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Hazardous Materials Guide
                          for

         First Responders




Federal Emergency Management Agency
      United States Fire Administration
How to Use this Guide

If you know the Chemical/Material Name:

   1. Go to the Specific Material Guides
         Ë locate the chemical in the alphabetical listing

   2. If you are unable to locate the chemical in the Specific Material Guide:
          Ë Go the Alphabetical Material Name Index
          Ë locate the chemical in the alphabetical listing
          Ë go to the page listed for guidance information

   3. If the chemical is not found in the index, go to the HAZMAT General Response
      Scheme



If you have only the UN Number for the Chemical/Material:

   1. Go to the UN/NA Number Index
         Ë locate the UN/NA number in the numerical listing
         Ë go to the page listed for guidance information

   2. If material UN number is not found in the index go to the HAZMAT General
      Response Scheme



If you have only NFPA Placard Information:

   1. Go to the guidance information for using the NFPA 704 Placard


If you have only DOT Placard information:

   1. Go the HAZMAT General Response Scheme


   WARNING!
   The best time to learn how to use this book is BEFORE you need it. Train with
   this book the way you would train with any new piece of equipment - in advance!
Hazardous
                                                     Materials
                                                             Guide
                                                                     for
                                                                 First
                                              Responders




The information in this book was collected from a variety of sources which were reviewed by the Firefighters’ Safety Study Technical Commit-
tee and are believed to be accurate. However, the Federal Emergency Management Agency makes no claim that these data and recommenda-
tions are either correct or sufficient and assumes no liability for any adverse consequences arising from their use.

The action recommendations in this book should be considered as suggestions only. Specific circumstances at the scene of an incident as well as
the number and training of first responders will dictate what actions are actually appropriate. Final decisions are the responsibility of the Incident
Commander.
Acknowledgments
This document was prepared under a Cooperative Agreement (EMW-93-K-4351) between the Federal Emergency
Management Agency/United States Fire Administration and the University of Louisville. The data was assembled and
formatted by an active Writing Committee with direction and oversight by the Firefighters’ Safety Study Project Commit-
tee. Technical content was also reviewed under a separate contract (EMW-3-4649) with Louisiana State University.


Writing Committee

George C. Rodgers, Jr., Editor               Steve Burton                                       Gary M. Hart
Medical Director                             Assistant Chief, Fire/EMS/Hazmat                   President
Kentucky Regional Poison Center              Rohm and Haas Co., Louisville (Kentucky)           Paragon Enterprises, Inc.
                                             Plant                                              Louisville (Kentucky)

Nancy J. Matyunas, Associate Editor          Thomas L. Coomes, II                               Brad Learn
Clinical Assistant Professor of Pediatrics   Environmental Health Coordinator/                  Medical Training Coordinator
and Toxicology                               HazMat Response, Ret.                              City of Louisville (Kentucky)
University of Louisville                     Louisville/Jefferson County (Kentucky)             Division of Fire
                                                                                                Health Department

Clark Bledsoe                                A. J. “Bud” Fekete
Assistant Director                           Deputy Chief
Jefferson County (Kentucky)                  Louisville (Kentucky) Fire Department, Ret.
Planning and Environmental Management        Coordinator of Technical Hazards, Louisville/
                                             Jefferson County Disaster and Emergency Services




This project could not have been undertaken without the expertise of the following individuals who provided
invaluable guidance and input by serving on the Firefighters’ Safety Study Project Committee.


Steven C. Bailey (Chair)                     Patricia Frazier                                   George C. Rodgers, Jr.
Assistant Chief, Ret.                        Tri Data Corporation                               Medical Director
Seattle (Washington) Fire Department                                                            Kentucky Regional Poison Center

James Brizzell                               Richard L. Hartnett                                Jerry M. Schroy, P. E., DEE
Chief, Hazardous Materials Bureau            Chief, Emergency Management Division               Senior Fellow
NY Office of Fire Prevention & Control       Boston (Massachusetts) Fire Department             Solutia Inc.

Gary E. Curmode                              Charles B. Henry, Jr.                              Alan L. Schneider
Chief                                        Institute for Environmental Studies                Chemical Engineer
Sedgwick County (Kansas) Fire Department     Louisiana State University                         US Coast Guard

John Eversole                                Bradley S. Pabody
Chief, Hazardous Materials                   Fire Program Specialist
Chicago (Illinois) Fire Department           United States Fire Administration



In addition to the project committee members listed above, the following organizations and individuals provided invalu-
able assistance in the field testing and evaluation of the Hazardous Material Guide for First Responders

National Association of State Fire Marshals
Ray E. Carnahan                              Michael Durst                                      Donald Bliss
Commander, Fire Marshal’s Office             State Fire Marshal                                 State Fire Marshal
Arkansas State Police                        Nebraska State Fire Marshal’s Office               New Hampshire Division of Fire Safety
Table of Contents


How to Use this Guide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Inside Front Cover
Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Alphabetical Material Name Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
UN/NA Number Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39
Specific Material Guides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
Materials Summary Response Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . 481
DOT Placards — Chart 10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 521
Silhouettes of Rail Cars, Tank Trucks and Chemical Tanks . . . . . . . . . . 525
General Approach to a Hazmat Incident . . . . . . . . . . . . . . . . . . . . . . . . . 547
Glossary of Terms and Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . 557
Important Telephone Numbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 562
First Responder Strategy Using the NFPA 704 Placard . . . . . . . Inside Back Cover
Hazmat General Response Scheme . . . . . . . . . . . . . . . . . . . . . Outside Back Cover
Introduction
I. Objectives                                                       (E) An understanding of the role of the first responder
                                                                        awareness individual in the employers emergency response
This book is the result of an extensive study of available              plan including site security and control and the U.S.
hazardous materials response resources for first responders             Department of Transportation’s Emergency Response
undertaken by the United States Fire Administration (USFA)              Guidebook.
as part of the Firefighters’ Safety Study Act of 1990 (P.L. 101-
446). The study concluded that, while several excellent and         (F) The ability to realize the need for additional resources,
technically accurate resources are available, none are directed         and to make appropriate notifications to the communication
to the specific needs of the first responder trained at the             center.
Awareness or Operational Levels of Training; the training levels
of most first responders. It is the hope and the intent of the      First Responder Operations Level: First responders at the
USFA that this book will be that much needed resource.              Operations Level are individuals who respond to releases or
                                                                    potential releases of hazardous substances as part of the initial
This book provides important information for the initial response   response to the site for the purpose of protecting nearby
to both transportation and fixed facility incidents. It has been    persons, property, or the environment from the effects of the
designed to present the first responder with a maximum amount       release. They are trained to respond in a defensive fashion
of useful key information in a limited amount of space. As with     without actually trying to stop the release. Their function is to
any reference, it cannot include all information that might be      contain the release from a safe distance, keep it from spreading,
useful or discuss all situations which might occur; nor can it      and prevent exposures. First responders at the Operations
replace the training and experience of individual responders.       Level shall have received at least eight hours of training or
The information contained in this book has been reviewed by         have had sufficient experience to objectively demonstrate
several sources and is as technically accurate as possible.         competency in the following areas in addition to those listed
For major incidents it will be necessary to obtain more detailed    for the Awareness Level and the employer shall so certify:
information from other resources as well as more advanced
expertise from those with more extensive training.                  (A) Knowledge of the basic hazard and risk assessment
                                                                        techniques.
It is assumed that those using this book will have had
some training in hazardous materials response. Because              (B) Know how to select and use proper personal protective
most first responders are trained at the Awareness or                   equipment provided to the first responder operational level.
Operational levels, this book is directed at appropriate
responses for these levels of training. These levels are defined    (C) An understanding of basic hazardous materials terms.
below as published by the National Fire Protection Association
(NFPA 472, 1992) and the Occupational Safety and Health             (D) Know how to perform basic control, containment, and/or
Administration (OSHA 1910.120).                                         confinement operations within the capabilities of the
                                                                        resources and personal protective equipment available with
OSHA 1910.120                                                           their unit.

First Responder At Awareness Level: First responders at             (E) Know how to implement basic decontamination procedures.
the Awareness Level are individuals who are likely to witness
or discover a hazardous substance release and who have been         (F) An understanding of the relevant standard operating
trained to initiate an emergency response sequence by notifying         procedures and termination procedures.
the authorities of the release. First responders at the
Awareness Level shall have sufficient training or have had          II. How The Book is Organized
sufficient experience to objectively demonstrate competency
in the following areas:                                             The body of this book is divided into seven sections:
                                                                    • Indexes: ALPHABETICAL MATERIAL NAME INDEX followed by a UN/
(A) An understanding of what hazardous substances are, and             NA NUMBER INDEX.
    the risks associated with them in an incident.
                                                                    •   SPECIFIC MATERIAL GUIDES: specific recommendations for 430
(B) An understanding of the potential outcomes associated               commonly encountered materials.
    with an emergency created when hazardous substances
    are present.                                                    •   MATERIALS SUMMARY RESPONSE TABLE: summary information
                                                                        for 1,422 less commonly encountered materials.
(C) The ability to recognize the presence of hazardous
    substances in an emergency.                                     •   DOT PLACARDS - CHART 10.

(D) The ability to identify the hazardous substances, if            •   SILHOUETTES OF RAIL CARS, TANK TRUCKS AND CHEMICAL TANKS.
    possible.
                                                                                                                                   1
•   GENERAL APPROACH TO A HAZMAT INCIDENT.                            found in the top center of each page. Underneath the primary
•   GLOSSARY OF TERMS AND ABBREVIATIONS used in the book.             name is the UN (United Nations) number or the NA (North
                                                                      American) number. The UN number is commonly used for
The main body of the book provides information on about 1750          materials in commerce and can be found on shipping papers.
different materials. The materials included in these sections         A few materials in this section do not have an assigned UN
include most of those which have been reported to have been           number. This may mean either that the material is not
involved in hazardous materials incidents. Most drugs have            considered a hazard, or that it is not found in transport in a
been excluded. Materials were assigned to the SPECIFIC MATERIAL       sizeable amount. The shipping name of the material appears
GUIDE section or the MATERIALS SUMMARY RESPONSE TABLE based           directly under the chemical name. Finally, other less commonly
upon the likelihood that they would be encountered and the            used names for the material are listed.
magnitude of the hazards they represent, using a formula
designed for this project. The information in these two sections      In the upper right hand corner of the page are the DOT
is intended to be used during an actual incident.                     placard(s)/label(s) assigned to the material when transported
                                                                      within the United States. A complete list of current DOT
The GENERAL APPROACH TO A HAZMAT INCIDENT section provides            placards is found in Chart 10 on page 521. For a few materials,
specific information about a number of different response             no specific DOT placard designation has been made in 49CFR
scenarios. It also provides useful information and techniques         and this area is left blank.
for assisting in the identification of materials. This section
should be studied as part of training for Hazmat response. It is      In the upper left corner of the page is the NFPA 704 placard
not intended for use during an actual incident.                       providing summary information on acute health, fire and
                                                                      reactivity hazards plus any special concerns such as water
Following the General Approach section is a Glossary of the           reactivity which apply to the material. An explanation of the
technical terms and abbreviations used throughout the book.           number designations used in the NFPA placard taken from /
While the authors have tried to use simple and straightforward        NFPA 704 is found on page 550. The placard is commonly
language, some terms may not be familiar to all users. Also           found on storage containers or is posted at fixed facilities.
included in this last section are several Appendices providing        When posted on fixed facilities each designation represents
reference information mentioned in the text.                          the worst hazard in that category within the building or facility.
                                                                      The placard is not found on materials in transport.
This book has been extensively indexed using all of the material
names and synonyms (other names for the same chemical)                NFPA 704 designations were taken, when available, from the
found in the book. There is a separate index for UN and NA            1994 editions of NFPA 49 and NFPA 325. If the material was
numbers which are commonly found on shipping papers when              not rated in these references, values were determined and
materials are in transport. While the SPECIFIC MATERIAL GUIDES        assigned from published data, where available, or were based
section is arranged in alphabetical order by the most widely          on reasonable estimation from data published on structurally
used name of the material, the index should be used as the            similar materials, using the definitions for these designations
most rapid way of locating information about a specific               from NFPA 49. If the information in the placard is from the
material.                                                             NFPA 49 or NFPA 325, the designation “NFPA” appears along
                                                                      the right edge of the placard. If there is no such designation,
This book does not contain specific recommendations about             the content of the NFPA 704 placard was determined by the
isolation or evacuation distances. Because this book is               authors.
designed to be used in a wide range of scenarios involving
different container sizes, it was felt that the calculation of such   Below the list of synonyms may appear a section printed in red
distances could be misleading and perhaps dangerous.                  entitled WARNING. This section is vitally important. It provides
Isolation distances are best determined by those trained above        crucial information about hazards that are immediately life
the operations level, taking into account the amount of material      threatening to the first responder. A WARNING indicates a
involved, the weather conditions and the specific                     very dangerous material because of the health risk or because
circumstances of the release.                                         of the extreme fire, explosion or reactivity risk(s). Most materials
                                                                      will not have a WARNING section. This does not mean that
III. How to Use The Specific Material Guides (Chemical                they are not dangerous and cannot injure or kill, only that they
     Specific) Pages                                                  are not likely to do so if they are handled properly.

