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VESTAMID® HTplus
Taking the Heat
Evonik Industries AG is the creative
industrial group from Germany focused
on chemicals, energy and real estate.
Evonik is a global leader in specialty
chemicals.
Together with the Acrylic Monomers
and Acrylic Polymers Business Lines,
the High Performance Polymers Busi-
ness Line is part of the Performance
Polymers Business Unit, and specializes
in customized products and product
systems. We have been producing high-
performance plastics for over 40 years.
The extension, with polyphthalamide
(PPA), into the field of HT polymers
represents a logical expansion of our
product portfolio.




                               VESTAMID® HTplus:
                                 tailored to your needs
                                          Automotive                                      It is therefore the material of choice for
                                          For many years, we have maintained a            the electronics industry, where the trend
                                          strong presence in the automotive market        toward miniaturization is placing higher
                                          in all areas of expertise such as assembly,     demands on the materials used.
                                          coating, polymer engineering, and rein-
                                          forcement. Increased temperatures and           Our products are tailorable to meet the
                                          weight reduction are the factors driving        demands of your application.
                                          design decisions in the industry. Because       Come and talk to us!
                                          of its excellent high-temperature and
                                          chemical resistance, PPA is moving into
                                          focus for all kinds of applications, injected
                                          as well as extruded.

                                          Industrial Technology/Appliances
                                          VESTAMID® HTplus has unique charac-
                                          teristics, such as its resistance toward
                                          aggressive chemicals. It is suitable for
                                          applications involving direct contact with
                                          drinking water and food.

                                          Electrics and Electronics
                                          VESTAMID® HTplus is not only high-
                                          temperature resistant but also has high
                                          dimensional stability and wear resistance.
Injection molding                                              K&K (Plastic & Rubber)




                  Extrusion                                                             Fibers




 Optimum support
   through many years of expertise
       VESTAMID® HTplus: suitable for               Our customers are supported by our
       all processes                                technical experts, from the initial concept
       VESTAMID® HTplus belongs to the family       until the finished product is ready for mass
       of polyphthalamide polymers. We at           production. Our state-of-the-art facilities
       Evonik have combined high temperature        are at your disposal; these include our
       durability, excellent chemical resistance,   cutting-edge technical centers with injec-
       and outstanding mechanical properties        tion molding and extrusion machines as
       with the flexibility of multiple process     well as our analytical labs.
       technologies:                                Furthermore, we offer CAE support at all
                                                    stages of your product development.
       •   Injection molding
       •   Extrusion
                                                    Please contact us to discuss your project
       •   K&K (plastic-rubber composites)
                                                    or for more detailed information.
       •   Fibers


                                                      Your global experts:

                                                      Automotive
                                                      Frank Lorenz
                                                      frank.lorenz@evonik.com

                                                      Industrial technology, electronics
                                                      Volker Strohm
                                                      volker.strohm@evonik.com
Properties of VESTAMID® HTplus compounds

                                                                                  VESTAMID® HTplus
Properties                                         Test method          Unit      M1000     M1031          M1032       M1033
                                                                                  base grade   reinforced resins; not flame-retardant
Glass fiber content                                                     %         0            15          20          30
Tensile modulus                         +23 °C     ISO 527              MPa       3500         7100        8700        11200
Tensile strength                        +23 °C     ISO 527              MPa       90           110         140         180
Strain at break                         +23 °C     ISO 527              %         3            2           1.8         2
Flexural modulus                        +23 °C     ISO 178              MPa                                7100        10000
Stress at break                         +23 °C     ISO 178              MPa                                185         260
Charpy impact strength                  +23 °C     ISO 179/1eU          kJ/m 2    50 C         19 C        27 C        45 C
                                        -40 °C     ISO 179/1eU          kJ/m 2    40 C         18 C        23 C        40 C
Charpy notched impact strength          +23 °C     ISO 179/1eA          kJ/m 2    7C           4C          5C          7C
                                        -40 °C     ISO 179/1eA          kJ/m 2    4C           4C          4C          7C
Density                                  23 °C     ISO 1183             g/cm3     1.20         1.31        1.34        1.44
Water absorption (air)             24 h/23 °C      ISO 62               %         0.31                     0.26
Temperature of deflection under load
 Method A                          1.8 MPa         ISO 75-1             °C        126          280                     288
 Method B                            0.45 MPa      ISO 75-2             °C        223          303                     306
 Method C                             8.0 MPa      ISO 75-3             °C                     129                     196
Vicat softening temperature
 Method A                                 10 N     ISO 306              °C
 Method B                                 50 N     ISO 306              °C
Flammability acc. UL94                 0.4 mm      IEC 60695
                                       0.8 mm      IEC 60695                      V2
Melting range                      2nd heating     ISO 11357            °C        300 -315     300 -315    300 -315    300 -315
Electrical strength                                IEC 60243-1          kV/mm                              29.3
Volume resistivity                                 IEC 60093            Ohm*cm                             6.22 1015
Surface resistance                                 IEC 60093            Ohm                                1.5 1014
Shrinkage                      in flow direction                        %         1.49         0.69        0.93        0.22
                         in transverse direction                        %         0.98         0.84        0.70        0.99
Melt temperature                                                        °C        320 -330     330 -340    330 -340    330 -340
Mold temperature                                                        °C        120 -160     120 -180    120 -180    120 -180




