SlideShare uma empresa Scribd logo
1 de 54
Chapter 5 Thermochemistry John D. Bookstaver St. Charles Community College Cottleville, MO Chemistry, The Central Science , 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
Energy ,[object Object],[object Object],[object Object]
Potential Energy ,[object Object]
Kinetic Energy ,[object Object],1 2 KE  =     mv 2
Units of Energy ,[object Object],[object Object],[object Object],1 J = 1   kg m 2 s 2
Definitions: System and Surroundings ,[object Object],[object Object]
Definitions: Work ,[object Object],[object Object],[object Object]
Heat ,[object Object],[object Object]
Conversion of Energy ,[object Object],[object Object]
Conversion of Energy ,[object Object],[object Object]
First Law of Thermodynamics ,[object Object],[object Object]
Internal Energy ,[object Object]
Internal Energy ,[object Object],[object Object]
Changes in Internal Energy ,[object Object],[object Object],[object Object]
Changes in Internal Energy ,[object Object],[object Object],[object Object]
Changes in Internal Energy ,[object Object],[object Object]
 E ,  q ,  w , and Their Signs
Exchange of Heat between System and Surroundings ,[object Object]
Exchange of Heat between System and Surroundings ,[object Object],[object Object]
State Functions ,[object Object]
State Functions ,[object Object],[object Object]
State Functions ,[object Object],[object Object],[object Object]
State Functions ,[object Object],[object Object],[object Object]
Work ,[object Object]
Work ,[object Object],[object Object]
Enthalpy ,[object Object],[object Object],H  =  E  +  PV
Enthalpy ,[object Object],[object Object],[object Object],[object Object]
Enthalpy ,[object Object],[object Object],[object Object],[object Object],[object Object]
Endothermicity and Exothermicity ,[object Object]
Endothermicity and Exothermicity ,[object Object],[object Object]
Enthalpy of Reaction ,[object Object],[object Object]
Enthalpy of Reaction ,[object Object]
The Truth about Enthalpy ,[object Object],[object Object],[object Object]
Calorimetry ,[object Object]
Heat Capacity and Specific Heat ,[object Object]
Heat Capacity and Specific Heat ,[object Object]
Heat Capacity and Specific Heat ,[object Object],Specific heat = heat transferred mass    temperature change s  = q m       T
Constant Pressure Calorimetry ,[object Object]
Constant Pressure Calorimetry ,[object Object],[object Object]
Bomb Calorimetry ,[object Object],[object Object]
Bomb Calorimetry ,[object Object],[object Object]
Hess’s Law ,[object Object],[object Object]
Hess’s Law ,[object Object]
Hess’s Law ,[object Object]
Enthalpies of Formation ,[object Object]
Standard Enthalpies of Formation ,[object Object]
Calculation of   H ,[object Object],[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l )
Calculation of   H ,[object Object],[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l )
Calculation of   H ,[object Object],[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l )
Calculation of   H ,[object Object],C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l ) C 3 H 8 ( g )    3 C  ( graphite )  + 4 H 2 ( g ) 3 C  ( graphite )  + 3 O 2 ( g )     3 CO 2 ( g )   4 H 2 ( g )  + 2 O 2 ( g )     4 H 2 O  ( l ) C 3 H 8 ( g )  + 5 O 2 ( g )     3 CO 2 ( g )  + 4 H 2 O  ( l )
Calculation of   H ,[object Object],[object Object],[object Object]
[object Object],[object Object],[object Object],Calculation of   H C 3 H 8 ( g )  + 5 O 2 ( g )    3 CO 2 ( g )  + 4 H 2 O  ( l )
Energy in Foods ,[object Object]
Energy in Fuels ,[object Object]

Mais conteúdo relacionado

Mais procurados

3 Enthalpy
3 Enthalpy3 Enthalpy
3 Enthalpy
janetra
 
Entropy ok1294987599
Entropy    ok1294987599Entropy    ok1294987599
Entropy ok1294987599
Navin Joshi
 
12 Entropy
12 Entropy12 Entropy
12 Entropy
janetra
 
Chemistry- JIB Topic 9 Thermochemistry
Chemistry- JIB Topic 9 ThermochemistryChemistry- JIB Topic 9 Thermochemistry
Chemistry- JIB Topic 9 Thermochemistry
Sam Richard
 
AP Chemistry Chapter 19 Outline
AP Chemistry Chapter 19 OutlineAP Chemistry Chapter 19 Outline
AP Chemistry Chapter 19 Outline
Jane Hamze
 

Mais procurados (19)

3 Enthalpy
3 Enthalpy3 Enthalpy
3 Enthalpy
 
Entropy ok1294987599
Entropy    ok1294987599Entropy    ok1294987599
Entropy ok1294987599
 