The SPECIFIC MATERIAL GUIDES (RED TAB) provides detailed              Below the WARNING section is a section entitled HAZARDS.
response information for 430 materials. These materials were          This section describes the physical, chemical, or toxic
systematically selected based on their likelihood of being            properties of the material which create risks for the first
encountered and the magnitude of the hazard they pose to              responder. This section includes such things as explosion
the first responder. An example of a specific material guide          hazard, flammability risk and acute health hazards. Hazards
is shown in Figure 1 on page 4.                                       are arranged in the approximate order of their importance to
                                                                      the first responder.
The most widely accepted chemical name for the material is

2
Next to the Hazards is a section entitled Description. This         more detailed references as an indexing number. It is provided
section describes what the material looks and smells like,          as another positive identifier and to allow quick reference to
along with some important information about the physical            other data bases.
properties of the material, such as whether it floats or sinks
in water or whether it is heavier or lighter than air (if it is a   IV. How to Use the Materials Summary Response Table
gas). The information in this section may be useful in verifying
the identity of a hazardous material and in anticipating some       The MATERIALS SUMMARY RESPONSE TABLE (YELLOW TAB)
of its actions.                                                     provides summary information on 1,422 additional materials.
                                                                    These materials are either less likely to be encountered by
In the middle of the page are sections entitled Awareness           the first responder. This table is arranged in alphabetic order
and Operational Level Training Response and                         using the most common chemical name of the material. For
Operational Level Training Response. These sections list            each material the UN number and DOT placard designation
the appropriate actions for the first responder trained to each     are provided, if available. NFPA designations are provided for
of these two levels of expertise. Not all of the statements         all materials. In the case where NFPA designations were not
listed may be appropriate for every situation, but actions should   available from NFPA 49 or 325, values were assigned by the
not be more aggressive than those listed. The most important        authors using NFPA 49 definitions along with available data
recommendations are given first. Remember that these are            on the material or on structurally similar materials. NFPA 704
initial recommendations for the first responder. They may be        designations taken from NFPA sources are shown in green
modified by the on-scene Hazmat Incident Commander.                 while the those assigned by the authors are in black.
Awareness Level Response actions are all defensive in
nature. Operational Level Response actions are divided into
two general situations, those involving releases of material
without an accompanying fire and those where a fire is involved,
whether or not the material itself is burning. Operational
Level Responders must remember that actions listed under
Awareness and Operational Level Response should be
completed before beginning the more definitive Operational
Level Response actions.

At the bottom of the page is a First Aid section. These
recommendations should be used in caring for victims who
are out of the Hot zone. Rescue of victims from within a Hot
zone should only be performed by trained personnel wearing
appropriate chemical resistant gear and is not generally a first
responder action.

Removal of hazardous material from the skin, eyes or clothing
of a victim (decontamination) is usually the most important
first aid action that can be initiated. It should be performed
only by appropriately trained and equipped individuals. Rapid
removal of the material may be the difference between a minor
injury and a serious injury. The details of decontamination
techniques are beyond the scope of this book. In general,
using large quantities of water to rinse off materials is almost
always the first choice for decontamination in the field.
Materials which are so toxic that first aid should not be
performed on contaminated victims because of the risk of
serious injury to the responder are clearly labeled. There are
very few antidotes for treating victims exposed to chemicals
and they are listed in this section for the benefit of hospital
personnel who may care for these victims. Other First Aid
information is also provided.

Finally, at the middle of the page below the first aid section is
a CHEMICAL ABSTRACTS SERVICE REGISTRY NUMBER
(CAS: _ _ _-_ _-_). This is a specific identifying number given
to each chemical by the Chemical Abstract Service. Mixtures
are usually not assigned CAS numbers. While not commonly
used in shipping, the CAS number may be found on containers
and Material Safety Data Sheets (MSDS) and is used by many
                                                                                                                                 3
Figure 1.



                                     HYDROGEN CYANIDE
           4                                            (STABILIZED)
      4 2                                                     UN 1051
                                     Shipping Name: Hydrogen cyanide, stabilized with less than 3 percent water
                  PA




                                     Other Names: AC                Hydrocyanic acid solution
                NF




                                                    HCN            Prussic acid
                                                    Hydrocyanic acid
    WARNING!           POISON! BREATHING THE VAPORS OR SKIN CONTACT CAN KILL YOU!
                       Firefighting gear (including SCBA) provides NO protection. If exposure occurs, remove and
                       isolate gear immediately and thoroughly decontaminate personnel
                       EXTREMELY FLAMMABLE!
    Hazards:                                                        Description:
     Odor is not a reliable indicator of the presence of toxic        Colorless liquid that boils at 78˚ F
     amounts of vapor                                                 Sweet odor like bitter almonds; many people cannot smell it
     May react with itself without warning with explosive             Dissolves slowly in water but is soluble in water
     violence                                                         Extremely flammable
     Container may BLEVE or explode when exposed to fire              Vapors are slightly lighter than air but will collect and stay
     Vapors may travel long distances to ignition sources and         in low areas
     flashback                                                        Transported in red and white candy striped containers
     Vapors in confined areas (e.g., tanks, sewers, buildings)        Produces large amounts of vapor
     may explode when exposed to fire                                 Freezes at 8˚ F
     Vapors are slightly lighter than air but will collect and stay Operational Level Training Response:
     in low areas                                                   RELEASE, NO FIRE:
     Combustion products are less toxic than the material itself
                                                                      Stop the release if it can be done safely from a distance
    Awareness and Operational Level Training                          Use large amounts of water well away from the material to
    Response:                                                         disperse vapors - contain runoff
     DO NOT ATTEMPT RESCUE!                                           Ventilate confined area if it can be done without placing
     Stay upwind and uphill                                           personnel at risk
     Determine the extent of the problem                            FIRE:
     BACK OFF! - Isolate a wide area around the release or            If material is on fire and conditions permit, DO NOT
     fire, deny entry and call for expert help                        EXTINGUISH; combustion products are less toxic then the
     Remove all ignition sources                                      original material. Cool exposures using unattended monitors.
     For container exposed to fire evacuate the area in all           Specially trained personnel operating from a safe distance
     directions because of the risk of BLEVE or explosion             can fight fires using alcohol resistant (AFFF) foam or dry
     Evacuate the immediate area and downwind for a large             chemical if available in sufficient amounts. Under favorable
     release                                                          conditions, experienced crews can use coordinated fog
     Notify local health and fire officials and pollution control     streams to sweep the flames off the surface of the burning
     agencies                                                         liquid. Do not direct straight streams into the liquid.
     If material or contaminated runoff enters waterways, notify      Cool exposed containers with large quantities of water
     downstream users of potentially contaminated water               from unattended equipment or remove intact containers if
                                                                      it can be done safely
                                                                      If cooling streams are ineffective (unvented container
                                                                      distorts, bulges or shows any other signs of expanding),
                                                                      withdraw immediately to a secure location
                                                              First Aid:
      DO NOT ATTEMPT RESCUE!
      The contaminated victim poses a health risk to the responder
      Decontaminate the victim from a safe distance with a stream of water; have the victim remove clothing if possible; provide
      Basic Life Support/CPR as needed
      Decontaminate the victim as follows:
           Inhalation - remove the victim to fresh air and give oxygen if available
           Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for
           15 minutes
           Eye - rinse eyes with large volumes of water or saline for 15 minutes
           Swallowed - do not make the victim vomit
      Victims should be examined by a physician as soon as possible
      Toxic effects may be delayed
      Do NOT perform direct mouth to mouth resuscitation; use a bag/mask apparatus
      Note to physician: can produce cyanide toxicity; if symptoms indicate, initial treatment includes the cyanide antidote kit
                                                           CAS: 74-90-8




4
References
1. North American Emergency Response Guide, 1996             16. R.J. Lewis, SAX’s Dangerous Properties of Industrial
   Edition, U.S. Department of Transportation, Washington,       Materials, 8th Edition (1992), Van Nostrand Reinhold,
   DC.                                                           New York, NY.

2. The Merck Index, 12th Edition (1996), Merck and Co.,      17. R.J. Lewis, Hazardous Chemicals Desk Reference, 3rd
   Inc., Rahway, NJ.                                             Edition (1993), Van Nostrand Reinhold, New York, NY.

3. Emergency Handling of Hazardous Materials in Surface      18. A Guide to Fire Hazard Properties of Flammable Liquids,
   Transportation (1992), American Association of                Gases and Volatile Solids, ANSI/NFPA 325 (1994),
   Railroads, Washington, DC.                                    National Fire Protective Association, Quincy, MA.

4. Emergency Action Guide (1995), American Association       19. Hazardous Chemicals Data, ANSI/NFPA 49 (1994),
   of Railroads, Washington, DC.                                 National Fire Protective Association, Quincy, MA.

5. Chemical Hazards Response Information System,             20. Code of Federal Regulations 49 Transportation (1996),
   Hazardous Chemical Data Manual, Vol. II (1993), U.S.          Office of Federal Register National Archives and Records
   Department of Transportation, U.S. Coast Guard,               Administration, Washington, DC.
   Washington, DC.
                                                             21. Chemical/Biological Incident Handbook, (1995), The
6. NIOSH Pocket Guide to Chemical Hazards (1990), U.S.           Director of Central Intelligence Committee on Terrorism/
   Department of Health and Human Services,                      Community Counterterrorism Board.
   Washington, DC.

7. L. Bretherick, Bretherick’s Handbook of Reactive
   Chemical Hazards, 4th Edition (1990), Butterworth-
   Heinemann, Ltd., Boston, MA.

8. Tomes Plus (1995), Micromedex, Denver, CO.

9. CAMEO (1990), U.S. Environmental Protection Agency,
   National Oceanic and Atmospheric Administration,
   National Safety Council, Washington, DC.

10. Fire Protection Guide to Hazardous Materials; 10th
    Edition (1991), National Fire Protection Association,
    Quincy, MA.

11. Responding to Hazardous Materials Incidents, ANSI/
    NFPA 473 (1992), National Fire Protective Association,
    Quincy, MA.

12. Responders to Hazardous Materials Incidents, ANSI/
    NFPA 472 (1992), National Fire Protective Association,
    Quincy, MA.

13. Identification of the Fire Hazards of Materials, ANSI/
    NFPA 704 (1990), National Fire Protective Association,
    Quincy, MA.

14. Field Guide to Tank Care Identification (1992),
    Association of American Railroads, Washington, D.C.

15. Hazardous Materials Response Handbook, 2nd Edition
    (1993), National Fire Protective Association, Quincy,
    MA.




                                                                                                                            5
Alphabetical Material Name Index

A                   J                   S
B                   K                   T
C                   L                   U
D                  M                    V
E                   N                   W
F                   O                   X
G                   P                   Y
H                   Q                   Z
I                   R
     Click on letter to go to section
Alphabetical Material Index
A-150 .......................................................................... 476     Acrylic acid .................................................................. 62
AA ................................................................................ 67   Acrylic acid chloride ..................................................... 64
AC .............................................................................. 285    Acrylic acid, butyl ester .............................................. 114
Acetaldehyde ................................................................ 51         Acrylic acid, ethyl ester .............................................. 231
Acetaldehyde cyanohydrin ......................................... 305                   Acrylic acid, methyl ester ........................................... 321
Acetaldehyde ethylacetal .............................................. 50               Acrylic amide ................................................................ 61
Acetamide ................................................................... 482        Acrylonitrile ................................................................... 63
Acetene ...................................................................... 243       Acryloyl chloride ........................................................... 64
Acetic acid .................................................................... 52      Acrylyl chloride ............................................................. 64
Acetic acid anhydride ................................................... 53             Actidione ..................................................................... 171
Acetic acid bromide ...................................................... 57            Actidone ..................................................................... 171
Acetic acid chloride ...................................................... 58           Adipic acid .................................................................. 482
Acetic acid dimethylamide .......................................... 206                 Adipic acid dinitrile ....................................................... 65
Acetic acid, ethinyl ester ............................................. 468             Adiponitrile .................................................................... 65
Acetic acid, methyl ester ............................................. 319              Agent T ....................................................................... 482
Acetic acid, n-butyl ester ............................................ 113              Alachlor ...................................................................... 482
Acetic acid, n-propyl ester .......................................... 408               Alcide ......................................................................... 140
Acetic acid, vinyl ester ................................................ 468            Aldicarb ........................................................................ 66
Acetic aldehyde ............................................................ 51          Aldifen ........................................................................ 223
Acetic anhydride ........................................................... 53          Aldrin .......................................................................... 482
Acetic chloride .............................................................. 58        Algrain ........................................................................ 232
Acetic ester ................................................................ 230        Alkyl benzene sulfonic acids ....................................... 482
Acetic ether ................................................................ 230        Allene .......................................................................... 482
Acetoacetone .............................................................. 381          Allene-methyl acetylene mixture .................................. 320
Acetocyanohydrin ......................................................... 55            Allethrin ....................................................................... 482
Acetocyanohydrin ....................................................... 305             Allyl acetate ................................................................ 482
Acetol ........................................................................... 50    Allyl al ........................................................................... 67
Acetone ........................................................................ 54      Allyl alcohol ................................................................... 67
Acetone cyanohydrin .................................................... 55              Allyl aldehyde ................................................................ 60
Acetone thiosemicarbazide ......................................... 482                  Allyl bromide ................................................................. 69
Acetonitrile .................................................................... 56     Allyl chloride ................................................................. 70
                                                                                         Allyl chlorocarbonate ..................................................... 71
Acetophenone ............................................................. 482           Ally chloroformate ......................................................... 71
1-Acetoxyethylene ...................................................... 468             Allyl ether .................................................................... 482
1-Acetoxypropane ....................................................... 408             Allyl ethyl ether ............................................................ 482
Acetyl acetone ............................................................ 381          Allyl iodide .................................................................. 482
Acetyl anhydride ........................................................... 53          Allyl isothiocyanate ..................................................... 482
Acetyl bromide .............................................................. 57         Allylamine ..................................................................... 68
Acetyl chloride .............................................................. 58        Allylic alcohol ................................................................ 67
Acetyl ether .................................................................. 53       Allyltrichlorosilane ......................................................... 72
Acetyl ketene .............................................................. 204         alpha-Bromotoluene ...................................................... 95
Acetyl oxide .................................................................. 53       alpha-Chlorobenzaldehyde ............................................ 94
Acetyl peroxide solution .............................................. 482              alpha-Chloropropionic ................................................. 155
2-Acetylaminofluorene ................................................ 482               alpha-Chlorotoluene ...................................................... 96
Acetylene ...................................................................... 59      alpha-Cumene hydroperoxide ..................................... 161
Acetylene dichloride ................................................... 186             alpha-Endosulfan ........................................................ 497
Acetylene tetrachloride ............................................... 438              alpha-Methacrylic acid ................................................ 313
Acetylene trichloride ................................................... 454            alpha-Methyl benzyl alcohol ........................................ 505
Acetylenogen .............................................................. 128          alpha-Methyl styrene ................................................... 299
Acetylsilicon trichloride ................................................. 72           alpha-Naphthylamine ................................................... 507
Acid ............................................................................ 155    alpha-Pinene ............................................................... 398
Acridine ...................................................................... 482      alpha-Tolunitrile ........................................................... 385
Acroleic acid ................................................................. 62       Aluminum (dust) .......................................................... 482
Acrolein ........................................................................ 60     Aluminum borohydride ................................................ 482
Acrylaldehyde .............................................................. 60          Aluminum chloride ...................................................... 482
Acrylamide .................................................................... 61       Aluminum fluoride ....................................................... 482


