Dillon Walker

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Case Western Reserve University - College of Arts and Sciences

Hyper-Rayleigh Scattering

Dillon Walker, Guangyao Li, Ken Singer Hyper-Rayleigh Scattering NSF Grant DMR-0850037

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Light Scattering Phenomenon: The blue color of the sky and the red color of the sun at sunset result from scattering of light of small dust particles, H2O molecules and other gases in the atmosphere. The efficiency with which light is scattered depends on its wavelength(λ). The sky is blue because violet and blue light are scattered to a greater extent than other longer wavelengths. A clear cloudless day-time sky is blue because molecules in the air scatter blue light from the sun more than they scatter red light. When we look towards the sun at sunset, we see red and orange colours because the blue light has been scattered out and away from the line of sight. Scattered radiation: • Radiate scattering- second major spectral method of analysis. • In this technique some radiation that passes through a sample strikes particles of the analyte and is scattered in a different direction. • A detector is used to measure either the intensity of the scattered radiation or the decreased intensity of the incident radiation • Depending on the scattering mechanism, the method can be employed for either qualitative or quantitative analysis. For chemical analysis three forms of radiative scattering are important – viz. Tyndall, Raman, and Rayleigh scattering. Tyndall Scattering occurs when the dimensions of the particles that are causing the scattering are larger than the wavelength of the scattered radiation. It is caused by reflection of the incident radiation from the surfaces of the particles, reflection from the interior walls of the particles, and refraction and diffraction of the radiation as it passes through the particles. Scattering of light - by particles in a colloid or suspension. The longer-wavelength light is more transmitted while the shorter- wavelength light is more reflected via scattering Nephelometry & Turbidimetry: When electromagnetic radiation (light) strikes a particle in solution, some of the light will be absorbed by the particle, some will be transmitted through the solution and some of the light will be scattered or reflected . The amount of light scattered is proportional to the concentration of insoluble particle. In Nephelometry, the intensity of the scattered light is measured. In Turbidimetry, the intensity of light transmitted through the medium, the unscattered light, is measured. Light scattering is the physical phenomenon resulting from the interaction of light with a particles in solution Turbidimetry is involved with measuring the amount of transmitted light (and calculating the absorbed light) by particles in suspension to determine the concentration of the substance in question. Amount of absorbed light, and therefore, concentration is dependent on ; 1) number of particles, and 2) size of particles. • Measurements are made using light spectrophotometers Factors affecting on scattering of light: Concentration of particles Particle size Wavelength Distance of

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