CHEMICAL THERMODYNAMICS (SPONTANEITY AND ENTROPY)
CHEMICAL THERMODYNAMICS (SPONTANEITY AND ENTROPY)CHEMICAL THERMODYNAMICS (SPONTANEITY AND ENTROPY)
CHEMICAL THERMODYNAMICS (SPONTANEITY AND ENTROPY)
 
12 Entropy
12 Entropy12 Entropy
12 Entropy
 
Chemistry- JIB Topic 9 Thermochemistry
Chemistry- JIB Topic 9 ThermochemistryChemistry- JIB Topic 9 Thermochemistry
Chemistry- JIB Topic 9 Thermochemistry
 
Thermodynamics
ThermodynamicsThermodynamics
Thermodynamics
 
Chemical Thermodynamics
Chemical Thermodynamics Chemical Thermodynamics
Chemical Thermodynamics
 
Fundamentals of Thermo-Chemistry
Fundamentals of Thermo-ChemistryFundamentals of Thermo-Chemistry
Fundamentals of Thermo-Chemistry
 
Enthalpy Hess's Law
Enthalpy Hess's LawEnthalpy Hess's Law
Enthalpy Hess's Law
 
Thermodynamics
ThermodynamicsThermodynamics
Thermodynamics
 
Standard Enthalpy Changes of Reactions
Standard Enthalpy Changes of ReactionsStandard Enthalpy Changes of Reactions
Standard Enthalpy Changes of Reactions
 
Inorganic Chemistry: Thermochemistry
Inorganic Chemistry: ThermochemistryInorganic Chemistry: Thermochemistry
Inorganic Chemistry: Thermochemistry
 
C H5
C H5C H5
C H5
 
AP Chemistry Chapter 19 Outline
AP Chemistry Chapter 19 OutlineAP Chemistry Chapter 19 Outline
AP Chemistry Chapter 19 Outline
 
Thermodynamics notes
Thermodynamics notesThermodynamics notes
Thermodynamics notes
 
Chapter 5 lecture- Thermochemistry
Chapter 5 lecture- ThermochemistryChapter 5 lecture- Thermochemistry
Chapter 5 lecture- Thermochemistry
 
Chem 2 - Gibbs Free Energy and Spontaneous Reactions VI
Chem 2 - Gibbs Free Energy and Spontaneous Reactions VIChem 2 - Gibbs Free Energy and Spontaneous Reactions VI
Chem 2 - Gibbs Free Energy and Spontaneous Reactions VI
 
Thermochemistry
ThermochemistryThermochemistry
Thermochemistry
 
Enthalpy
EnthalpyEnthalpy
Enthalpy
 

Destaque (20)

Ch09 outline
Ch09 outlineCh09 outline
Ch09 outline
 
Ch07 outline
Ch07 outlineCh07 outline
Ch07 outline
 
Ch04 outline
Ch04 outlineCh04 outline
Ch04 outline
 
Ch06 outline
Ch06 outlineCh06 outline
Ch06 outline
 
Ch08 outline
Ch08 outlineCh08 outline
Ch08 outline
 
Ch02 outline
Ch02 outlineCh02 outline
Ch02 outline
 
Ch10 outline
Ch10 outlineCh10 outline
Ch10 outline
 
Ch03 outline
Ch03 outlineCh03 outline
Ch03 outline
 
Ap chem unit 11 presentation
Ap chem unit 11 presentationAp chem unit 11 presentation
Ap chem unit 11 presentation
 
Ch01 outline
Ch01 outlineCh01 outline
Ch01 outline
 
Ch13 outline
Ch13 outlineCh13 outline
Ch13 outline
 
Ch11 outline
Ch11 outlineCh11 outline
Ch11 outline
 
AP Chem Chapter 2 Outline
AP Chem Chapter 2 OutlineAP Chem Chapter 2 Outline
AP Chem Chapter 2 Outline
 
AP Chemistry Chapter 17 Outline
AP Chemistry Chapter 17 OutlineAP Chemistry Chapter 17 Outline
AP Chemistry Chapter 17 Outline
 
AP Chemistry Chapter 14 Outline
AP Chemistry Chapter 14 OutlineAP Chemistry Chapter 14 Outline
AP Chemistry Chapter 14 Outline
 
AP Chemistry Chapter 1 Outline
AP Chemistry Chapter 1 OutlineAP Chemistry Chapter 1 Outline
AP Chemistry Chapter 1 Outline
 
AP Chemistry Chapter 15 Outline
AP Chemistry Chapter 15 OutlineAP Chemistry Chapter 15 Outline
AP Chemistry Chapter 15 Outline
 