Bonding behavior of VESTAMID® HTplus compounds with different rubbers

Rubber                   VESTAMID® HTplus R1033                VESTAMID® HTplus R1035
ACM                      +                                     +
FKM                      +++                                   *)
NBR                      *)                                    *)
X-NBR                    -                                     -
H-NBR                    +++                                   +++
EPDM                     *)                                    *)
VMQ                      *)                                    *)
AEM                      *)                                    *)

*) under evaluation


The bonding results are evaluated on our rubber recipes described in the brochure
"High Performance Polymers in Plastic-Rubber Composites". We recommend to test
your own recipes in our technical labs.
M1035       M1036      M1900        M1933       R1033       R1035
                       HF flame-retardant       rubber bondable
50          60         0            30          30          50
19000       23000      4200         11300       10700       16800
250         280        75           105         171         211         VESTAMID® HTplus M —Injection
2           1.5        1.8          1.7         1.8         1.6         Molding
16000       21000                                                       VESTAMID® HTplus represents a signif-
                                                                        icant advance in high-temperature poly-
360         410
                                                                        amide polymers. The combination of high
65 C        60 C       22 C         28 C        38 C        57 C        strength, heat stability, and chemical sta-
50 C        40 C       24 C         26 C        34 C        37 C        bility provides a material to solve your
12 C        17 C       3C           4C          7C          9C          most challenging problems for engineered
14 C        19 C       3C           3C          6C          8C          products. Standard unfilled grades and
1.64        1.77       1.23         1.44                                basic injection molding grades with glass
                                                                        fiber content of up to 60% represent the
0.12
                                                                        starting point for development of special-
                                                                        ty grades.
295         293        138          267
305         309        256          301                                 VESTAMID® HTplus R—direct bonding
225         236                                                         to Rubbers
                                                                        Our latest development exploits the high
                                                305         310         heat deflection temperature and dimen-
                                                275         282         sional stability of VESTAMID® HTplus and
                       V0           V0                                  adds the special functionality of allowing
                                                                        direct bonding to a variety of elastomers.
                                                                        Cost reductions are achieved through
300 -315    300 -315   300 -315     300 -315
                                                                        reduction of the number of processes,
29.1                                                                    elimination of adhesives, and decrease in
8.97 1015                                                               cycle times.
1.6 1014
                                                                        Our standard grades are available as
0.17
                                                                        black and natural colored granules
0.61
                                                                        packed in bags. Should you have speci-
330 -340    330 -340   320 -330     330 -340    330 -340    330 -340    fic requirements, please do not hesitate
120 -180    120 -180   120 -160     120 -180    120 -180    120 -180    to contact us.

                              C = Complete break, incl. hinge break H
Integrated expertise: no region without direct contacts
Northern Germany, Benelux               Italy                       Brazil
Karsten Goldstein                       Roberto Sacchi              Germano Coelho
phone +49 2365204790                    phone +39 0371219363        phone +55 1131464150
mobile +49 1718130033                   mobile +39 3356840731       mobile +55 1181427897
karsten.goldstein@evonik.com            roberto.sacchi@evonik.com   germano.coelho@evonik.com

Southern Germany, Iberia                Poland                      Australia
Ludger Malmedy                          Andrzej Wolak               Peter Gibson
phone +49 8251870157                    phone +48 223181007         phone +61 298914011
mobile +49 1718130072                   mobile +48 603202152        mobile +61 418270474
ludger.malmedy@evonik.com               andrzej.wolak@evonik.com    peter.gibson@evonik.com