8
Alphabetical Material Index
Aluminum nitrate ......................................................... 482          Ammonium fluoborate ................................................. 483
Aluminum oxide ........................................................... 482          Ammonium fluoride ..................................................... 483
Aluminum phosphide ................................................... 482              Ammonium formate ..................................................... 483
Aluminum sulfate ......................................................... 482          Ammonium gluconate .................................................. 483
Aluminum, triisobutyl ................................................... 459           Ammonium hydroxide ................................................... 77
AMFO ........................................................................... 84     Ammonium hypophosphite .......................................... 483
Am-fol ........................................................................... 74   Ammonium iodide ....................................................... 483
Aminic acid ................................................................. 269       Ammonium lactate ....................................................... 483
1-Amino-2,4-dinitrobenzene ........................................ 220                 Ammonium lauryl sulfate ............................................. 483
2-Amino-2-methyl-1-propanol ..................................... 482                   Ammonium molybdate ................................................. 483
1-Amino-2-propanol .................................................... 298             Ammonium monosulfide ................................................ 79
4-Aminoazobenzene ................................................... 482               Ammonium nitrate ....................................................... 483
Aminobenzene .............................................................. 85          Ammonium nitrate fertilizers ........................................ 483
1-Aminobutane ............................................................ 116          Ammonium nitrate: fuel oil ............................................. 84
4-Aminobutyl diethoxymethyl silane ............................. 482                    Ammonium nitrate-phosphate mixture ......................... 483
Aminocyclohexane ...................................................... 172             Ammonium nitrate-sulfate mixture ............................... 483
Aminoethane ............................................................... 233         Ammonium nitrate-urea solution .................................. 483
2-Aminoethanol ........................................................... 229          Ammonium oleate ....................................................... 483
2-(2-Aminoethoxy)ethanol ........................................... 482                Ammonium oxalate ...................................................... 483
Aminoethyl ethanol amine ........................................... 482                Ammonium pentaborate .............................................. 483
Aminoethylethandiamine ............................................. 198                Ammonium perchlorate .................................................. 78
Aminohexahydrobenzene ............................................ 172                  Ammonium perchlorate high explosive .......................... 78
2-Aminoisobutane ....................................................... 117            Ammonium perchlorate oxidizer .................................... 78
Aminomethane ............................................................ 323           Ammonium permanganate .......................................... 483
Aminomethane ............................................................ 324           Ammonium persulfate ................................................. 483
4-Amino-N,N-dimethylaniline ....................................... 215                 Ammonium phosphate ................................................. 483
2-Aminopentane .......................................................... 195           Ammonium picrate (wet) ............................................. 483
Aminophen .................................................................... 85       Ammonium rhodanate ................................................... 81
2-Aminopropane ......................................................... 300            Ammonium silicofluoride ............................................. 483
3-Aminopropene ........................................................... 68           Ammonium stearate .................................................... 483
4-Aminopropiophenone ............................................... 482                Ammonium sulfamate .................................................. 483
3-Aminopropylene ......................................................... 68           Ammonium sulfate ....................................................... 483
4-Aminopyridine ........................................................... 73          Ammonium sulfide ......................................................... 79
Aminopyridines ............................................................. 73         Ammonium sulfite .......................................................... 80
Aminotoluene .............................................................. 451         Ammonium sulfocyanide ............................................... 81
Amiton ........................................................................ 482     Ammonium sulphite ....................................................... 80
Amiton oxalate ............................................................. 482        Ammonium tartrate ...................................................... 483
Amitrole ...................................................................... 482     Ammonium thiocyanate ................................................. 81
Ammonia ....................................................................... 74      Ammonium thiosulfate ................................................. 483
Ammonia monohydrate ................................................. 77                AMS ............................................................................ 299
Ammonia solution .......................................................... 77          Amthio .......................................................................... 81
Ammonia water ............................................................. 77          Amyl alcohol ................................................................. 82
Ammonia, anhydrous .................................................... 74              Amyl methyl ketone ..................................................... 325
Ammonium acetate ..................................................... 483              Amyl phthalate ............................................................ 484
Ammonium aminoformate ............................................. 76                  Amylol ........................................................................... 82
Ammonium benzoate ..................................................... 75              Amyltricholorsilane ........................................................ 83
Ammonium bicarbonate .............................................. 483                 AN/FO ........................................................................... 84
Ammonium bifluoride .................................................. 483              Anhydrol ..................................................................... 232
Ammonium bisulfite ..................................................... 483            Anhydrous ammonia ..................................................... 74
Ammonium bromide .................................................... 483               Anhydrous ethanol ...................................................... 232
Ammonium carbamate .................................................. 76                Anhydrous hydrobromic acid ...................................... 283
Ammonium carbonate ................................................. 483                Anhydrous hydrofluoric acid ....................................... 286
Ammonium chloride .................................................... 483              Aniline ........................................................................... 85
Ammonium chromate .................................................. 483                Aniline oil ...................................................................... 85
Ammonium citrate ....................................................... 483            Anisole ........................................................................ 484
Ammonium dichromate ............................................... 483                 Anisoyl chloride .......................................................... 484


                                                                                                                                                                            9
Alphabetical Material Index
Anone ......................................................................... 170       Barium peroxide .......................................................... 485
Ansul ether 121 ........................................................... 205           BCME ......................................................................... 188
Anthion ....................................................................... 401       BD .............................................................................. 111
Anthracene ................................................................. 484          Benomyl ...................................................................... 485
Antimony (powder) ...................................................... 484              Bentazon ..................................................................... 485
Antimony pentachloride .............................................. 484                 Benzal chloride ............................................................. 98
Antimony pentafluoride ............................................... 484                Benzaldehyde ............................................................... 88
Antimony potassium tartrate ........................................ 484                  Benzalmalonoitrile ....................................................... 145
Antimony tribromide .................................................... 484              Benzamide .................................................................... 89
Antimony trichloride .................................................... 484             Benzenamine ................................................................ 85
Antimony trifluoride ..................................................... 484            Benzene ....................................................................... 90
Antimony trioxide ........................................................ 484            Benzene arsonic acid ................................................. 485
ANTU .......................................................................... 484       Benzene chloride ........................................................ 147
Aqua fortis .................................................................. 361        Benzene fluoride ......................................................... 264
Aqueous ammonia ........................................................ 77               Benzene hexachloride ................................................. 485
Aramite ....................................................................... 484       Benzene methylal .......................................................... 88
Arctic .......................................................................... 331     Benzene nitro ............................................................. 263
Argon .......................................................................... 484      Benzene phosphorous dichloride ................................ 388
Arsenic ....................................................................... 484       Benzene sulfonyl chloride ........................................... 485
Arsenic acid ............................................................... 484          Benzeneacetonitrile .................................................... 385
Arsenic butter ............................................................... 86         Benzenecarbonal .......................................................... 88
Arsenic chloride ............................................................ 86          Benzenecarbonyl chloride ............................................ 94
Arsenic dichloroethane ............................................... 241                Benzenehexahydride .................................................. 169
Arsenic disulfide ......................................................... 484           Benzenenitrile ............................................................... 91
Arsenic hydride ............................................................ 87           Benzenethiol ............................................................... 387
Arsenic pentoxide ....................................................... 484             Benzenol ..................................................................... 384
Arsenic trichloride ......................................................... 86          Benzidine .................................................................... 485
Arsenic trihydride ......................................................... 87           Benzin ........................................................................ 258
Arsenic trioxide ........................................................... 484          Benzo (A) anthracene ................................................. 485
Arsenic trisulfide ......................................................... 484          Benzo (A) pyrene ....................................................... 485
Arsenous chloride ......................................................... 86            Benzo (B) fluoranthene ............................................... 485
Arsenous trichloride ...................................................... 86            Benzo (GHI) perylene ................................................. 485
Arsine ........................................................................... 87     Benzoic acid ............................................................... 485
Asbestos ..................................................................... 484        Benzoic acid amide ...................................................... 89
Asphalt ........................................................................ 484      Benzoic aldehyde ......................................................... 88
Asphalt blending stocks: roofers flux ........................... 484                     Benzoic trichloride ........................................................ 93
Asphalt blending stocks: straight run residue .............. 484                          Benzol ........................................................................... 90
asym-Dimethylhydrazine ............................................. 214                  Benzonitrile ................................................................... 91
Atrazine ...................................................................... 484       Benzophenone ............................................................ 485
Auramine .................................................................... 484         Benzoquinone ............................................................... 92
Avitrol ............................................................................ 73   1,4-Benzoquinone ......................................................... 92
Azabenzene ................................................................ 415           Benzotrichloride ............................................................ 93
Azacyclohexane .......................................................... 399             Benzoyl chloride ........................................................... 94
Azacyclopropane ........................................................ 253              Benzoyl peroxide ........................................................ 485
Azide .......................................................................... 419      Benzoylamide ............................................................... 89
Azine .......................................................................... 415      Benzyl acetate ............................................................ 485
Azirane ....................................................................... 253       Benzyl alcohol ............................................................. 485
Aziridine ..................................................................... 253       Benzyl amine .............................................................. 485
Azophos ...................................................................... 349        Benzyl bromide ............................................................. 95
Barium ........................................................................ 485       Benzyl carbonyl chloride ............................................... 97
Barium carbonate ....................................................... 485              Benzyl chloride ............................................................. 96
Barium chlorate .......................................................... 485            Benzyl chlorocarbonate ................................................ 97
Barium cyanide .......................................................... 485             Benzyl chloroformate .................................................... 97
Barium nitrate ............................................................. 485          Benzyl cyanide ........................................................... 385
Barium perchlorate ..................................................... 485              Benzyl dichloride .......................................................... 98
Barium permanganate ................................................. 485                 Benzyl dimethyl amine ................................................ 485


10
Alphabetical Material Index
Benzyl dimethyl octadecyl ammonium chloride ........... 485                             Black powder, pellets .................................................. 486
Benzyl ether ................................................................ 178       Bladan ........................................................................ 377
Benzyl iodide .............................................................. 485        Bladan-M .................................................................... 349
Benzyl nitrile ............................................................... 385      Blasting oil .................................................................. 366
Benzyl oxide ............................................................... 178        Bleach ........................................................................ 422
Benzyl trichloride .......................................................... 93        Blue oil .......................................................................... 85
Benzyl trimethyl ammonium chloride ........................... 485                      Bolero ......................................................................... 486
Benzyl violet ................................................................ 485      Bondolane A ............................................................... 427
Benzylene chloride ....................................................... 98           Bonoform .................................................................... 438
Benzylidene chloride ..................................................... 98           Boric acid ................................................................... 486
Beryllium ..................................................................... 485     Borneol ....................................................................... 486
Beryllium chloride ....................................................... 485          Boroethane ................................................................. 179
Beryllium fluoride ........................................................ 485         Boron bromide ............................................................ 100
Beryllium nitrate .......................................................... 485        Boron chloride ............................................................ 101
Beryllium oxide ............................................................ 485        Boron fluoride ............................................................. 102
Beryllium sulfate .......................................................... 485        Boron hydride ............................................................. 177
beta-Butyrolactone ...................................................... 487           Boron hydride ............................................................. 179
beta-Chloroprene ........................................................ 154           Boron hydride ............................................................. 378
beta-Endosulfan .......................................................... 497          Boron tribromide ......................................................... 100
beta-Methyl acrolein .................................................... 160           Boron trichloride ......................................................... 101
beta-Propiolactone ...................................................... 405           Boron trifluoride .......................................................... 102
BHA ............................................................................ 485    Boron trifluoride: dimethyl etherate ............................. 486
BHC, alpha- ................................................................ 485        Bottled gas .................................................................. 308
BHC, beta- .................................................................. 485       BPL ............................................................................ 405
BHC, delta- ................................................................. 486       Brimstone ................................................................... 428
BHC, gamma- ............................................................. 486           Brom ........................................................................... 103
BIC ............................................................................. 121   Bromacil ..................................................................... 486
Bicylcopentadiene ...................................................... 192            Bromadiolone .............................................................. 486
Biethylene ................................................................... 111      Bromide fluoride ......................................................... 104
Bimethyl ...................................................................... 228     Bromine ...................................................................... 103
Biocide ......................................................................... 60    Bromine chloride ......................................................... 486
Biogas ........................................................................ 315     Bromine cyanide ......................................................... 164
Bioxirane ..................................................................... 193     Bromine fluoride ......................................................... 105
Biphenyl ...................................................................... 486     Bromine pentafluoride ................................................. 104
Bis (chloromethyl) ketone ........................................... 181               Bromine trifluoride ...................................................... 105
Bis-(2-aminoethyl) amine ............................................ 198               3-Bromo-1-propene ...................................................... 69
Bis-(2-chloro-1-methyl ethyl) ether .............................. 486                  1-Bromo-3-methylbutane ............................................. 486
Bis-(2-chloroethoxy) methane ..................................... 486                  Bromoacetic acid ........................................................ 486
Bis-(2-chloroethyl) ether ............................................. 184             Bromoacetone ............................................................ 486
Bis-(2-chloroethyl) methylamine .................................. 311                  Bromoacetyl bromide .................................................. 106
Bis-(2-chloroethyl) sulfide ............................................ 99             Bromoallylene ............................................................... 69
Bis-(2-chloroisopropyl) ether ...................................... 486                Bromobenzene ............................................................ 107
Bis-(2-ethyl hexyl) adipate .......................................... 486              1-Bromobutane ........................................................... 108
Bis-(2-ethyl hexyl) phthalate ........................................ 486              2-Bromobutane ........................................................... 486
Bis-(chloromethyl) ether ............................................. 188              Bromochloromethane .................................................. 486
Bismuth oxychloride .................................................... 486            Bromocyan ................................................................. 164
Bis-O,O-diethylpyrophosphoric anhydride .................. 441                          Bromoethanoyl bromide .............................................. 106
Bisphenol A ................................................................ 486        Bromoethene .............................................................. 469
Bisphenol A diglycidyl ether ........................................ 486               2-Bromoethyl ethyl ether ............................................. 486
Bisulfite ....................................................................... 430   Bromoethylene ............................................................ 469
Bithionol ...................................................................... 486    Bromoform .................................................................. 486
Bitoscanate ................................................................. 486       Bromofume ................................................................. 247
Bivinyl ......................................................................... 111   Brom-O-Gas ............................................................... 326
B-K Liquid ................................................................... 422      Bromomethane ............................................................ 326
Black powder, compressed ......................................... 486                  2-Bromopentane ......................................................... 486
Black powder, granular ............................................... 486              4-Bromophenyl phenyl ether ....................................... 486