Thermochemistry Presentation
Thermochemistry PresentationThermochemistry Presentation
Thermochemistry Presentation
 
Chapter Four Lecture- Ecosystems
Chapter Four Lecture- EcosystemsChapter Four Lecture- Ecosystems
Chapter Four Lecture- Ecosystems
 
Chapter 13
Chapter 13Chapter 13
Chapter 13
 

Semelhante a Ch05 outline (20)

Ch. 5 thermochemistry
Ch. 5 thermochemistryCh. 5 thermochemistry
Ch. 5 thermochemistry
 
Thermochem
ThermochemThermochem
Thermochem
 
Chapter5.pdf
Chapter5.pdfChapter5.pdf
Chapter5.pdf
 
Chapter 10
Chapter 10Chapter 10
Chapter 10
 
Ch 8 - Energy, Enthalpy, and Thermochemistry.pdf
Ch 8 - Energy, Enthalpy, and Thermochemistry.pdfCh 8 - Energy, Enthalpy, and Thermochemistry.pdf
Ch 8 - Energy, Enthalpy, and Thermochemistry.pdf
 
005 lecture f
005 lecture f005 lecture f
005 lecture f
 
06 thermochemistry
06 thermochemistry06 thermochemistry
06 thermochemistry
 
Chapter 5 gen chem
Chapter 5 gen chemChapter 5 gen chem
Chapter 5 gen chem
 
AP_Chem_Thermodynamics.pptx
AP_Chem_Thermodynamics.pptxAP_Chem_Thermodynamics.pptx
AP_Chem_Thermodynamics.pptx
 
CHE 101 Thermochem.ppt
CHE 101 Thermochem.pptCHE 101 Thermochem.ppt
CHE 101 Thermochem.ppt
 
Energy ch 16
Energy ch 16Energy ch 16
Energy ch 16
 
Chapter 5 final(1)
Chapter 5 final(1)Chapter 5 final(1)
Chapter 5 final(1)
 
Chemical reactions
Chemical reactionsChemical reactions
Chemical reactions
 
entropy-and-gibbs-free-energy.ppt
entropy-and-gibbs-free-energy.pptentropy-and-gibbs-free-energy.ppt
entropy-and-gibbs-free-energy.ppt
 
Test Document
Test DocumentTest Document
Test Document
 
Adv chem chapt 6
Adv chem chapt 6 Adv chem chapt 6
Adv chem chapt 6
 
THERMODYANAMICS.pptx
THERMODYANAMICS.pptxTHERMODYANAMICS.pptx
THERMODYANAMICS.pptx
 
Lect w10 abbrev_ thermochemistry_alg
Lect w10 abbrev_ thermochemistry_algLect w10 abbrev_ thermochemistry_alg
Lect w10 abbrev_ thermochemistry_alg
 
chemical equilibrium and thermodynamics
chemical equilibrium and thermodynamicschemical equilibrium and thermodynamics
chemical equilibrium and thermodynamics
 
Chapter5
Chapter5Chapter5
Chapter5
 

Último

Why Teams call analytics are critical to your entire business
Why Teams call analytics are critical to your entire businessWhy Teams call analytics are critical to your entire business
Why Teams call analytics are critical to your entire business
panagenda
 

Último (20)

Strategize a Smooth Tenant-to-tenant Migration and Copilot Takeoff
Strategize a Smooth Tenant-to-tenant Migration and Copilot TakeoffStrategize a Smooth Tenant-to-tenant Migration and Copilot Takeoff
Strategize a Smooth Tenant-to-tenant Migration and Copilot Takeoff
 
Mcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot Model
Mcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot ModelMcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot Model
Mcleodganj Call Girls 🥰 8617370543 Service Offer VIP Hot Model
 
presentation ICT roal in 21st century education
presentation ICT roal in 21st century educationpresentation ICT roal in 21st century education
presentation ICT roal in 21st century education
 
Rising Above_ Dubai Floods and the Fortitude of Dubai International Airport.pdf
Rising Above_ Dubai Floods and the Fortitude of Dubai International Airport.pdfRising Above_ Dubai Floods and the Fortitude of Dubai International Airport.pdf
Rising Above_ Dubai Floods and the Fortitude of Dubai International Airport.pdf
 
Apidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, Adobe
Apidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, AdobeApidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, Adobe
Apidays New York 2024 - Scaling API-first by Ian Reasor and Radu Cotescu, Adobe
 
ProductAnonymous-April2024-WinProductDiscovery-MelissaKlemke
ProductAnonymous-April2024-WinProductDiscovery-MelissaKlemkeProductAnonymous-April2024-WinProductDiscovery-MelissaKlemke
ProductAnonymous-April2024-WinProductDiscovery-MelissaKlemke
 
