Journal of Environmental Engineering, Vol. 115,No. 3. www.iosrjournals.org 8 | Page