                                                                                                                                                                          11
Alphabetical Material Index
Bromophenylmethane ................................................... 95               2,3-Butylene oxide ...................................................... 487
1-Bromopropane ......................................................... 486            Butylethylamine ........................................................... 236
2-Bromopropane ......................................................... 109            Butylsilicon trichloride ................................................. 123
3-Bromopropylene ........................................................ 69            Butyltrichlorosilane ...................................................... 123
Bromopropyne ............................................................ 110           2-Butyne-1,4-diol ........................................................ 124
3-Bromopropyne ......................................................... 110            Butynediol ................................................................... 124
Bromotrifluoroethylene ................................................ 486             1,4-Butynediol ............................................................. 124
Bromotrifluoromethane ................................................ 486              2-Butynediol ................................................................ 124
Brucine ....................................................................... 487     Butyral ........................................................................ 125
Butadiene ................................................................... 111       Butyraldehyde ............................................................. 125
1,3-Butadiene ............................................................. 111         Butyric acid chloride ................................................... 127
Butadiene diepoxide .................................................... 193            Butyric acid nitrile ....................................................... 126
Butadiene dioxide ....................................................... 193           Butyric acid, ethyl ester .............................................. 237
Butal ........................................................................... 125   Butyric acid, methyl ester ........................................... 330
Butaldehyde ................................................................ 125        Butyric aldehyde ......................................................... 125
Butanal ........................................................................ 125    Butyric chloride .......................................................... 127
Butane ........................................................................ 112     Butyronitrile ................................................................ 126
Butane nitrile ............................................................... 126      Butyryl chloride ........................................................... 127
Butanedione ................................................................ 487        BZCF ............................................................................ 97
Butanethiol .................................................................. 122      C.I. acid blue 9, diammonium salt ............................... 490
1-Butanethiol ............................................................... 122       C.I. acid blue 9, disodium salt ..................................... 490
2-Butanone ................................................................. 338        C.I. acid green 3 ......................................................... 490
Butanoyl chloride ........................................................ 127          C.I. basic green 4 ....................................................... 490
3-Buten-2-one ............................................................. 356         C.I. basic red 1 ........................................................... 490
2-Butenal .................................................................... 160      C.I. disperse yellow 3 ................................................. 490
Butene ........................................................................ 118     C.I. food red 15 .......................................................... 490
1-Butene oxide ............................................................ 119         C.I. food red 5 ............................................................ 490
1,4-Butenediol ............................................................. 487        C.I. solvent orange 7 ................................................... 490
3-Buteno-beta-lactone ................................................. 204             C.I. solvent yellow 14 .................................................. 490
1-Butyl acetate ............................................................ 113        C.I. solvent yellow 3 .................................................... 490
Butyl acid phosphate ................................................... 487            C.I. vat yellow 4 .......................................................... 490
Butyl acrylate .............................................................. 114       Cacodylic acid ............................................................ 487
Butyl alcohol ............................................................... 115       Cadmium acetate ........................................................ 487
Butyl aldehyde ............................................................ 125         Cadmium bromide ....................................................... 487
Butyl benzyl phthalate ................................................. 487            Cadmium chloride ....................................................... 487
Butyl bromide .............................................................. 108        Cadmium fluoroborate ................................................. 487
Butyl butyrate .............................................................. 487       Cadmium nitrate .......................................................... 487
Butyl chloride .............................................................. 148       Cadmium oxide ........................................................... 487
Butyl ethanoate ........................................................... 113         Cadmium stearate ....................................................... 487
Butyl ether .................................................................. 487      Cadmium sulfate ......................................................... 487
Butyl ethylene ............................................................. 277        Cadmium(powder) ...................................................... 487
Butyl isocyanate ......................................................... 121          CADOXTHB................................................................. 120
Butyl isovalerate .......................................................... 487        CAF ............................................................................ 144
Butyl mercaptan .......................................................... 122          Calcium ...................................................................... 488
Butyl methyl ether ....................................................... 487          Calcium acetylide ....................................................... 128
Butyl nitrite .................................................................. 487    Calcium arsenite ......................................................... 488
Butyl toluene ............................................................... 487       Calcium carbide .......................................................... 128
Butyl, decyl, cetyl-eicosyl methacrylate ...................... 487                     Calcium chlorate ......................................................... 488
Butyl-2-propenoate ..................................................... 114            Calcium chloride ......................................................... 488
Butylacetic acid .......................................................... 129         Calcium chromate ....................................................... 488
Butylacetone ............................................................... 325        Calcium cyanide ......................................................... 488
Butylamine .................................................................. 116       Calcium fluoride .......................................................... 488
Butylated hydroxyanisole ............................................ 487               Calcium hydride .......................................................... 489
Butylene ...................................................................... 118     Calcium hydroxide ...................................................... 488
1,2-Butylene oxide ...................................................... 119           Calcium hypochlorite .................................................. 488
1-Butylene oxide ......................................................... 119          Calcium nitrate ............................................................ 488


12
Alphabetical Material Index
Calcium oxide ............................................................. 488        Carbonic oxide ............................................................ 134
Calcium peroxide ........................................................ 488          Carbonochloride acid, ethyl ester ............................... 240
Calcium phosphate ..................................................... 488            Carbonyl chloride ....................................................... 390
Calcium phosphide ..................................................... 489            Carbonyl fluoride ........................................................ 136
Calcium resinate ......................................................... 488         Carbonyl sulfide .......................................................... 137
Camphene .................................................................. 488        Carene ........................................................................ 488
Camphor oil ................................................................ 488       Casing head gasoline ................................................. 272
Cantharidin ................................................................. 488      Castor oil, edible ......................................................... 488
CAP ............................................................................ 144   Caswell No 805 ........................................................... 424
Caproic acid ............................................................... 129       Catechol ..................................................................... 488
Caprolactam ............................................................... 488        Caustic potash solution ............................................... 488
Capronic acid ............................................................. 129        Caustic soda ............................................................... 421
Caprylene ................................................................... 373      Caustic soda, solution ................................................. 421
Capsicum ................................................................... 488       Cellon ......................................................................... 438
Capsine ...................................................................... 222     Certox ......................................................................... 424
Captan ........................................................................ 488    Cesium ....................................................................... 489
Carbachol ................................................................... 130      CHA ............................................................................ 172
Carbachol chloride ...................................................... 130          Chloral ........................................................................ 138
Carbacholin ................................................................ 130       Chlorallylene ................................................................. 70
Carbacholine dichloride .............................................. 130             Chloramben ................................................................ 488
Carbacryl ...................................................................... 63    Chlorbisan .................................................................. 488
Carbamic acid, ammonium salt ..................................... 76                  Chlordane, flammable liquid ........................................ 488
Carbamide peroxide .................................................... 466            Chlordecone ............................................................... 488
Carbamiotin ................................................................ 130       Chlorex ....................................................................... 184
Carbamoyl dimethyl chloride ....................................... 209                Chlorfenvinfos ............................................................. 488
Carbamyl ...................................................................... 66     Chloride of phosphorus ............................................... 396
Carbaryl (solid) ........................................................... 488       Chlorine ...................................................................... 139
Carbide ....................................................................... 128    Chlorine cyanide ......................................................... 165
Carbinol ...................................................................... 318    Chlorine dioxide .......................................................... 140
Carbofuran ................................................................. 131       Chlorine dioxide hydrate ............................................. 140
Carbolic acid .............................................................. 384       Chlorine dioxide hydrate (frozen) ................................ 140
Carbolic oil .................................................................. 488    Chlorine fluoride ......................................................... 141
Carbon bisulfide .......................................................... 133        Chlorine monoxide ...................................................... 489
Carbon chloride .......................................................... 135         Chlorine pentafluoride ................................................. 489
Carbon dichloride oxide .............................................. 390             Chlorine peroxide ........................................................ 140
Carbon difluoride ........................................................ 136         Chlorine sulfide ........................................................... 429
Carbon dioxide ............................................................ 132        Chlorine trifluoride ...................................................... 141
Carbon disulfide .......................................................... 133        Chlormephos ............................................................... 489
Carbon disulphide ....................................................... 133          Chlormequat chloride .................................................. 489
Carbon monoxide ........................................................ 134
Carbon nitride ............................................................. 163       2-Chlorobenzylidine malononitrile............................... 145
Carbon oxide .............................................................. 134        Chloro methyl sulfane ................................................. 316
Carbon oxide sulfide ................................................... 137           Chloro(chloromethoxy) methane ................................. 188
Carbon oxychloride ..................................................... 390           2-Chloro-1,3-butadiene ............................................... 154
Carbon oxyfluoride ...................................................... 136          2-Chloro-1-ethanol ...................................................... 244
Carbon oxysulfide ....................................................... 137          4-Chloro-1-methylbenzene .......................................... 158
Carbon sulfide ............................................................ 133        1-Chloro-1-propene .................................................... 489
Carbon tet ................................................................... 135     1-Chloro-2,3-epoxypropane ........................................ 227
Carbon tetrachloride ................................................... 135           1-Chloro-2-cyanoethane ............................................. 156
Carbona ...................................................................... 135     1-Chloro-2-nitrobenzene ............................................. 151
Carbonic acid anhydride ............................................ 132               1-Chloro-4-methylbenzene .......................................... 158
Carbonic acid gas ...................................................... 132           10-Chloro-5,10-dihydrophenarsazine (DM) ................ 489
Carbonic acid, diethyl ester ........................................ 197              Chloroacetaldehyde .................................................... 142
Carbonic anhydride .................................................... 132            2-Chloroacetaldehyde ................................................. 142
Carbonic difluoride oxide ............................................ 136             Chloroacetaldehyde monomer .................................... 142
Carbonic ether ............................................................ 197        Chloroacetaphenone ................................................... 144


                                                                                                                                                                       13
Alphabetical Material Index
Chloroacetic acid ........................................................ 489      1-Chloropropane ......................................................... 489
Chloroacetic acid chloride .......................................... 146           2-Chloropropane ......................................................... 489
Chloroacetic acid, ethyl ester ..................................... 239            3-Chloropropanenitrile ................................................ 156
Chloroacetic acid, methyl ester ................................... 332             Chloropropene .............................................................. 70
Chloroacetic chloride .................................................. 146        2-Chloropropene ......................................................... 489
Chloroacetone, stabilized ............................................ 489          3-Chloropropene ........................................................... 70
Chloroacetonitrile ........................................................ 143     Chloropropham ........................................................... 489
Chloroacetyl chloride .................................................. 146        2-Chloropropionic acid ............................................... 155
2-Chloroacrylic acid, methyl ester .............................. 333               3-Chloropropionitrile ................................................... 156
Chloroaldehyde ........................................................... 142      3-Chloropropyl octyl sulfoxide ..................................... 489
Chlorobenzene ............................................................ 147      Chloropropylene ........................................................... 70
Chlorobenzilate ........................................................... 489     1-Chloropropylene ...................................................... 489
2-Chlorobuta -1,3-diene .............................................. 154          Chloropropylene oxide ................................................ 227
Chlorobutadiene .......................................................... 154      Chlorosulfane .............................................................. 432
Chlorobutane .............................................................. 148     Chlorosulfonic acid ..................................................... 157
1-Chlorobutane ........................................................... 148      Chlorosulfuric acid ...................................................... 157
2-Chlorobutane ........................................................... 489      Chlorothalonil .............................................................. 489
Chlorocarbonic acid, ethyl ester ................................. 240              Chlorotoluene .............................................................. 158
Chlorocyan ................................................................. 165    3-Chlorotoluene .......................................................... 489
Chlorocyanogen ......................................................... 165        4-Chlorotoluene .......................................................... 158
Chlorodibromomethane ............................................... 489            Chlorotrifluoride .......................................................... 141
Chlorodifluoromethane ................................................ 489          Chlorotrifluoroethane ................................................... 489
Chloroethanal .............................................................. 142    Chlorotrifluoroethylene ................................................ 458
2-Chloroethanal .......................................................... 142      Chlorotrifluoromethane ................................................ 490
Chloroethane .............................................................. 238     Chlorotrimethylsilane ................................................... 462
Chloroethane .............................................................. 453     Chlorovinylarsine dichloride ........................................ 306
2-Chloroethane sulfonyl chloride ................................. 489              Chlorovinyldichloroarsine ............................................ 306
Chloroethanenitrile ...................................................... 143      Chloroxuron ................................................................ 490
Chloroethanol .............................................................. 244    Chlorpyrifos ................................................................ 159
2-Chloroethanol .......................................................... 244      Chlorthiophos .............................................................. 490
Chloroethene .............................................................. 470     Chlorylen .................................................................... 453
2-Chloroethyl chlorocarbonate .................................... 149              Choline chloride carbamate ........................................ 130
2-Chloroethyl vinyl ether ............................................. 489
Chloroethylene ............................................................ 470     Chromic acetate ......................................................... 490
Chloroform .................................................................. 150   Chromic acid .............................................................. 490
Chloroformate ............................................................. 149     Chromic anhydride ..................................................... 490
Chloroformic acid, isopropyl ester .............................. 302               Chromic sulfate ........................................................... 490
Chloroformyl chloride .................................................. 390        Chromium (dust) ......................................................... 490
Chlorohydrins ............................................................. 489     Chromium oxychloride ................................................ 490
Chloromethane ............................................................ 331      Chromous chloride ...................................................... 490
(Chloromethyl) benzene ............................................... 96           Chrysene .................................................................... 490
Chloromethyl cyanide ................................................. 143          Cinnamenol ................................................................. 425
Chloromethyl ether ...................................................... 188       cis-Butene .................................................................. 118
Chloromethyl ethyl ether ............................................. 489          Citric acid ................................................................... 490
Chloromethyl methyl ether ........................................... 489           Citrus red No. 2 .......................................................... 490
1-(Chloromethyl)-4-nitrobenzene ................................ 489                CK .............................................................................. 165
Chloromethyloxirane ................................................... 227         Clorox ......................................................................... 422
2-Chloronaphthalene ................................................... 489         CN .............................................................................. 144
Chloronitrobenzene ..................................................... 151        CO .............................................................................. 134
Chlorophenyl methane .................................................. 96          Coal gas ..................................................................... 490
4-Chlorophenyl phenyl ether ....................................... 489             Coal naphtha ................................................................. 90
2-Chlorophenylthiourea ............................................... 152          Coal oil ........................................................................ 304
Chloropicrin ................................................................ 153   Cobalt ......................................................................... 490
Chloropicrin: methyl chloride ...................................... 489            Cobalt acetate ............................................................. 490
Chloropivaloyl chloride ................................................ 489        Cobalt bromide ............................................................ 490
Chloroprene ................................................................ 154    Cobalt carbonyl ........................................................... 490