Central Germany                         Turkey                      China
Achim Hiltrop                           Mehmet Ali Ersudas          Kenny Chee
phone +49 2017988871                    phone +90 2163959961255     phone +86 2161191359
mobile +49 1718130045                   mobile +90 5322311525       mobile +86 13816673822
achim.hiltrop@evonik.com                ali.ersudas@evonik.com      kenny.chee@evonik.com

Austria, Switzerland                    UK, Eire                    India
Beat Bertschinger                       Hameem Yasin                Ashok Bandella
phone +41 19380665                      phone +44 1212361001        phone +91 2256307070
mobile +41 794453703                    mobile +44 7890536447       mobile +91 9820211866
beat.bertschinger@evonik.com            hameem.yasin@evonik.com     ashok.bandella@evonik.com

Czech. Republic, Slovakia               Americas                    Japan
Miroslav Sarman                         Frank Tyrybon               Mitsunori Naganuma
phone +420 272111817                    phone +1 2484973340         phone +81 353246332
mobile +420 602336106                   mobile +1 2484973340        mobile +81 9061229653
miroslav.sarman@evonik.com              frank.tyrybon@evonik.com    m.naganuma@daicel-evonik.com

France                                  Mexico                      Korea
Géraud Apchin                           Miguel Angel Delgado        Hongil Kim
phone +33 139757985                     phone +52 5554831023        phone +82 325102442
mobile +33 607244714                    mobile +52 5529808891       mobile +82 112520181
geraud.apchin@evonik.com                miguel.delgado@evonik.com   hongil.kim@evonik.com

                                                                    Singapore
                                                                    ChiangHow Heng
                                                                    phone +65 68906891
                                                                    mobile +65 83220420
                                                                    chianghow.heng@evonik.com




            Evonik Degussa GmbH
            High Performance Polymers
            45764 Marl
                                                                    This information and all further technical advice are based on
                                                                    Evonik Degussa’s present knowledge and experience.
                                                                    However, Evonik Degussa assumes no liability for providing
            Germany
            phone +49 2365 49-9878
                                                                    such information and advice including the extent to which
                                                                    such information and advice may relate to existing third party

            fax +49 2365 49-5992
                                                                    intellectual property rights, especially patent rights. In partic-
                                                                    ular, Evonik Degussa disclaims all conditions and warranties,
                                                                    whether expressed or implied, including the implied warran-
            www.evonik.com/hp                                       ties of fitness for a particular purpose or merchantability.
                                                                    Evonik Degussa shall not be responsible for consequential,
                                                                    indirect or incidental damages (including loss of profits) of
                                                                    any kind. Evonik Degussa reserves the right to make any
                                                                    changes according to technological progress or further devel-
                                                                    opments. It is the customer’s responsibility and obligation to
                                                                    carefully inspect and test any incoming goods. Performance of
                                                                    the product(s) described herein should be verified by testing
                                                                                                                                         01/lau/1000/e




                                                                    and carried out only by qualified experts. It is the sole respon-
                                                                    sibility of the customer to carry out and arrange for any such
                                                                    testing. Reference to trade names used by other companies is
                                                                    neither a recommendation, nor an endorsement of any product
                                                                    and does not imply that similar products could not be used.
                                                                    ®
                                                                      = registered trademark