Introduction to Multilingual Retrieval Augmented Generation (RAG)
Introduction to Multilingual Retrieval Augmented Generation (RAG)Introduction to Multilingual Retrieval Augmented Generation (RAG)
Introduction to Multilingual Retrieval Augmented Generation (RAG)
 
Why Teams call analytics are critical to your entire business
Why Teams call analytics are critical to your entire businessWhy Teams call analytics are critical to your entire business
Why Teams call analytics are critical to your entire business
 
Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...
Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...
Biography Of Angeliki Cooney | Senior Vice President Life Sciences | Albany, ...
 
Boost Fertility New Invention Ups Success Rates.pdf
Boost Fertility New Invention Ups Success Rates.pdfBoost Fertility New Invention Ups Success Rates.pdf
Boost Fertility New Invention Ups Success Rates.pdf
 
Strategies for Landing an Oracle DBA Job as a Fresher
Strategies for Landing an Oracle DBA Job as a FresherStrategies for Landing an Oracle DBA Job as a Fresher
Strategies for Landing an Oracle DBA Job as a Fresher
 
Understanding the FAA Part 107 License ..
Understanding the FAA Part 107 License ..Understanding the FAA Part 107 License ..
Understanding the FAA Part 107 License ..
 
Exploring Multimodal Embeddings with Milvus
Exploring Multimodal Embeddings with MilvusExploring Multimodal Embeddings with Milvus
Exploring Multimodal Embeddings with Milvus
 
Platformless Horizons for Digital Adaptability
Platformless Horizons for Digital AdaptabilityPlatformless Horizons for Digital Adaptability
Platformless Horizons for Digital Adaptability
 
Repurposing LNG terminals for Hydrogen Ammonia: Feasibility and Cost Saving
Repurposing LNG terminals for Hydrogen Ammonia: Feasibility and Cost SavingRepurposing LNG terminals for Hydrogen Ammonia: Feasibility and Cost Saving
Repurposing LNG terminals for Hydrogen Ammonia: Feasibility and Cost Saving
 
Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...
Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...
Apidays New York 2024 - Passkeys: Developing APIs to enable passwordless auth...
 
Apidays New York 2024 - The Good, the Bad and the Governed by David O'Neill, ...
Apidays New York 2024 - The Good, the Bad and the Governed by David O'Neill, ...Apidays New York 2024 - The Good, the Bad and the Governed by David O'Neill, ...
Apidays New York 2024 - The Good, the Bad and the Governed by David O'Neill, ...
 
CNIC Information System with Pakdata Cf In Pakistan
CNIC Information System with Pakdata Cf In PakistanCNIC Information System with Pakdata Cf In Pakistan
CNIC Information System with Pakdata Cf In Pakistan
 
Apidays New York 2024 - APIs in 2030: The Risk of Technological Sleepwalk by ...
Apidays New York 2024 - APIs in 2030: The Risk of Technological Sleepwalk by ...Apidays New York 2024 - APIs in 2030: The Risk of Technological Sleepwalk by ...
Apidays New York 2024 - APIs in 2030: The Risk of Technological Sleepwalk by ...
 
TrustArc Webinar - Unlock the Power of AI-Driven Data Discovery
TrustArc Webinar - Unlock the Power of AI-Driven Data DiscoveryTrustArc Webinar - Unlock the Power of AI-Driven Data Discovery
TrustArc Webinar - Unlock the Power of AI-Driven Data Discovery
 

Ch05 outline

  • 1. Chapter 5 Thermochemistry John D. Bookstaver St. Charles Community College Cottleville, MO Chemistry, The Central Science , 11th edition Theodore L. Brown; H. Eugene LeMay, Jr.; and Bruce E. Bursten
  • 2.
  • 3.
  • 4.
  • 5.
  • 6.
  • 7.
  • 8.
  • 9.
  • 10.
  • 11.
  • 12.
  • 13.
  • 14.
  • 15.
  • 16.
  • 17.  E , q , w , and Their Signs
  • 18.
  • 19.
  • 20.
  • 21.
  • 22.
  • 23.
  • 24.
  • 25.
  • 26.
  • 27.
  • 28.
  • 29.
  • 30.
  • 31.
  • 32.
  • 33.
  • 34.
  • 35.
  • 36.
  • 37.
  • 38.
  • 39.
  • 40.
  • 41.
  • 42.
  • 43.
  • 44.
  • 45.
  • 46.
  • 47.
  • 48.
  • 49.
  • 50.
  • 51.
  • 52.
  • 53.
  • 54.