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Hazardous materials guide

  • 1. Hazardous Materials Guide for First Responders Federal Emergency Management Agency United States Fire Administration
  • 2. How to Use this Guide If you know the Chemical/Material Name: 1. Go to the Specific Material Guides Ë locate the chemical in the alphabetical listing 2. If you are unable to locate the chemical in the Specific Material Guide: Ë Go the Alphabetical Material Name Index Ë locate the chemical in the alphabetical listing Ë go to the page listed for guidance information 3. If the chemical is not found in the index, go to the HAZMAT General Response Scheme If you have only the UN Number for the Chemical/Material: 1. Go to the UN/NA Number Index Ë locate the UN/NA number in the numerical listing Ë go to the page listed for guidance information 2. If material UN number is not found in the index go to the HAZMAT General Response Scheme If you have only NFPA Placard Information: 1. Go to the guidance information for using the NFPA 704 Placard If you have only DOT Placard information: 1. Go the HAZMAT General Response Scheme WARNING! The best time to learn how to use this book is BEFORE you need it. Train with this book the way you would train with any new piece of equipment - in advance!
  • 3. Hazardous Materials Guide for First Responders The information in this book was collected from a variety of sources which were reviewed by the Firefighters’ Safety Study Technical Commit- tee and are believed to be accurate. However, the Federal Emergency Management Agency makes no claim that these data and recommenda- tions are either correct or sufficient and assumes no liability for any adverse consequences arising from their use. The action recommendations in this book should be considered as suggestions only. Specific circumstances at the scene of an incident as well as the number and training of first responders will dictate what actions are actually appropriate. Final decisions are the responsibility of the Incident Commander.
  • 4. Acknowledgments This document was prepared under a Cooperative Agreement (EMW-93-K-4351) between the Federal Emergency Management Agency/United States Fire Administration and the University of Louisville. The data was assembled and formatted by an active Writing Committee with direction and oversight by the Firefighters’ Safety Study Project Commit- tee. Technical content was also reviewed under a separate contract (EMW-3-4649) with Louisiana State University. Writing Committee George C. Rodgers, Jr., Editor Steve Burton Gary M. Hart Medical Director Assistant Chief, Fire/EMS/Hazmat President Kentucky Regional Poison Center Rohm and Haas Co., Louisville (Kentucky) Paragon Enterprises, Inc. Plant Louisville (Kentucky) Nancy J. Matyunas, Associate Editor Thomas L. Coomes, II Brad Learn Clinical Assistant Professor of Pediatrics Environmental Health Coordinator/ Medical Training Coordinator and Toxicology HazMat Response, Ret. City of Louisville (Kentucky) University of Louisville Louisville/Jefferson County (Kentucky) Division of Fire Health Department Clark Bledsoe A. J. “Bud” Fekete Assistant Director Deputy Chief Jefferson County (Kentucky) Louisville (Kentucky) Fire Department, Ret. Planning and Environmental Management Coordinator of Technical Hazards, Louisville/ Jefferson County Disaster and Emergency Services This project could not have been undertaken without the expertise of the following individuals who provided invaluable guidance and input by serving on the Firefighters’ Safety Study Project Committee. Steven C. Bailey (Chair) Patricia Frazier George C. Rodgers, Jr. Assistant Chief, Ret. Tri Data Corporation Medical Director Seattle (Washington) Fire Department Kentucky Regional Poison Center James Brizzell Richard L. Hartnett Jerry M. Schroy, P. E., DEE Chief, Hazardous Materials Bureau Chief, Emergency Management Division Senior Fellow NY Office of Fire Prevention & Control Boston (Massachusetts) Fire Department Solutia Inc. Gary E. Curmode Charles B. Henry, Jr. Alan L. Schneider Chief Institute for Environmental Studies Chemical Engineer Sedgwick County (Kansas) Fire Department Louisiana State University US Coast Guard John Eversole Bradley S. Pabody Chief, Hazardous Materials Fire Program Specialist Chicago (Illinois) Fire Department United States Fire Administration In addition to the project committee members listed above, the following organizations and individuals provided invalu- able assistance in the field testing and evaluation of the Hazardous Material Guide for First Responders National Association of State Fire Marshals Ray E. Carnahan Michael Durst Donald Bliss Commander, Fire Marshal’s Office State Fire Marshal State Fire Marshal Arkansas State Police Nebraska State Fire Marshal’s Office New Hampshire Division of Fire Safety
  • 5. Table of Contents How to Use this Guide . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . Inside Front Cover Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Alphabetical Material Name Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7 UN/NA Number Index . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 39 Specific Material Guides . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 Materials Summary Response Table . . . . . . . . . . . . . . . . . . . . . . . . . . . . 481 DOT Placards — Chart 10 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 521 Silhouettes of Rail Cars, Tank Trucks and Chemical Tanks . . . . . . . . . . 525 General Approach to a Hazmat Incident . . . . . . . . . . . . . . . . . . . . . . . . . 547 Glossary of Terms and Abbreviations . . . . . . . . . . . . . . . . . . . . . . . . . . . 557 Important Telephone Numbers . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 562 First Responder Strategy Using the NFPA 704 Placard . . . . . . . Inside Back Cover Hazmat General Response Scheme . . . . . . . . . . . . . . . . . . . . . Outside Back Cover
  • 6. Introduction I. Objectives (E) An understanding of the role of the first responder awareness individual in the employers emergency response This book is the result of an extensive study of available plan including site security and control and the U.S. hazardous materials response resources for first responders Department of Transportation’s Emergency Response undertaken by the United States Fire Administration (USFA) Guidebook. as part of the Firefighters’ Safety Study Act of 1990 (P.L. 101- 446). The study concluded that, while several excellent and (F) The ability to realize the need for additional resources, technically accurate resources are available, none are directed and to make appropriate notifications to the communication to the specific needs of the first responder trained at the center. Awareness or Operational Levels of Training; the training levels of most first responders. It is the hope and the intent of the First Responder Operations Level: First responders at the USFA that this book will be that much needed resource. Operations Level are individuals who respond to releases or potential releases of hazardous substances as part of the initial This book provides important information for the initial response response to the site for the purpose of protecting nearby to both transportation and fixed facility incidents. It has been persons, property, or the environment from the effects of the designed to present the first responder with a maximum amount release. They are trained to respond in a defensive fashion of useful key information in a limited amount of space. As with without actually trying to stop the release. Their function is to any reference, it cannot include all information that might be contain the release from a safe distance, keep it from spreading, useful or discuss all situations which might occur; nor can it and prevent exposures. First responders at the Operations replace the training and experience of individual responders. Level shall have received at least eight hours of training or The information contained in this book has been reviewed by have had sufficient experience to objectively demonstrate several sources and is as technically accurate as possible. competency in the following areas in addition to those listed For major incidents it will be necessary to obtain more detailed for the Awareness Level and the employer shall so certify: information from other resources as well as more advanced expertise from those with more extensive training. (A) Knowledge of the basic hazard and risk assessment techniques. It is assumed that those using this book will have had some training in hazardous materials response. Because (B) Know how to select and use proper personal protective most first responders are trained at the Awareness or equipment provided to the first responder operational level. Operational levels, this book is directed at appropriate responses for these levels of training. These levels are defined (C) An understanding of basic hazardous materials terms. below as published by the National Fire Protection Association (NFPA 472, 1992) and the Occupational Safety and Health (D) Know how to perform basic control, containment, and/or Administration (OSHA 1910.120). confinement operations within the capabilities of the resources and personal protective equipment available with OSHA 1910.120 their unit. First Responder At Awareness Level: First responders at (E) Know how to implement basic decontamination procedures. the Awareness Level are individuals who are likely to witness or discover a hazardous substance release and who have been (F) An understanding of the relevant standard operating trained to initiate an emergency response sequence by notifying procedures and termination procedures. the authorities of the release. First responders at the Awareness Level shall have sufficient training or have had II. How The Book is Organized sufficient experience to objectively demonstrate competency in the following areas: The body of this book is divided into seven sections: • Indexes: ALPHABETICAL MATERIAL NAME INDEX followed by a UN/ (A) An understanding of what hazardous substances are, and NA NUMBER INDEX. the risks associated with them in an incident. • SPECIFIC MATERIAL GUIDES: specific recommendations for 430 (B) An understanding of the potential outcomes associated commonly encountered materials. with an emergency created when hazardous substances are present. • MATERIALS SUMMARY RESPONSE TABLE: summary information for 1,422 less commonly encountered materials. (C) The ability to recognize the presence of hazardous substances in an emergency. • DOT PLACARDS - CHART 10. (D) The ability to identify the hazardous substances, if • SILHOUETTES OF RAIL CARS, TANK TRUCKS AND CHEMICAL TANKS. possible. 1
  • 7. GENERAL APPROACH TO A HAZMAT INCIDENT. found in the top center of each page. Underneath the primary • GLOSSARY OF TERMS AND ABBREVIATIONS used in the book. name is the UN (United Nations) number or the NA (North American) number. The UN number is commonly used for The main body of the book provides information on about 1750 materials in commerce and can be found on shipping papers. different materials. The materials included in these sections A few materials in this section do not have an assigned UN include most of those which have been reported to have been number. This may mean either that the material is not involved in hazardous materials incidents. Most drugs have considered a hazard, or that it is not found in transport in a been excluded. Materials were assigned to the SPECIFIC MATERIAL sizeable amount. The shipping name of the material appears GUIDE section or the MATERIALS SUMMARY RESPONSE TABLE based directly under the chemical name. Finally, other less commonly upon the likelihood that they would be encountered and the used names for the material are listed. magnitude of the hazards they represent, using a formula designed for this project. The information in these two sections In the upper right hand corner of the page are the DOT is intended to be used during an actual incident. placard(s)/label(s) assigned to the material when transported within the United States. A complete list of current DOT The GENERAL APPROACH TO A HAZMAT INCIDENT section provides placards is found in Chart 10 on page 521. For a few materials, specific information about a number of different response no specific DOT placard designation has been made in 49CFR scenarios. It also provides useful information and techniques and this area is left blank. for assisting in the identification of materials. This section should be studied as part of training for Hazmat response. It is In the upper left corner of the page is the NFPA 704 placard not intended for use during an actual incident. providing summary information on acute health, fire and reactivity hazards plus any special concerns such as water Following the General Approach section is a Glossary of the reactivity which apply to the material. An explanation of the technical terms and abbreviations used throughout the book. number designations used in the NFPA placard taken from / While the authors have tried to use simple and straightforward NFPA 704 is found on page 550. The placard is commonly language, some terms may not be familiar to all users. Also found on storage containers or is posted at fixed facilities. included in this last section are several Appendices providing When posted on fixed facilities each designation represents reference information mentioned in the text. the worst hazard in that category within the building or facility. The placard is not found on materials in transport. This book has been extensively indexed using all of the material names and synonyms (other names for the same chemical) NFPA 704 designations were taken, when available, from the found in the book. There is a separate index for UN and NA 1994 editions of NFPA 49 and NFPA 325. If the material was numbers which are commonly found on shipping papers when not rated in these references, values were determined and materials are in transport. While the SPECIFIC MATERIAL GUIDES assigned from published data, where available, or were based section is arranged in alphabetical order by the most widely on reasonable estimation from data published on structurally used name of the material, the index should be used as the similar materials, using the definitions for these designations most rapid way of locating information about a specific from NFPA 49. If the information in the placard is from the material. NFPA 49 or NFPA 325, the designation “NFPA” appears along the right edge of the placard. If there is no such designation, This book does not contain specific recommendations about the content of the NFPA 704 placard was determined by the isolation or evacuation distances. Because this book is authors. designed to be used in a wide range of scenarios involving different container sizes, it was felt that the calculation of such Below the list of synonyms may appear a section printed in red distances could be misleading and perhaps dangerous. entitled WARNING. This section is vitally important. It provides Isolation distances are best determined by those trained above crucial information about hazards that are immediately life the operations level, taking into account the amount of material threatening to the first responder. A WARNING indicates a involved, the weather conditions and the specific very dangerous material because of the health risk or because circumstances of the release. of the extreme fire, explosion or reactivity risk(s). Most materials will not have a WARNING section. This does not mean that III. How to Use The Specific Material Guides (Chemical they are not dangerous and cannot injure or kill, only that they Specific) Pages are not likely to do so if they are handled properly. The SPECIFIC MATERIAL GUIDES (RED TAB) provides detailed Below the WARNING section is a section entitled HAZARDS. response information for 430 materials. These materials were This section describes the physical, chemical, or toxic systematically selected based on their likelihood of being properties of the material which create risks for the first encountered and the magnitude of the hazard they pose to responder. This section includes such things as explosion the first responder. An example of a specific material guide hazard, flammability risk and acute health hazards. Hazards is shown in Figure 1 on page 4. are arranged in the approximate order of their importance to the first responder. The most widely accepted chemical name for the material is 2
  • 8. Next to the Hazards is a section entitled Description. This more detailed references as an indexing number. It is provided section describes what the material looks and smells like, as another positive identifier and to allow quick reference to along with some important information about the physical other data bases. properties of the material, such as whether it floats or sinks in water or whether it is heavier or lighter than air (if it is a IV. How to Use the Materials Summary Response Table gas). The information in this section may be useful in verifying the identity of a hazardous material and in anticipating some The MATERIALS SUMMARY RESPONSE TABLE (YELLOW TAB) of its actions. provides summary information on 1,422 additional materials. These materials are either less likely to be encountered by In the middle of the page are sections entitled Awareness the first responder. This table is arranged in alphabetic order and Operational Level Training Response and using the most common chemical name of the material. For Operational Level Training Response. These sections list each material the UN number and DOT placard designation the appropriate actions for the first responder trained to each are provided, if available. NFPA designations are provided for of these two levels of expertise. Not all of the statements all materials. In the case where NFPA designations were not listed may be appropriate for every situation, but actions should available from NFPA 49 or 325, values were assigned by the not be more aggressive than those listed. The most important authors using NFPA 49 definitions along with available data recommendations are given first. Remember that these are on the material or on structurally similar materials. NFPA 704 initial recommendations for the first responder. They may be designations taken from NFPA sources are shown in green modified by the on-scene Hazmat Incident Commander. while the those assigned by the authors are in black. Awareness Level Response actions are all defensive in nature. Operational Level Response actions are divided into two general situations, those involving releases of material without an accompanying fire and those where a fire is involved, whether or not the material itself is burning. Operational Level Responders must remember that actions listed under Awareness and Operational Level Response should be completed before beginning the more definitive Operational Level Response actions. At the bottom of the page is a First Aid section. These recommendations should be used in caring for victims who are out of the Hot zone. Rescue of victims from within a Hot zone should only be performed by trained personnel wearing appropriate chemical resistant gear and is not generally a first responder action. Removal of hazardous material from the skin, eyes or clothing of a victim (decontamination) is usually the most important first aid action that can be initiated. It should be performed only by appropriately trained and equipped individuals. Rapid removal of the material may be the difference between a minor injury and a serious injury. The details of decontamination techniques are beyond the scope of this book. In general, using large quantities of water to rinse off materials is almost always the first choice for decontamination in the field. Materials which are so toxic that first aid should not be performed on contaminated victims because of the risk of serious injury to the responder are clearly labeled. There are very few antidotes for treating victims exposed to chemicals and they are listed in this section for the benefit of hospital personnel who may care for these victims. Other First Aid information is also provided. Finally, at the middle of the page below the first aid section is a CHEMICAL ABSTRACTS SERVICE REGISTRY NUMBER (CAS: _ _ _-_ _-_). This is a specific identifying number given to each chemical by the Chemical Abstract Service. Mixtures are usually not assigned CAS numbers. While not commonly used in shipping, the CAS number may be found on containers and Material Safety Data Sheets (MSDS) and is used by many 3
