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chemistry

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11.3

Reactions in Aqueous Solution

Structures in limestone caverns
are formed when carbon dioxide
converts calcium hydrogen
carbonate into calcium carbonate.
The calcium carbonate
precipitates and forms dramatic
stalactites and stalagmites. You
will learn to predict the formation
of precipitates and write equations
to describe the reactions that
produce them.
© Copyright Pearson Prentice Hall

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11.3

Reactions in Aqueous
Solution

>

Net Ionic Equations

Net Ionic Equations
What does a net ionic equation show?

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© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Net Ionic Equations

A complete ionic equation is an equation
that shows dissolved ionic compounds as
dissociated free ions.

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4 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Net Ionic Equations

An ion that appears on both sides of an
equation and is not directly involved in the
reaction is called a spectator ion.
The net ionic equation is an equation for a
reaction in solution that shows only those
particles that are directly involved in the
chemical change.

Slide
5 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Net Ionic Equations

A net ionic equation shows only those
particles involved in the reaction and is
balanced with respect to both mass and
charge.

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6 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Net Ionic Equations

Sodium ions and nitrate ions are not
changed during the chemical reaction of silver
nitrate and sodium chloride so the net ionic
equation is

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© Copyright Pearson Prentice Hall
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© Copyright Pearson Prentice Hall
Slide
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© Copyright Pearson Prentice Hall
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© Copyright Pearson Prentice Hall
Practice Problems for Conceptual Problem 11.9

Problem Solving 11.28 Solve
Problem 28 with the help of an
interactive guided tutorial.
Slide
11 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Predicting the Formation of a
Precipitate

Predicting the Formation of a Precipitate
How can you predict the formation of a
precipitate in a double-replacement
reaction?

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12 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Predicting the Formation of a
Precipitate

You can predict the
formation of a precipitate by
using the general rules for
solubility of ionic
compounds.

Slide
13 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Predicting the Formation of a
Precipitate

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14 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Predicting the Formation of a
Precipitate

Will a precipitate form when a sodium
carbonate solution is mixed with a barium
nitrate solution?

Slide
15 of 21
© Copyright Pearson Prentice Hall
11.3

Reactions in Aqueous
Solution

>

Predicting the Formation of a
Precipitate

Sodium nitrate is soluble but barium
carbonate is insoluble. The net ionic equation
is

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© Copyright Pearson Prentice Hall
11.3 Section Quiz.

Assess students’ understanding
of the concepts in Section 11.3.
Continue to:

-or-

Launch:

Section Quiz

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17 of 21
© Copyright Pearson Prentice Hall
11.3 Section Quiz.
1. Identify the correct net ionic equation for the following
reaction and the spectator ion, if there is one.
FeO(s) + 2HClO4(aq) → H2O(l) + Fe(ClO4)2(aq)
a. FeO(s) + 2H+(aq) + 2ClO4-(aq) → H2O(l) + Fe2+(aq) +
2ClO4-(aq); no spectator ion
b. FeO(s) + 2H+(aq) + 2ClO4-(aq) → H2O(l) + Fe2+(aq) +
2ClO4-(aq); ClO4- is a spectator ion
c. FeO(s) + 2H+(aq) → H2O(l) + Fe2+(aq); ClO4d. FeO(s) + 2HClO4(aq) → H2O(l) + Fe(ClO4)2(aq); no Slide
18 of 21
spectator ion
© Copyright Pearson Prentice Hall
11.3 Section Quiz.
2. Which one of the following products of doublereplacement reactions would NOT form a
precipitate?
a. AgCl
b. PbSO4
c. Mg(OH)2
d. Mo(NO3)2
Slide
19 of 21
© Copyright Pearson Prentice Hall
11.3 Section Quiz
3. Which reaction will NOT produce a precipitate
from aqueous solution?
a. Hg2(NO3)2 + KCl
b. FeSO4 + Ba(OH)2
c. Pb(NO3)2 + Na2CO3
d. NaBr + Al2(SO4)2
Slide
20 of 21
© Copyright Pearson Prentice Hall
Reactions in Aqueous
Solution

>

Concept Map 11

Concept Map 11 Solve the
Concept Map with the help of an
interactive tutorial.
Slide
21 of 21
© Copyright Pearson Prentice Hall
END OF SHOW

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Chapter11 Sec. 3 Reactions in Aqueous Solution By Hamdy Karim.