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Folder Vestamid HT Plus

  • 2. Evonik Industries AG is the creative industrial group from Germany focused on chemicals, energy and real estate. Evonik is a global leader in specialty chemicals. Together with the Acrylic Monomers and Acrylic Polymers Business Lines, the High Performance Polymers Busi- ness Line is part of the Performance Polymers Business Unit, and specializes in customized products and product systems. We have been producing high- performance plastics for over 40 years. The extension, with polyphthalamide (PPA), into the field of HT polymers represents a logical expansion of our product portfolio. VESTAMID® HTplus: tailored to your needs Automotive It is therefore the material of choice for For many years, we have maintained a the electronics industry, where the trend strong presence in the automotive market toward miniaturization is placing higher in all areas of expertise such as assembly, demands on the materials used. coating, polymer engineering, and rein- forcement. Increased temperatures and Our products are tailorable to meet the weight reduction are the factors driving demands of your application. design decisions in the industry. Because Come and talk to us! of its excellent high-temperature and chemical resistance, PPA is moving into focus for all kinds of applications, injected as well as extruded. Industrial Technology/Appliances VESTAMID® HTplus has unique charac- teristics, such as its resistance toward aggressive chemicals. It is suitable for applications involving direct contact with drinking water and food. Electrics and Electronics VESTAMID® HTplus is not only high- temperature resistant but also has high dimensional stability and wear resistance.
  • 3. Injection molding K&K (Plastic & Rubber) Extrusion Fibers Optimum support through many years of expertise VESTAMID® HTplus: suitable for Our customers are supported by our all processes technical experts, from the initial concept VESTAMID® HTplus belongs to the family until the finished product is ready for mass of polyphthalamide polymers. We at production. Our state-of-the-art facilities Evonik have combined high temperature are at your disposal; these include our durability, excellent chemical resistance, cutting-edge technical centers with injec- and outstanding mechanical properties tion molding and extrusion machines as with the flexibility of multiple process well as our analytical labs. technologies: Furthermore, we offer CAE support at all stages of your product development. • Injection molding • Extrusion Please contact us to discuss your project • K&K (plastic-rubber composites) or for more detailed information. • Fibers Your global experts: Automotive Frank Lorenz frank.lorenz@evonik.com Industrial technology, electronics Volker Strohm volker.strohm@evonik.com
  • 4. Properties of VESTAMID® HTplus compounds VESTAMID® HTplus Properties Test method Unit M1000 M1031 M1032 M1033 base grade reinforced resins; not flame-retardant Glass fiber content % 0 15 20 30 Tensile modulus +23 °C ISO 527 MPa 3500 7100 8700 11200 Tensile strength +23 °C ISO 527 MPa 90 110 140 180 Strain at break +23 °C ISO 527 % 3 2 1.8 2 Flexural modulus +23 °C ISO 178 MPa 7100 10000 Stress at break +23 °C ISO 178 MPa 185 260 Charpy impact strength +23 °C ISO 179/1eU kJ/m 2 50 C 19 C 27 C 45 C -40 °C ISO 179/1eU kJ/m 2 40 C 18 C 23 C 40 C Charpy notched impact strength +23 °C ISO 179/1eA kJ/m 2 7C 4C 5C 7C -40 °C ISO 179/1eA kJ/m 2 4C 4C 4C 7C Density 23 °C ISO 1183 g/cm3 1.20 1.31 1.34 1.44 Water absorption (air) 24 h/23 °C ISO 62 % 0.31 0.26 Temperature of deflection under load Method A 1.8 MPa ISO 75-1 °C 126 280 288 Method B 0.45 MPa ISO 75-2 °C 223 303 306 Method C 8.0 MPa ISO 75-3 °C 129 196 Vicat softening temperature Method A 10 N ISO 306 °C Method B 50 N ISO 306 °C Flammability acc. UL94 0.4 mm IEC 60695 0.8 mm IEC 60695 V2 Melting range 2nd heating ISO 11357 °C 300 -315 300 -315 300 -315 300 -315 Electrical strength IEC 60243-1 kV/mm 29.3 Volume resistivity IEC 60093 Ohm*cm 6.22 1015 Surface resistance IEC 60093 Ohm 1.5 1014 Shrinkage in flow direction % 1.49 0.69 0.93 0.22 in transverse direction % 0.98 0.84 0.70 0.99 Melt temperature °C 320 -330 330 -340 330 -340 330 -340 Mold temperature °C 120 -160 120 -180 120 -180 120 -180 Bonding behavior of VESTAMID® HTplus compounds with different rubbers Rubber VESTAMID® HTplus R1033 VESTAMID® HTplus R1035 ACM + + FKM +++ *) NBR *) *) X-NBR - - H-NBR +++ +++ EPDM *) *) VMQ *) *) AEM *) *) *) under evaluation The bonding results are evaluated on our rubber recipes described in the brochure "High Performance Polymers in Plastic-Rubber Composites". We recommend to test your own recipes in our technical labs.