  • 9. Figure 1. HYDROGEN CYANIDE 4 (STABILIZED) 4 2 UN 1051 Shipping Name: Hydrogen cyanide, stabilized with less than 3 percent water PA Other Names: AC Hydrocyanic acid solution NF HCN Prussic acid Hydrocyanic acid WARNING! POISON! BREATHING THE VAPORS OR SKIN CONTACT CAN KILL YOU! Firefighting gear (including SCBA) provides NO protection. If exposure occurs, remove and isolate gear immediately and thoroughly decontaminate personnel EXTREMELY FLAMMABLE! Hazards: Description: Odor is not a reliable indicator of the presence of toxic Colorless liquid that boils at 78˚ F amounts of vapor Sweet odor like bitter almonds; many people cannot smell it May react with itself without warning with explosive Dissolves slowly in water but is soluble in water violence Extremely flammable Container may BLEVE or explode when exposed to fire Vapors are slightly lighter than air but will collect and stay Vapors may travel long distances to ignition sources and in low areas flashback Transported in red and white candy striped containers Vapors in confined areas (e.g., tanks, sewers, buildings) Produces large amounts of vapor may explode when exposed to fire Freezes at 8˚ F Vapors are slightly lighter than air but will collect and stay Operational Level Training Response: in low areas RELEASE, NO FIRE: Combustion products are less toxic than the material itself Stop the release if it can be done safely from a distance Awareness and Operational Level Training Use large amounts of water well away from the material to Response: disperse vapors - contain runoff DO NOT ATTEMPT RESCUE! Ventilate confined area if it can be done without placing Stay upwind and uphill personnel at risk Determine the extent of the problem FIRE: BACK OFF! - Isolate a wide area around the release or If material is on fire and conditions permit, DO NOT fire, deny entry and call for expert help EXTINGUISH; combustion products are less toxic then the Remove all ignition sources original material. Cool exposures using unattended monitors. For container exposed to fire evacuate the area in all Specially trained personnel operating from a safe distance directions because of the risk of BLEVE or explosion can fight fires using alcohol resistant (AFFF) foam or dry Evacuate the immediate area and downwind for a large chemical if available in sufficient amounts. Under favorable release conditions, experienced crews can use coordinated fog Notify local health and fire officials and pollution control streams to sweep the flames off the surface of the burning agencies liquid. Do not direct straight streams into the liquid. If material or contaminated runoff enters waterways, notify Cool exposed containers with large quantities of water downstream users of potentially contaminated water from unattended equipment or remove intact containers if it can be done safely If cooling streams are ineffective (unvented container distorts, bulges or shows any other signs of expanding), withdraw immediately to a secure location First Aid: DO NOT ATTEMPT RESCUE! The contaminated victim poses a health risk to the responder Decontaminate the victim from a safe distance with a stream of water; have the victim remove clothing if possible; provide Basic Life Support/CPR as needed Decontaminate the victim as follows: Inhalation - remove the victim to fresh air and give oxygen if available Skin - remove and isolate contaminated clothing (including shoes) and wash skin with soap and large volumes of water for 15 minutes Eye - rinse eyes with large volumes of water or saline for 15 minutes Swallowed - do not make the victim vomit Victims should be examined by a physician as soon as possible Toxic effects may be delayed Do NOT perform direct mouth to mouth resuscitation; use a bag/mask apparatus Note to physician: can produce cyanide toxicity; if symptoms indicate, initial treatment includes the cyanide antidote kit CAS: 74-90-8 4
  • 10. References 1. North American Emergency Response Guide, 1996 16. R.J. Lewis, SAX’s Dangerous Properties of Industrial Edition, U.S. Department of Transportation, Washington, Materials, 8th Edition (1992), Van Nostrand Reinhold, DC. New York, NY. 2. The Merck Index, 12th Edition (1996), Merck and Co., 17. R.J. Lewis, Hazardous Chemicals Desk Reference, 3rd Inc., Rahway, NJ. Edition (1993), Van Nostrand Reinhold, New York, NY. 3. Emergency Handling of Hazardous Materials in Surface 18. A Guide to Fire Hazard Properties of Flammable Liquids, Transportation (1992), American Association of Gases and Volatile Solids, ANSI/NFPA 325 (1994), Railroads, Washington, DC. National Fire Protective Association, Quincy, MA. 4. Emergency Action Guide (1995), American Association 19. Hazardous Chemicals Data, ANSI/NFPA 49 (1994), of Railroads, Washington, DC. National Fire Protective Association, Quincy, MA. 5. Chemical Hazards Response Information System, 20. Code of Federal Regulations 49 Transportation (1996), Hazardous Chemical Data Manual, Vol. II (1993), U.S. Office of Federal Register National Archives and Records Department of Transportation, U.S. Coast Guard, Administration, Washington, DC. Washington, DC. 21. Chemical/Biological Incident Handbook, (1995), The 6. NIOSH Pocket Guide to Chemical Hazards (1990), U.S. Director of Central Intelligence Committee on Terrorism/ Department of Health and Human Services, Community Counterterrorism Board. Washington, DC. 7. L. Bretherick, Bretherick’s Handbook of Reactive Chemical Hazards, 4th Edition (1990), Butterworth- Heinemann, Ltd., Boston, MA. 8. Tomes Plus (1995), Micromedex, Denver, CO. 9. CAMEO (1990), U.S. Environmental Protection Agency, National Oceanic and Atmospheric Administration, National Safety Council, Washington, DC. 10. Fire Protection Guide to Hazardous Materials; 10th Edition (1991), National Fire Protection Association, Quincy, MA. 11. Responding to Hazardous Materials Incidents, ANSI/ NFPA 473 (1992), National Fire Protective Association, Quincy, MA. 12. Responders to Hazardous Materials Incidents, ANSI/ NFPA 472 (1992), National Fire Protective Association, Quincy, MA. 13. Identification of the Fire Hazards of Materials, ANSI/ NFPA 704 (1990), National Fire Protective Association, Quincy, MA. 14. Field Guide to Tank Care Identification (1992), Association of American Railroads, Washington, D.C. 15. Hazardous Materials Response Handbook, 2nd Edition (1993), National Fire Protective Association, Quincy, MA. 5
  • 11. Alphabetical Material Name Index A J S B K T C L U D M V E N W F O X G P Y H Q Z I R Click on letter to go to section
  • 12. Alphabetical Material Index A-150 .......................................................................... 476 Acrylic acid .................................................................. 62 AA ................................................................................ 67 Acrylic acid chloride ..................................................... 64 AC .............................................................................. 285 Acrylic acid, butyl ester .............................................. 114 Acetaldehyde ................................................................ 51 Acrylic acid, ethyl ester .............................................. 231 Acetaldehyde cyanohydrin ......................................... 305 Acrylic acid, methyl ester ........................................... 321 Acetaldehyde ethylacetal .............................................. 50 Acrylic amide ................................................................ 61 Acetamide ................................................................... 482 Acrylonitrile ................................................................... 63 Acetene ...................................................................... 243 Acryloyl chloride ........................................................... 64 Acetic acid .................................................................... 52 Acrylyl chloride ............................................................. 64 Acetic acid anhydride ................................................... 53 Actidione ..................................................................... 171 Acetic acid bromide ...................................................... 57 Actidone ..................................................................... 171 Acetic acid chloride ...................................................... 58 Adipic acid .................................................................. 482 Acetic acid dimethylamide .......................................... 206 Adipic acid dinitrile ....................................................... 65 Acetic acid, ethinyl ester ............................................. 468 Adiponitrile .................................................................... 65 Acetic acid, methyl ester ............................................. 319 Agent T ....................................................................... 482 Acetic acid, n-butyl ester ............................................ 113 Alachlor ...................................................................... 482 Acetic acid, n-propyl ester .......................................... 408 Alcide ......................................................................... 140 Acetic acid, vinyl ester ................................................ 468 Aldicarb ........................................................................ 66 Acetic aldehyde ............................................................ 51 Aldifen ........................................................................ 223 Acetic anhydride ........................................................... 53 Aldrin .......................................................................... 482 Acetic chloride .............................................................. 58 Algrain ........................................................................ 232 Acetic ester ................................................................ 230 Alkyl benzene sulfonic acids ....................................... 482 Acetic ether ................................................................ 230 Allene .......................................................................... 482 Acetoacetone .............................................................. 381 Allene-methyl acetylene mixture .................................. 320 Acetocyanohydrin ......................................................... 55 Allethrin ....................................................................... 482 Acetocyanohydrin ....................................................... 305 Allyl acetate ................................................................ 482 Acetol ........................................................................... 50 Allyl al ........................................................................... 67 Acetone ........................................................................ 54 Allyl alcohol ................................................................... 67 Acetone cyanohydrin .................................................... 55 Allyl aldehyde ................................................................ 60 Acetone thiosemicarbazide ......................................... 482 Allyl bromide ................................................................. 69 Acetonitrile .................................................................... 56 Allyl chloride ................................................................. 70 Allyl chlorocarbonate ..................................................... 71 Acetophenone ............................................................. 482 Ally chloroformate ......................................................... 71 1-Acetoxyethylene ...................................................... 468 Allyl ether .................................................................... 482 1-Acetoxypropane ....................................................... 408 Allyl ethyl ether ............................................................ 482 Acetyl acetone ............................................................ 381 Allyl iodide .................................................................. 482 Acetyl anhydride ........................................................... 53 Allyl isothiocyanate ..................................................... 482 Acetyl bromide .............................................................. 57 Allylamine ..................................................................... 68 Acetyl chloride .............................................................. 58 Allylic alcohol ................................................................ 67 Acetyl ether .................................................................. 53 Allyltrichlorosilane ......................................................... 72 Acetyl ketene .............................................................. 204 alpha-Bromotoluene ...................................................... 95 Acetyl oxide .................................................................. 53 alpha-Chlorobenzaldehyde ............................................ 94 Acetyl peroxide solution .............................................. 482 alpha-Chloropropionic ................................................. 155 2-Acetylaminofluorene ................................................ 482 alpha-Chlorotoluene ...................................................... 96 Acetylene ...................................................................... 59 alpha-Cumene hydroperoxide ..................................... 161 Acetylene dichloride ................................................... 186 alpha-Endosulfan ........................................................ 497 Acetylene tetrachloride ............................................... 438 alpha-Methacrylic acid ................................................ 313 Acetylene trichloride ................................................... 454 alpha-Methyl benzyl alcohol ........................................ 505 Acetylenogen .............................................................. 128 alpha-Methyl styrene ................................................... 299 Acetylsilicon trichloride ................................................. 72 alpha-Naphthylamine ................................................... 507 Acid ............................................................................ 155 alpha-Pinene ............................................................... 398 Acridine ...................................................................... 482 alpha-Tolunitrile ........................................................... 385 Acroleic acid ................................................................. 62 Aluminum (dust) .......................................................... 482 Acrolein ........................................................................ 60 Aluminum borohydride ................................................ 482 Acrylaldehyde .............................................................. 60 Aluminum chloride ...................................................... 482 Acrylamide .................................................................... 61 Aluminum fluoride ....................................................... 482 8
  • 13. Alphabetical Material Index Aluminum nitrate ......................................................... 482 Ammonium fluoborate ................................................. 483 Aluminum oxide ........................................................... 482 Ammonium fluoride ..................................................... 483 Aluminum phosphide ................................................... 482 Ammonium formate ..................................................... 483 Aluminum sulfate ......................................................... 482 Ammonium gluconate .................................................. 483 Aluminum, triisobutyl ................................................... 459 Ammonium hydroxide ................................................... 77 AMFO ........................................................................... 84 Ammonium hypophosphite .......................................... 483 Am-fol ........................................................................... 74 Ammonium iodide ....................................................... 483 Aminic acid ................................................................. 269 Ammonium lactate ....................................................... 483 1-Amino-2,4-dinitrobenzene ........................................ 220 Ammonium lauryl sulfate ............................................. 483 2-Amino-2-methyl-1-propanol ..................................... 482 Ammonium molybdate ................................................. 483 1-Amino-2-propanol .................................................... 298 Ammonium monosulfide ................................................ 79 4-Aminoazobenzene ................................................... 482 Ammonium nitrate ....................................................... 483 Aminobenzene .............................................................. 85 Ammonium nitrate fertilizers ........................................ 483 1-Aminobutane ............................................................ 116 Ammonium nitrate: fuel oil ............................................. 84 4-Aminobutyl diethoxymethyl silane ............................. 482 Ammonium nitrate-phosphate mixture ......................... 483 Aminocyclohexane ...................................................... 172 Ammonium nitrate-sulfate mixture ............................... 483 Aminoethane ............................................................... 233 Ammonium nitrate-urea solution .................................. 483 2-Aminoethanol ........................................................... 229 Ammonium oleate ....................................................... 483 2-(2-Aminoethoxy)ethanol ........................................... 482 Ammonium oxalate ...................................................... 483 Aminoethyl ethanol amine ........................................... 482 Ammonium pentaborate .............................................. 483 Aminoethylethandiamine ............................................. 198 Ammonium perchlorate .................................................. 78 Aminohexahydrobenzene ............................................ 172 Ammonium perchlorate high explosive .......................... 78 2-Aminoisobutane ....................................................... 117 Ammonium perchlorate oxidizer .................................... 78 Aminomethane ............................................................ 323 Ammonium permanganate .......................................... 483 Aminomethane ............................................................ 324 Ammonium persulfate ................................................. 483 4-Amino-N,N-dimethylaniline ....................................... 215 Ammonium phosphate ................................................. 483 2-Aminopentane .......................................................... 195 Ammonium picrate (wet) ............................................. 483 Aminophen .................................................................... 85 Ammonium rhodanate ................................................... 81 2-Aminopropane ......................................................... 300 Ammonium silicofluoride ............................................. 483 3-Aminopropene ........................................................... 68 Ammonium stearate .................................................... 483 4-Aminopropiophenone ............................................... 482 Ammonium sulfamate .................................................. 483 3-Aminopropylene ......................................................... 68 Ammonium sulfate ....................................................... 483 4-Aminopyridine ........................................................... 73 Ammonium sulfide ......................................................... 79 Aminopyridines ............................................................. 73 Ammonium sulfite .......................................................... 80 Aminotoluene .............................................................. 451 Ammonium sulfocyanide ............................................... 81 Amiton ........................................................................ 482 Ammonium sulphite ....................................................... 80 Amiton oxalate ............................................................. 482 Ammonium tartrate ...................................................... 483 Amitrole ...................................................................... 482 Ammonium thiocyanate ................................................. 81 Ammonia ....................................................................... 74 Ammonium thiosulfate ................................................. 483 Ammonia monohydrate ................................................. 77 AMS ............................................................................ 299 Ammonia solution .......................................................... 77 Amthio .......................................................................... 81 Ammonia water ............................................................. 77 Amyl alcohol ................................................................. 82 Ammonia, anhydrous .................................................... 74 Amyl methyl ketone ..................................................... 325 Ammonium acetate ..................................................... 483 Amyl phthalate ............................................................ 484 Ammonium aminoformate ............................................. 76 Amylol ........................................................................... 82 Ammonium benzoate ..................................................... 75 Amyltricholorsilane ........................................................ 83 Ammonium bicarbonate .............................................. 483 AN/FO ........................................................................... 84 Ammonium bifluoride .................................................. 483 Anhydrol ..................................................................... 232 Ammonium bisulfite ..................................................... 483 Anhydrous ammonia ..................................................... 74 Ammonium bromide .................................................... 483 Anhydrous ethanol ...................................................... 232 Ammonium carbamate .................................................. 76 Anhydrous hydrobromic acid ...................................... 283 Ammonium carbonate ................................................. 483 Anhydrous hydrofluoric acid ....................................... 286 Ammonium chloride .................................................... 483 Aniline ........................................................................... 85 Ammonium chromate .................................................. 483 Aniline oil ...................................................................... 85 Ammonium citrate ....................................................... 483 Anisole ........................................................................ 484 Ammonium dichromate ............................................... 483 Anisoyl chloride .......................................................... 484 9