  • 2. 11.3 Reactions in Aqueous Solution Structures in limestone caverns are formed when carbon dioxide converts calcium hydrogen carbonate into calcium carbonate. The calcium carbonate precipitates and forms dramatic stalactites and stalagmites. You will learn to predict the formation of precipitates and write equations to describe the reactions that produce them. © Copyright Pearson Prentice Hall Slide 2 of 21
  • 3. 11.3 Reactions in Aqueous Solution > Net Ionic Equations Net Ionic Equations What does a net ionic equation show? Slide 3 of 21 © Copyright Pearson Prentice Hall
  • 4. 11.3 Reactions in Aqueous Solution > Net Ionic Equations A complete ionic equation is an equation that shows dissolved ionic compounds as dissociated free ions. Slide 4 of 21 © Copyright Pearson Prentice Hall
  • 5. 11.3 Reactions in Aqueous Solution > Net Ionic Equations An ion that appears on both sides of an equation and is not directly involved in the reaction is called a spectator ion. The net ionic equation is an equation for a reaction in solution that shows only those particles that are directly involved in the chemical change. Slide 5 of 21 © Copyright Pearson Prentice Hall
  • 6. 11.3 Reactions in Aqueous Solution > Net Ionic Equations A net ionic equation shows only those particles involved in the reaction and is balanced with respect to both mass and charge. Slide 6 of 21 © Copyright Pearson Prentice Hall
  • 7. 11.3 Reactions in Aqueous Solution > Net Ionic Equations Sodium ions and nitrate ions are not changed during the chemical reaction of silver nitrate and sodium chloride so the net ionic equation is Slide 7 of 21 © Copyright Pearson Prentice Hall
  • 8. Slide 8 of 21 © Copyright Pearson Prentice Hall
  • 9. Slide 9 of 21 © Copyright Pearson Prentice Hall
  • 10. Slide 10 of 21 © Copyright Pearson Prentice Hall
  • 11. Practice Problems for Conceptual Problem 11.9 Problem Solving 11.28 Solve Problem 28 with the help of an interactive guided tutorial. Slide 11 of 21 © Copyright Pearson Prentice Hall
  • 12. 11.3 Reactions in Aqueous Solution > Predicting the Formation of a Precipitate Predicting the Formation of a Precipitate How can you predict the formation of a precipitate in a double-replacement reaction? Slide 12 of 21 © Copyright Pearson Prentice Hall
  • 13. 11.3 Reactions in Aqueous Solution > Predicting the Formation of a Precipitate You can predict the formation of a precipitate by using the general rules for solubility of ionic compounds. Slide 13 of 21 © Copyright Pearson Prentice Hall
  • 14. 11.3 Reactions in Aqueous Solution > Predicting the Formation of a Precipitate Slide 14 of 21 © Copyright Pearson Prentice Hall
  • 15. 11.3 Reactions in Aqueous Solution > Predicting the Formation of a Precipitate Will a precipitate form when a sodium carbonate solution is mixed with a barium nitrate solution? Slide 15 of 21 © Copyright Pearson Prentice Hall
  • 16. 11.3 Reactions in Aqueous Solution > Predicting the Formation of a Precipitate Sodium nitrate is soluble but barium carbonate is insoluble. The net ionic equation is Slide 16 of 21 © Copyright Pearson Prentice Hall
  • 17. 11.3 Section Quiz. Assess students’ understanding of the concepts in Section 11.3. Continue to: -or- Launch: Section Quiz Slide 17 of 21 © Copyright Pearson Prentice Hall
  • 18. 11.3 Section Quiz. 1. Identify the correct net ionic equation for the following reaction and the spectator ion, if there is one. FeO(s) + 2HClO4(aq) → H2O(l) + Fe(ClO4)2(aq) a. FeO(s) + 2H+(aq) + 2ClO4-(aq) → H2O(l) + Fe2+(aq) + 2ClO4-(aq); no spectator ion b. FeO(s) + 2H+(aq) + 2ClO4-(aq) → H2O(l) + Fe2+(aq) + 2ClO4-(aq); ClO4- is a spectator ion c. FeO(s) + 2H+(aq) → H2O(l) + Fe2+(aq); ClO4d. FeO(s) + 2HClO4(aq) → H2O(l) + Fe(ClO4)2(aq); no Slide 18 of 21 spectator ion © Copyright Pearson Prentice Hall
  • 19. 11.3 Section Quiz. 2. Which one of the following products of doublereplacement reactions would NOT form a precipitate? a. AgCl b. PbSO4 c. Mg(OH)2 d. Mo(NO3)2 Slide 19 of 21 © Copyright Pearson Prentice Hall
  • 20. 11.3 Section Quiz 3. Which reaction will NOT produce a precipitate from aqueous solution? a. Hg2(NO3)2 + KCl b. FeSO4 + Ba(OH)2 c. Pb(NO3)2 + Na2CO3 d. NaBr + Al2(SO4)2 Slide 20 of 21 © Copyright Pearson Prentice Hall
  • 21. Reactions in Aqueous Solution > Concept Map 11 Concept Map 11 Solve the Concept Map with the help of an interactive tutorial. Slide 21 of 21 © Copyright Pearson Prentice Hall

Notas do Editor

  1. Illustration from page 342
  2. A precipitate of silver chloride forms when aqueous solutions of silver nitrate and sodium chloride are mixed. Inferring Which ions do not participate in the reaction?
  3. Equation from text page 343
  4. Conceptual problem 11-9
  5. Equation from text page 344