  • 5. M1035 M1036 M1900 M1933 R1033 R1035 HF flame-retardant rubber bondable 50 60 0 30 30 50 19000 23000 4200 11300 10700 16800 250 280 75 105 171 211 VESTAMID® HTplus M —Injection 2 1.5 1.8 1.7 1.8 1.6 Molding 16000 21000 VESTAMID® HTplus represents a signif- icant advance in high-temperature poly- 360 410 amide polymers. The combination of high 65 C 60 C 22 C 28 C 38 C 57 C strength, heat stability, and chemical sta- 50 C 40 C 24 C 26 C 34 C 37 C bility provides a material to solve your 12 C 17 C 3C 4C 7C 9C most challenging problems for engineered 14 C 19 C 3C 3C 6C 8C products. Standard unfilled grades and 1.64 1.77 1.23 1.44 basic injection molding grades with glass fiber content of up to 60% represent the 0.12 starting point for development of special- ty grades. 295 293 138 267 305 309 256 301 VESTAMID® HTplus R—direct bonding 225 236 to Rubbers Our latest development exploits the high 305 310 heat deflection temperature and dimen- 275 282 sional stability of VESTAMID® HTplus and V0 V0 adds the special functionality of allowing direct bonding to a variety of elastomers. Cost reductions are achieved through 300 -315 300 -315 300 -315 300 -315 reduction of the number of processes, 29.1 elimination of adhesives, and decrease in 8.97 1015 cycle times. 1.6 1014 Our standard grades are available as 0.17 black and natural colored granules 0.61 packed in bags. Should you have speci- 330 -340 330 -340 320 -330 330 -340 330 -340 330 -340 fic requirements, please do not hesitate 120 -180 120 -180 120 -160 120 -180 120 -180 120 -180 to contact us. C = Complete break, incl. hinge break H
  • 6. Integrated expertise: no region without direct contacts Northern Germany, Benelux Italy Brazil Karsten Goldstein Roberto Sacchi Germano Coelho phone +49 2365204790 phone +39 0371219363 phone +55 1131464150 mobile +49 1718130033 mobile +39 3356840731 mobile +55 1181427897 karsten.goldstein@evonik.com roberto.sacchi@evonik.com germano.coelho@evonik.com Southern Germany, Iberia Poland Australia Ludger Malmedy Andrzej Wolak Peter Gibson phone +49 8251870157 phone +48 223181007 phone +61 298914011 mobile +49 1718130072 mobile +48 603202152 mobile +61 418270474 ludger.malmedy@evonik.com andrzej.wolak@evonik.com peter.gibson@evonik.com Central Germany Turkey China Achim Hiltrop Mehmet Ali Ersudas Kenny Chee phone +49 2017988871 phone +90 2163959961255 phone +86 2161191359 mobile +49 1718130045 mobile +90 5322311525 mobile +86 13816673822 achim.hiltrop@evonik.com ali.ersudas@evonik.com kenny.chee@evonik.com Austria, Switzerland UK, Eire India Beat Bertschinger Hameem Yasin Ashok Bandella phone +41 19380665 phone +44 1212361001 phone +91 2256307070 mobile +41 794453703 mobile +44 7890536447 mobile +91 9820211866 beat.bertschinger@evonik.com hameem.yasin@evonik.com ashok.bandella@evonik.com Czech. Republic, Slovakia Americas Japan Miroslav Sarman Frank Tyrybon Mitsunori Naganuma phone +420 272111817 phone +1 2484973340 phone +81 353246332 mobile +420 602336106 mobile +1 2484973340 mobile +81 9061229653 miroslav.sarman@evonik.com frank.tyrybon@evonik.com m.naganuma@daicel-evonik.com France Mexico Korea Géraud Apchin Miguel Angel Delgado Hongil Kim phone +33 139757985 phone +52 5554831023 phone +82 325102442 mobile +33 607244714 mobile +52 5529808891 mobile +82 112520181 geraud.apchin@evonik.com miguel.delgado@evonik.com hongil.kim@evonik.com Singapore ChiangHow Heng phone +65 68906891 mobile +65 83220420 chianghow.heng@evonik.com Evonik Degussa GmbH High Performance Polymers 45764 Marl This information and all further technical advice are based on Evonik Degussa’s present knowledge and experience. However, Evonik Degussa assumes no liability for providing Germany phone +49 2365 49-9878 such information and advice including the extent to which such information and advice may relate to existing third party fax +49 2365 49-5992 intellectual property rights, especially patent rights. In partic- ular, Evonik Degussa disclaims all conditions and warranties, whether expressed or implied, including the implied warran- www.evonik.com/hp ties of fitness for a particular purpose or merchantability. Evonik Degussa shall not be responsible for consequential, indirect or incidental damages (including loss of profits) of any kind. Evonik Degussa reserves the right to make any changes according to technological progress or further devel- opments. It is the customer’s responsibility and obligation to carefully inspect and test any incoming goods. Performance of the product(s) described herein should be verified by testing 01/lau/1000/e and carried out only by qualified experts. It is the sole respon- sibility of the customer to carry out and arrange for any such testing. Reference to trade names used by other companies is neither a recommendation, nor an endorsement of any product and does not imply that similar products could not be used. ® = registered trademark