  • 14. Alphabetical Material Index Anone ......................................................................... 170 Barium peroxide .......................................................... 485 Ansul ether 121 ........................................................... 205 BCME ......................................................................... 188 Anthion ....................................................................... 401 BD .............................................................................. 111 Anthracene ................................................................. 484 Benomyl ...................................................................... 485 Antimony (powder) ...................................................... 484 Bentazon ..................................................................... 485 Antimony pentachloride .............................................. 484 Benzal chloride ............................................................. 98 Antimony pentafluoride ............................................... 484 Benzaldehyde ............................................................... 88 Antimony potassium tartrate ........................................ 484 Benzalmalonoitrile ....................................................... 145 Antimony tribromide .................................................... 484 Benzamide .................................................................... 89 Antimony trichloride .................................................... 484 Benzenamine ................................................................ 85 Antimony trifluoride ..................................................... 484 Benzene ....................................................................... 90 Antimony trioxide ........................................................ 484 Benzene arsonic acid ................................................. 485 ANTU .......................................................................... 484 Benzene chloride ........................................................ 147 Aqua fortis .................................................................. 361 Benzene fluoride ......................................................... 264 Aqueous ammonia ........................................................ 77 Benzene hexachloride ................................................. 485 Aramite ....................................................................... 484 Benzene methylal .......................................................... 88 Arctic .......................................................................... 331 Benzene nitro ............................................................. 263 Argon .......................................................................... 484 Benzene phosphorous dichloride ................................ 388 Arsenic ....................................................................... 484 Benzene sulfonyl chloride ........................................... 485 Arsenic acid ............................................................... 484 Benzeneacetonitrile .................................................... 385 Arsenic butter ............................................................... 86 Benzenecarbonal .......................................................... 88 Arsenic chloride ............................................................ 86 Benzenecarbonyl chloride ............................................ 94 Arsenic dichloroethane ............................................... 241 Benzenehexahydride .................................................. 169 Arsenic disulfide ......................................................... 484 Benzenenitrile ............................................................... 91 Arsenic hydride ............................................................ 87 Benzenethiol ............................................................... 387 Arsenic pentoxide ....................................................... 484 Benzenol ..................................................................... 384 Arsenic trichloride ......................................................... 86 Benzidine .................................................................... 485 Arsenic trihydride ......................................................... 87 Benzin ........................................................................ 258 Arsenic trioxide ........................................................... 484 Benzo (A) anthracene ................................................. 485 Arsenic trisulfide ......................................................... 484 Benzo (A) pyrene ....................................................... 485 Arsenous chloride ......................................................... 86 Benzo (B) fluoranthene ............................................... 485 Arsenous trichloride ...................................................... 86 Benzo (GHI) perylene ................................................. 485 Arsine ........................................................................... 87 Benzoic acid ............................................................... 485 Asbestos ..................................................................... 484 Benzoic acid amide ...................................................... 89 Asphalt ........................................................................ 484 Benzoic aldehyde ......................................................... 88 Asphalt blending stocks: roofers flux ........................... 484 Benzoic trichloride ........................................................ 93 Asphalt blending stocks: straight run residue .............. 484 Benzol ........................................................................... 90 asym-Dimethylhydrazine ............................................. 214 Benzonitrile ................................................................... 91 Atrazine ...................................................................... 484 Benzophenone ............................................................ 485 Auramine .................................................................... 484 Benzoquinone ............................................................... 92 Avitrol ............................................................................ 73 1,4-Benzoquinone ......................................................... 92 Azabenzene ................................................................ 415 Benzotrichloride ............................................................ 93 Azacyclohexane .......................................................... 399 Benzoyl chloride ........................................................... 94 Azacyclopropane ........................................................ 253 Benzoyl peroxide ........................................................ 485 Azide .......................................................................... 419 Benzoylamide ............................................................... 89 Azine .......................................................................... 415 Benzyl acetate ............................................................ 485 Azirane ....................................................................... 253 Benzyl alcohol ............................................................. 485 Aziridine ..................................................................... 253 Benzyl amine .............................................................. 485 Azophos ...................................................................... 349 Benzyl bromide ............................................................. 95 Barium ........................................................................ 485 Benzyl carbonyl chloride ............................................... 97 Barium carbonate ....................................................... 485 Benzyl chloride ............................................................. 96 Barium chlorate .......................................................... 485 Benzyl chlorocarbonate ................................................ 97 Barium cyanide .......................................................... 485 Benzyl chloroformate .................................................... 97 Barium nitrate ............................................................. 485 Benzyl cyanide ........................................................... 385 Barium perchlorate ..................................................... 485 Benzyl dichloride .......................................................... 98 Barium permanganate ................................................. 485 Benzyl dimethyl amine ................................................ 485 10
  • 15. Alphabetical Material Index Benzyl dimethyl octadecyl ammonium chloride ........... 485 Black powder, pellets .................................................. 486 Benzyl ether ................................................................ 178 Bladan ........................................................................ 377 Benzyl iodide .............................................................. 485 Bladan-M .................................................................... 349 Benzyl nitrile ............................................................... 385 Blasting oil .................................................................. 366 Benzyl oxide ............................................................... 178 Bleach ........................................................................ 422 Benzyl trichloride .......................................................... 93 Blue oil .......................................................................... 85 Benzyl trimethyl ammonium chloride ........................... 485 Bolero ......................................................................... 486 Benzyl violet ................................................................ 485 Bondolane A ............................................................... 427 Benzylene chloride ....................................................... 98 Bonoform .................................................................... 438 Benzylidene chloride ..................................................... 98 Boric acid ................................................................... 486 Beryllium ..................................................................... 485 Borneol ....................................................................... 486 Beryllium chloride ....................................................... 485 Boroethane ................................................................. 179 Beryllium fluoride ........................................................ 485 Boron bromide ............................................................ 100 Beryllium nitrate .......................................................... 485 Boron chloride ............................................................ 101 Beryllium oxide ............................................................ 485 Boron fluoride ............................................................. 102 Beryllium sulfate .......................................................... 485 Boron hydride ............................................................. 177 beta-Butyrolactone ...................................................... 487 Boron hydride ............................................................. 179 beta-Chloroprene ........................................................ 154 Boron hydride ............................................................. 378 beta-Endosulfan .......................................................... 497 Boron tribromide ......................................................... 100 beta-Methyl acrolein .................................................... 160 Boron trichloride ......................................................... 101 beta-Propiolactone ...................................................... 405 Boron trifluoride .......................................................... 102 BHA ............................................................................ 485 Boron trifluoride: dimethyl etherate ............................. 486 BHC, alpha- ................................................................ 485 Bottled gas .................................................................. 308 BHC, beta- .................................................................. 485 BPL ............................................................................ 405 BHC, delta- ................................................................. 486 Brimstone ................................................................... 428 BHC, gamma- ............................................................. 486 Brom ........................................................................... 103 BIC ............................................................................. 121 Bromacil ..................................................................... 486 Bicylcopentadiene ...................................................... 192 Bromadiolone .............................................................. 486 Biethylene ................................................................... 111 Bromide fluoride ......................................................... 104 Bimethyl ...................................................................... 228 Bromine ...................................................................... 103 Biocide ......................................................................... 60 Bromine chloride ......................................................... 486 Biogas ........................................................................ 315 Bromine cyanide ......................................................... 164 Bioxirane ..................................................................... 193 Bromine fluoride ......................................................... 105 Biphenyl ...................................................................... 486 Bromine pentafluoride ................................................. 104 Bis (chloromethyl) ketone ........................................... 181 Bromine trifluoride ...................................................... 105 Bis-(2-aminoethyl) amine ............................................ 198 3-Bromo-1-propene ...................................................... 69 Bis-(2-chloro-1-methyl ethyl) ether .............................. 486 1-Bromo-3-methylbutane ............................................. 486 Bis-(2-chloroethoxy) methane ..................................... 486 Bromoacetic acid ........................................................ 486 Bis-(2-chloroethyl) ether ............................................. 184 Bromoacetone ............................................................ 486 Bis-(2-chloroethyl) methylamine .................................. 311 Bromoacetyl bromide .................................................. 106 Bis-(2-chloroethyl) sulfide ............................................ 99 Bromoallylene ............................................................... 69 Bis-(2-chloroisopropyl) ether ...................................... 486 Bromobenzene ............................................................ 107 Bis-(2-ethyl hexyl) adipate .......................................... 486 1-Bromobutane ........................................................... 108 Bis-(2-ethyl hexyl) phthalate ........................................ 486 2-Bromobutane ........................................................... 486 Bis-(chloromethyl) ether ............................................. 188 Bromochloromethane .................................................. 486 Bismuth oxychloride .................................................... 486 Bromocyan ................................................................. 164 Bis-O,O-diethylpyrophosphoric anhydride .................. 441 Bromoethanoyl bromide .............................................. 106 Bisphenol A ................................................................ 486 Bromoethene .............................................................. 469 Bisphenol A diglycidyl ether ........................................ 486 2-Bromoethyl ethyl ether ............................................. 486 Bisulfite ....................................................................... 430 Bromoethylene ............................................................ 469 Bithionol ...................................................................... 486 Bromoform .................................................................. 486 Bitoscanate ................................................................. 486 Bromofume ................................................................. 247 Bivinyl ......................................................................... 111 Brom-O-Gas ............................................................... 326 B-K Liquid ................................................................... 422 Bromomethane ............................................................ 326 Black powder, compressed ......................................... 486 2-Bromopentane ......................................................... 486 Black powder, granular ............................................... 486 4-Bromophenyl phenyl ether ....................................... 486 11
  • 16. Alphabetical Material Index Bromophenylmethane ................................................... 95 2,3-Butylene oxide ...................................................... 487 1-Bromopropane ......................................................... 486 Butylethylamine ........................................................... 236 2-Bromopropane ......................................................... 109 Butylsilicon trichloride ................................................. 123 3-Bromopropylene ........................................................ 69 Butyltrichlorosilane ...................................................... 123 Bromopropyne ............................................................ 110 2-Butyne-1,4-diol ........................................................ 124 3-Bromopropyne ......................................................... 110 Butynediol ................................................................... 124 Bromotrifluoroethylene ................................................ 486 1,4-Butynediol ............................................................. 124 Bromotrifluoromethane ................................................ 486 2-Butynediol ................................................................ 124 Brucine ....................................................................... 487 Butyral ........................................................................ 125 Butadiene ................................................................... 111 Butyraldehyde ............................................................. 125 1,3-Butadiene ............................................................. 111 Butyric acid chloride ................................................... 127 Butadiene diepoxide .................................................... 193 Butyric acid nitrile ....................................................... 126 Butadiene dioxide ....................................................... 193 Butyric acid, ethyl ester .............................................. 237 Butal ........................................................................... 125 Butyric acid, methyl ester ........................................... 330 Butaldehyde ................................................................ 125 Butyric aldehyde ......................................................... 125 Butanal ........................................................................ 125 Butyric chloride .......................................................... 127 Butane ........................................................................ 112 Butyronitrile ................................................................ 126 Butane nitrile ............................................................... 126 Butyryl chloride ........................................................... 127 Butanedione ................................................................ 487 BZCF ............................................................................ 97 Butanethiol .................................................................. 122 C.I. acid blue 9, diammonium salt ............................... 490 1-Butanethiol ............................................................... 122 C.I. acid blue 9, disodium salt ..................................... 490 2-Butanone ................................................................. 338 C.I. acid green 3 ......................................................... 490 Butanoyl chloride ........................................................ 127 C.I. basic green 4 ....................................................... 490 3-Buten-2-one ............................................................. 356 C.I. basic red 1 ........................................................... 490 2-Butenal .................................................................... 160 C.I. disperse yellow 3 ................................................. 490 Butene ........................................................................ 118 C.I. food red 15 .......................................................... 490 1-Butene oxide ............................................................ 119 C.I. food red 5 ............................................................ 490 1,4-Butenediol ............................................................. 487 C.I. solvent orange 7 ................................................... 490 3-Buteno-beta-lactone ................................................. 204 C.I. solvent yellow 14 .................................................. 490 1-Butyl acetate ............................................................ 113 C.I. solvent yellow 3 .................................................... 490 Butyl acid phosphate ................................................... 487 C.I. vat yellow 4 .......................................................... 490 Butyl acrylate .............................................................. 114 Cacodylic acid ............................................................ 487 Butyl alcohol ............................................................... 115 Cadmium acetate ........................................................ 487 Butyl aldehyde ............................................................ 125 Cadmium bromide ....................................................... 487 Butyl benzyl phthalate ................................................. 487 Cadmium chloride ....................................................... 487 Butyl bromide .............................................................. 108 Cadmium fluoroborate ................................................. 487 Butyl butyrate .............................................................. 487 Cadmium nitrate .......................................................... 487 Butyl chloride .............................................................. 148 Cadmium oxide ........................................................... 487 Butyl ethanoate ........................................................... 113 Cadmium stearate ....................................................... 487 Butyl ether .................................................................. 487 Cadmium sulfate ......................................................... 487 Butyl ethylene ............................................................. 277 Cadmium(powder) ...................................................... 487 Butyl isocyanate ......................................................... 121 CADOXTHB................................................................. 120 Butyl isovalerate .......................................................... 487 CAF ............................................................................ 144 Butyl mercaptan .......................................................... 122 Calcium ...................................................................... 488 Butyl methyl ether ....................................................... 487 Calcium acetylide ....................................................... 128 Butyl nitrite .................................................................. 487 Calcium arsenite ......................................................... 488 Butyl toluene ............................................................... 487 Calcium carbide .......................................................... 128 Butyl, decyl, cetyl-eicosyl methacrylate ...................... 487 Calcium chlorate ......................................................... 488 Butyl-2-propenoate ..................................................... 114 Calcium chloride ......................................................... 488 Butylacetic acid .......................................................... 129 Calcium chromate ....................................................... 488 Butylacetone ............................................................... 325 Calcium cyanide ......................................................... 488 Butylamine .................................................................. 116 Calcium fluoride .......................................................... 488 Butylated hydroxyanisole ............................................ 487 Calcium hydride .......................................................... 489 Butylene ...................................................................... 118 Calcium hydroxide ...................................................... 488 1,2-Butylene oxide ...................................................... 119 Calcium hypochlorite .................................................. 488 1-Butylene oxide ......................................................... 119 Calcium nitrate ............................................................ 488 12
  • 17. Alphabetical Material Index Calcium oxide ............................................................. 488 Carbonic oxide ............................................................ 134 Calcium peroxide ........................................................ 488 Carbonochloride acid, ethyl ester ............................... 240 Calcium phosphate ..................................................... 488 Carbonyl chloride ....................................................... 390 Calcium phosphide ..................................................... 489 Carbonyl fluoride ........................................................ 136 Calcium resinate ......................................................... 488 Carbonyl sulfide .......................................................... 137 Camphene .................................................................. 488 Carene ........................................................................ 488 Camphor oil ................................................................ 488 Casing head gasoline ................................................. 272 Cantharidin ................................................................. 488 Castor oil, edible ......................................................... 488 CAP ............................................................................ 144 Caswell No 805 ........................................................... 424 Caproic acid ............................................................... 129 Catechol ..................................................................... 488 Caprolactam ............................................................... 488 Caustic potash solution ............................................... 488 Capronic acid ............................................................. 129 Caustic soda ............................................................... 421 Caprylene ................................................................... 373 Caustic soda, solution ................................................. 421 Capsicum ................................................................... 488 Cellon ......................................................................... 438 Capsine ...................................................................... 222 Certox ......................................................................... 424 Captan ........................................................................ 488 Cesium ....................................................................... 489 Carbachol ................................................................... 130 CHA ............................................................................ 172 Carbachol chloride ...................................................... 130 Chloral ........................................................................ 138 Carbacholin ................................................................ 130 Chlorallylene ................................................................. 70 Carbacholine dichloride .............................................. 130 Chloramben ................................................................ 488 Carbacryl ...................................................................... 63 Chlorbisan .................................................................. 488 Carbamic acid, ammonium salt ..................................... 76 Chlordane, flammable liquid ........................................ 488 Carbamide peroxide .................................................... 466 Chlordecone ............................................................... 488 Carbamiotin ................................................................ 130 Chlorex ....................................................................... 184 Carbamoyl dimethyl chloride ....................................... 209 Chlorfenvinfos ............................................................. 488 Carbamyl ...................................................................... 66 Chloride of phosphorus ............................................... 396 Carbaryl (solid) ........................................................... 488 Chlorine ...................................................................... 139 Carbide ....................................................................... 128 Chlorine cyanide ......................................................... 165 Carbinol ...................................................................... 318 Chlorine dioxide .......................................................... 140 Carbofuran ................................................................. 131 Chlorine dioxide hydrate ............................................. 140 Carbolic acid .............................................................. 384 Chlorine dioxide hydrate (frozen) ................................ 140 Carbolic oil .................................................................. 488 Chlorine fluoride ......................................................... 141 Carbon bisulfide .......................................................... 133 Chlorine monoxide ...................................................... 489 Carbon chloride .......................................................... 135 Chlorine pentafluoride ................................................. 489 Carbon dichloride oxide .............................................. 390 Chlorine peroxide ........................................................ 140 Carbon difluoride ........................................................ 136 Chlorine sulfide ........................................................... 429 Carbon dioxide ............................................................ 132 Chlorine trifluoride ...................................................... 141 Carbon disulfide .......................................................... 133 Chlormephos ............................................................... 489 Carbon disulphide ....................................................... 133 Chlormequat chloride .................................................. 489 Carbon monoxide ........................................................ 134 Carbon nitride ............................................................. 163 2-Chlorobenzylidine malononitrile............................... 145 Carbon oxide .............................................................. 134 Chloro methyl sulfane ................................................. 316 Carbon oxide sulfide ................................................... 137 Chloro(chloromethoxy) methane ................................. 188 Carbon oxychloride ..................................................... 390 2-Chloro-1,3-butadiene ............................................... 154 Carbon oxyfluoride ...................................................... 136 2-Chloro-1-ethanol ...................................................... 244 Carbon oxysulfide ....................................................... 137 4-Chloro-1-methylbenzene .......................................... 158 Carbon sulfide ............................................................ 133 1-Chloro-1-propene .................................................... 489 Carbon tet ................................................................... 135 1-Chloro-2,3-epoxypropane ........................................ 227 Carbon tetrachloride ................................................... 135 1-Chloro-2-cyanoethane ............................................. 156 Carbona ...................................................................... 135 1-Chloro-2-nitrobenzene ............................................. 151 Carbonic acid anhydride ............................................ 132 1-Chloro-4-methylbenzene .......................................... 158 Carbonic acid gas ...................................................... 132 10-Chloro-5,10-dihydrophenarsazine (DM) ................ 489 Carbonic acid, diethyl ester ........................................ 197 Chloroacetaldehyde .................................................... 142 Carbonic anhydride .................................................... 132 2-Chloroacetaldehyde ................................................. 142 Carbonic difluoride oxide ............................................ 136 Chloroacetaldehyde monomer .................................... 142 Carbonic ether ............................................................ 197 Chloroacetaphenone ................................................... 144 13
  • 18. Alphabetical Material Index Chloroacetic acid ........................................................ 489 1-Chloropropane ......................................................... 489 Chloroacetic acid chloride .......................................... 146 2-Chloropropane ......................................................... 489 Chloroacetic acid, ethyl ester ..................................... 239 3-Chloropropanenitrile ................................................ 156 Chloroacetic acid, methyl ester ................................... 332 Chloropropene .............................................................. 70 Chloroacetic chloride .................................................. 146 2-Chloropropene ......................................................... 489 Chloroacetone, stabilized ............................................ 489 3-Chloropropene ........................................................... 70 Chloroacetonitrile ........................................................ 143 Chloropropham ........................................................... 489 Chloroacetyl chloride .................................................. 146 2-Chloropropionic acid ............................................... 155 2-Chloroacrylic acid, methyl ester .............................. 333 3-Chloropropionitrile ................................................... 156 Chloroaldehyde ........................................................... 142 3-Chloropropyl octyl sulfoxide ..................................... 489 Chlorobenzene ............................................................ 147 Chloropropylene ........................................................... 70 Chlorobenzilate ........................................................... 489 1-Chloropropylene ...................................................... 489 2-Chlorobuta -1,3-diene .............................................. 154 Chloropropylene oxide ................................................ 227 Chlorobutadiene .......................................................... 154 Chlorosulfane .............................................................. 432 Chlorobutane .............................................................. 148 Chlorosulfonic acid ..................................................... 157 1-Chlorobutane ........................................................... 148 Chlorosulfuric acid ...................................................... 157 2-Chlorobutane ........................................................... 489 Chlorothalonil .............................................................. 489 Chlorocarbonic acid, ethyl ester ................................. 240 Chlorotoluene .............................................................. 158 Chlorocyan ................................................................. 165 3-Chlorotoluene .......................................................... 489 Chlorocyanogen ......................................................... 165 4-Chlorotoluene .......................................................... 158 Chlorodibromomethane ............................................... 489 Chlorotrifluoride .......................................................... 141 Chlorodifluoromethane ................................................ 489 Chlorotrifluoroethane ................................................... 489 Chloroethanal .............................................................. 142 Chlorotrifluoroethylene ................................................ 458 2-Chloroethanal .......................................................... 142 Chlorotrifluoromethane ................................................ 490 Chloroethane .............................................................. 238 Chlorotrimethylsilane ................................................... 462 Chloroethane .............................................................. 453 Chlorovinylarsine dichloride ........................................ 306 2-Chloroethane sulfonyl chloride ................................. 489 Chlorovinyldichloroarsine ............................................ 306 Chloroethanenitrile ...................................................... 143 Chloroxuron ................................................................ 490 Chloroethanol .............................................................. 244 Chlorpyrifos ................................................................ 159 2-Chloroethanol .......................................................... 244 Chlorthiophos .............................................................. 490 Chloroethene .............................................................. 470 Chlorylen .................................................................... 453 2-Chloroethyl chlorocarbonate .................................... 149 Choline chloride carbamate ........................................ 130 2-Chloroethyl vinyl ether ............................................. 489 Chloroethylene ............................................................ 470 Chromic acetate ......................................................... 490 Chloroform .................................................................. 150 Chromic acid .............................................................. 490 Chloroformate ............................................................. 149 Chromic anhydride ..................................................... 490 Chloroformic acid, isopropyl ester .............................. 302 Chromic sulfate ........................................................... 490 Chloroformyl chloride .................................................. 390 Chromium (dust) ......................................................... 490 Chlorohydrins ............................................................. 489 Chromium oxychloride ................................................ 490 Chloromethane ............................................................ 331 Chromous chloride ...................................................... 490 (Chloromethyl) benzene ............................................... 96 Chrysene .................................................................... 490 Chloromethyl cyanide ................................................. 143 Cinnamenol ................................................................. 425 Chloromethyl ether ...................................................... 188 cis-Butene .................................................................. 118 Chloromethyl ethyl ether ............................................. 489 Citric acid ................................................................... 490 Chloromethyl methyl ether ........................................... 489 Citrus red No. 2 .......................................................... 490 1-(Chloromethyl)-4-nitrobenzene ................................ 489 CK .............................................................................. 165 Chloromethyloxirane ................................................... 227 Clorox ......................................................................... 422 2-Chloronaphthalene ................................................... 489 CN .............................................................................. 144 Chloronitrobenzene ..................................................... 151 CO .............................................................................. 134 Chlorophenyl methane .................................................. 96 Coal gas ..................................................................... 490 4-Chlorophenyl phenyl ether ....................................... 489 Coal naphtha ................................................................. 90 2-Chlorophenylthiourea ............................................... 152 Coal oil ........................................................................ 304 Chloropicrin ................................................................ 153 Cobalt ......................................................................... 490 Chloropicrin: methyl chloride ...................................... 489 Cobalt acetate ............................................................. 490 Chloropivaloyl chloride ................................................ 489 Cobalt bromide ............................................................ 490 Chloroprene ................................................................ 154 Cobalt carbonyl ........................................................... 490 14